CN101379018B - 丙烯非均相催化部分气相氧化形成丙烯酸的方法 - Google Patents

丙烯非均相催化部分气相氧化形成丙烯酸的方法 Download PDF

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CN101379018B
CN101379018B CN2006800531606A CN200680053160A CN101379018B CN 101379018 B CN101379018 B CN 101379018B CN 2006800531606 A CN2006800531606 A CN 2006800531606A CN 200680053160 A CN200680053160 A CN 200680053160A CN 101379018 B CN101379018 B CN 101379018B
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propylene
reaction
propane
gas mixture
catalyst
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CN101379018A (zh
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M·迪特勒
A·迪芬巴赫尔
K·J·米勒-恩格尔
J·佩佐尔特
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BASF SE
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BASF SE
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8876—Arsenic, antimony or bismuth
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/888—Tungsten
    • B01J23/8885—Tungsten containing also molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • B01J35/55—Cylinders or rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
    • C07C45/35—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds in propene or isobutene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/42—Separation; Purification; Stabilisation; Use of additives
    • C07C51/43—Separation; Purification; Stabilisation; Use of additives by change of the physical state, e.g. crystallisation
    • C07C51/44—Separation; Purification; Stabilisation; Use of additives by change of the physical state, e.g. crystallisation by distillation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/08—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides with the hydroxy or O-metal group of organic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
CN2006800531606A 2005-12-22 2006-12-11 丙烯非均相催化部分气相氧化形成丙烯酸的方法 Active CN101379018B (zh)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US75236905P 2005-12-22 2005-12-22
DE102005062026.4 2005-12-22
US60/752,369 2005-12-22
DE102005062026A DE102005062026A1 (de) 2005-12-22 2005-12-22 Verfahren der heterogen katalysierten partiellen Gasphasenoxidation von Propylen zu Acrylsäure
PCT/EP2006/069527 WO2007074045A1 (de) 2005-12-22 2006-12-11 Verfahren der heterogen katalysierten partiellen gasphasenoxidation von propylen zu acrylsäure

Publications (2)

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CN101379018A CN101379018A (zh) 2009-03-04
CN101379018B true CN101379018B (zh) 2012-07-04

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US (1) US7807853B2 (enExample)
EP (1) EP1963248B1 (enExample)
JP (2) JP2009520748A (enExample)
KR (2) KR20140058697A (enExample)
CN (1) CN101379018B (enExample)
DE (1) DE102005062026A1 (enExample)
MY (1) MY145843A (enExample)
RU (1) RU2464256C2 (enExample)
TW (1) TWI377193B (enExample)
WO (1) WO2007074045A1 (enExample)

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DE102007055086A1 (de) 2007-11-16 2009-05-20 Basf Se Verfahren zur Herstellung von Acrylsäure
DE102007004960A1 (de) 2007-01-26 2008-07-31 Basf Se Verfahren zur Herstellung von Acrylsäure
DE102007029053A1 (de) * 2007-06-21 2008-01-03 Basf Ag Verfahren der heterogen katalysierten partiellen Direktoxidation von n-Propan zu Acrylsäure
US9149799B2 (en) * 2010-04-28 2015-10-06 Basf Se Eggshell catalyst consisting of a hollow cylindrical support body and a catalytically active oxide material applied to the outer surface of the support body
DE102010042216A1 (de) 2010-10-08 2011-06-09 Basf Se Verfahren zur Hemmung der unerwünschten radikalischen Polymerisation von in einer flüssigen Phase P befindlicher Acrylsäure
EP2658643B1 (en) 2010-12-29 2020-02-12 Rohm and Haas Company Process for the propane oxidation
DE102011076931A1 (de) 2011-06-03 2012-12-06 Basf Se Wässrige Lösung, enthaltend Acrylsäure und deren konjugierte Base
CN103889942B (zh) 2011-10-18 2016-05-11 罗门哈斯公司 从丙烷和丙烯制备丙烯酸的方法
EP2983818A1 (en) 2013-04-08 2016-02-17 Saudi Basic Industries Corporation Catalyst for conversion of propylene to product comprising a carboxylic acid moiety
DE102013006251A1 (de) * 2013-04-11 2014-10-16 Clariant International Ltd. Verfahren zur Herstellung eines Katalysators zur partiellen Oxidation von Olefinen
CN105622822B (zh) * 2016-03-02 2018-11-27 中国石油集团东北炼化工程有限公司吉林设计院 一种用于乙丙橡胶生产的催化剂的使用工艺
WO2019116483A1 (ja) * 2017-12-14 2019-06-20 三菱重工エンジニアリング株式会社 アクリル酸の製造プラント及びアクリル酸の製造方法
DE102018200841A1 (de) 2018-01-19 2019-07-25 Basf Se Mo, Bi, Fe und Cu enthaltende Multimetalloxidmassen
US11447439B2 (en) 2018-07-26 2022-09-20 Basf Se Method for inhibiting unwanted radical polymerisation of acrylic acid present in a liquid phase P
EP3770145A1 (en) 2019-07-24 2021-01-27 Basf Se A process for the continuous production of either acrolein or acrylic acid as the target product from propene
WO2021191042A1 (de) 2020-03-26 2021-09-30 Basf Se Verfahren zur hemmung der unerwünschten radikalischen polymerisation von in einer flüssigen phase p befindlicher acrylsäure
WO2025172146A1 (de) 2024-02-15 2025-08-21 Basf Se Verfahren zur herstellung von acrylsäure
WO2025219137A1 (en) 2024-04-17 2025-10-23 Basf Se Process for utilizing acrylic acid production waste streams by gasification and fermentation
WO2025219135A1 (en) 2024-04-17 2025-10-23 Basf Se Process for utilizing high calorific acrylic acid production waste streams
WO2025219136A1 (en) 2024-04-17 2025-10-23 Basf Se Process for utilizing acrylic acid production waste streams

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CN1701054A (zh) * 2002-09-27 2005-11-23 巴斯福股份公司 丙烯的至少部分氧化和/或氨氧化产物的制备方法

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Also Published As

Publication number Publication date
RU2464256C2 (ru) 2012-10-20
TW200732301A (en) 2007-09-01
EP1963248B1 (de) 2016-06-08
US7807853B2 (en) 2010-10-05
JP2009520748A (ja) 2009-05-28
TWI377193B (en) 2012-11-21
WO2007074045A1 (de) 2007-07-05
DE102005062026A1 (de) 2007-06-28
JP5940045B2 (ja) 2016-06-29
RU2008129548A (ru) 2010-01-27
US20070149808A1 (en) 2007-06-28
KR20140058697A (ko) 2014-05-14
EP1963248A1 (de) 2008-09-03
MY145843A (en) 2012-04-30
KR101507616B1 (ko) 2015-03-31
KR20080081328A (ko) 2008-09-09
CN101379018A (zh) 2009-03-04
JP2014148500A (ja) 2014-08-21

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