KR20140058697A - 프로필렌의 불균질 촉매화 부분 기상 산화에 의한 아크릴산의 형성 방법 - Google Patents

프로필렌의 불균질 촉매화 부분 기상 산화에 의한 아크릴산의 형성 방법 Download PDF

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Publication number
KR20140058697A
KR20140058697A KR1020147011903A KR20147011903A KR20140058697A KR 20140058697 A KR20140058697 A KR 20140058697A KR 1020147011903 A KR1020147011903 A KR 1020147011903A KR 20147011903 A KR20147011903 A KR 20147011903A KR 20140058697 A KR20140058697 A KR 20140058697A
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South Korea
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reaction
gas mixture
catalyst
propylene
mol
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Ceased
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Korean (ko)
Inventor
마르틴 디터레
아르민 디펜바허
클라우스 요아힘 뮐러-엥겔
요헨 펫촐트
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바스프 에스이
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8876—Arsenic, antimony or bismuth
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/888—Tungsten
    • B01J23/8885—Tungsten containing also molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • B01J35/55—Cylinders or rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
    • C07C45/35—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds in propene or isobutene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/42—Separation; Purification; Stabilisation; Use of additives
    • C07C51/43—Separation; Purification; Stabilisation; Use of additives by change of the physical state, e.g. crystallisation
    • C07C51/44—Separation; Purification; Stabilisation; Use of additives by change of the physical state, e.g. crystallisation by distillation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/08—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides with the hydroxy or O-metal group of organic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
KR1020147011903A 2005-12-22 2006-12-11 프로필렌의 불균질 촉매화 부분 기상 산화에 의한 아크릴산의 형성 방법 Ceased KR20140058697A (ko)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US75236905P 2005-12-22 2005-12-22
DE102005062026A DE102005062026A1 (de) 2005-12-22 2005-12-22 Verfahren der heterogen katalysierten partiellen Gasphasenoxidation von Propylen zu Acrylsäure
US60/752,369 2005-12-22
DE102005062026.4 2005-12-22
PCT/EP2006/069527 WO2007074045A1 (de) 2005-12-22 2006-12-11 Verfahren der heterogen katalysierten partiellen gasphasenoxidation von propylen zu acrylsäure

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
KR1020087017752A Division KR101507616B1 (ko) 2005-12-22 2006-12-11 프로필렌의 불균질 촉매화 부분 기상 산화에 의한아크릴산의 형성 방법

Publications (1)

Publication Number Publication Date
KR20140058697A true KR20140058697A (ko) 2014-05-14

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KR1020147011903A Ceased KR20140058697A (ko) 2005-12-22 2006-12-11 프로필렌의 불균질 촉매화 부분 기상 산화에 의한 아크릴산의 형성 방법
KR1020087017752A Expired - Fee Related KR101507616B1 (ko) 2005-12-22 2006-12-11 프로필렌의 불균질 촉매화 부분 기상 산화에 의한아크릴산의 형성 방법

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Country Status (10)

Country Link
US (1) US7807853B2 (enExample)
EP (1) EP1963248B1 (enExample)
JP (2) JP2009520748A (enExample)
KR (2) KR20140058697A (enExample)
CN (1) CN101379018B (enExample)
DE (1) DE102005062026A1 (enExample)
MY (1) MY145843A (enExample)
RU (1) RU2464256C2 (enExample)
TW (1) TWI377193B (enExample)
WO (1) WO2007074045A1 (enExample)

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DE102007055086A1 (de) 2007-11-16 2009-05-20 Basf Se Verfahren zur Herstellung von Acrylsäure
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DE102007029053A1 (de) * 2007-06-21 2008-01-03 Basf Ag Verfahren der heterogen katalysierten partiellen Direktoxidation von n-Propan zu Acrylsäure
US9149799B2 (en) * 2010-04-28 2015-10-06 Basf Se Eggshell catalyst consisting of a hollow cylindrical support body and a catalytically active oxide material applied to the outer surface of the support body
DE102010042216A1 (de) 2010-10-08 2011-06-09 Basf Se Verfahren zur Hemmung der unerwünschten radikalischen Polymerisation von in einer flüssigen Phase P befindlicher Acrylsäure
JP5852134B2 (ja) 2010-12-29 2016-02-03 ローム アンド ハース カンパニーＲｏｈｍ Ａｎｄ Ｈａａｓ Ｃｏｍｐａｎｙ プロパン酸化のための反応器及び方法
DE102011076931A1 (de) 2011-06-03 2012-12-06 Basf Se Wässrige Lösung, enthaltend Acrylsäure und deren konjugierte Base
SG11201401606WA (en) 2011-10-18 2014-05-29 Rohm & Haas Method for preparing acrylic acid from propane and propylene
EP2983818A1 (en) 2013-04-08 2016-02-17 Saudi Basic Industries Corporation Catalyst for conversion of propylene to product comprising a carboxylic acid moiety
DE102013006251A1 (de) * 2013-04-11 2014-10-16 Clariant International Ltd. Verfahren zur Herstellung eines Katalysators zur partiellen Oxidation von Olefinen
CN105622822B (zh) * 2016-03-02 2018-11-27 中国石油集团东北炼化工程有限公司吉林设计院 一种用于乙丙橡胶生产的催化剂的使用工艺
WO2019116483A1 (ja) * 2017-12-14 2019-06-20 三菱重工エンジニアリング株式会社 アクリル酸の製造プラント及びアクリル酸の製造方法
DE102018200841A1 (de) 2018-01-19 2019-07-25 Basf Se Mo, Bi, Fe und Cu enthaltende Multimetalloxidmassen
WO2020020697A1 (de) 2018-07-26 2020-01-30 Basf Se Verfahren zur hemmung der unerwünschten radikalischen polymerisation von in einer flüssigen phase p befindlicher acrylsäure
EP3770145A1 (en) 2019-07-24 2021-01-27 Basf Se A process for the continuous production of either acrolein or acrylic acid as the target product from propene
JP7651589B2 (ja) 2020-03-26 2025-03-26 ベーアーエスエフ・エスエー 液相ｐに存在するアクリル酸の望ましくないフリーラジカル重合を抑制する方法
WO2025172146A1 (de) 2024-02-15 2025-08-21 Basf Se Verfahren zur herstellung von acrylsäure
WO2025219137A1 (en) 2024-04-17 2025-10-23 Basf Se Process for utilizing acrylic acid production waste streams by gasification and fermentation
WO2025219136A1 (en) 2024-04-17 2025-10-23 Basf Se Process for utilizing acrylic acid production waste streams
WO2025219135A1 (en) 2024-04-17 2025-10-23 Basf Se Process for utilizing high calorific acrylic acid production waste streams

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DE102005009885A1 (de) 2005-03-01 2006-09-14 Basf Ag Verfahren zur Herstellung von Acrolein oder Acrylsäure oder deren Gemisch durch heterogen katalysierte partielle Gasphasenoxidation von Propylen
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Also Published As

Publication number Publication date
EP1963248B1 (de) 2016-06-08
TW200732301A (en) 2007-09-01
US20070149808A1 (en) 2007-06-28
CN101379018B (zh) 2012-07-04
TWI377193B (en) 2012-11-21
KR101507616B1 (ko) 2015-03-31
JP2009520748A (ja) 2009-05-28
RU2008129548A (ru) 2010-01-27
DE102005062026A1 (de) 2007-06-28
KR20080081328A (ko) 2008-09-09
WO2007074045A1 (de) 2007-07-05
US7807853B2 (en) 2010-10-05
JP2014148500A (ja) 2014-08-21
RU2464256C2 (ru) 2012-10-20
CN101379018A (zh) 2009-03-04
MY145843A (en) 2012-04-30
EP1963248A1 (de) 2008-09-03
JP5940045B2 (ja) 2016-06-29

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