RU2464256C2 - Способ гетерогенно-катализируемого парциального газофазного окисления пропилена до акриловой кислоты - Google Patents

Способ гетерогенно-катализируемого парциального газофазного окисления пропилена до акриловой кислоты Download PDF

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RU2464256C2
RU2464256C2 RU2008129548/04A RU2008129548A RU2464256C2 RU 2464256 C2 RU2464256 C2 RU 2464256C2 RU 2008129548/04 A RU2008129548/04 A RU 2008129548/04A RU 2008129548 A RU2008129548 A RU 2008129548A RU 2464256 C2 RU2464256 C2 RU 2464256C2
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reaction
mol
propylene
gas mixture
propane
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RU2008129548/04A
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Russian (ru)
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RU2008129548A (ru
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Мартин ДИТЕРЛЕ (DE)
Мартин ДИТЕРЛЕ
Армин ДИФФЕНБАХЕР (DE)
Армин ДИФФЕНБАХЕР
Клаус Йоахим МЮЛЛЕР-ЭНГЕЛЬ (DE)
Клаус Йоахим МЮЛЛЕР-ЭНГЕЛЬ
Йохен ПЕТЦОЛЬДТ (DE)
Йохен ПЕТЦОЛЬДТ
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Басф Се
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85Chromium, molybdenum or tungsten
    • B01J23/88Molybdenum
    • B01J23/887Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8876Arsenic, antimony or bismuth
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002Mixed oxides other than spinels, e.g. perovskite
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85Chromium, molybdenum or tungsten
    • B01J23/888Tungsten
    • B01J23/8885Tungsten containing also molybdenum
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/50Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • B01J35/55Cylinders or rings
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C07C45/34Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
    • C07C45/35Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds in propene or isobutene
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • C07C51/252Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/42Separation; Purification; Stabilisation; Use of additives
    • C07C51/43Separation; Purification; Stabilisation; Use of additives by change of the physical state, e.g. crystallisation
    • C07C51/44Separation; Purification; Stabilisation; Use of additives by change of the physical state, e.g. crystallisation by distillation
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00Preparation of carboxylic acid esters
    • C07C67/08Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides with the hydroxy or O-metal group of organic compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00Constitutive chemical elements of heterogeneous catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
RU2008129548/04A 2005-12-22 2006-12-11 Способ гетерогенно-катализируемого парциального газофазного окисления пропилена до акриловой кислоты RU2464256C2 (ru)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US75236905P 2005-12-22 2005-12-22
US60/752,369 2005-12-22
DE102005062026.4 2005-12-22
DE102005062026A DE102005062026A1 (de) 2005-12-22 2005-12-22 Verfahren der heterogen katalysierten partiellen Gasphasenoxidation von Propylen zu Acrylsäure

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RU2008129548A RU2008129548A (ru) 2010-01-27
RU2464256C2 true RU2464256C2 (ru) 2012-10-20

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Country Status (10)

Country Link
US (1) US7807853B2 (enExample)
EP (1) EP1963248B1 (enExample)
JP (2) JP2009520748A (enExample)
KR (2) KR101507616B1 (enExample)
CN (1) CN101379018B (enExample)
DE (1) DE102005062026A1 (enExample)
MY (1) MY145843A (enExample)
RU (1) RU2464256C2 (enExample)
TW (1) TWI377193B (enExample)
WO (1) WO2007074045A1 (enExample)

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DE102007004960A1 (de) 2007-01-26 2008-07-31 Basf Se Verfahren zur Herstellung von Acrylsäure
DE102007055086A1 (de) 2007-11-16 2009-05-20 Basf Se Verfahren zur Herstellung von Acrylsäure
DE102007029053A1 (de) * 2007-06-21 2008-01-03 Basf Ag Verfahren der heterogen katalysierten partiellen Direktoxidation von n-Propan zu Acrylsäure
US9149799B2 (en) * 2010-04-28 2015-10-06 Basf Se Eggshell catalyst consisting of a hollow cylindrical support body and a catalytically active oxide material applied to the outer surface of the support body
DE102010042216A1 (de) 2010-10-08 2011-06-09 Basf Se Verfahren zur Hemmung der unerwünschten radikalischen Polymerisation von in einer flüssigen Phase P befindlicher Acrylsäure
WO2012091865A1 (en) 2010-12-29 2012-07-05 Rohm And Haas Company Reactor and process for propane oxidation
DE102011076931A1 (de) 2011-06-03 2012-12-06 Basf Se Wässrige Lösung, enthaltend Acrylsäure und deren konjugierte Base
EP2768794B1 (en) 2011-10-18 2017-08-23 Rohm and Haas Company Method for preparing acrylic acid from propane and propylene
JP6388638B2 (ja) 2013-04-08 2018-09-12 サウディ ベーシック インダストリーズ コーポレイション カルボン酸基を含む生成物にプロピレンを転化するための触媒
DE102013006251A1 (de) * 2013-04-11 2014-10-16 Clariant International Ltd. Verfahren zur Herstellung eines Katalysators zur partiellen Oxidation von Olefinen
CN105622822B (zh) * 2016-03-02 2018-11-27 中国石油集团东北炼化工程有限公司吉林设计院 一种用于乙丙橡胶生产的催化剂的使用工艺
WO2019116483A1 (ja) * 2017-12-14 2019-06-20 三菱重工エンジニアリング株式会社 アクリル酸の製造プラント及びアクリル酸の製造方法
DE102018200841A1 (de) 2018-01-19 2019-07-25 Basf Se Mo, Bi, Fe und Cu enthaltende Multimetalloxidmassen
WO2020020697A1 (de) 2018-07-26 2020-01-30 Basf Se Verfahren zur hemmung der unerwünschten radikalischen polymerisation von in einer flüssigen phase p befindlicher acrylsäure
EP3770145A1 (en) 2019-07-24 2021-01-27 Basf Se A process for the continuous production of either acrolein or acrylic acid as the target product from propene
WO2021191042A1 (de) 2020-03-26 2021-09-30 Basf Se Verfahren zur hemmung der unerwünschten radikalischen polymerisation von in einer flüssigen phase p befindlicher acrylsäure
WO2025172146A1 (de) 2024-02-15 2025-08-21 Basf Se Verfahren zur herstellung von acrylsäure
WO2025219135A1 (en) 2024-04-17 2025-10-23 Basf Se Process for utilizing high calorific acrylic acid production waste streams
WO2025219136A1 (en) 2024-04-17 2025-10-23 Basf Se Process for utilizing acrylic acid production waste streams
WO2025219137A1 (en) 2024-04-17 2025-10-23 Basf Se Process for utilizing acrylic acid production waste streams by gasification and fermentation

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WO2004031106A1 (de) * 2002-09-27 2004-04-15 Basf Aktiengesellschaft Verfahren zur herstellung von wenigstens einem partiellen oxidations- und/oder ammoxidationsprodukt des propylens
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DE19902562A1 (de) * 1999-01-22 2000-07-27 Basf Ag Verfahren zur Herstellung von Acrolein durch heterogen katalysierte Gasphasen-Partialoxidation von Propen
WO2004031106A1 (de) * 2002-09-27 2004-04-15 Basf Aktiengesellschaft Verfahren zur herstellung von wenigstens einem partiellen oxidations- und/oder ammoxidationsprodukt des propylens
WO2004031107A1 (de) * 2002-09-27 2004-04-15 Basf Aktiengesellschaft Verfahren zur herstellung von wenigstens einem partiellen oxidations- und/oder ammoxidationsprodukt des propylens
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Publication number Publication date
CN101379018B (zh) 2012-07-04
KR20140058697A (ko) 2014-05-14
RU2008129548A (ru) 2010-01-27
KR101507616B1 (ko) 2015-03-31
JP5940045B2 (ja) 2016-06-29
EP1963248B1 (de) 2016-06-08
US20070149808A1 (en) 2007-06-28
WO2007074045A1 (de) 2007-07-05
DE102005062026A1 (de) 2007-06-28
TW200732301A (en) 2007-09-01
JP2014148500A (ja) 2014-08-21
KR20080081328A (ko) 2008-09-09
US7807853B2 (en) 2010-10-05
CN101379018A (zh) 2009-03-04
JP2009520748A (ja) 2009-05-28
TWI377193B (en) 2012-11-21
MY145843A (en) 2012-04-30
EP1963248A1 (de) 2008-09-03

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