CN101379010B - 催化剂组合物和乙烯的低聚方法 - Google Patents

催化剂组合物和乙烯的低聚方法 Download PDF

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Publication number
CN101379010B
CN101379010B CN2007800048418A CN200780004841A CN101379010B CN 101379010 B CN101379010 B CN 101379010B CN 2007800048418 A CN2007800048418 A CN 2007800048418A CN 200780004841 A CN200780004841 A CN 200780004841A CN 101379010 B CN101379010 B CN 101379010B
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CN
China
Prior art keywords
catalyst
catalyzer
straightαolefin
ethylene
oligomerization
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Expired - Fee Related
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CN2007800048418A
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English (en)
Chinese (zh)
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CN101379010A (zh
Inventor
V·O·阿里耶夫
A·阿布-拉克巴哈
F·阿尔-科代里
A·H·阿齐佐夫
A·A·克罕米托夫
B·V·古里耶夫
R·V·阿里耶瓦
C·K·拉苏洛夫
M·J·伊布拉西莫娃
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Saudi Basic Industries Corp
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Saudi Basic Industries Corp
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
    • B01J31/223—At least two oxygen atoms present in one at least bidentate or bridging ligand
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/26—Catalytic processes with hydrides or organic compounds
    • C07C2/32—Catalytic processes with hydrides or organic compounds as complexes, e.g. acetyl-acetonates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/20—Olefin oligomerisation or telomerisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/48—Zirconium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0201—Oxygen-containing compounds
    • B01J31/0211—Oxygen-containing compounds with a metal-oxygen link
    • B01J31/0214—Aryloxylates, e.g. phenolates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0215—Sulfur-containing compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0235—Nitrogen containing compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/22—Organic complexes

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CN2007800048418A 2006-02-08 2007-02-06 催化剂组合物和乙烯的低聚方法 Expired - Fee Related CN101379010B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP06002513 2006-02-08
EP06002513.7 2006-02-08
PCT/EA2007/000001 WO2007090412A2 (en) 2006-02-08 2007-02-06 A catalyst composition and a process for the oligomerization of ethylene

Publications (2)

Publication Number Publication Date
CN101379010A CN101379010A (zh) 2009-03-04
CN101379010B true CN101379010B (zh) 2013-06-19

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CN2007800048418A Expired - Fee Related CN101379010B (zh) 2006-02-08 2007-02-06 催化剂组合物和乙烯的低聚方法

Country Status (6)

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US (1) US8524845B2 (enExample)
EP (1) EP1981832A2 (enExample)
JP (2) JP2009525855A (enExample)
CN (1) CN101379010B (enExample)
EA (1) EA015044B1 (enExample)
WO (1) WO2007090412A2 (enExample)

Families Citing this family (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2595614Y2 (ja) 1993-02-24 1999-05-31 鹿島建設株式会社 大スパン構造物のプッシュアップ架台
DE602007008268D1 (de) * 2007-12-06 2010-09-16 Linde Ag Katalysatorzusammensetzung und Verfahren zur Herstellung linearer Alphaolefine
US8557936B2 (en) * 2009-10-28 2013-10-15 Exxonmobil Chemical Patents Inc. Catalyst compounds and use thereof
EP2493933A4 (en) * 2009-10-28 2013-06-12 Exxonmobil Chem Patents Inc CATALYTIC COMPOUNDS AND THEIR USE
WO2011056423A2 (en) * 2009-10-28 2011-05-12 Exxonmobil Chemical Patents Inc. Catalyst compounds and use thereof
US8546501B2 (en) 2009-10-28 2013-10-01 Exxonmobil Chemical Patents Inc. Catalyst compounds and use thereof
WO2011056432A2 (en) 2009-10-28 2011-05-12 Exxonmobil Chemical Patents Inc. Catalyst compounds and use thereof
JP6207336B2 (ja) * 2012-11-12 2017-10-04 日本ポリプロ株式会社 ジオール化合物及びオレフィン重合用触媒並びにオレフィン重合体の製造方法
ES2913079T3 (es) * 2014-07-18 2022-05-31 Sabic Global Technologies Bv Composición catalizadora y proceso para preparar alfa-olefinas lineales
US10683377B2 (en) 2018-07-16 2020-06-16 Exxonmobil Chemical Patents Inc. Catalysts for olefin polymerization
WO2020018254A1 (en) * 2018-07-16 2020-01-23 Exxonmobil Chemical Patents Inc. Catalysts for olefin polymerization
IN201921051272A (enExample) * 2019-12-11 2022-01-06
US11739169B2 (en) 2020-04-24 2023-08-29 Exxonmobil Chemical Patents Inc. Solubility improvement of non-metallocene transition metal complexes in aliphatic hydrocarbon solvents
JP7543376B2 (ja) 2021-11-23 2024-09-02 インディアン オイル コーポレイション リミテッド エチレンのオリゴマー化における直鎖状α－オレフィンを高収率で製造するためのプロセス及び触媒組成物
CN120303060A (zh) * 2022-12-15 2025-07-11 弗门尼舍有限公司 制备α,β-不饱和羰基化合物的方法
WO2024227724A2 (en) 2023-05-02 2024-11-07 Topsoe A/S Process and plant for producing synthetic paraffinic kerosene as jet fuel
WO2024227723A2 (en) 2023-05-02 2024-11-07 Topsoe A/S Process and plant for producing synthetic paraffinic kerosene as jet fuel
DK181857B1 (en) 2023-05-02 2025-02-20 Topsoe As Process and plant for producing synthetic paraffinic kerosene as jet fuel
CN119954580A (zh) * 2023-11-09 2025-05-09 中国石油天然气股份有限公司 长链线性α-烯烃及其制备方法
WO2025257295A1 (en) * 2024-06-13 2025-12-18 Firmenich Sa Process for preparing carbonyl compounds

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0241596A1 (en) * 1986-04-17 1987-10-21 Idemitsu Petrochemical Co. Ltd. A process for preparing linear alpha-olefins
EP0606125A2 (en) * 1993-01-08 1994-07-13 Shell Internationale Researchmaatschappij B.V. Use of titanium and zirconium compounds as homogeneous catalyst and novel titanium and zirconium compounds

Family Cites Families (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4486615A (en) * 1960-09-14 1984-12-04 Exxon Research & Engineering Co. Preparation of linear olefin products
US4442309A (en) * 1960-09-14 1984-04-10 Exxon Reserch And Engineering Co. Preparation of linear olefin products
US4396788A (en) * 1960-09-14 1983-08-02 Exxon Research And Engineering Co. Preparation of linear olefin products
GB1509918A (en) * 1974-08-29 1978-05-04 Ici Ltd Oligomerisation of ethylene
US4434312A (en) * 1978-03-02 1984-02-28 Exxon Research And Engineering Co. Preparation of linear olefin products
SU1042701A1 (ru) 1978-07-19 1983-09-23 Отделение ордена Ленина института химической физики АН СССР Катализатор дл олигомеризации этилена в высшие альфа-олефины
US4361714A (en) * 1981-12-14 1982-11-30 Exxon Research And Engineering Co. Preparation of linear olefin products
US4434313A (en) * 1981-12-14 1984-02-28 Exxon Research And Engineering Co. Preparation of linear olefin products
US4377720A (en) * 1981-12-14 1983-03-22 Exxon Research And Engineering Co. Preparation of linear olefin products
US4410750A (en) * 1981-12-14 1983-10-18 Exxon Research And Engineering Co. Preparation of linear olefin products
US4409409A (en) * 1982-06-10 1983-10-11 Exxon Research And Engineering Co. Two stage olefin wax process
JP2603059B2 (ja) * 1985-10-11 1997-04-23 住友化学工業株式会社 オレフィン重合用触媒成分
US4783571A (en) * 1986-12-19 1988-11-08 Mobil Oil Corporation Catalytic conversion over dehydroxylated zeolite
GB8929269D0 (en) 1989-12-28 1990-02-28 Shell Int Research Process and catalyst composition for the preparation of linear alpha olefins
FR2693455B1 (fr) * 1992-07-09 1994-09-30 Inst Francais Du Petrole Procédé de fabrication d'oléfines alpha légères par oligomérisation de l'éthylène.
JPH072924A (ja) * 1993-01-08 1995-01-06 Shell Internatl Res Maatschappij Bv 均質触媒としてのチタン及びジルコニウム化合物の使用並びに新規チタン及びジルコニウム化合物
JPH06298825A (ja) * 1993-02-22 1994-10-25 Idemitsu Kosan Co Ltd エチレン系重合体の製造方法及びその方法により得られたエチレン系重合体
JPH08259472A (ja) * 1995-03-22 1996-10-08 Maruzen Petrochem Co Ltd 線状α−オレフィンの製造方法
US5780698A (en) * 1997-03-31 1998-07-14 Chevron Chemical Company Olefin oligomerization catalyst and process employing and preparing same
DE19741876A1 (de) * 1997-09-23 1999-03-25 Basf Ag Verfahren zur selektiven Herstellung racemischer Metallocenkomplexe
DE69820223T2 (de) * 1997-10-15 2004-09-16 Daicel Chemical Industries, Ltd., Sakai Verfahren zur herstellung von monodispersen polymeren, verfahren zur kontinuierlichen polymerisation von cyclischen monomeren und daraus hergestellte polymere
JPH11240910A (ja) * 1997-12-10 1999-09-07 Sumitomo Chem Co Ltd オレフィン系重合体の製造方法
ID26707A (id) * 1999-01-21 2001-02-01 Idemitsu Petrochemical Co Katalisator untuk produksi-olefin dan metode produksi-olefin
JP4409695B2 (ja) * 1999-02-19 2010-02-03 出光興産株式会社 α−オレフィン製造用触媒及びα−オレフィンの製造方法
JP2003501434A (ja) * 1999-06-07 2003-01-14 バセル テクノロジー カンパニー ビー．ブイ． ジアニオン性の二座配位子を有する遷移−金属−アルキル錯体の製造
US6906147B2 (en) * 2002-03-20 2005-06-14 Cyclics Corporation Catalytic systems
US6531555B2 (en) * 2000-12-19 2003-03-11 Univation Technologies, Llp Olefin oligomerization catalysts, their production and use
GB0102440D0 (en) * 2001-01-31 2001-03-14 Borealis Tech Oy Catalyst
GB0228888D0 (en) * 2002-12-11 2003-01-15 Johnson Matthey Plc Polymerisation reaction and catalyst therefor

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0241596A1 (en) * 1986-04-17 1987-10-21 Idemitsu Petrochemical Co. Ltd. A process for preparing linear alpha-olefins
EP0606125A2 (en) * 1993-01-08 1994-07-13 Shell Internationale Researchmaatschappij B.V. Use of titanium and zirconium compounds as homogeneous catalyst and novel titanium and zirconium compounds

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
Hongjun Zhu, et al.Preparation and structures of 6- and 7-coordinate salen-type zirconium complexes and their catalytic properties for oligomerization of ethylene.《Journal of Organometallic Chemistry》.2005,第690卷3929-3936. *
Robert D. J. Froese, et al.Theoretical Studies of Ethylene Polymerization Reactions Catalyzed by Zirconium and Titanium Chelating Alkoxide Complexes.《J. Am. Chem. Soc.》.1997,第119卷(第31期),7190-7196. *
Stefan Fokken, et al.Nine-Membered Titanacyclic Complexes Based on an Ethylene-Bridged Bis(phenolato) Ligand: Synthesis, Structure, and Olefin Polymerization Activity.《Organometallics》.1997,第16卷(第20期),4240-4242. *

Also Published As

Publication number Publication date
US8524845B2 (en) 2013-09-03
EA015044B1 (ru) 2011-04-29
JP2015120732A (ja) 2015-07-02
WO2007090412A3 (en) 2007-11-08
JP2009525855A (ja) 2009-07-16
EA200801804A1 (ru) 2008-12-30
US20100152398A1 (en) 2010-06-17
JP6027638B2 (ja) 2016-11-16
EP1981832A2 (en) 2008-10-22
CN101379010A (zh) 2009-03-04
WO2007090412A2 (en) 2007-08-16

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