EA015044B1 - Способ олигомеризации этилена - Google Patents
Способ олигомеризации этилена Download PDFInfo
- Publication number
- EA015044B1 EA015044B1 EA200801804A EA200801804A EA015044B1 EA 015044 B1 EA015044 B1 EA 015044B1 EA 200801804 A EA200801804 A EA 200801804A EA 200801804 A EA200801804 A EA 200801804A EA 015044 B1 EA015044 B1 EA 015044B1
- Authority
- EA
- Eurasian Patent Office
- Prior art keywords
- ethylene
- oligomerization
- zirconium
- catalyst
- bisphenolate
- Prior art date
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
- B01J31/2208—Oxygen, e.g. acetylacetonates
- B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
- B01J31/223—At least two oxygen atoms present in one at least bidentate or bridging ligand
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
- B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
- B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
- C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
- C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
- C07C2/08—Catalytic processes
- C07C2/26—Catalytic processes with hydrides or organic compounds
- C07C2/32—Catalytic processes with hydrides or organic compounds as complexes, e.g. acetyl-acetonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/20—Olefin oligomerisation or telomerisation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
- B01J2531/48—Zirconium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0201—Oxygen-containing compounds
- B01J31/0211—Oxygen-containing compounds with a metal-oxygen link
- B01J31/0214—Aryloxylates, e.g. phenolates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0215—Sulfur-containing compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
- B01J31/0235—Nitrogen containing compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- C07C2531/22—Organic complexes
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP06002513 | 2006-02-08 | ||
| PCT/EA2007/000001 WO2007090412A2 (en) | 2006-02-08 | 2007-02-06 | A catalyst composition and a process for the oligomerization of ethylene |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EA200801804A1 EA200801804A1 (ru) | 2008-12-30 |
| EA015044B1 true EA015044B1 (ru) | 2011-04-29 |
Family
ID=36609590
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EA200801804A EA015044B1 (ru) | 2006-02-08 | 2007-02-06 | Способ олигомеризации этилена |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US8524845B2 (enExample) |
| EP (1) | EP1981832A2 (enExample) |
| JP (2) | JP2009525855A (enExample) |
| CN (1) | CN101379010B (enExample) |
| EA (1) | EA015044B1 (enExample) |
| WO (1) | WO2007090412A2 (enExample) |
Families Citing this family (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2595614Y2 (ja) | 1993-02-24 | 1999-05-31 | 鹿島建設株式会社 | 大スパン構造物のプッシュアップ架台 |
| DE602007008268D1 (de) * | 2007-12-06 | 2010-09-16 | Linde Ag | Katalysatorzusammensetzung und Verfahren zur Herstellung linearer Alphaolefine |
| US8557936B2 (en) * | 2009-10-28 | 2013-10-15 | Exxonmobil Chemical Patents Inc. | Catalyst compounds and use thereof |
| EP2493933A4 (en) * | 2009-10-28 | 2013-06-12 | Exxonmobil Chem Patents Inc | CATALYTIC COMPOUNDS AND THEIR USE |
| WO2011056423A2 (en) * | 2009-10-28 | 2011-05-12 | Exxonmobil Chemical Patents Inc. | Catalyst compounds and use thereof |
| US8546501B2 (en) | 2009-10-28 | 2013-10-01 | Exxonmobil Chemical Patents Inc. | Catalyst compounds and use thereof |
| WO2011056432A2 (en) | 2009-10-28 | 2011-05-12 | Exxonmobil Chemical Patents Inc. | Catalyst compounds and use thereof |
| JP6207336B2 (ja) * | 2012-11-12 | 2017-10-04 | 日本ポリプロ株式会社 | ジオール化合物及びオレフィン重合用触媒並びにオレフィン重合体の製造方法 |
| ES2913079T3 (es) * | 2014-07-18 | 2022-05-31 | Sabic Global Technologies Bv | Composición catalizadora y proceso para preparar alfa-olefinas lineales |
| US10683377B2 (en) | 2018-07-16 | 2020-06-16 | Exxonmobil Chemical Patents Inc. | Catalysts for olefin polymerization |
| WO2020018254A1 (en) * | 2018-07-16 | 2020-01-23 | Exxonmobil Chemical Patents Inc. | Catalysts for olefin polymerization |
| IN201921051272A (enExample) * | 2019-12-11 | 2022-01-06 | ||
| US11739169B2 (en) | 2020-04-24 | 2023-08-29 | Exxonmobil Chemical Patents Inc. | Solubility improvement of non-metallocene transition metal complexes in aliphatic hydrocarbon solvents |
| JP7543376B2 (ja) | 2021-11-23 | 2024-09-02 | インディアン オイル コーポレイション リミテッド | エチレンのオリゴマー化における直鎖状α-オレフィンを高収率で製造するためのプロセス及び触媒組成物 |
| CN120303060A (zh) * | 2022-12-15 | 2025-07-11 | 弗门尼舍有限公司 | 制备α,β-不饱和羰基化合物的方法 |
| WO2024227724A2 (en) | 2023-05-02 | 2024-11-07 | Topsoe A/S | Process and plant for producing synthetic paraffinic kerosene as jet fuel |
| WO2024227723A2 (en) | 2023-05-02 | 2024-11-07 | Topsoe A/S | Process and plant for producing synthetic paraffinic kerosene as jet fuel |
| DK181857B1 (en) | 2023-05-02 | 2025-02-20 | Topsoe As | Process and plant for producing synthetic paraffinic kerosene as jet fuel |
| CN119954580A (zh) * | 2023-11-09 | 2025-05-09 | 中国石油天然气股份有限公司 | 长链线性α-烯烃及其制备方法 |
| WO2025257295A1 (en) * | 2024-06-13 | 2025-12-18 | Firmenich Sa | Process for preparing carbonyl compounds |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0606125A2 (en) * | 1993-01-08 | 1994-07-13 | Shell Internationale Researchmaatschappij B.V. | Use of titanium and zirconium compounds as homogeneous catalyst and novel titanium and zirconium compounds |
Family Cites Families (30)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4486615A (en) * | 1960-09-14 | 1984-12-04 | Exxon Research & Engineering Co. | Preparation of linear olefin products |
| US4442309A (en) * | 1960-09-14 | 1984-04-10 | Exxon Reserch And Engineering Co. | Preparation of linear olefin products |
| US4396788A (en) * | 1960-09-14 | 1983-08-02 | Exxon Research And Engineering Co. | Preparation of linear olefin products |
| GB1509918A (en) * | 1974-08-29 | 1978-05-04 | Ici Ltd | Oligomerisation of ethylene |
| US4434312A (en) * | 1978-03-02 | 1984-02-28 | Exxon Research And Engineering Co. | Preparation of linear olefin products |
| SU1042701A1 (ru) | 1978-07-19 | 1983-09-23 | Отделение ордена Ленина института химической физики АН СССР | Катализатор дл олигомеризации этилена в высшие альфа-олефины |
| US4361714A (en) * | 1981-12-14 | 1982-11-30 | Exxon Research And Engineering Co. | Preparation of linear olefin products |
| US4434313A (en) * | 1981-12-14 | 1984-02-28 | Exxon Research And Engineering Co. | Preparation of linear olefin products |
| US4377720A (en) * | 1981-12-14 | 1983-03-22 | Exxon Research And Engineering Co. | Preparation of linear olefin products |
| US4410750A (en) * | 1981-12-14 | 1983-10-18 | Exxon Research And Engineering Co. | Preparation of linear olefin products |
| US4409409A (en) * | 1982-06-10 | 1983-10-11 | Exxon Research And Engineering Co. | Two stage olefin wax process |
| JP2603059B2 (ja) * | 1985-10-11 | 1997-04-23 | 住友化学工業株式会社 | オレフィン重合用触媒成分 |
| DE3675385D1 (de) * | 1986-04-17 | 1990-12-06 | Idemitsu Petrochemical Co | Verfahren zur herstellung von linearen alpha-olefinen. |
| US4783571A (en) * | 1986-12-19 | 1988-11-08 | Mobil Oil Corporation | Catalytic conversion over dehydroxylated zeolite |
| GB8929269D0 (en) | 1989-12-28 | 1990-02-28 | Shell Int Research | Process and catalyst composition for the preparation of linear alpha olefins |
| FR2693455B1 (fr) * | 1992-07-09 | 1994-09-30 | Inst Francais Du Petrole | Procédé de fabrication d'oléfines alpha légères par oligomérisation de l'éthylène. |
| JPH072924A (ja) * | 1993-01-08 | 1995-01-06 | Shell Internatl Res Maatschappij Bv | 均質触媒としてのチタン及びジルコニウム化合物の使用並びに新規チタン及びジルコニウム化合物 |
| JPH06298825A (ja) * | 1993-02-22 | 1994-10-25 | Idemitsu Kosan Co Ltd | エチレン系重合体の製造方法及びその方法により得られたエチレン系重合体 |
| JPH08259472A (ja) * | 1995-03-22 | 1996-10-08 | Maruzen Petrochem Co Ltd | 線状α−オレフィンの製造方法 |
| US5780698A (en) * | 1997-03-31 | 1998-07-14 | Chevron Chemical Company | Olefin oligomerization catalyst and process employing and preparing same |
| DE19741876A1 (de) * | 1997-09-23 | 1999-03-25 | Basf Ag | Verfahren zur selektiven Herstellung racemischer Metallocenkomplexe |
| DE69820223T2 (de) * | 1997-10-15 | 2004-09-16 | Daicel Chemical Industries, Ltd., Sakai | Verfahren zur herstellung von monodispersen polymeren, verfahren zur kontinuierlichen polymerisation von cyclischen monomeren und daraus hergestellte polymere |
| JPH11240910A (ja) * | 1997-12-10 | 1999-09-07 | Sumitomo Chem Co Ltd | オレフィン系重合体の製造方法 |
| ID26707A (id) * | 1999-01-21 | 2001-02-01 | Idemitsu Petrochemical Co | Katalisator untuk produksi-olefin dan metode produksi-olefin |
| JP4409695B2 (ja) * | 1999-02-19 | 2010-02-03 | 出光興産株式会社 | α−オレフィン製造用触媒及びα−オレフィンの製造方法 |
| JP2003501434A (ja) * | 1999-06-07 | 2003-01-14 | バセル テクノロジー カンパニー ビー.ブイ. | ジアニオン性の二座配位子を有する遷移−金属−アルキル錯体の製造 |
| US6906147B2 (en) * | 2002-03-20 | 2005-06-14 | Cyclics Corporation | Catalytic systems |
| US6531555B2 (en) * | 2000-12-19 | 2003-03-11 | Univation Technologies, Llp | Olefin oligomerization catalysts, their production and use |
| GB0102440D0 (en) * | 2001-01-31 | 2001-03-14 | Borealis Tech Oy | Catalyst |
| GB0228888D0 (en) * | 2002-12-11 | 2003-01-15 | Johnson Matthey Plc | Polymerisation reaction and catalyst therefor |
-
2007
- 2007-02-06 US US12/223,218 patent/US8524845B2/en not_active Expired - Fee Related
- 2007-02-06 EA EA200801804A patent/EA015044B1/ru not_active IP Right Cessation
- 2007-02-06 EP EP07702543A patent/EP1981832A2/en not_active Ceased
- 2007-02-06 CN CN2007800048418A patent/CN101379010B/zh not_active Expired - Fee Related
- 2007-02-06 JP JP2008553622A patent/JP2009525855A/ja active Pending
- 2007-02-06 WO PCT/EA2007/000001 patent/WO2007090412A2/en not_active Ceased
-
2015
- 2015-02-05 JP JP2015021055A patent/JP6027638B2/ja not_active Expired - Fee Related
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0606125A2 (en) * | 1993-01-08 | 1994-07-13 | Shell Internationale Researchmaatschappij B.V. | Use of titanium and zirconium compounds as homogeneous catalyst and novel titanium and zirconium compounds |
Non-Patent Citations (6)
| Title |
|---|
| FOKKEN S. ET AL.: "NINE-MEMBERED TITANACYCLIC COMPLEXES BASED ON AN ETHYLENE-BRIDGED BIS(PHENOLATO) LIGAND: SYNTHESIS, STRUCTURE, AND OLEFIN POLYMERIZATION ACTIVITY" ORGANOMETALLICS, WASHINGTON, DC, US, vol. 16, no. 20, 1997, pages 4240-4242, XP000989574, ISSN: 0276-7333, table 1 * |
| FROESE, ROBERT D.J. ET AL.: "Theoretical Studies of Ethyiene Polymerization Reactions Catalyzed by Zirconium and Titanium Chelating Alkoxide Complexes", JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 119(31), 7190-7196 CODEN: JACSAT; ISSN: 0002-7863 JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 119(31), 7190-7196 CODEN: JACSAT; ISSN: 0002-7863, 1997, XP008066298, the whole document * |
| LINDEN VAN DER A. ET AL.: "POLYMERIZATION OF A-OLEFINS AND BUTADINE AND CATALYTIC CYCLOTRIMERIZATION OF 1-ALKYNES BY A NEW CLASS OF GROUP IV CATALYSTS. CONTROL OF MOLECULAR WEIGHT AND POLYMER MICROSTRUCTURE VIA LIGAND TUNING IN STERICALLY HINDERED CHELATING PHENOXIDE TITANIUM AND ZIRCONIUM SPECIES", JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, AMERICAN CHEMICAL SOCIETY, WASHINGTON, DC, US, vol. 117, no. 11, 1995, pages 3008-3021, XP000887019, ISSN: 0002-7863, page 3010, 3011, 3014, table 5 * |
| OKUDA J. ET AL.: "SYNDIOSPECIFIC POLYMERIZATION OF STYRENE USING METHYLALUMINOXANE-ACTIVATED BIS(PHENOLATO)TITANIUM COMPLEXES", MACROMOLECULAR CHEMISTRY AND PHYSICS, WILEY-VCH VERLAG, WEINHEIM, DE, vol. 199, 1998, pages 543-545, XP009032661, ISSN: 1022-1352, table 1 * |
| SERNETZ F.G. ET AL.: "COPOLYMERIZATION OF ETHENE WITH STYRENE USING METHYLALUMINOXANE-ACTIVATED BIS(PHENOLATE) COMPLEXES", MACROMOLECULES, ACS, WASHINGTON, DC, US, vol. 30, no. 6, 24 March 1997 (1997-03-24), pages 562-1569, XP000682472 ISSN: 0024-9297, tables 1, 2 * |
| ZHU ET AL.: "Preparation and structures of 6- and 7-coordinate salen-type zirconium complexes and their catalytic properties for oligomerization of ethylene", JOURNAL OF ORGANOMETALLIC CHEMISTRY, ELSEVIER-SEQUOIA S.A. LAUSANNE, CH, vol. 690, no. 17, 1 September 2005 (2005-09-01), pages 3929-3936, XP005027115, ISSN:0022-328X, table 3 * |
Also Published As
| Publication number | Publication date |
|---|---|
| US8524845B2 (en) | 2013-09-03 |
| JP2015120732A (ja) | 2015-07-02 |
| WO2007090412A3 (en) | 2007-11-08 |
| JP2009525855A (ja) | 2009-07-16 |
| EA200801804A1 (ru) | 2008-12-30 |
| US20100152398A1 (en) | 2010-06-17 |
| JP6027638B2 (ja) | 2016-11-16 |
| EP1981832A2 (en) | 2008-10-22 |
| CN101379010B (zh) | 2013-06-19 |
| CN101379010A (zh) | 2009-03-04 |
| WO2007090412A2 (en) | 2007-08-16 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MM4A | Lapse of a eurasian patent due to non-payment of renewal fees within the time limit in the following designated state(s) |
Designated state(s): AM AZ BY KZ KG MD TJ TM |
|
| MM4A | Lapse of a eurasian patent due to non-payment of renewal fees within the time limit in the following designated state(s) |
Designated state(s): RU |