EA015044B1 - Способ олигомеризации этилена - Google Patents

Способ олигомеризации этилена Download PDF

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Publication number
EA015044B1
EA015044B1 EA200801804A EA200801804A EA015044B1 EA 015044 B1 EA015044 B1 EA 015044B1 EA 200801804 A EA200801804 A EA 200801804A EA 200801804 A EA200801804 A EA 200801804A EA 015044 B1 EA015044 B1 EA 015044B1
Authority
EA
Eurasian Patent Office
Prior art keywords
ethylene
oligomerization
zirconium
catalyst
bisphenolate
Prior art date
Application number
EA200801804A
Other languages
English (en)
Russian (ru)
Other versions
EA200801804A1 (ru
Inventor
Вугар О. Алиев
Атих Абу-Раквабах
Фахад Аль-Койдари
Акиф Г. Азизов
Акбер А. Кхаметов
Билал В. Гулиев
Рейхан В. Алиева
Чингиз К. Разулов
Минавар Дж. Ибрахимова
Original Assignee
Сауди Бейсик Индастриз Корпорейшн
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Сауди Бейсик Индастриз Корпорейшн filed Critical Сауди Бейсик Индастриз Корпорейшн
Publication of EA200801804A1 publication Critical patent/EA200801804A1/ru
Publication of EA015044B1 publication Critical patent/EA015044B1/ru

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
    • B01J31/223—At least two oxygen atoms present in one at least bidentate or bridging ligand
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/26—Catalytic processes with hydrides or organic compounds
    • C07C2/32—Catalytic processes with hydrides or organic compounds as complexes, e.g. acetyl-acetonates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/20—Olefin oligomerisation or telomerisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/48—Zirconium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0201—Oxygen-containing compounds
    • B01J31/0211—Oxygen-containing compounds with a metal-oxygen link
    • B01J31/0214—Aryloxylates, e.g. phenolates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0215—Sulfur-containing compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0235—Nitrogen containing compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/22—Organic complexes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
EA200801804A 2006-02-08 2007-02-06 Способ олигомеризации этилена EA015044B1 (ru)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP06002513 2006-02-08
PCT/EA2007/000001 WO2007090412A2 (en) 2006-02-08 2007-02-06 A catalyst composition and a process for the oligomerization of ethylene

Publications (2)

Publication Number Publication Date
EA200801804A1 EA200801804A1 (ru) 2008-12-30
EA015044B1 true EA015044B1 (ru) 2011-04-29

Family

ID=36609590

Family Applications (1)

Application Number Title Priority Date Filing Date
EA200801804A EA015044B1 (ru) 2006-02-08 2007-02-06 Способ олигомеризации этилена

Country Status (6)

Country Link
US (1) US8524845B2 (enExample)
EP (1) EP1981832A2 (enExample)
JP (2) JP2009525855A (enExample)
CN (1) CN101379010B (enExample)
EA (1) EA015044B1 (enExample)
WO (1) WO2007090412A2 (enExample)

Families Citing this family (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2595614Y2 (ja) 1993-02-24 1999-05-31 鹿島建設株式会社 大スパン構造物のプッシュアップ架台
DE602007008268D1 (de) * 2007-12-06 2010-09-16 Linde Ag Katalysatorzusammensetzung und Verfahren zur Herstellung linearer Alphaolefine
EP2493932A4 (en) * 2009-10-28 2013-06-12 Exxonmobil Chem Patents Inc CATALYTIC COMPOUNDS AND THEIR USE
EP2493933A4 (en) * 2009-10-28 2013-06-12 Exxonmobil Chem Patents Inc CATALYTIC COMPOUNDS AND THEIR USE
WO2011056428A2 (en) * 2009-10-28 2011-05-12 Exxonmobil Chemical Patents Inc. Catalyst compounds and use thereof
EP2493935A4 (en) * 2009-10-28 2013-06-26 Exxonmobil Chem Patents Inc CATALYST CONNECTIONS AND ITS USE
US8530593B2 (en) 2009-10-28 2013-09-10 Exxonmobil Chemical Patents Inc. Catalyst compounds and use thereof
JP6207336B2 (ja) * 2012-11-12 2017-10-04 日本ポリプロ株式会社 ジオール化合物及びオレフィン重合用触媒並びにオレフィン重合体の製造方法
CN106536044A (zh) 2014-07-18 2017-03-22 沙特基础工业全球技术有限公司 催化剂组合物和制备线性α烯烃的方法
WO2020018254A1 (en) * 2018-07-16 2020-01-23 Exxonmobil Chemical Patents Inc. Catalysts for olefin polymerization
US10683377B2 (en) 2018-07-16 2020-06-16 Exxonmobil Chemical Patents Inc. Catalysts for olefin polymerization
IN201921051272A (enExample) * 2019-12-11 2022-01-06
US11739169B2 (en) 2020-04-24 2023-08-29 Exxonmobil Chemical Patents Inc. Solubility improvement of non-metallocene transition metal complexes in aliphatic hydrocarbon solvents
EP4183486A1 (en) 2021-11-23 2023-05-24 Indian Oil Corporation Limited Process and catalyst composition for producing linear alpha olefins in high yield by ethylene oligomerization
JP2025542009A (ja) * 2022-12-15 2025-12-24 フイルメニツヒ ソシエテ アノニム α，β－不飽和カルボニル化合物を調製するための方法
DK181857B1 (en) 2023-05-02 2025-02-20 Topsoe As Process and plant for producing synthetic paraffinic kerosene as jet fuel
EP4705411A2 (en) 2023-05-02 2026-03-11 Topsoe A/S Process and plant for producing synthetic paraffinic kerosene as jet fuel
EP4705410A2 (en) 2023-05-02 2026-03-11 Topsoe A/S Process and plant for producing synthetic paraffinic kerosene as jet fuel
CN119954580B (zh) * 2023-11-09 2026-04-17 中国石油天然气股份有限公司 长链线性α-烯烃及其制备方法
WO2025257295A1 (en) * 2024-06-13 2025-12-18 Firmenich Sa Process for preparing carbonyl compounds

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0606125A2 (en) * 1993-01-08 1994-07-13 Shell Internationale Researchmaatschappij B.V. Use of titanium and zirconium compounds as homogeneous catalyst and novel titanium and zirconium compounds

Family Cites Families (30)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4396788A (en) 1960-09-14 1983-08-02 Exxon Research And Engineering Co. Preparation of linear olefin products
US4442309A (en) 1960-09-14 1984-04-10 Exxon Reserch And Engineering Co. Preparation of linear olefin products
US4486615A (en) 1960-09-14 1984-12-04 Exxon Research & Engineering Co. Preparation of linear olefin products
GB1509918A (en) * 1974-08-29 1978-05-04 Ici Ltd Oligomerisation of ethylene
US4434312A (en) 1978-03-02 1984-02-28 Exxon Research And Engineering Co. Preparation of linear olefin products
SU1042701A1 (ru) 1978-07-19 1983-09-23 Отделение ордена Ленина института химической физики АН СССР Катализатор дл олигомеризации этилена в высшие альфа-олефины
US4434313A (en) 1981-12-14 1984-02-28 Exxon Research And Engineering Co. Preparation of linear olefin products
US4410750A (en) 1981-12-14 1983-10-18 Exxon Research And Engineering Co. Preparation of linear olefin products
US4361714A (en) 1981-12-14 1982-11-30 Exxon Research And Engineering Co. Preparation of linear olefin products
US4377720A (en) 1981-12-14 1983-03-22 Exxon Research And Engineering Co. Preparation of linear olefin products
US4409409A (en) 1982-06-10 1983-10-11 Exxon Research And Engineering Co. Two stage olefin wax process
JP2603059B2 (ja) * 1985-10-11 1997-04-23 住友化学工業株式会社 オレフィン重合用触媒成分
EP0241596B1 (en) 1986-04-17 1990-10-31 Idemitsu Petrochemical Co. Ltd. A process for preparing linear alpha-olefins
US4783571A (en) 1986-12-19 1988-11-08 Mobil Oil Corporation Catalytic conversion over dehydroxylated zeolite
GB8929269D0 (en) * 1989-12-28 1990-02-28 Shell Int Research Process and catalyst composition for the preparation of linear alpha olefins
FR2693455B1 (fr) 1992-07-09 1994-09-30 Inst Francais Du Petrole Procédé de fabrication d'oléfines alpha légères par oligomérisation de l'éthylène.
JPH072924A (ja) * 1993-01-08 1995-01-06 Shell Internatl Res Maatschappij Bv 均質触媒としてのチタン及びジルコニウム化合物の使用並びに新規チタン及びジルコニウム化合物
JPH06298825A (ja) * 1993-02-22 1994-10-25 Idemitsu Kosan Co Ltd エチレン系重合体の製造方法及びその方法により得られたエチレン系重合体
JPH08259472A (ja) * 1995-03-22 1996-10-08 Maruzen Petrochem Co Ltd 線状α−オレフィンの製造方法
US5780698A (en) * 1997-03-31 1998-07-14 Chevron Chemical Company Olefin oligomerization catalyst and process employing and preparing same
DE19741876A1 (de) * 1997-09-23 1999-03-25 Basf Ag Verfahren zur selektiven Herstellung racemischer Metallocenkomplexe
JP4311768B2 (ja) * 1997-10-15 2009-08-12 ダイセル化学工業株式会社 単分散重合体の製造方法、並びに、環状モノマーの連続重合方法及びそれによる重合体
JPH11240910A (ja) * 1997-12-10 1999-09-07 Sumitomo Chem Co Ltd オレフィン系重合体の製造方法
CN1174805C (zh) * 1999-01-21 2004-11-10 出光石油化学株式会社 α-烯烃制造用催化剂和α-烯烃制造方法
JP4409695B2 (ja) * 1999-02-19 2010-02-03 出光興産株式会社 α−オレフィン製造用触媒及びα−オレフィンの製造方法
KR20010072330A (ko) * 1999-06-07 2001-07-31 간디 지오프레이 에이치. 두자리 음이온성 리간드를 운반하는 전이금속-알킬 착물의제조방법
US6906147B2 (en) * 2002-03-20 2005-06-14 Cyclics Corporation Catalytic systems
US6531555B2 (en) * 2000-12-19 2003-03-11 Univation Technologies, Llp Olefin oligomerization catalysts, their production and use
GB0102440D0 (en) 2001-01-31 2001-03-14 Borealis Tech Oy Catalyst
GB0228888D0 (en) * 2002-12-11 2003-01-15 Johnson Matthey Plc Polymerisation reaction and catalyst therefor

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0606125A2 (en) * 1993-01-08 1994-07-13 Shell Internationale Researchmaatschappij B.V. Use of titanium and zirconium compounds as homogeneous catalyst and novel titanium and zirconium compounds

Non-Patent Citations (6)

* Cited by examiner, † Cited by third party
Title
FOKKEN S. ET AL.: "NINE-MEMBERED TITANACYCLIC COMPLEXES BASED ON AN ETHYLENE-BRIDGED BIS(PHENOLATO) LIGAND: SYNTHESIS, STRUCTURE, AND OLEFIN POLYMERIZATION ACTIVITY" ORGANOMETALLICS, WASHINGTON, DC, US, vol. 16, no. 20, 1997, pages 4240-4242, XP000989574, ISSN: 0276-7333, table 1 *
FROESE, ROBERT D.J. ET AL.: "Theoretical Studies of Ethyiene Polymerization Reactions Catalyzed by Zirconium and Titanium Chelating Alkoxide Complexes", JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 119(31), 7190-7196 CODEN: JACSAT; ISSN: 0002-7863 JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 119(31), 7190-7196 CODEN: JACSAT; ISSN: 0002-7863, 1997, XP008066298, the whole document *
LINDEN VAN DER A. ET AL.: "POLYMERIZATION OF A-OLEFINS AND BUTADINE AND CATALYTIC CYCLOTRIMERIZATION OF 1-ALKYNES BY A NEW CLASS OF GROUP IV CATALYSTS. CONTROL OF MOLECULAR WEIGHT AND POLYMER MICROSTRUCTURE VIA LIGAND TUNING IN STERICALLY HINDERED CHELATING PHENOXIDE TITANIUM AND ZIRCONIUM SPECIES", JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, AMERICAN CHEMICAL SOCIETY, WASHINGTON, DC, US, vol. 117, no. 11, 1995, pages 3008-3021, XP000887019, ISSN: 0002-7863, page 3010, 3011, 3014, table 5 *
OKUDA J. ET AL.: "SYNDIOSPECIFIC POLYMERIZATION OF STYRENE USING METHYLALUMINOXANE-ACTIVATED BIS(PHENOLATO)TITANIUM COMPLEXES", MACROMOLECULAR CHEMISTRY AND PHYSICS, WILEY-VCH VERLAG, WEINHEIM, DE, vol. 199, 1998, pages 543-545, XP009032661, ISSN: 1022-1352, table 1 *
SERNETZ F.G. ET AL.: "COPOLYMERIZATION OF ETHENE WITH STYRENE USING METHYLALUMINOXANE-ACTIVATED BIS(PHENOLATE) COMPLEXES", MACROMOLECULES, ACS, WASHINGTON, DC, US, vol. 30, no. 6, 24 March 1997 (1997-03-24), pages 562-1569, XP000682472 ISSN: 0024-9297, tables 1, 2 *
ZHU ET AL.: "Preparation and structures of 6- and 7-coordinate salen-type zirconium complexes and their catalytic properties for oligomerization of ethylene", JOURNAL OF ORGANOMETALLIC CHEMISTRY, ELSEVIER-SEQUOIA S.A. LAUSANNE, CH, vol. 690, no. 17, 1 September 2005 (2005-09-01), pages 3929-3936, XP005027115, ISSN:0022-328X, table 3 *

Also Published As

Publication number Publication date
JP2015120732A (ja) 2015-07-02
CN101379010A (zh) 2009-03-04
US20100152398A1 (en) 2010-06-17
JP2009525855A (ja) 2009-07-16
WO2007090412A2 (en) 2007-08-16
WO2007090412A3 (en) 2007-11-08
EP1981832A2 (en) 2008-10-22
CN101379010B (zh) 2013-06-19
EA200801804A1 (ru) 2008-12-30
US8524845B2 (en) 2013-09-03
JP6027638B2 (ja) 2016-11-16

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