CN101374596B - 一种油粘合剂的制备方法以及由此方法制备的油粘合剂 - Google Patents

一种油粘合剂的制备方法以及由此方法制备的油粘合剂 Download PDF

Info

Publication number
CN101374596B
CN101374596B CN2007800033639A CN200780003363A CN101374596B CN 101374596 B CN101374596 B CN 101374596B CN 2007800033639 A CN2007800033639 A CN 2007800033639A CN 200780003363 A CN200780003363 A CN 200780003363A CN 101374596 B CN101374596 B CN 101374596B
Authority
CN
China
Prior art keywords
percentage
weight
clay
potter
raw material
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN2007800033639A
Other languages
English (en)
Other versions
CN101374596A (zh
Inventor
弗朗茨·约瑟夫·菲利普
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Commerzialbank Mattersburg im Burgenland AG
Original Assignee
Commerzialbank Mattersburg im Burgenland AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Commerzialbank Mattersburg im Burgenland AG filed Critical Commerzialbank Mattersburg im Burgenland AG
Publication of CN101374596A publication Critical patent/CN101374596A/zh
Application granted granted Critical
Publication of CN101374596B publication Critical patent/CN101374596B/zh
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/12—Naturally occurring clays or bleaching earth
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
    • B01J20/24—Naturally occurring macromolecular compounds, e.g. humic acids or their derivatives
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00—Clay-wares
    • C04B33/02—Preparing or treating the raw materials individually or as batches
    • C04B33/025—Mixtures of materials with different sizes
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00—Clay-wares
    • C04B33/02—Preparing or treating the raw materials individually or as batches
    • C04B33/13—Compounding ingredients
    • C04B33/132—Waste materials; Refuse; Residues
    • C04B33/1321—Waste slurries, e.g. harbour sludge, industrial muds
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00—Clay-wares
    • C04B33/02—Preparing or treating the raw materials individually or as batches
    • C04B33/13—Compounding ingredients
    • C04B33/132—Waste materials; Refuse; Residues
    • C04B33/135—Combustion residues, e.g. fly ash, incineration waste
    • C04B33/1352—Fuel ashes, e.g. fly ash
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/626—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
    • C04B35/62605—Treating the starting powders individually or as mixtures
    • C04B35/62625—Wet mixtures
    • C04B35/6263—Wet mixtures characterised by their solids loadings, i.e. the percentage of solids
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/626—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
    • C04B35/62605—Treating the starting powders individually or as mixtures
    • C04B35/62695—Granulation or pelletising
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B38/00—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
    • C04B38/009—Porous or hollow ceramic granular materials, e.g. microballoons
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K3/00—Materials not provided for elsewhere
    • C09K3/32—Materials not provided for elsewhere for absorbing liquids to remove pollution, e.g. oil, gasoline, fat
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2220/00—Aspects relating to sorbent materials
    • B01J2220/40—Aspects relating to the composition of sorbent or filter aid materials
    • B01J2220/48—Sorbents characterised by the starting material used for their preparation
    • B01J2220/4875—Sorbents characterised by the starting material used for their preparation the starting material being a waste, residue or of undefined composition
    • B01J2220/4887—Residues, wastes, e.g. garbage, municipal or industrial sludges, compost, animal manure; fly-ashes
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3205—Alkaline earth oxides or oxide forming salts thereof, e.g. beryllium oxide
    • C04B2235/3206—Magnesium oxides or oxide-forming salts thereof
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3205—Alkaline earth oxides or oxide forming salts thereof, e.g. beryllium oxide
    • C04B2235/3208—Calcium oxide or oxide-forming salts thereof, e.g. lime
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3231—Refractory metal oxides, their mixed metal oxides, or oxide-forming salts thereof
    • C04B2235/3232—Titanium oxides or titanates, e.g. rutile or anatase
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3231—Refractory metal oxides, their mixed metal oxides, or oxide-forming salts thereof
    • C04B2235/3241—Chromium oxides, chromates, or oxide-forming salts thereof
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3262—Manganese oxides, manganates, rhenium oxides or oxide-forming salts thereof, e.g. MnO
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/327—Iron group oxides, their mixed metal oxides, or oxide-forming salts thereof
    • C04B2235/3272—Iron oxides or oxide forming salts thereof, e.g. hematite, magnetite
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3427—Silicates other than clay, e.g. water glass
    • C04B2235/3463—Alumino-silicates other than clay, e.g. mullite
    • C04B2235/3481—Alkaline earth metal alumino-silicates other than clay, e.g. cordierite, beryl, micas such as margarite, plagioclase feldspars such as anorthite, zeolites such as chabazite
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/50—Constituents or additives of the starting mixture chosen for their shape or used because of their shape or their physical appearance
    • C04B2235/54—Particle size related information
    • C04B2235/5418—Particle size related information expressed by the size of the particles or aggregates thereof
    • C04B2235/5427—Particle size related information expressed by the size of the particles or aggregates thereof millimeter or submillimeter sized, i.e. larger than 0,1 mm
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/50—Constituents or additives of the starting mixture chosen for their shape or used because of their shape or their physical appearance
    • C04B2235/54—Particle size related information
    • C04B2235/5418—Particle size related information expressed by the size of the particles or aggregates thereof
    • C04B2235/5436—Particle size related information expressed by the size of the particles or aggregates thereof micrometer sized, i.e. from 1 to 100 micron
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/50—Constituents or additives of the starting mixture chosen for their shape or used because of their shape or their physical appearance
    • C04B2235/54—Particle size related information
    • C04B2235/549—Particle size related information the particle size being expressed by crystallite size or primary particle size
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/60—Aspects relating to the preparation, properties or mechanical treatment of green bodies or pre-forms
    • C04B2235/602—Making the green bodies or pre-forms by moulding
    • C04B2235/6021—Extrusion moulding
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
    • C04B2235/72—Products characterised by the absence or the low content of specific components, e.g. alkali metal free alumina ceramics
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
    • C04B2235/72—Products characterised by the absence or the low content of specific components, e.g. alkali metal free alumina ceramics
    • C04B2235/727—Phosphorus or phosphorus compound content
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
    • C04B2235/80—Phases present in the sintered or melt-cast ceramic products other than the main phase
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P40/00—Technologies relating to the processing of minerals
    • Y02P40/60—Production of ceramic materials or ceramic elements, e.g. substitution of clay or shale by alternative raw materials, e.g. ashes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Analytical Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Environmental & Geological Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Public Health (AREA)
  • Health & Medical Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Combustion & Propulsion (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Treatment Of Sludge (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Solid Fuels And Fuel-Associated Substances (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

一种油粘合剂的制备方法，所述油粘合剂是通过在原材料中利用废纸和陶土制得的，具有陶瓷基质的颗粒状、开放多孔结构，其特征在于，在总原料混合物中分别取重量百分比为35-60％的淤泥，其含水量为70至85％、重量百分比为25-55％的废纸，其含水量为35至55％、重量百分比为10-25％的陶土，还有可选择性的重量百分比为1-3％的沸石、重量百分比为1至2％的生石灰和/或占重量百分比达3％的飞灰混合成一种均匀的混合物，而后，将所述原材料加工成平均直径为4-6mm的颗粒，紧接着将所述颗粒干燥并随后在950-1050℃下进行烧制。所述按照本发明方法制备的油粘合剂具有0.4至0.75kg/1的松散比重以及每千克油粘合剂结合0.7至1.01油的油粘合能力。

Description

一种油粘合剂的制备方法以及由此方法制备的油粘合剂
技术领域
本发明涉及一种油粘合剂的制备方法以及按照此方法制备的油粘合剂，通过在原料中利用废纸和陶土，所述油粘合剂具有硅酸盐陶瓷基质的颗粒状、开放多孔结构。
背景技术
在实践中公开了一系列不同的由无机或有机材料构成或制备的油粘合剂。由无机材料例如像硅藻土、浮石等这样来源于天然硅酸盐的材料、或者被加工成硅酸盐产品的天然材料构成的油粘合剂大多数都是颗粒状的。由有机材料构成的油粘合剂是由塑料组成的，例如，由聚氨酯、聚丙烯组成。
JP6100284A公开了一种吸油颗粒，所述吸油颗粒由无机粘合剂、含陶土的有机粘合剂以及一种含有亲脂疏水物质的粉末制成。所述无机粉末包含由矿渣沉积物、石料粉末沉积物、废纸或飞灰构成的混合物和陶土。通过在无机粉末中混入锯末、蛭石或珍珠岩来提高其孔隙率。所述已与油结合的颗粒在被亲油物质重新浸渍之后被烧结、贮存或再使用。
JP57165034A公开了一种多孔材料作为油粘合剂，所述材料由锯末和一种粉末硅土和陶土的混合物衍生而来。在该搅拌均匀的混合物转变成预期的形状后，待干燥后在高温下烧制。然后，将所述被烧制后的材料与一疏水性液体一起进行加工处理。
JP7018290A和JP7265696A公开了一种由废纸组成的吸油剂，所述废纸中加入了沸石，选择性地借助粘合剂，如聚乙二醇。
然而，上述公开的油粘合剂都有制备过程费时以及其制品所需部分材料相对昂贵的特点。此外，在油粘合剂的制备中尽可能利用高比例的如淤泥这样的废料并没有得到令人满意的效果。而且，在先公开的油粘合剂的使用可能性以及在此种孔隙率下与油结合的效果并不令人满意。
发明内容
在环境保护的领域，特别是在石油污染水域或者土地的情况下，对于消除或者至少减少导致例如油污染的污染源来说，油粘合剂是不可或缺的物质。如同环保地清除废料的想法，在上述情况中申请人也力求将使用废料作为发明的任务。这种将废料运用于其中而生产出的油粘合剂具有更广泛的应用领域和高度的油粘合能力。
术语“油粘合剂”或“油粘合剂”在下文中将不再仅仅理解为石油、油类产品或者液体碳氢化合物的粘合剂，也要理解为化学试剂。
本发明的目的通过上文中所述方法来解决，即，在总原材料中分别取重量百分比为35-60％的淤泥，其含水量为70至85％、重量百分比为25-55％的废纸，其含水量为35至55％、重量百分比为10-25％的陶土、还有可选择的加入重量百分比为1-3％的沸石、重量百分比为1-2％的生石灰和/或重量百分比达3％的飞灰混合成一种均匀的混合物；然后，将所得到的原材料加工成平均直径为4-6mm的颗粒，紧接着将所述颗粒干燥并随后在950-1050℃下进行烧制。
然而，尤其是考虑到油粘合剂特殊的使用和生产可能性，相对于总原料重量的淤泥组分的重量百分比降至35％以下一直到15％，这样是完全可能的，因此淤泥的重量百分比可以处于20-60％的范围内。
按照本发明方法生产的油粘合剂的优势，一方面在于由此可以额外地有目的性的利用废料，另一方面在于生产出一种满足所有要求的油粘合剂，特别是例如，根据德国标准类别III所要求的油粘合剂的油粘合能力和洗脱性能。
按照本发明所述的方法，其特征还在于，为了制造包含有机和矿物组分的混合物，至少所使用的矿物组分的颗粒度小于100μm。
本发明的一个具体实施方式是利用部分脱水后的城政淤泥，其含水量约为70至85％以及其有机物成分在其总干燥材料中的重量百分比约为40至60％。此外，根据本发明，所利用的废纸的含水量为35至55％，其有机成分在其总干燥材料中的重量百分比大约为70至90％。
按照本发明，所利用的陶土是颗粒度小于100μm，特别是小于60μm的粉末状陶土。
按照本发明所述方法的一个具体实施方式，所利用的生石灰和/或飞灰的比例相当于其在废纸中的比例。在任何情况下，生石灰和飞灰都用作混合物粘度的离子供体和稳定剂。
按照本发明所述方法的另一个特征，陶土成分中重量百分比达3％的陶土被木质素或木质素衍生物与陶土的预混合物替代，优选木质素或木质素衍生物/陶土的预混合物含有木质素或木质素衍生物相对于预先混合物总成分的重量百分比达10％。
按照本发明所述方法的其他特征，所述原材料被挤压形成通心管状颗粒或者还可以随后继续被加工成丸状。
按照本发明方法生产的油粘合剂具有的松散比重为0.4至0.75kg/l，以及其油粘合能力为每千克油粘合剂结合0.7至1.0l油。
根据DIN以及
Figure S2007800033639D00031
确定的，例如，借助室式过滤机或离心机将在预制备混合物中使用的部分市政淤泥的水分排出至水分占其重量百分比的70至85％。在第一个加工步骤中，将所述部分脱水的淤泥、废纸、和磨碎成颗粒小于100μm，优选小于60μm的陶土以及沸石以规定的量在混合设备中相互紧密混合以形成高均质性的原材料，其中优选将后两者预先混合在一起。
所述混合过程可以批量进行。将各组分分批加入并混合或搅拌混合物中的各组分使得原材料的均匀性达到最高标准。均匀性程度的标准是按照后续加工过程所使用的均匀度，在新鲜原材料的任何所给部分的量中精确统计各个组分的分配。
所述原材料在法律定义上来讲代表的是一种次级原材料，其最终状态是一种凝固的膏状物，所述膏状物的均匀性绝大部分(超过50％)在10至100μm(＜100μm)的范围内。
在某种需要下，将木质素和木质素衍生物或含膨润土的木质素和木质素衍生物的混合物加入到陶土中使其重量比达到3％，其中，陶土成分减少了同样的份量。
得到的原材料在烧制之后没有通过造粒装置继续加工生产成标准的粒化颗粒(90％小于4mm)，而是借助螺旋挤压机将原材料加工成连续的圆柱状通心管式结构。其中，挤压时可利用例如孔径为4.5-5mm的筛孔喷嘴(Siebmundstueck)，在继续加工的过程同样通过烧制、必要时通过切碎方法使最终得到的颗粒具有如前面所规定粒化颗粒的标准直径。
所述原材料也能利用制砖技术进行成型，其中，在此情况下所得到的砖形物体必须在烧制之后通过标准粒子区分法消减成颗粒。
特别是在利用制砖技术加工原材料时，必要时在进行单独预干燥后在火炉中例如，回转窑或隧道炉中烧制加工后的原材料，其烧制温度大约为950-1050℃。在烧制原材料时淤泥和废纸的水分以及有机成分会挥发。结果得到一种由高孔隙硅酸盐陶瓷材料构成的粒状产品(颗粒度小于4mm)。所得到的产品可以直接作为油粘合剂使用。
接下来将逐个展示所述混合物组分的特性以及作用：
淤泥
在脱水处理之后，根据不同的方法淤泥的含水量大约占其总重量的70-85％(按照DIN和
Figure S2007800033639D00041
来确定)。在城政淤泥中，有机物质的比例大约占其干燥物质(Trockenmasse)重量的40-60％。淤泥的作用是作为燃尽物质(与废纸一起)在烧制时促使油粘合剂达到相应的孔隙率。淤泥的矿物成分有助于油粘合剂产生陶瓷基质。
废纸
这里使用的废纸具有水分含量大约占其总重量的35-55％。有机成分大约占干燥物质总重量的70-90％。废纸同淤泥一样是一种燃尽物质，并且用作生孔剂。矿物成分有助于使油粘合剂产生陶瓷基质。
陶土粉末
陶土粉末的根本作用是在烧制过程中使油粘合剂生成陶瓷基质(陶瓷结构)。此外，陶土降低了有害物质的流动性，特别是在原材料中的有害物质。在矿物学上此成分基本上指的是一般成分的伊利石-高岭石、方解石/文石和无白云石陶土。
沸石
沸石粉末用于结合有害物质(特指重金属)以及减小原材料的气味，同时也促进陶瓷基质的生成。
生石灰和飞灰
这两个组分作为水份调节剂，由此来促进混合物的稳定性并调节混合物的粘度，同时也作为离子供体。
矿物-有机添加剂
由木质素和膨润土混合物组成的添加剂能促进陶瓷结构的形成(多孔性和陶瓷基质)并且有助于降低有害物质的流动性，特别是在原材料中的有害物质。
如扫描电子显微实验所示，所述烧制而成的产品指的是一种作为油粘合剂来使用的、高孔隙的陶瓷产品，由于水蒸气的挥发以及特别是有机物质的烧尽，使其具有孔隙直径在1-100μm范围内的开孔。依赖于原材料的混合条件和加工方法，所述油粘合剂的松散比重松散比重处于0.42至0.75kg/l之间。
颗粒度的分配标准为：
10％以下的颗粒大于4mm(＞4mm＜10％)
90％以上的颗粒大小在0.125-4mm之间(0.125-4mm＞90％)
10％以下的颗粒小于0.125mm(＜0.125mm＜10％)
油粘合能力为每千克油粘合剂结合0.7至1.0l标准油。
具体实施方式
按照本发明制备的油粘合剂特性的产品的具体实施例：
实施例1：
油粘合剂A：
a)混合物组分：
部分脱水的城市下水道淤泥    废纸    陶土粉末    沸石粉末
(离心分离)                          (＜60μm)   (＜60μm)
56％                        28％    15％        1％
b)化学成分：
利用RFA的测量结果
淤泥：水分含量占其总重量的81.5％；干燥物质中有机成分
重量百分比为56.7％
废纸：水分含量占其总重量的54.9％
c)制造方法：挤压和在回转窑中烧制
d)油粘合剂的矿物含量、主要成分(X光衍射测定法)：
石英：重量百分比大约为17％
赤铁矿：重量百分比大约为8％
低结晶度的长石(斜长岩、钾碱长石)以及
+/-X光非结晶的、类长石硅酸铝化合物和其他X光非晶形的化合物。
e)油粘合剂数据
松散比重          油粘合能力
420g/l            1kg油粘合剂粘合0.700l油
所述油粘合剂满足德国标准类别III的所有条件(特别是油粘合能力和洗脱性能)。
实施例2：
油粘合剂B：
混合物成分：
部分脱水的城政淤泥    废纸    陶土*        沸石粉末**
(腔室压滤器)                  (＜60μm)    (＜60μm)
56％                  28％    15％         1％
淤泥：水分含量占总重量的74.2％；干燥物质中有机成分的重量百分比为56.7％
*陶土粉末，**沸石粉末
生产方法：挤压和在回转窑中烧制
实施例3：
a)混合物成分：
淤泥：重量百分比为37.7％
废纸：重量百分比为47.0％
陶土：重量百分比为10.5％
生石灰：重量百分比为1.5％
飞灰：重量百分比为3.0％
木质素：重量百分比为0.3％
b)油粘合剂数据
b1)颗粒度分布：
  参数   单位   结果
  粗粒成分＞4mm   重量百分比％   ＜0.1
  4mm-0.5mm   重量百分比％   82.0
  0.5mm-0.125mm   重量百分比％   17.8
  细粒成分＜0.125mm   重量百分比％   0.2
b2)松散比重        b3)油粘合能力
690g/l             1kg油粘合剂粘合0.997l油
所述油粘合剂满足德国标准类别III的所有条件(特别是油粘合能力和洗脱性能)。
b4)洗脱检测结果
pH值                     11
导电能力                 600μS/cm
TOC                      4.9mg/l
苯酚指数                 ＜0.01mg/l
砷                       ＜0.01mg/l
铅                       ＜0.02mg/l
镉                       ＜0.002mg/l
铬-VI                    ＜0.01mg/l
铜                       0.03mg/l
镍                       0.013mg/l
汞                       ＜0.0005mg/l
锌                       0.01mg/l
氟化物                   0.47mg/l
铵                       ＜0.5mg/l
氰化物，易清除的         ＜0.01mg/l
AOX                      0.033mg/l
水溶性物质成分           0.49％

Claims (16)

1.一种油粘合剂的制备方法，所述油粘合剂是通过利用在原材料中的废纸和陶土制得的，具有陶瓷基质的颗粒状、开放多孔结构，其特征在于，相对总原材料分别取重量百分比为35-60％的淤泥，其含水量为所述淤泥的70至85％重量百分比；重量百分比为25-55％的废纸，其含水量为所述废纸的35至55％重量百分比；重量百分比为10-25％的陶土；而后，将所述原材料加工成平均直径为4-6mm的颗粒，紧接着将所述颗粒干燥并随后在950-1050℃下进行烧制。
2.根据权利要求1所述的方法，其特征在于，所述原材料中包含有机物和矿物组分，其中使用颗粒度小于100μm的矿物组分，以生成包含有机和矿物组分的混合物。
3.根据权利要求1所述的方法，其特征在于，所述淤泥中有机物质占所述淤泥的总干燥物质40至60％重量百分比。
4.根据权利要求1或2所述的方法，其特征在于，所利用的废纸含有有机成分占所述废纸的总重量的70至90％。
5.根据权利要求1所述的方法，其特征在于，所利用的陶土是颗粒度小于100μm的粉末状陶土。
6.根据权利要求1所述的方法，其特征在于，所利用的陶土是颗粒度小于60μm的粉末状陶土。
7.根据权利要求1所述的方法，其特征在于，所述原材料中还含有生石灰和/或飞灰，以替代废纸。
8.根据权利要求7所述的方法，其特征在于，所述的生石灰和/或飞灰为重量百分比为1-2％的生石灰和/或占重量百分比达3％的飞灰。
9.根据权利要求1所述的方法，其特征在于，在所述的原材料中还加入沸石。
10.根据权利要求9所述的方法，其特征在于，所述的沸石重量百分比为1-3％。
11.根据权利要求1所述的方法，其特征在于，重量百分比达3％的陶土被木质素与陶土的预先混合物替代。
12.根据权利要求11所述的方法，其特征在于，木质素/陶土的预混合物含有的木质素相对于预先混合物总成分的重量百分比达10％。
13.根据权利要求1至3中任意一项所述的方法，其特征在于，原材料被挤压形成空心管状的颗粒。
14.根据权利要求1至3中任意一项所述的方法，其特征在于，原材料被进一步加工形成丸状。
15.根据权利要求1-12所述的任意一种方法制备的油粘合剂，其特征在于，所述油粘合剂具有0.4至0.75kg/l的松散比重，其中，所述油粘合剂的总原材料含有重量百分比为35-60％的淤泥，其含水量为所述淤泥的70至85％重量百分比、重量百分比为25-55％的废纸，其含水量为所述废纸的35至55％重量百分比、重量百分比为10-25％的陶土。
16.根据权利要求1-12所述任意一种方法制备的油粘合剂，其特征在于，所述油粘合剂具有油粘合能力为每千克油粘合剂结合0.7至1.0升油，其中，所述油粘合剂的总原材料含有重量百分比为35-60％的淤泥，其含水量为所述淤泥的70至85％重量百分比、重量百分比为25-55％的废纸，其含水量为所述废纸的35至55％重量百分比、重量百分比为10-25％的陶土。
CN2007800033639A 2006-01-25 2007-01-22 一种油粘合剂的制备方法以及由此方法制备的油粘合剂 Expired - Fee Related CN101374596B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
AT0011006A AT503198B1 (de) 2006-01-25 2006-01-25 Verfahren zur herstellung eines ölbindemittels und danach hergestellte ölbindemittel
ATA110/2006 2006-01-25
PCT/AT2007/000024 WO2007085031A1 (de) 2006-01-25 2007-01-22 Verfahren zur herstellung eines ölbindemittels und danach hergestelltes ölbindemittel

Publications (2)

Publication Number Publication Date
CN101374596A CN101374596A (zh) 2009-02-25
CN101374596B true CN101374596B (zh) 2012-06-13

Family

ID=38009611

Family Applications (1)

Application Number Title Priority Date Filing Date
CN2007800033639A Expired - Fee Related CN101374596B (zh) 2006-01-25 2007-01-22 一种油粘合剂的制备方法以及由此方法制备的油粘合剂

Country Status (15)

Country Link
US (1) US7932203B2 (zh)
EP (1) EP1979091B1 (zh)
CN (1) CN101374596B (zh)
AT (1) AT503198B1 (zh)
BR (1) BRPI0707240B1 (zh)
DK (1) DK1979091T3 (zh)
EG (1) EG25152A (zh)
ES (1) ES2681680T3 (zh)
HK (1) HK1123769A1 (zh)
HU (1) HUE038415T2 (zh)
MX (1) MX2008009554A (zh)
PL (1) PL1979091T3 (zh)
PT (1) PT1979091T (zh)
RU (1) RU2389546C1 (zh)
WO (1) WO2007085031A1 (zh)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102007006137A1 (de) * 2007-02-07 2008-08-21 First Vandalia Luxembourg Holding S.A. Misch-Produkt
AT506602B1 (de) * 2008-03-17 2010-03-15 Commerzialbank Mattersburg Im Verfahren zur herstellung eines ölbindemittels
IN2015DN01683A (zh) * 2012-10-17 2015-07-03 Saudi Arabian Oil Co

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0353605A1 (de) * 1988-07-31 1990-02-07 Günther Dr. Marx Verwendung eines mineralischen Stoffes zum Aufsaugen von toxischen Flüssigkeiten, Emulsionen oder Suspensionen

Family Cites Families (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2850624A1 (de) 1978-11-22 1980-06-04 Kneer Franz X Verfahren zur herstellung eines aufsaugenden oelbindemittels
DE3071051D1 (en) 1980-03-10 1985-10-10 Bbc Brown Boveri & Cie Excluding device for gaseous media comprising an equipment for damping of selfexciting acoustic vibrations in cavities
JPS57165034A (en) * 1982-03-15 1982-10-09 Kozo Shibata Porous material for adsorbing oils
JPS61284A (ja) 1984-06-12 1986-01-06 Tatsu Amaike 油吸着粒
DE3430731C2 (de) 1984-08-21 1994-11-24 Handelskontor Ludbert Graf Zu Herstellungsverfahren für keramische Pellets
DE3728812A1 (de) * 1987-04-08 1988-10-20 Marx Guenther Mineralischer stoff, verfahren zu seiner herstellung und verwendung desselben
US4872993A (en) * 1988-02-24 1989-10-10 Harrison George C Waste treatment
DE3908172A1 (de) 1989-03-13 1990-09-20 Andreas Dipl Ing Gumbmann Poroeses mineralisches leichtzuschlagstoffgranulat sowie verfahren zu seiner herstellung
US5268131A (en) * 1989-11-30 1993-12-07 Harrison George C Method for making light weight ceramic particles
DE4117916A1 (de) 1991-05-31 1992-12-03 Zuercher Ziegeleien Verfahren zur herstellung eines harten, poroesen granulates, granulat und vorrichtung zur herstellung eines granulates
JPH06100284A (ja) * 1992-09-18 1994-04-12 Hitachi Kiden Kogyo Ltd リフテイングマグネツト用電源装置
JPH0718290A (ja) * 1993-07-02 1995-01-20 Nippon Telegr & Teleph Corp <Ntt> 油吸収材および油吸収器
DE4327159A1 (de) 1993-08-12 1995-02-16 Sued Chemie Ag Verfahren zur Herstellung von Sorptionsmitteln auf der Basis von Smektiten und cellulosehaltigen Materialien mit niedrigem Schüttgewicht
JP3338973B2 (ja) * 1994-03-28 2002-10-28 日本電信電話株式会社 油吸収材とその製造方法
WO1997025286A1 (en) * 1996-01-05 1997-07-17 Asset Associates Limited Improvements in or relating to the production of rock wool
KR100284110B1 (ko) * 1998-07-28 2001-04-02 김호성 산업부산물(폐기물)을주재로한인공어초의제조방법
US6962616B1 (en) 2003-08-08 2005-11-08 Research Foundation Of The City University Of New York Preparation of adsorbents from organic fertilizer and mineral oil and their application for removal of acidic gases from sulfur containing wet gas streams
AT501328B1 (de) 2005-01-18 2007-02-15 Abwasserreinigung Region Dornb Ölbindemittel

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0353605A1 (de) * 1988-07-31 1990-02-07 Günther Dr. Marx Verwendung eines mineralischen Stoffes zum Aufsaugen von toxischen Flüssigkeiten, Emulsionen oder Suspensionen

Also Published As

Publication number Publication date
EP1979091A1 (de) 2008-10-15
RU2389546C1 (ru) 2010-05-20
HK1123769A1 (en) 2009-06-26
PL1979091T3 (pl) 2018-11-30
BRPI0707240A2 (pt) 2011-04-26
CN101374596A (zh) 2009-02-25
AT503198B1 (de) 2008-10-15
AT503198A1 (de) 2007-08-15
EP1979091B1 (de) 2018-05-02
WO2007085031A1 (de) 2007-08-02
RU2008134462A (ru) 2010-02-27
HUE038415T2 (hu) 2018-10-29
BRPI0707240B1 (pt) 2016-12-27
MX2008009554A (es) 2008-10-21
ES2681680T3 (es) 2018-09-14
PT1979091T (pt) 2018-08-03
US20090203514A1 (en) 2009-08-13
EG25152A (en) 2011-09-26
DK1979091T3 (en) 2018-08-13
US7932203B2 (en) 2011-04-26

Similar Documents

Publication Publication Date Title
CN100522854C (zh) 污水厂产生的脱水污泥进行固化/稳定化处理的方法
KR101925418B1 (ko) 인산비료의 제조 방법
CN105753279B (zh) 一种淤/污泥固化剂及其使用方法
JP2007306844A (ja) 廃棄物を用いた緑化資材の製造方法及び緑化資材
CN101265070A (zh) 一种污泥固化剂以及应用
CN102712534B (zh) 用于从废料制备复合材料的方法和所得材料
KR101334533B1 (ko) 슬러지고화제조성물 및 이를 이용한 복토재제조방법
CN107673572A (zh) 一种污淤泥固化剂及其应用
JP2014047121A (ja) 石炭灰造粒体および造粒体混合物
US20100137126A1 (en) Mixed product
CN114409432B (zh) 一种利用垃圾焚烧炉渣和钼尾矿制备水处理陶粒的方法
CN101374596B (zh) 一种油粘合剂的制备方法以及由此方法制备的油粘合剂
CN101293768A (zh) 一种生物滤料及其制备方法
DE102011112657B4 (de) Gasabsorptionsgranulat sowie seine Verwendung
CN101417851B (zh) 一种降低活性污泥中重金属生物有效性的方法
CN1291926C (zh) 一种用于废水处理球型煤质微孔生物滤料的制造方法
JP2007223841A (ja) 廃棄物スラグを主原料とする人工骨材の製造方法
JP6199325B2 (ja) 発泡性焼成体とその製造方法
JP2002512935A (ja) セメント状混合物
JP2005255496A (ja) 下水汚泥焼却灰を用いたセラミック製品の製造方法および得られたセラミック製品
EP3140055A1 (en) A method of disposal and utilisation of dusts from an incineration installation and sludge from flotation enrichment of non-ferrous metal ores containing hazardous substances in the process of light aggregate production for the construction industry
JP7007768B1 (ja) 泥土の改質材及び泥土の改質方法、泥土の改質材の製造方法
CN105439535B (zh) 干化/半干化污泥理化性能调理剂、应用方法
JP6227267B2 (ja) 石膏を含有した特定有害物質の不溶化固化材及びこれを用いた土壌の改良方法
CN101481150A (zh) 一种污水处理剂及其制备方法

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
REG Reference to a national code

Ref country code: HK

Ref legal event code: DE

Ref document number: 1123769

Country of ref document: HK

C14 Grant of patent or utility model
GR01 Patent grant
REG Reference to a national code

Ref country code: HK

Ref legal event code: GR

Ref document number: 1123769

Country of ref document: HK

CF01 Termination of patent right due to non-payment of annual fee
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20120613

Termination date: 20220122