CN101134842B - 低密度硬质增强聚氨酯及其生产方法 - Google Patents

低密度硬质增强聚氨酯及其生产方法 Download PDF

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Publication number
CN101134842B
CN101134842B CN2007101472387A CN200710147238A CN101134842B CN 101134842 B CN101134842 B CN 101134842B CN 2007101472387 A CN2007101472387 A CN 2007101472387A CN 200710147238 A CN200710147238 A CN 200710147238A CN 101134842 B CN101134842 B CN 101134842B
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China
Prior art keywords
isocyanate
reactive component
polyvalent alcohol
component
urethane
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Expired - Fee Related
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CN2007101472387A
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English (en)
Chinese (zh)
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CN101134842A (zh
Inventor
U·E·尤尼斯
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Covestro LLC
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Bayer MaterialScience LLC
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08Processes
    • C08G18/10Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30Low-molecular-weight compounds
    • C08G18/36Hydroxylated esters of higher fatty acids
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40High-molecular-weight compounds
    • C08G18/48Polyethers
    • C08G18/4804Two or more polyethers of different physical or chemical nature
    • C08G18/482Mixtures of polyethers containing at least one polyether containing nitrogen
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40High-molecular-weight compounds
    • C08G18/48Polyethers
    • C08G18/50Polyethers having heteroatoms other than oxygen
    • C08G18/5021Polyethers having heteroatoms other than oxygen having nitrogen
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0085Use of fibrous compounding ingredients
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/122Hydrogen, oxygen, CO2, nitrogen or noble gases
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00Foam properties
    • C08G2110/0025Foam properties rigid
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00Foam properties
    • C08G2110/0041Foam properties having specified density
    • C08G2110/0066≥ 150kg/m3
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2375/00Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
    • C08J2375/04Polyurethanes

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Reinforced Plastic Materials (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
CN2007101472387A 2006-08-31 2007-08-30 低密度硬质增强聚氨酯及其生产方法 Expired - Fee Related CN101134842B (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US11/513,764 US20080058468A1 (en) 2006-08-31 2006-08-31 Low density rigid reinforced polyurethanes and a process for their production
US11/513,764 2006-08-31

Publications (2)

Publication Number Publication Date
CN101134842A CN101134842A (zh) 2008-03-05
CN101134842B true CN101134842B (zh) 2011-10-05

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Family Applications (1)

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CN2007101472387A Expired - Fee Related CN101134842B (zh) 2006-08-31 2007-08-30 低密度硬质增强聚氨酯及其生产方法

Country Status (9)

Country Link
US (1) US20080058468A1 (enExample)
EP (1) EP1894956A1 (enExample)
JP (1) JP5319090B2 (enExample)
KR (1) KR101471663B1 (enExample)
CN (1) CN101134842B (enExample)
BR (1) BRPI0703686A (enExample)
CA (1) CA2599099A1 (enExample)
MX (1) MX2007010441A (enExample)
RU (1) RU2007132674A (enExample)

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DE102007050100A1 (de) * 2007-10-19 2009-04-23 Entwicklungsgesellschaft für Akustik (EfA) mit beschränkter Haftung Schallisolierung mit CO2-beladener Kompakt-Polyurethan-Schaumstoff (RIM)-Schicht
US20090313909A1 (en) * 2008-06-20 2009-12-24 Bayer Materialscience Llc Low density semi-rigid flame resistant foams
CN102317339B (zh) * 2009-02-11 2014-10-22 Ppg工业俄亥俄公司 纤维增强的聚合复合材料及其制造方法
EP2287254A1 (de) * 2009-07-10 2011-02-23 Evonik Goldschmidt GmbH Kompositformkörper enthaltend oberflächenaktives Additiv
US11113299B2 (en) 2009-12-01 2021-09-07 Apple Inc. System and method for metadata transfer among search entities
RU2557234C2 (ru) * 2010-10-22 2015-07-20 Наньцзин Хунбаоли Полиуритэйн Ко., Лтд. Быстрореагирующая композиция для приготовления твердой полиуретановой пены низкой плотности
JP2014524965A (ja) 2011-07-25 2014-09-25 ノボマー, インコーポレイテッド ポリウレタンに使用するための脂肪族ポリカーボネート
US20130072588A1 (en) * 2011-09-21 2013-03-21 Bayer Materialscience Llc Medium density foams having good impact resistance and a process for their production
WO2013127850A1 (en) * 2012-02-29 2013-09-06 Bayer Intellectual Property Gmbh 2-k pultrusion formulation and process
CN102731989B (zh) * 2012-07-17 2015-04-29 上海珀理玫化学科技有限公司 拉挤用聚氨酯树脂的复合材料及其制备方法
ES2752043T3 (es) 2012-11-07 2020-04-02 Saudi Aramco Tech Co Composiciones de espuma de poliuretano de gran resistencia y métodos
JP6121159B2 (ja) * 2012-12-26 2017-04-26 コベストロ、ドイチュラント、アクチエンゲゼルシャフトCovestro Deutschland Ag 植物繊維で補強された発泡ポリウレタン成形品およびその製造方法
US20140265000A1 (en) 2013-03-14 2014-09-18 Bayer Materialscience, Llc Water-clear aliphatic polyurethane pultrusion formulations and processes
US9200132B2 (en) * 2013-03-15 2015-12-01 Covestro Llc Process for the production of spray polyurethane elastomers and the elastomers produced by this process
US20160115288A1 (en) * 2013-05-13 2016-04-28 Novomer, Inc. Co2 containing foams and related methods
CN104290765A (zh) * 2014-10-28 2015-01-21 南车石家庄车辆有限公司 铁路棚车复合地板
JP6909074B2 (ja) * 2017-06-28 2021-07-28 サンスター技研株式会社 ポリウレタン組成物
CN109836807A (zh) * 2019-01-24 2019-06-04 天津市大邱庄泡沫塑料有限公司 一种软质聚氨酯泡沫塑料及其加工方法
CN112239594A (zh) * 2019-07-19 2021-01-19 施建辉 一种静音效果好的骰子及其制作工艺
US20210040362A1 (en) * 2019-08-08 2021-02-11 Covestro Llc Flexible polyureas for flexible packaging adhesive without aromatic amine migration
US20210039359A1 (en) * 2019-08-08 2021-02-11 Covestro Llc Flexibilized polyurethanes for flexible packaging adhesive without aromatic amine migration
CN111607118A (zh) * 2020-06-15 2020-09-01 斯匹格科技(厦门)有限公司 一种基于微孔发泡技术的碳纤维增强减震缓冲材料的制作方法
KR20230013746A (ko) 2021-07-20 2023-01-27 현대자동차주식회사 폴리올 조성물, 이를 이용하여 폴리우레탄 폼을 제조하는 방법 및 이 방법을 통해 제조된 폴리우레탄 폼
CN114672149B (zh) * 2021-09-09 2025-11-18 巴斯夫欧洲公司 聚氨酯复合材料、其制备方法和含有该聚氨酯复合材料的覆盖制品
US20240376250A1 (en) * 2021-09-10 2024-11-14 Sekisui Chemical Co., Ltd. Curable resin material, resin molded body, and method for producing resin molded body
CN116350036A (zh) * 2023-04-12 2023-06-30 东莞市楷模家居用品制造有限公司 一种全人体睡姿智能调节卧具及其方法

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4882363A (en) * 1987-12-11 1989-11-21 Bayer Aktiengesellschaft Process for the production of polyurethane foam moldings
US5216035A (en) * 1992-06-22 1993-06-01 Basf Corporation Water-blown polyurethane integral skin foam
EP0936240A2 (de) * 1998-02-13 1999-08-18 Basf Aktiengesellschaft Verfahren zur Herstellung von Hartschaumstoffen auf Isocyanatbasis
US6458861B1 (en) * 2001-01-18 2002-10-01 Bayer Antwerp N.V. Carbon dioxide blown low density, flexible microcellular elastomers suitable for preparing shoe components
CN1487006A (zh) * 2002-09-13 2004-04-07 阿基里斯株式会社 硬质聚氨酯泡沫塑料的制备方法
CN1514849A (zh) * 2001-01-24 2004-07-21 亨茨曼国际有限公司 具有降低的塑模停留时间和改善品质的塑模泡沫制品

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US4073840A (en) * 1973-10-19 1978-02-14 Exxon Research & Engineering Co. Method for forming a fiber reinforced foam article
US4680214A (en) * 1986-03-12 1987-07-14 Polymetrics Corporation Reinforced foam composites
JPH06271643A (ja) * 1993-03-23 1994-09-27 Nippon Polyurethane Ind Co Ltd ポリウレタンフォームの製造方法
AU1670399A (en) * 1997-12-05 1999-06-28 Bayer Aktiengesellschaft Polyurethane and polyurethane/urea heat-cured and moisture-cured elastomers withimproved physical properties
JP3831149B2 (ja) * 1999-05-27 2006-10-11 住化バイエルウレタン株式会社 ポリウレタン反応射出成形発泡体の製造法
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Patent Citations (6)

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US4882363A (en) * 1987-12-11 1989-11-21 Bayer Aktiengesellschaft Process for the production of polyurethane foam moldings
US5216035A (en) * 1992-06-22 1993-06-01 Basf Corporation Water-blown polyurethane integral skin foam
EP0936240A2 (de) * 1998-02-13 1999-08-18 Basf Aktiengesellschaft Verfahren zur Herstellung von Hartschaumstoffen auf Isocyanatbasis
US6458861B1 (en) * 2001-01-18 2002-10-01 Bayer Antwerp N.V. Carbon dioxide blown low density, flexible microcellular elastomers suitable for preparing shoe components
CN1514849A (zh) * 2001-01-24 2004-07-21 亨茨曼国际有限公司 具有降低的塑模停留时间和改善品质的塑模泡沫制品
CN1487006A (zh) * 2002-09-13 2004-04-07 阿基里斯株式会社 硬质聚氨酯泡沫塑料的制备方法

Also Published As

Publication number Publication date
CN101134842A (zh) 2008-03-05
JP2008056928A (ja) 2008-03-13
JP5319090B2 (ja) 2013-10-16
CA2599099A1 (en) 2008-02-29
BRPI0703686A (pt) 2008-04-22
MX2007010441A (es) 2009-02-13
RU2007132674A (ru) 2009-03-10
US20080058468A1 (en) 2008-03-06
KR101471663B1 (ko) 2014-12-10
KR20080020558A (ko) 2008-03-05
EP1894956A1 (en) 2008-03-05

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Granted publication date: 20111005

Termination date: 20180830