CN101085754B - 六氟异丁烯及其高级同系物的氟代硫酸酯及它们的衍生物 - Google Patents
六氟异丁烯及其高级同系物的氟代硫酸酯及它们的衍生物 Download PDFInfo
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- CN101085754B CN101085754B CN2007101278546A CN200710127854A CN101085754B CN 101085754 B CN101085754 B CN 101085754B CN 2007101278546 A CN2007101278546 A CN 2007101278546A CN 200710127854 A CN200710127854 A CN 200710127854A CN 101085754 B CN101085754 B CN 101085754B
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- QMIWYOZFFSLIAK-UHFFFAOYSA-N 3,3,3-trifluoro-2-(trifluoromethyl)prop-1-ene Chemical group FC(F)(F)C(=C)C(F)(F)F QMIWYOZFFSLIAK-UHFFFAOYSA-N 0.000 title abstract description 36
- UQSQSQZYBQSBJZ-UHFFFAOYSA-M fluorosulfate group Chemical group S(=O)(=O)([O-])F UQSQSQZYBQSBJZ-UHFFFAOYSA-M 0.000 title abstract description 3
- -1 fluoro alkoxide Chemical class 0.000 claims description 76
- 239000012434 nucleophilic reagent Substances 0.000 claims description 48
- 238000000034 method Methods 0.000 claims description 20
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- 238000006243 chemical reaction Methods 0.000 abstract description 47
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- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 150000003384 small molecules Chemical class 0.000 description 1
- 239000012279 sodium borohydride Substances 0.000 description 1
- 229910000033 sodium borohydride Inorganic materials 0.000 description 1
- FVAUCKIRQBBSSJ-UHFFFAOYSA-M sodium iodide Chemical compound [Na+].[I-] FVAUCKIRQBBSSJ-UHFFFAOYSA-M 0.000 description 1
- 238000006277 sulfonation reaction Methods 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- WRECIMRULFAWHA-UHFFFAOYSA-N trimethyl borate Chemical compound COB(OC)OC WRECIMRULFAWHA-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C303/00—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides
- C07C303/02—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of sulfonic acids or halides thereof
- C07C303/22—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of sulfonic acids or halides thereof from sulfonic acids, by reactions not involving the formation of sulfo or halosulfonyl groups; from sulfonic halides by reactions not involving the formation of halosulfonyl groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C21/00—Acyclic unsaturated compounds containing halogen atoms
- C07C21/02—Acyclic unsaturated compounds containing halogen atoms containing carbon-to-carbon double bonds
- C07C21/18—Acyclic unsaturated compounds containing halogen atoms containing carbon-to-carbon double bonds containing fluorine
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C253/00—Preparation of carboxylic acid nitriles
- C07C253/16—Preparation of carboxylic acid nitriles by reaction of cyanides with lactones or compounds containing hydroxy groups or etherified or esterified hydroxy groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C255/00—Carboxylic acid nitriles
- C07C255/01—Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms
- C07C255/10—Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms containing cyano groups and halogen atoms, or nitro or nitroso groups, bound to the same acyclic carbon skeleton
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C305/00—Esters of sulfuric acids
- C07C305/26—Halogenosulfates, i.e. monoesters of halogenosulfuric acids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C43/00—Ethers; Compounds having groups, groups or groups
- C07C43/02—Ethers
- C07C43/03—Ethers having all ether-oxygen atoms bound to acyclic carbon atoms
- C07C43/14—Unsaturated ethers
- C07C43/17—Unsaturated ethers containing halogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F14/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F14/18—Monomers containing fluorine
- C08F14/28—Hexafluoropropene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F214/18—Monomers containing fluorine
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Toxicology (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Epoxy Compounds (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US38052802P | 2002-05-14 | 2002-05-14 | |
| US60/380528 | 2002-05-14 | ||
| US60/380,528 | 2002-05-14 |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB038108488A Division CN100334074C (zh) | 2002-05-14 | 2003-05-14 | 六氟异丁烯及其高级同系物的氟代硫酸酯及它们的衍生物 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101085754A CN101085754A (zh) | 2007-12-12 |
| CN101085754B true CN101085754B (zh) | 2013-01-23 |
Family
ID=29549973
Family Applications (5)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2007101278546A Expired - Fee Related CN101085754B (zh) | 2002-05-14 | 2003-05-14 | 六氟异丁烯及其高级同系物的氟代硫酸酯及它们的衍生物 |
| CN2007101278550A Expired - Fee Related CN101085752B (zh) | 2002-05-14 | 2003-05-14 | 六氟异丁烯及其高级同系物的氟代硫酸酯及它们的衍生物 |
| CNB038108488A Expired - Fee Related CN100334074C (zh) | 2002-05-14 | 2003-05-14 | 六氟异丁烯及其高级同系物的氟代硫酸酯及它们的衍生物 |
| CN2007101278565A Expired - Fee Related CN101085753B (zh) | 2002-05-14 | 2003-05-14 | 六氟异丁烯及其高级同系物的氟代硫酸酯及它们的衍生物 |
| CNA2007101278531A Pending CN101092378A (zh) | 2002-05-14 | 2003-05-14 | 六氟异丁烯及其高级同系物的氟代硫酸酯及它们的衍生物 |
Family Applications After (4)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2007101278550A Expired - Fee Related CN101085752B (zh) | 2002-05-14 | 2003-05-14 | 六氟异丁烯及其高级同系物的氟代硫酸酯及它们的衍生物 |
| CNB038108488A Expired - Fee Related CN100334074C (zh) | 2002-05-14 | 2003-05-14 | 六氟异丁烯及其高级同系物的氟代硫酸酯及它们的衍生物 |
| CN2007101278565A Expired - Fee Related CN101085753B (zh) | 2002-05-14 | 2003-05-14 | 六氟异丁烯及其高级同系物的氟代硫酸酯及它们的衍生物 |
| CNA2007101278531A Pending CN101092378A (zh) | 2002-05-14 | 2003-05-14 | 六氟异丁烯及其高级同系物的氟代硫酸酯及它们的衍生物 |
Country Status (7)
| Country | Link |
|---|---|
| US (6) | US7276624B2 (https=) |
| EP (1) | EP1513801B1 (https=) |
| JP (2) | JP4472519B2 (https=) |
| CN (5) | CN101085754B (https=) |
| DE (1) | DE60336720D1 (https=) |
| RU (1) | RU2004136314A (https=) |
| WO (1) | WO2003097588A2 (https=) |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7276624B2 (en) * | 2002-05-14 | 2007-10-02 | E. I. Du Pont De Nemours And Company | Fluorosulfates of hexafluoroisobutylene and its higher homologs |
| CN101090767A (zh) * | 2004-12-22 | 2007-12-19 | 纳幕尔杜邦公司 | 用于光化学反应的末端官能化全氟(烷基乙烯基醚)的官能化共聚物的反应器壁、增加烃和卤代烃的氟含量的方法和烯烃的制备 |
| EP2377611A3 (en) | 2004-12-22 | 2012-01-18 | E. I. du Pont de Nemours and Company | Process for producing an olefinic compound by photochemical reactions |
| AU2007316613B2 (en) * | 2006-11-09 | 2013-11-28 | Boehringer Ingelheim International Gmbh | Combination therapy with SGLT-2 inhibitors and their pharmaceutical compositions |
| JP5136070B2 (ja) * | 2008-01-15 | 2013-02-06 | 旭硝子株式会社 | パーフルオロアリルブロミドの製造方法 |
| US20100004518A1 (en) * | 2008-07-03 | 2010-01-07 | Masimo Laboratories, Inc. | Heat sink for noninvasive medical sensor |
| WO2011122573A1 (ja) * | 2010-03-29 | 2011-10-06 | ダイキン工業株式会社 | ３－クロロ－ペンタフルオロプロペンの製造方法 |
| RU2430914C1 (ru) * | 2010-04-09 | 2011-10-10 | Федеральное государственное унитарное предприятие "Ордена Ленина и ордена Трудового Красного Знамени научно-исследовательский институт синтетического каучука имени академика С.В. Лебедева" | Перфтор[(2-фторсульфат)этилаллиловый] эфир |
| EP2588507B1 (en) * | 2010-07-01 | 2014-06-04 | Solvay Specialty Polymers Italy S.p.A. | Process for the treatment of sulfonyl fluoride polymers |
| CN102225980B (zh) * | 2011-04-29 | 2012-11-21 | 内蒙古三爱富万豪氟化工有限公司 | 一种含氟醚端基结构的聚偏氟乙烯树脂及其制备方法 |
| JP5793996B2 (ja) * | 2011-06-29 | 2015-10-14 | セントラル硝子株式会社 | フルオロ硫酸芳香環エステル類の製造方法 |
| CN108290823B (zh) * | 2015-12-02 | 2021-01-22 | 3M创新有限公司 | 烯丙基封端的不饱和氢氟胺和烯丙基封端的不饱和氢氟醚化合物以及其使用方法 |
| KR102374272B1 (ko) * | 2016-05-09 | 2022-03-15 | 쓰리엠 이노베이티브 프로퍼티즈 컴파니 | 하이드로플루오로올레핀 및 이의 사용 방법 |
| CN107286061A (zh) * | 2017-06-09 | 2017-10-24 | 武汉理工大学 | 一种酚类化合物脱氧还原方法 |
| EP3890869A1 (en) * | 2018-12-06 | 2021-10-13 | Grillo-Werke AG | Method for the recycling or disposal of halocarbons |
| CN114644539B (zh) * | 2022-04-01 | 2023-07-14 | 安徽农业大学 | 一种含烯烃的二氟芳氧醚的合成方法及其在农药中的用途 |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1219063A (en) * | 1968-09-10 | 1971-01-13 | Allied Chem | Process for preparing fluoroisobutylenes |
| GB2027709A (en) * | 1978-08-08 | 1980-02-27 | Du Pont | Perfluorallyl Fluorosulfate and its Sultone and Processes for their Preparation |
Family Cites Families (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2352554A (en) * | 1939-06-02 | 1944-06-27 | Redington Co F B | Stamp feeding and gluing mechanism |
| US2852554A (en) | 1956-07-12 | 1958-09-16 | Du Pont | Alpha-sulfopolyfluoromonocarboxylic acids and derivatives hydrolyzable thereto |
| US3862978A (en) * | 1967-08-24 | 1975-01-28 | Dow Chemical Co | Catalytic synthesis of organic halogen compounds from an ethylenically unsaturated compound and a halogenated organic compound |
| US3655786A (en) * | 1968-09-10 | 1972-04-11 | Allied Chem | Process for preparing fluoroisobutylenes and novel product |
| US3706723A (en) | 1970-04-29 | 1972-12-19 | Allied Chem | Copolymer of 3,3,3 - trifluoro-2-trifluoromethyl propene and vinylidene fluoride |
| US4131740A (en) | 1977-04-20 | 1978-12-26 | E. I. Du Pont De Nemours And Company | Alkyl perfluoro-ω-fluoroformyl esters and their preparation |
| US4235804A (en) | 1978-08-08 | 1980-11-25 | E. I. Du Pont De Nemours And Company | Preparation of perfluoroallyl fluorosulfate |
| US4273728A (en) * | 1979-03-14 | 1981-06-16 | E. I. Du Pont De Nemours And Company | Polyfluoroallyloxy compounds, their preparation and copolymers therefrom |
| DE3464866D1 (en) | 1983-03-07 | 1987-08-27 | Ausimont Usa | A process of rotational molding fluoropolymers |
| US4704324A (en) * | 1985-04-03 | 1987-11-03 | The Dow Chemical Company | Semi-permeable membranes prepared via reaction of cationic groups with nucleophilic groups |
| KR100320251B1 (ko) | 1994-06-09 | 2002-01-12 | 이노우에 노리유끼 | 불소 함유 올레핀 |
| US6025092A (en) | 1998-02-13 | 2000-02-15 | E. I. Du Pont De Nemours And Company | Fluorinated ionomers and their uses |
| KR100750752B1 (ko) | 1999-03-16 | 2007-08-20 | 이 아이 듀폰 디 네모아 앤드 캄파니 | 플라스틱 렌즈 및 장치용 저반사성 플루오로중합체 층 |
| EP1238310A1 (en) | 1999-11-17 | 2002-09-11 | E.I. Du Pont De Nemours And Company | Ultraviolet and vacuum ultraviolet transparent polymer compositions and their uses |
| IT1318488B1 (it) | 2000-04-21 | 2003-08-25 | Ausimont Spa | Fluorovinileteri e polimeri da essi ottenibili. |
| WO2002093261A1 (en) | 2001-05-14 | 2002-11-21 | E.I. Du Pont De Nemours And Company | Use of partially fluorinated polymers in applications requiring transparency in the ultraviolet and vacuum ultraviolet |
| US6713567B2 (en) | 2001-07-13 | 2004-03-30 | E. I. Du Pont De Nemours And Company | Method for forming fluorinated ionomers |
| US6653515B2 (en) * | 2001-12-14 | 2003-11-25 | Ballard Power Systems Inc. | Synthesis of α, β, β-trifluorostyrene via in-situ formation of trifluorovinyl metal halide |
| US7276624B2 (en) * | 2002-05-14 | 2007-10-02 | E. I. Du Pont De Nemours And Company | Fluorosulfates of hexafluoroisobutylene and its higher homologs |
| US7129009B2 (en) * | 2002-05-14 | 2006-10-31 | E. I. Du Pont De Nemours And Company | Polymer-liquid compositions useful in ultraviolet and vacuum ultraviolet uses |
-
2003
- 2003-05-09 US US10/435,003 patent/US7276624B2/en not_active Expired - Lifetime
- 2003-05-14 DE DE60336720T patent/DE60336720D1/de not_active Expired - Lifetime
- 2003-05-14 CN CN2007101278546A patent/CN101085754B/zh not_active Expired - Fee Related
- 2003-05-14 WO PCT/US2003/015107 patent/WO2003097588A2/en not_active Ceased
- 2003-05-14 CN CN2007101278550A patent/CN101085752B/zh not_active Expired - Fee Related
- 2003-05-14 RU RU2004136314/04A patent/RU2004136314A/ru not_active Application Discontinuation
- 2003-05-14 JP JP2004505321A patent/JP4472519B2/ja not_active Expired - Fee Related
- 2003-05-14 CN CNB038108488A patent/CN100334074C/zh not_active Expired - Fee Related
- 2003-05-14 CN CN2007101278565A patent/CN101085753B/zh not_active Expired - Fee Related
- 2003-05-14 EP EP03728891A patent/EP1513801B1/en not_active Expired - Lifetime
- 2003-05-14 CN CNA2007101278531A patent/CN101092378A/zh active Pending
-
2007
- 2007-03-22 US US11/726,485 patent/US7579499B2/en not_active Expired - Fee Related
- 2007-03-22 US US11/726,772 patent/US20070167589A1/en not_active Abandoned
- 2007-03-22 US US11/726,488 patent/US7531689B2/en not_active Expired - Fee Related
- 2007-03-22 US US11/726,449 patent/US7301059B2/en not_active Expired - Lifetime
-
2009
- 2009-04-22 US US12/428,041 patent/US20090203865A1/en not_active Abandoned
- 2009-11-16 JP JP2009260902A patent/JP5149885B2/ja not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1219063A (en) * | 1968-09-10 | 1971-01-13 | Allied Chem | Process for preparing fluoroisobutylenes |
| GB2027709A (en) * | 1978-08-08 | 1980-02-27 | Du Pont | Perfluorallyl Fluorosulfate and its Sultone and Processes for their Preparation |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2003097588A2 (en) | 2003-11-27 |
| US7531689B2 (en) | 2009-05-12 |
| CN100334074C (zh) | 2007-08-29 |
| JP4472519B2 (ja) | 2010-06-02 |
| DE60336720D1 (de) | 2011-05-26 |
| US20040019237A1 (en) | 2004-01-29 |
| CN101092378A (zh) | 2007-12-26 |
| EP1513801A2 (en) | 2005-03-16 |
| CN101085753B (zh) | 2012-07-18 |
| US7301059B2 (en) | 2007-11-27 |
| JP2005525428A (ja) | 2005-08-25 |
| US20070167589A1 (en) | 2007-07-19 |
| US7579499B2 (en) | 2009-08-25 |
| CN101085753A (zh) | 2007-12-12 |
| CN101085752B (zh) | 2012-07-11 |
| JP5149885B2 (ja) | 2013-02-20 |
| CN1665779A (zh) | 2005-09-07 |
| US20090203865A1 (en) | 2009-08-13 |
| JP2010031058A (ja) | 2010-02-12 |
| US20070167640A1 (en) | 2007-07-19 |
| CN101085754A (zh) | 2007-12-12 |
| EP1513801B1 (en) | 2011-04-13 |
| WO2003097588A3 (en) | 2004-04-22 |
| US20070167652A1 (en) | 2007-07-19 |
| RU2004136314A (ru) | 2005-05-10 |
| US20070167651A1 (en) | 2007-07-19 |
| CN101085752A (zh) | 2007-12-12 |
| US7276624B2 (en) | 2007-10-02 |
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| Date | Code | Title | Description |
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| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20171227 Address after: Delaware, USA Patentee after: Como Efsee Co.,Ltd. Address before: Wilmington, Delaware, USA Patentee before: E. I. du Pont de Nemours and Co. |
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| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20130123 Termination date: 20200514 |