CN101070261B - 链增长反应方法 - Google Patents

链增长反应方法 Download PDF

Info

Publication number
CN101070261B
CN101070261B CN2007101264295A CN200710126429A CN101070261B CN 101070261 B CN101070261 B CN 101070261B CN 2007101264295 A CN2007101264295 A CN 2007101264295A CN 200710126429 A CN200710126429 A CN 200710126429A CN 101070261 B CN101070261 B CN 101070261B
Authority
CN
China
Prior art keywords
iii
alkyl
group
zinc
substituted
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
CN2007101264295A
Other languages
English (en)
Chinese (zh)
Other versions
CN101070261A (zh
Inventor
G·J·P·布里托夫塞克
S·A·科亨
V·C·吉布森
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
O And D Trading Co ltd
PetroIneos Europe Ltd
Ineos Commercial Services UK Ltd
Ineos Sales UK Ltd
Original Assignee
BP Chemicals Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BP Chemicals Ltd filed Critical BP Chemicals Ltd
Publication of CN101070261A publication Critical patent/CN101070261A/zh
Application granted granted Critical
Publication of CN101070261B publication Critical patent/CN101070261B/zh
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Images

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/26—Catalytic processes with hydrides or organic compounds
    • C07C2/30—Catalytic processes with hydrides or organic compounds containing metal-to-carbon bond; Metal hydrides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/32—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from compounds containing hetero-atoms other than or in addition to oxygen or halogen
    • C07C1/325—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from compounds containing hetero-atoms other than or in addition to oxygen or halogen the hetero-atom being a metal atom
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/48—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups
    • C07C29/50—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups with molecular oxygen only
    • C07C29/54—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups with molecular oxygen only starting from compounds containing carbon-to-metal bonds and followed by conversion of the -O- metal to -OH groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F3/00—Compounds containing elements of Groups 2 or 12 of the Periodic Table
    • C07F3/06—Zinc compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/01—Additive used together with the catalyst, excluding compounds containing Al or B
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/941—Synthetic resins or natural rubbers -- part of the class 520 series having the transition metal bonded directly to carbon
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CN2007101264295A 2001-08-06 2002-07-05 链增长反应方法 Expired - Lifetime CN101070261B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US09/921695 2001-08-06
US09/921,695 2001-08-06
US09/921,695 US7087686B2 (en) 2001-08-06 2001-08-06 Chain growth reaction process

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
CNB028194128A Division CN100457695C (zh) 2001-08-06 2002-07-05 链增长反应方法

Publications (2)

Publication Number Publication Date
CN101070261A CN101070261A (zh) 2007-11-14
CN101070261B true CN101070261B (zh) 2012-11-14

Family

ID=25445836

Family Applications (2)

Application Number Title Priority Date Filing Date
CN2007101264295A Expired - Lifetime CN101070261B (zh) 2001-08-06 2002-07-05 链增长反应方法
CNB028194128A Expired - Lifetime CN100457695C (zh) 2001-08-06 2002-07-05 链增长反应方法

Family Applications After (1)

Application Number Title Priority Date Filing Date
CNB028194128A Expired - Lifetime CN100457695C (zh) 2001-08-06 2002-07-05 链增长反应方法

Country Status (10)

Country Link
US (3) US7087686B2 (enExample)
EP (2) EP1414772B1 (enExample)
JP (1) JP2004537584A (enExample)
KR (1) KR100895599B1 (enExample)
CN (2) CN101070261B (enExample)
CA (1) CA2456711C (enExample)
EA (2) EA007922B1 (enExample)
ES (2) ES2623164T3 (enExample)
MY (1) MY143732A (enExample)
WO (1) WO2003014046A1 (enExample)

Families Citing this family (89)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20020063300A (ko) * 2000-01-21 2002-08-01 미쓰이 가가쿠 가부시키가이샤 올레핀계 블록 공중합체, 그 제조방법 및 그 용도
US8426535B2 (en) * 2001-08-06 2013-04-23 Ineos Europe Limited Chain growth reaction process
US7087686B2 (en) * 2001-08-06 2006-08-08 Bp Chemicals Limited Chain growth reaction process
EP1430088B1 (de) * 2001-09-14 2008-10-22 Basell Polyolefine GmbH Verfahren zur polymerisation von olefinen
DE10145453A1 (de) * 2001-09-14 2003-06-05 Basell Polyolefine Gmbh Monocyclopentadienylkomplexe mit einem kondensierten Heterocyclus
US7666918B2 (en) 2004-03-17 2010-02-23 Dow Global Technologies, Inc. Foams made from interpolymers of ethylene/α-olefins
US7514517B2 (en) 2004-03-17 2009-04-07 Dow Global Technologies Inc. Anti-blocking compositions comprising interpolymers of ethylene/α-olefins
US7714071B2 (en) 2004-03-17 2010-05-11 Dow Global Technologies Inc. Polymer blends from interpolymers of ethylene/α-olefins and flexible molded articles made therefrom
US7662881B2 (en) 2004-03-17 2010-02-16 Dow Global Technologies Inc. Viscosity index improver for lubricant compositions
US7897689B2 (en) 2004-03-17 2011-03-01 Dow Global Technologies Inc. Functionalized ethylene/α-olefin interpolymer compositions
US7557147B2 (en) 2004-03-17 2009-07-07 Dow Global Technologies Inc. Soft foams made from interpolymers of ethylene/alpha-olefins
US7803728B2 (en) 2004-03-17 2010-09-28 Dow Global Technologies Inc. Fibers made from copolymers of ethylene/α-olefins
US7863379B2 (en) 2004-03-17 2011-01-04 Dow Global Technologies Inc. Impact modification of thermoplastics with ethylene/alpha-olefin interpolymers
US7608668B2 (en) 2004-03-17 2009-10-27 Dow Global Technologies Inc. Ethylene/α-olefins block interpolymers
EP2792690B1 (en) * 2004-03-17 2019-05-15 Dow Global Technologies LLC Catalyst composition comprising shuttling agent for ethylene multi-block copolymer formation
US7622179B2 (en) 2004-03-17 2009-11-24 Dow Global Technologies Inc. Three dimensional random looped structures made from interpolymers of ethylene/α-olefins and uses thereof
US7524911B2 (en) 2004-03-17 2009-04-28 Dow Global Technologies Inc. Adhesive and marking compositions made from interpolymers of ethylene/α-olefins
JP5133050B2 (ja) 2004-03-17 2013-01-30 ダウ グローバル テクノロジーズ エルエルシー エチレンマルチブロックコポリマーを形成するためのシャトリング剤を含む触媒組成物
US7671106B2 (en) 2004-03-17 2010-03-02 Dow Global Technologies Inc. Cap liners, closures and gaskets from multi-block polymers
US7671131B2 (en) 2004-03-17 2010-03-02 Dow Global Technologies Inc. Interpolymers of ethylene/α-olefins blends and profiles and gaskets made therefrom
US7741397B2 (en) 2004-03-17 2010-06-22 Dow Global Technologies, Inc. Filled polymer compositions made from interpolymers of ethylene/α-olefins and uses thereof
US7687442B2 (en) 2004-03-17 2010-03-30 Dow Global Technologies Inc. Low molecular weight ethylene/α-olefin interpolymer as base lubricant oils
US7504347B2 (en) 2004-03-17 2009-03-17 Dow Global Technologies Inc. Fibers made from copolymers of propylene/α-olefins
US7622529B2 (en) 2004-03-17 2009-11-24 Dow Global Technologies Inc. Polymer blends from interpolymers of ethylene/alpha-olefin with improved compatibility
US7582716B2 (en) 2004-03-17 2009-09-01 Dow Global Technologies Inc. Compositions of ethylene/α-olefin multi-block interpolymer for blown films with high hot tack
US7355089B2 (en) 2004-03-17 2008-04-08 Dow Global Technologies Inc. Compositions of ethylene/α-olefin multi-block interpolymer for elastic films and laminates
US7795321B2 (en) 2004-03-17 2010-09-14 Dow Global Technologies Inc. Rheology modification of interpolymers of ethylene/α-olefins and articles made therefrom
US8816006B2 (en) 2004-03-17 2014-08-26 Dow Global Technologies Llc Compositions of ethylene/α-olefin multi-block interpolymer suitable for films
US7579408B2 (en) 2004-03-17 2009-08-25 Dow Global Technologies Inc. Thermoplastic vulcanizate comprising interpolymers of ethylene/α-olefins
US8273838B2 (en) 2004-03-17 2012-09-25 Dow Global Technologies Llc Propylene/α-olefins block interpolymers
KR100617990B1 (ko) * 2004-07-30 2006-09-01 한국화학연구원 다핵으로 연결된 전이금속 화합물 및 이를 이용한 개환복분해 중합체의 제조방법
US7910658B2 (en) 2005-03-17 2011-03-22 Dow Global Technologies Llc Compositions of ethylene/α-olefin multi-block interpolymer for elastic films and laminates
US7786216B2 (en) 2005-03-17 2010-08-31 Dow Global Technologies Inc. Oil based blends of interpolymers of ethylene/α-olefins
TW200635961A (en) 2005-03-17 2006-10-16 Dow Global Technologies Inc Cap liners, closures and gaskets from multi-block polymers
AR055748A1 (es) 2005-03-17 2007-09-05 Dow Global Technologies Inc Composiciones adhesivas y de marcado realizadas de interpolimeros de etileno/alfa-olefinas
US7737215B2 (en) 2005-03-17 2010-06-15 Dow Global Technologies Inc. Compositions of ethylene/α-olefin multi-block interpolymer for elastic films and laminates
CA2601330A1 (en) 2005-03-17 2006-09-28 Dow Global Technologies Inc. Compositions of ethylene/alpha-olefin multi-block interpolymer for elastic films and laminates
US7695812B2 (en) 2005-09-16 2010-04-13 Dow Global Technologies, Inc. Fibers made from copolymers of ethylene/α-olefins
US7906587B2 (en) 2005-09-16 2011-03-15 Dow Global Technologies Llc Polymer blends from interpolymer of ethylene/α olefin with improved compatibility
AR058496A1 (es) 2005-10-26 2008-02-06 Dow Global Technologies Inc Articulos elasticos de multiples capas
US8153243B2 (en) 2005-12-09 2012-04-10 Dow Global Technologies Llc Interpolymers suitable for multilayer films
JP5502325B2 (ja) 2005-12-09 2014-05-28 ダウ グローバル テクノロジーズ エルエルシー エチレン／α−オレフィン組成物における分子量分布の制御方法
EP2052857A1 (en) 2007-10-22 2009-04-29 Dow Global Technologies Inc. Multilayer films
US8188200B2 (en) † 2007-11-09 2012-05-29 University Of Maryland, College Park Process for preparation of polyolefins via living coordinative chain transfer polymerization
KR100973929B1 (ko) * 2008-02-11 2010-08-03 한국도로공사 도로의 음원생성장치 및 그 시공방법
KR101006996B1 (ko) * 2008-06-02 2011-01-12 주식회사 유일컴 지하철 보도용 점자블록
CN102089310A (zh) * 2008-06-20 2011-06-08 Tpi企业有限公司 用于合成n-去甲基吗啡烷化合物的方法
US8791284B2 (en) 2009-07-01 2014-07-29 Mitsui Chemicals, Inc. Organometallic compound and production method thereof
EP2665754A1 (en) 2011-01-20 2013-11-27 Ineos Commercial Services UK Limited Activating supports
US20130131294A1 (en) * 2011-11-21 2013-05-23 John R. Hagadorn Amidinate Catalyst Compounds, Process for Their Use and Polymers Produced Therefrom
CN106660029A (zh) * 2014-01-08 2017-05-10 多伦多大学管理委员会 包含三齿pnp配体的铁(ii)催化剂、它们的合成和其用途
EP3037438A1 (en) 2014-12-23 2016-06-29 SABIC Global Technologies B.V. Process for the preparation of a branched polyolefin
EP3037437A1 (en) 2014-12-23 2016-06-29 SABIC Global Technologies B.V. Process for the preparation of a polyolefin having one or multiple end-functionalized branches.
EP3093280A1 (en) 2015-05-13 2016-11-16 Sasol Performance Chemicals GmbH Process for the oligomerisation of olefins by coordinative chain transfer polymerisation and catalyst synthesis
BR112017025509B1 (pt) * 2015-05-29 2022-05-10 Dow Global Technologies Llc Processo para produzir uma pololefina
EP3387047B1 (en) 2015-12-09 2020-01-01 SABIC Global Technologies B.V. Process for the preparation of polyolefin-based graft copolymers comprising a first long chain branched polyolefin block and one or multiple polymer side chains
KR102019467B1 (ko) 2015-12-23 2019-11-04 주식회사 엘지화학 메탈로센 담지 촉매 및 이를 이용하는 폴리올레핀의 제조방법
WO2018034760A1 (en) 2016-08-15 2018-02-22 Exxonmobil Chemical Patents Inc. Propylene-alpha olefin copolymers and methods for making the same
WO2018034759A1 (en) 2016-08-15 2018-02-22 Exxonmobil Chemical Patents Inc. Propylene-olefin copolymers and methods for making the same
JP6886858B2 (ja) * 2017-05-09 2021-06-16 Ｅｎｅｏｓ株式会社 オリゴマーの製造方法
JP7256169B2 (ja) 2017-07-25 2023-04-11 ダウ シリコーンズ コーポレーション ポリオレフィン主鎖とポリオルガノシロキサンペンダント基とを有する、グラフトコポリマーを調製するための方法
CN109422828A (zh) * 2017-09-05 2019-03-05 中国石油化工股份有限公司 用于烯烃聚合的催化剂体系和制备低分子量聚乙烯的催化体系及方法和低分子量聚乙烯
US11041035B2 (en) 2018-03-08 2021-06-22 Exxonmobil Chemical Patents Inc. Process to produce long-chain branched polyolefins using dienes
US11479625B2 (en) 2018-03-08 2022-10-25 Exxonmobil Chemical Patents Inc. Ethylene-propylene branched copolymers as viscosity modifiers with enhanced fuel economy
CA3101628A1 (en) 2018-03-19 2019-09-26 Dow Silicones Corporation Hot melt adhesive composition containing a polyolefin - polydiorganoosiloxane copolymer and methods for the preparation and use thereof
EP3768765B1 (en) 2018-03-19 2023-05-17 Dow Silicones Corporation Polyolefin-polydiorganosiloxane block copolymer and hydrosilylaton reaction method for the synthesis thereof
US11814555B2 (en) 2018-03-19 2023-11-14 Dow Silicones Corporation Hot melt adhesive compositions containing polyolefin-polydiorganosiloxane copolymers and methods for the preparation and use thereof
US12037462B2 (en) 2018-03-19 2024-07-16 Dow Global Technologies Llc Polyolefin-polydiorganosiloxane block copolymer and method for the synthesis thereof
EP3784677A4 (en) 2018-04-26 2022-03-09 ExxonMobil Chemical Patents Inc. NON-COORDINATING ANION TYPE ACTIVATORS WITH A CATION WITH LARGE ALKYL GROUPS
JP7334195B2 (ja) 2018-07-17 2023-08-28 ダウ シリコーンズ コーポレーション ポリシロキサン樹脂－ポリオレフィンコポリマー並びにその調製方法及び使用方法
WO2020069853A1 (en) 2018-10-02 2020-04-09 Sabic Global Technologies B.V. Method for the manufacture of a polyolefin compound
WO2020146375A2 (en) 2019-01-08 2020-07-16 Exxonmobil Chemical Patents Inc Olefin polymerization processes featuring in situ blending of an oil extension
EP3941949B1 (en) 2019-03-21 2025-10-22 ExxonMobil Chemical Patents Inc. Methods for improving gas phase polymerization
US12152095B2 (en) 2019-03-21 2024-11-26 Exxonmobil Chemical Patents Inc. Methods for improving production in gas phase polymerization
WO2021025903A1 (en) 2019-08-02 2021-02-11 Exxonmobil Chemical Patents Inc. Non-coordinating anion type activators for use with polyolefin polymerization catalysts
WO2021119089A1 (en) 2019-12-11 2021-06-17 Exxonmobil Chemical Patents Inc. Processes for introduction of liquid activators in olefin polymerization reactions
WO2021126523A1 (en) 2019-12-19 2021-06-24 Exxonmobil Chemical Patents Inc. Production of impact copolymer polypropylene using metallocene and ziegler-natta catalysts in parallel reactors
WO2021194831A1 (en) 2020-03-25 2021-09-30 Exxonmobil Chemical Patents Inc. Alkylation of transition metal coordination catalyst complexes
FR3109898B1 (fr) * 2020-05-07 2023-04-14 Ifp Energies Now Catalyseur d’hydrogénation sélective comprenant une répartition particulière du nickel et du molybdène
US20230242745A1 (en) 2020-06-03 2023-08-03 Exxonmobil Chemical Patents Inc Process for Production of Thermoplastic Vulcanizates using Supported Catalyst Systems and Compositions Made Therefrom
WO2021262838A1 (en) 2020-06-26 2021-12-30 Exxonmobil Chemical Patents Inc. Copolymers composed of ethylene, a-olefin, non-conjugated diene, and substituted styrene and articles therefrom
WO2022035484A1 (en) 2020-08-10 2022-02-17 Exxonmobil Chemical Patents Inc. Methods for delivery of non-aromatic solutions to polymerization reactors
US11780786B2 (en) * 2020-09-14 2023-10-10 Chevron Phillips Chemical Company Lp Transition metal-catalyzed production of alcohol and carbonyl compounds from hydrocarbons
AR124333A1 (es) * 2020-12-15 2023-03-15 Shell Int Research UN PROCESO PARA PRODUCIR a-OLEFINAS
JP2024518829A (ja) 2021-05-14 2024-05-07 エクソンモービル ケミカル パテンツ，インコーポレイティド 粘度調整剤として使用されるエチレン－プロピレン分岐コポリマー
CA3216256A1 (en) 2021-05-14 2022-11-17 Jo Ann M. Canich Ethylene-propylene branched copolymers as viscosity modifiers
WO2025117273A1 (en) 2023-12-01 2025-06-05 ExxonMobil Technology and Engineering Company Support-bound activators, supported catalyst systems, and processes for use thereof
GB202401660D0 (en) 2024-02-07 2024-03-20 Imperial College Innovations Ltd Polymers with antimicrobial properties
WO2025250307A1 (en) 2024-05-30 2025-12-04 ExxonMobil Technology and Engineering Company Methods for improving gas phase polymerization

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1991002707A1 (en) * 1989-08-14 1991-03-07 Exxon Chemical Patents Inc. Process for preparing linear alpha-olefins from ethylene

Family Cites Families (43)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4063009A (en) * 1954-01-19 1977-12-13 Studiengesellschaft Kohle M.B.H. Polymerization of ethylenically unsaturated hydrocarbons
NL278718A (enExample) 1961-05-29
US4308369A (en) * 1979-09-28 1981-12-29 The Dow Chemical Company High efficiency catalyst for polymerizing olefins
US4335016A (en) * 1981-02-23 1982-06-15 Chemplex Company Catalyst and method
US4361714A (en) * 1981-12-14 1982-11-30 Exxon Research And Engineering Co. Preparation of linear olefin products
US4855525A (en) * 1987-06-19 1989-08-08 Exxon Chemical Patents Inc. Process for preparing linear alpha-olefins using zirconium adducts as catalysts
US5034483A (en) * 1988-01-15 1991-07-23 Mobil Oil Corporation Process for preparing high density, broad molecular weight distribution alpha-olefin polymers
US5068489A (en) * 1989-12-28 1991-11-26 Union Carbide Chemicals And Plastics Technology Corporation Preparation of very low molecular weight polyethylene in a fluidized bed
AU636498B2 (en) * 1990-07-02 1993-04-29 Union Carbide Chemicals And Plastics Company Inc. Catalyst and process for making ethylene polymers
US5449850A (en) * 1991-03-12 1995-09-12 Exxon Chemical Patents Inc. Process for oligomerizing C3 and higher olefins using zirconium adducts as catalysts (CS-467)
US5210338A (en) 1991-10-25 1993-05-11 Ethyl Corporation Catalyzed chain growth process
US5221774A (en) * 1992-03-19 1993-06-22 Phillips Petroleum Company Ethylene oligomerization
US5276220A (en) 1992-06-18 1994-01-04 Ethyl Corporation Actinide catalyzed chain growth process
US5320993A (en) 1992-07-17 1994-06-14 Phillips Petroleum Company Dimerization catalyst systems and processes
BE1006453A3 (nl) * 1992-12-21 1994-08-30 Dsm Nv Katalysator en werkwijze voor een ziegler polymerisatie.
US5439862A (en) * 1993-10-21 1995-08-08 Kemp; Richard A. Oligomerization catalyst and process
KR100418168B1 (ko) 1995-01-24 2004-02-14 이.아이,듀우판드네모아앤드캄파니 중합 방법
US5714556A (en) 1995-06-30 1998-02-03 E. I. Dupont De Nemours And Company Olefin polymerization process
IL129929A0 (en) 1996-12-17 2000-02-29 Du Pont Polymerization of ethylene with specific iron or cobalt complexes novel pyridinebis (imines) and novel complexes of pyridinebis(imines) with iron and cobalt
CA2274817A1 (en) 1997-01-14 1998-07-16 E.I. Du Pont De Nemours And Company Polymerization of olefins
JP2002514252A (ja) 1997-03-10 2002-05-14 イーストマン ケミカル カンパニー 第８〜１０族遷移金属を含むオレフィン重合触媒、二座配位子、このような触媒の使用方法及びそれから得られるポリマー
US6410664B1 (en) 1997-03-24 2002-06-25 Cryovac, Inc. Catalyst compositions and processes for olefin polymers and copolymers
ID24448A (id) 1997-09-05 2000-07-20 Bp Chemical Ltd Katalis-katalis polimerisasi
JP3339441B2 (ja) * 1999-01-11 2002-10-28 東ソー株式会社 オレフィン重合体製造用触媒およびそれを用いたオレフィン重合体の製造方法
EP0942006B1 (en) * 1998-03-09 2003-06-04 Tosoh Corporation Catalyst for olefin polymer production and process for olefin polymer production employing the catalyst
US6410660B1 (en) 1998-03-27 2002-06-25 E. I. Du Pont De Nemours And Company Polymerization of olefins
US5932670A (en) * 1998-03-30 1999-08-03 Phillips Petroleum Company Polymerization catalysts and processes therefor
GB9809207D0 (en) * 1998-04-29 1998-07-01 Bp Chem Int Ltd Novel catalysts for olefin polymerisation
EP0967234A1 (en) * 1998-06-24 1999-12-29 Fina Research S.A. Production of polyethylene
GB9817004D0 (en) * 1998-08-06 1998-09-30 Bp Chem Int Ltd Preparation of polymerisation catalysts
GB9819847D0 (en) * 1998-09-12 1998-11-04 Bp Chem Int Ltd Novel compounds
DE69920053D1 (de) * 1998-11-30 2004-10-14 Bp Chem Int Ltd Polymerisationsverfahren
DE60018870T2 (de) * 1999-01-22 2006-04-13 Mitsui Chemicals, Inc. Verfahren zur herstellung eines olefinpolymers und olefinpolymer
GB9902697D0 (en) 1999-02-09 1999-03-31 Bp Chem Int Ltd Novel compounds
DE60014376T2 (de) 1999-02-22 2005-02-24 Eastman Chemical Co., Kingsport Katalysatoren, die n-pyrrolylsubstituierte stickstoffdonoren enthalten
GB9928679D0 (en) * 1999-12-03 2000-02-02 Bp Chem Int Ltd Polymerisation process
US6828398B2 (en) 2000-02-10 2004-12-07 Bp Chemicals Limited Polymerization catalyst
US6521724B2 (en) * 2000-03-10 2003-02-18 E. I. Du Pont De Nemours And Company Polymerization process
US6501000B1 (en) * 2000-04-04 2002-12-31 Exxonmobil Research And Engineering Company Late transition metal catalyst complexes and oligomers therefrom
NL1015608C2 (nl) 2000-07-04 2002-01-08 Duos B V Inrichting en werkwijze voor het scheiden van heterogeen afval.
US20030176360A1 (en) 2000-07-05 2003-09-18 Yasutaka Igari Medicinal preparations for treating sex hormone-dependent diseases
WO2003011876A1 (en) * 2001-08-01 2003-02-13 Shell Internationale Research Maatschappij B.V. Ligands and catalyst systems thereof for ethylene oligomerisation to linear alpha olefins
US7087686B2 (en) * 2001-08-06 2006-08-08 Bp Chemicals Limited Chain growth reaction process

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1991002707A1 (en) * 1989-08-14 1991-03-07 Exxon Chemical Patents Inc. Process for preparing linear alpha-olefins from ethylene

Also Published As

Publication number Publication date
CN101070261A (zh) 2007-11-14
CN100457695C (zh) 2009-02-04
ES2623164T3 (es) 2017-07-10
ES2711251T3 (es) 2019-04-30
KR20040032897A (ko) 2004-04-17
EP1414772A1 (en) 2004-05-06
EA200601455A1 (ru) 2006-12-29
US7767771B2 (en) 2010-08-03
EP1414772B1 (en) 2017-02-01
EP2308815A1 (en) 2011-04-13
US20030078458A1 (en) 2003-04-24
CN1561317A (zh) 2005-01-05
EP2308815B1 (en) 2018-11-14
KR100895599B1 (ko) 2009-05-06
CA2456711C (en) 2013-01-08
US20080200709A1 (en) 2008-08-21
EA011711B1 (ru) 2009-04-28
CA2456711A1 (en) 2003-02-20
US7964681B2 (en) 2011-06-21
EA200400255A1 (ru) 2004-10-28
WO2003014046A1 (en) 2003-02-20
US7087686B2 (en) 2006-08-08
EA007922B1 (ru) 2007-02-27
US20070142656A1 (en) 2007-06-21
JP2004537584A (ja) 2004-12-16
MY143732A (en) 2011-07-15

Similar Documents

Publication Publication Date Title
CN101070261B (zh) 链增长反应方法
EP1373282B1 (en) Bimetallic catalysts for olefin polymerization
CN102725251A (zh) 聚合物的形成减少的烯属化合物的低聚合
JPH03139504A (ja) 金属錯体化合物
KR101483247B1 (ko) 폴리올레핀 중합용 촉매의 제조 방법 및 폴리올레핀 제조방법
CN104080792A (zh) 用于制备茂金属络合物的方法
CN109476779A (zh) 乙烯的低聚
US20040054150A1 (en) Multimetallic catalyst compositions for the polymerization of olefins
CN107721797A (zh) 用于制备茂金属络合物的方法
US9434795B2 (en) Production of vinyl terminated polyethylene using supported catalyst system
CN111620914B (zh) 含中性苄杂原子配位基侧臂单茂四价过渡金属配合物及其用途
US20180280951A1 (en) Process for the Oligomerisation of Olefins by Coordinative Chain Transfer Polymerisation
JP4242150B2 (ja) ２種金属からなるオレフイン重合触媒
US7157398B2 (en) Covalently fixed nonmetallocenes, process for preparing them and their use for the polymerization of olefins
US6228959B1 (en) Single-site catalysts containing homoaromatic ligands
US8426535B2 (en) Chain growth reaction process
WO2003051936A1 (en) Bidentate ligand based catalyst for the polymerization of olefins
US20040102311A1 (en) Bridged metallocene catalyst component, method of making, polyolefin catalyst having C1, C2, or Cs symmetry, methods of making, methods of polymerizing, olefins and products made thereof
MXPA00009362A (en) Cyclopentadienyl transition metal compounds, as polymerization catalysts

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
ASS Succession or assignment of patent right

Owner name: INEOS COMMERCIAL SERVICES UK LIMITED

Free format text: FORMER OWNER: INNOVENE EUROP LTD.

Effective date: 20140730

Owner name: INEOS SALES (UK) LIMITED

Free format text: FORMER OWNER: INEOS COMMERCIAL SERVICES UK LIMITED

Effective date: 20140730

Owner name: O + D TRADING CO., LTD.

Free format text: FORMER OWNER: BP CHEMICALS LTD.

Effective date: 20140730

C41 Transfer of patent application or patent right or utility model
C56 Change in the name or address of the patentee

Owner name: INNOVENE EUROP LTD.

Free format text: FORMER NAME: O + D TRADING CO., LTD.

CP01 Change in the name or title of a patent holder

Address after: The Middlesex County

Patentee after: INNOVENE EUROPE LTD.

Address before: The Middlesex County

Patentee before: O and D Trading Co.,Ltd.

CP03 Change of name, title or address

Address after: England Hampshire

Patentee after: INEOS EUROPE LTD.

Address before: The Middlesex County

Patentee before: INNOVENE EUROPE LTD.

TR01 Transfer of patent right

Effective date of registration: 20140730

Address after: England Hampshire

Patentee after: Ineos sales (UK) Ltd.

Address before: England Hampshire

Patentee before: INEOS COMMERCIAL SERVICES UK Ltd.

Effective date of registration: 20140730

Address after: England Hampshire

Patentee after: INEOS COMMERCIAL SERVICES UK Ltd.

Address before: England Hampshire

Patentee before: INEOS EUROPE LTD.

Effective date of registration: 20140730

Address after: The Middlesex County

Patentee after: O and D Trading Co.,Ltd.

Address before: London, England, England

Patentee before: BP Chemicals Ltd.

CX01 Expiry of patent term

Granted publication date: 20121114

CX01 Expiry of patent term