CN101040825A - 毛发洗净剂组合物 - Google Patents
毛发洗净剂组合物 Download PDFInfo
- Publication number
- CN101040825A CN101040825A CNA2007100883762A CN200710088376A CN101040825A CN 101040825 A CN101040825 A CN 101040825A CN A2007100883762 A CNA2007100883762 A CN A2007100883762A CN 200710088376 A CN200710088376 A CN 200710088376A CN 101040825 A CN101040825 A CN 101040825A
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- CN
- China
- Prior art keywords
- acid
- weight
- hair cleansing
- cleansing composition
- dandruff
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Abstract
一种毛发洗净剂组合物，含有以下成分(A)、(B)以及(C)，用水稀释20重量倍时在25℃的pH值为1～5，(A)可以具有羟基的有机二羧酸或羟基单羧酸或其盐0.1～20重量％，(B)至少一种消炎剂0.001～10重量％，(C)阴离子表面活性剂0.5～60重量％。
Description
技术领域
本发明涉及毛发洗净剂组合物。
背景技术
毛发用洗发水的主要目的在于除去毛发和肌肤的污垢并保持清洁。为了获得去污力强、洗净力高的组合物，或者并用2种以上洗净剂主要成分阴离子表面活性剂，或者适当地组合使用其它表面活性剂，例如两性表面活性剂或非离子表面活性剂。但是，仅仅使用洗净力强的表面活性剂的话，在清洗时会有不顺滑的问题。因此，需要一种插入手指或洗发时使头发柔软等的具有调理性的类型的洗发水，从而使用了阳离子性聚合物或硅酮类。但是，这样的调理剂虽然对毛发发挥高的调理效果，但是对肌肤起到的效果差，肌肤由于高洗净力的影响而除去了必要以上的皮脂，因此受到感觉干燥等的干燥性皮肤烦恼的人近年来逐渐增加。另外，为了保护肌肤而使表面活性剂的量少的情况下，洗净力理所当然地下降并且在肌肤上残留污垢，成为头皮屑、疥疮的诱因。
通常，头皮屑、疥疮等被认为是由细菌繁殖所引起的，为了抑制这些细菌繁殖引起的头皮屑或疥疮，以往使用了含有以氧巯基吡啶锌为代表的氧巯基吡啶盐或烷基二甲基苄基氯化铵(benzalkoniumchloride)、Octopirox等的抗菌剂或杀菌剂的抗头皮屑用毛发化妆品(例如，参照美国专利第3753916号说明书和日本特开昭58-196300号公报)。
但是，近年来随着洗发频率的提高，相比于主要由细菌繁殖引起的头皮屑自身，主要由肌肤干燥造成的头皮屑或疥疮、干燥成为肌肤问题的主流。在这种情况中，希望有一种毛发洗净剂组合物，其不但对毛发和肌肤两者维持高洗净力，同时具有肌肤护理效果，并且可以抑制头皮屑、疥疮。
发明内容
本发明提供一种毛发洗净剂组合物，含有以下成分(A)、(B)以及(C)，用水稀释20重量倍时在25℃的pH值为1～5，
(A)可以具有羟基的有机二羧酸或羟基单羧酸或其盐 0.1～20重量％，
(B)至少一种消炎剂 0.001～10重量％，
(C)阴离子表面活性剂 0.5～60重量％
具体实施方式
本发明涉及一种毛发洗净剂组合物，即，涉及不仅抑制头皮屑、疥疮，还抑制丘疹或干燥的，肌肤护理效果优异的毛发洗净剂组合物。
本发明者们发现，在将阴离子表面活性剂作为洗净基剂的洗净剂中，通过并用特定的有机酸和消炎剂，进一步调节至规定的低pH区域，可以得到抑制头皮屑、疥疮、丘疹、干燥等的肌肤护理效果优异的毛发洗净剂组合物。
本发明的毛发洗净剂组合物在用水稀释20重量倍时，在25℃下的pH值为1～5，从抑制或改善头皮的头皮屑或疥疮、丘疹、干燥等的效果(以下称作头皮症状改善效果)的观点出发，优选上述pH值为2～4，更优选3～4。
作为成分(A)的可以具有羟基的二羧酸，可以举出例如丙二酸、琥珀酸、戊二酸、己二酸、马来酸、富马酸、邻苯二甲酸、草酸等不具有羟基的二羧酸，以及苹果酸、酒石酸等羟基二羧酸。此外，作为羟基单羧酸，可以举出羟基乙酸、乳酸、羟基丙烯酸、羟基丁酸、甘油酸等。其中，优选乳酸、丙二酸、马来酸、苹果酸。此外，作为这些有机羧酸的盐，可以举出与碱金属、碱土金属、铵、有机胺化合物的盐。
在本发明中，使用成份(A)不仅仅是为了调节pH值的目的，其作为有效成分也是必须的，在本发明的洗发水组合物中含有0.1～20重量％是必要的，但是从得到充分的头皮症状改善效果的观点出发，优选含有0.1～5重量％，更优选0.15～4重量％，特别优选0.2～3重量％。
作为成分(B)的消炎剂，除了甘草次酸、甘草酸、它们的衍生物等的抗炎症剂之外，还包括具有消炎功能的成分，例如ε-氨基己酸、尿囊素、薁磺酸钠、d-樟脑、l-薄荷醇、尿素、二棕榈酸吡哆醇、甘草亭酸硬脂酸酯、抗血纤溶环酸、维他命A油、氢化可的松、泼尼松龙、盐酸吡哆醇、感光素301号、氧化锌、醋酸氢化可的松等。作为甘草次酸或甘草酸的衍生物，可以举出钠盐、钾盐等碱金属盐或铵盐等的盐类，甘油酯、硬脂酸酯等酯类。具体地说，可以举出甘草酸二钾、甘草酸二钠、甘草酸三钠、甘草酸单铵、甘草次酸甘油酯、甘草次酸硬脂醇酯等。成分(B)的消炎剂在本发明的毛发洗净剂组合物中含有0.001～10重量％，优选0.005～5重量％，特别优选含有0.01～1重量％。
作为成分(C)的阴离子表面活性剂，可以使用硫酸系、磺酸盐系、羧酸系的物质。作为硫酸系的物质，可以举出例如烷基硫酸盐、聚氧化烯烷基醚硫酸盐、聚氧化烯链烯基醚硫酸盐、磺基琥珀酸烷基酯盐、聚氧化烯磺基琥珀酸烷基酯盐、聚氧化烯烷基苯基醚硫酸盐、高级脂肪酸盐、链烷磺酸盐等。其中，优选聚氧化烯烷基醚硫酸盐、烷基硫酸盐，还优选以下述通式(1)或(2)表示的物质。
R1O(CH2CH2O)aSO3M (1)
R2OSO3M (2)
[式中，R1表示碳原子数为10～18的烷基或链烯基，R2表示碳原子数为10～18的烷基，M表示碱金属、碱土类金属、铵、链烷醇胺或碱性氨基酸，a以重量平均表示为1～5的数。]
阴离子表面活性剂可以并用2种以上，并且从起泡性、使用时的液性、洗净性的观点出发，其在本发明的毛发洗净剂组合物中的含量为0.5～60重量％，优选1～30重量％，特别优选8～20重量％。
为了提高干燥后的质量，本发明的毛发洗净剂组合物中还可以配合选自阳离子性聚合物、阳离子表面活性剂、硅酮类和油剂的调理成分。
作为阳离子性聚合物，可以举出例如，阳离子化纤维素衍生物、阳离子性淀粉、阳离子化瓜尔豆胶衍生物、二烯丙基季铵盐的单聚物、二烯丙基季铵盐/丙烯酰胺共聚物、季铵化聚乙烯基吡咯烷酮衍生物、聚乙二醇聚胺缩聚物、乙烯基咪唑三氯化物/乙烯基吡咯烷酮共聚物(vinyl imidazolium trichloride/vinylpyrrolidone copolymer)、羟乙基纤维素/二甲基二烯丙基氯化铵共聚物、乙烯基吡咯烷酮/季铵化二甲胺基乙基甲基丙烯酸酯共聚物、聚乙烯基吡咯烷酮/烷胺基丙烯酸酯共聚物、聚乙烯吡咯烷酮/烷胺基丙烯酸酯/乙烯基己内酰胺共聚物、乙烯基吡咯烷酮/甲基丙烯酰胺丙基氯化三甲基铵共聚物、烷基丙烯酰胺/丙烯酸酯/烷基氨基烷基丙烯酰胺/聚乙二醇甲基丙烯酸酯共聚物、己二酸/二甲氨基羟丙基亚乙基三胺共聚物(美国Sandoz公司生产，″Cartaretine″)、日本特开昭53-139734号公报、日本特开昭60-36407号公报中记载的阳离子性聚合物等。其中，优选阳离子化纤维素衍生物、阳离子化瓜尔豆胶衍生物、二烯丙基季铵盐/丙烯酰胺共聚物。阳离子性聚合物可以并用2种以上，并且从提高洗净时的泡沫质量、以及提高干燥后头发的整齐性和触感的观点出发，其在本发明的毛发洗净剂组合物中的含量优选为0.02～5重量％，更优选为0.05～1重量％，特别优选为0.1～0.7重量％。
作为阳离子表面活性剂，可以举出例如，十二烷基三甲基氯化铵、十六烷基三甲基氯化铵、十六烷基三甲基溴化铵、硬脂基三甲基氯化铵、硬脂基三甲基溴化铵、十二烷基三甲基溴化铵等的烷基三甲基铵盐；双十六烷基二甲基氯化铵、二硬脂基二甲基氯化铵、二椰子基二甲基氯化铵等的二烷基二甲基铵盐。进一步，可以使用肉豆寇基二甲基苯基氯化铵、硬脂基二甲基苯基氯化铵、甲基硫酸羊毛脂脂肪酸氨基乙基三甲基铵、甲基硫酸羊毛脂脂肪酸氨基丙基乙基二甲基铵、乙基硫酸羊毛脂脂肪酸氨基丙基乙基二甲基铵、乙基硫酸羊毛脂脂肪酸氨基丙基三乙基铵、乙基硫酸羊毛脂脂肪酸氨基乙基三乙基铵、乙基硫酸异硬脂酸氨基丙基乙基二甲基铵、乙基硫酸异壬酸氨基丙基乙基二甲基铵、硬酯酰胺基丙基二甲基胺(及其盐)、硬酯酰胺基乙基二乙基胺(及其盐)、乙基硫酸异链烷酸(C14-C20)氨基丙基乙基二甲基铵、乙基硫酸异链烷酸(C18-C22)氨基丙基乙基二甲基铵、和烷基三甲基铵糖精等。阳离子表面活性剂可以并用2种以上，从洗发时到洗涤时的光滑性的观点出发，其在本发明的毛发洗净剂组合物的含量优选为0.01～10重量％，更优选为0.05～6重量％，特别优选为0.3～3重量％，尤其优选为0.5～2重量％。
作为硅酮类，例如可以举出以下表示的物质。
(硅酮类-1)二甲聚硅氧烷
R3(CH3)2SiO-[(CH3)2SiO]b-Si(CH3)2R3
[式中，R3表示甲基或羟基，b表示3～20000的数。]
例如，可以举出BY11-026、BY22-1 9[Dow Corning Toray株式会社]、FZ-3125[Nippon Unicar株式会社]等。高聚合二甲基聚硅氧烷可以溶解或分散在液状油(例如，低聚合二甲基聚硅氧烷油、环状硅酮等的液状硅酮油、以及异链烷烃等的液体烃油)中使用。
(硅酮类-2)氨基改性硅酮
可使用各种氨基改性硅酮，但是优选平均分子量约为3000～100000的，以氨基二甲聚硅氧烷(Amodimethicone)的名称记载在CTFA词典(美国，Cosmetic Ingredient Dictionary)第3版中的氨基改性硅酮。这些氨基改性硅酮优选作为该氨基改性硅酮的水性乳浊液使用，作为市售品，可以举出SM 8704C[Dow Corning Toray株式会社]、DC929[Dow Corning公司]等。
作为其它氨基改性硅酮，可以举出例如以下述通式所表示的化合物，作为市售品可以举出Dow Corning公司的“8500 ConditioningAgent”(CAS No.237753-63-8)。
[式中，R表示碳原子数为13～15的直链或支链烷基，X之中的75％表示-CH2CH(OH)CH2OH基，25％表示氢原子。]
作为氨基改性聚硅氧烷-聚氧化烯嵌段共聚物的优选例子，可以举出以下述通式表示的共聚物。
[式中，c表示2以上的数，d表示1以上的数，e表示4以上的数，f表示0～30的数，g表示2以上的数。]
在上述通式中，优选c为2～1000的数，d为1～50的数，e为4～200的数，g为2～100的数。此外，-O(C2H4O)e(C3H6O)f-可以是嵌段共聚物和无规共聚物中的任意一种。作为市售品可以举出DowCorning Toray株式会社的FZ-3789、硅酮SS-3588。
(硅酮类-3)其他的硅酮类
除上述之外，还有聚醚改性硅酮、甲苯基聚硅氧烷、脂肪酸改性硅酮、醇改性硅酮、烷氧基改性硅酮、环氧改性硅酮、氟改性硅酮、环状硅酮、烷基改性硅酮等。
这些硅酮类可以并用2种以上，从头发的光滑性、手指插入的良好性、赋予光泽度的观点出发，其在本发明的毛发洗净剂组合物中的含量优选为0.1～7重量％，更优选0.2～6重量％，特别优选0.5～5重量％。
油剂是指除了硅酮类的油性物质，可以举出例如，角鲨烯、角鲨烷、液体链烷烃、液体异链烷烃、环链烷烃等的烃类；蓖麻油、可可油、水貂油、鳄梨油、橄榄油等甘油酯类；蜂蜡、鲸蜡、羊毛脂、巴西棕榈蜡等蜡类；鲸蜡醇、油醇、硬脂醇、异硬脂醇、2-辛基十二烷醇等醇类；棕榈酸异丙酯、肉豆蔻酸异丙酯、肉豆蔻酸辛基十二烷酯、月桂酸己酯、乳酸鲸蜡酯、单硬脂酸丙二醇酯、油酸油醇酯、2-乙基己酸十六烷酯、异壬酸异壬酯、异壬酸十三烷酯等酯类；癸酸、月桂酸、肉豆蔻酸、棕榈酸、硬脂酸、山萮酸、油酸、椰子油脂肪酸、异硬脂酸、异棕榈酸等高级脂肪酸类；其它异硬脂基甘油醚、聚氧丙烯丁基醚等。这些中，优选酯类，更优选2-乙基己烷酸十六烷酯、异壬酸异壬酯、棕榈酸异丙酯等。这些油剂可以并用2种以上，其在本发明的毛发洗净剂组合物中的含量优选为0.2～2重量％，更优选为0.3～1.8重量％，特别优选为0.5～1.5重量％。
这些硅酮类可以并用2种以上，从泡沫的滑动性和从洗发时到洗涤时的光滑性的观点出发，其在本发明的毛发洗净剂组合物中的含量优选为0.05～10重量％，更优选0.1～5重量％，特别优选0.3～2重量％。
在本发明的毛发洗净剂组合物中，为了进一步提高发泡性能，可以含有选自非离子表面活性剂和两性离子表面活性剂的表面活性剂。
作为非离子表面活性剂可以举出，聚氧化烯山梨糖醇酐脂肪酸酯类，聚氧化烯山梨糖醇脂肪酸酯类，聚氧化烯甘油脂肪酸酯类，聚氧化烯脂肪酸酯类，烷基甘油基醚类，聚氧化烯烷基醚类，聚氧化烯烷基苯基醚类，聚氧化烯(硬化)蓖麻油类，蔗糖脂肪酸酯类，聚甘油烷基醚类，聚甘油脂肪酸酯类，脂肪酸烷醇酰胺类，烷基糖苷类等。这些中，优选单烷基甘油基醚类、烷基糖苷类、聚氧化烯(C8～C20)脂肪酸酯、聚氧乙烯山梨糖醇酐脂肪酸酯、聚氧乙烯硬化蓖麻油、脂肪酸烷醇酰胺。作为脂肪酸烷醇酰胺，优选具有碳原子数8～18、特别是碳原子数10～16的酰基的脂肪酸烷醇酰胺。此外，作为脂肪酸烷醇酰胺，可以是单烷醇酰胺、二烷醇酰胺中的任一种，优选具有碳原子数2～3的羟烷基的脂肪酸烷醇酰胺，例如可以举出油酸二乙醇酰胺、棕榈仁油脂肪酸二乙醇酰胺、椰子油脂肪酸二乙醇酰胺、月桂酸二乙醇酰胺、聚氧乙烯椰子油脂肪酸单乙醇酰胺、椰子油脂肪酸单乙醇酰胺、月桂酸异丙醇酰胺、月桂酸单乙醇酰胺等。
作为两性表面活性剂，可以举出甜菜碱系列表面活性剂等。其中，更优选烷基二甲胺基醋酸甜菜碱、脂肪酰胺丙基甜菜碱等甜菜碱类表面活性剂，特别优选脂肪酰胺丙基甜菜碱。脂肪酰胺丙基甜菜碱，优选具有碳原子数8～18、特别是碳原子数10～16的酰基的脂肪酰胺丙基甜菜碱，具体地说优选月桂酰胺丙基甜菜碱、棕榈仁油脂肪酰胺丙基甜菜碱、椰子油脂肪酰胺丙基甜菜碱等。
本发明的水性毛发洗净剂中，除上述成分外还可根据目的适当配合用于通常的毛发洗净剂的成分。作为这样的成分，例如可以举出：螯合剂；山梨糖醇、泛酰醇等保湿剂；染料、颜料等着色剂；羟乙基纤维素、甲基纤维素、聚乙二醇、聚乙烯醇、粘土矿物等粘度调节剂；氢氧化钾、氢氧化钠、柠檬酸等pH调节剂；植物提取物类；珠光剂；香料；紫外线吸收剂；防氧化剂；其它在洗发剂成分百科全书[ENCYCLOPEDIA OF SHAMPOO INGREDIENTS(MICELLEPRESS)]中记载的成分等。
本发明的毛发洗净剂组合物对头皮的抑制头皮屑、疥疮、丘疹、干燥等的效果优异，作为抗头皮屑洗发水是有用的。
实施例
以下实施例和比较例中的pH值为是用水稀释20重量倍时在25℃的值。
参考例1～3和比较例1～4
调制表1所示的洗发水，对其进行评价。
(透明症状改善效果的评价)
从20～40代的普通男女中，选择40名(男性20名，女性20名)肉眼观察看见头皮上有头皮屑和丘疹症状的受试者。对该受试者使用对照洗发水1个月内后，使用试验洗发水大约6周，肉眼观察评价其前后头皮状态变化。
将头皮分成12个区域，每个区域分成0～6级别的7个阶段，共计分成0～72个阶段的级别，头皮屑症状是将级别在10以上的作为头皮屑群的受试对象。丘疹症状是将头皮全体的丘疹数在3个以上的作为丘疹群的受试对象。健康群是头皮屑和丘疹的症状达不到头皮屑群和丘疹群的标准的情况。
头皮屑和丘疹的评价，是在双盲(double blind)条件下由熟练研究员进行的，按照使用前后的头皮屑级别、丘疹个数的平均变化量分等级，并表示在表1中。
疥疮、干燥的评价，是对受试者进行记录式5阶段(改善5点，稍改善4点，没有变化3点，稍恶化2点，恶化1点)的调查，按照评价点的平均(小数点以下第2位四舍五入)分等级，并表示在表1中。另外，以下表示对照洗发水的配方。
对照洗发水 (重量％)
聚氧乙烯(2)月桂醚硫酸钠 13.5
椰子油脂肪酸单乙醇胺 0.5
聚氧乙烯(16)月桂醚 2
月桂酰胺丙基甜菜碱 1.5
阳离子化纤维素 0.5
pH调节剂(柠檬酸，48重量％氢氧化钠水溶液) 调节至pH5.5*
精制水 余量
*：用水稀释20重量倍时，25℃
<头皮屑等级>
A(有效)：使用前后平均头皮屑级别减少10以上
B(稍微有效)：使用前后平均头皮屑级别减少5以上
C(没有变化)：使用前后平均头皮屑级别变化不到±5
D(恶化)：使用前后平均头皮屑级别增加5以上
<丘疹等级>
A(有效)：使用前后平均丘疹数减少5个以上
B(稍微有效)：使用前后平均丘疹数减少3个以上
C(没有变化)：使用前后平均丘疹数变化不到±3个
D(恶化)：使用前后平均丘疹数增加3个以上
<疥疮等级>
A(有效)：平均评价点为3.5以上
B(稍微有效)：平均评价点为3.2～3.4
C(没有变化)：平均评价点为2.8～3.1
D(恶化)：平均评价点为2.7以下
<干燥等级>
A(有效)：平均评价点为3.5以上
B(稍微有效)：平均评价点为3.2～3.4
C(没有变化)：平均评价点为2.8～3.1
D(恶化)：平均评价点为2.7以下
表1
| 成分名(重量％) | 实施例 | 比较例 | ||||||
| 1 | 2 | 3 | 1 | 2 | 3 | 4 | ||
| 聚氧乙烯(2)月桂醚硫酸钠 | 13.5 | 13.5 | 13.5 | 13.5 | 13.5 | 13.5 | 13.5 | |
| 椰子油脂肪酸单乙醇胺 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | |
| 聚氧乙烯(16)月桂醚 | 2 | 2 | 2 | 2 | 2 | 2 | 2 | |
| 月桂酰胺丙基甜菜碱 | 1.5 | 1.5 | 1.5 | 1.5 | 1.5 | 1.5 | 1.5 | |
| 苹果酸 | 0.75 | - | 0.75 | 0.75 | - | 0.75 | - | |
| 乳酸 | - | 0.75 | - | - | - | - | - | |
| 氧巯基吡啶锌 | - | - | - | - | - | - | 0.8 | |
| 甘草酸二钾 | 0.1 | 0.1 | - | - | 0.1 | 0.1 | - | |
| 甘草次酸硬脂醇酯 | - | - | 0.1 | - | - | - | - | |
| 阳离子化纤维素 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | |
| 柠檬酸 | - | - | - | - | 0.75 | - | 0.1 | |
| 48重量％氢氧化钠水溶液 | 适量* | 适量* | 适量* | 适量* | 适量* | 适量* | 适量* | |
| 精制水 | 余量 | 余量 | 余量 | 余量 | 余量 | 余量 | 余量 | |
| pH(用水稀释20重量倍时，25℃) | 3.7 | 3.7 | 3.7 | 3.7 | 3.7 | 3.7 | 3.7 | |
| 评价 | 头皮屑 | A | A | A | B | B | B | A |
| 疥疮 | A | A | A | C | B | B | A | |
| 丘疹 | A | A | A | B | C | C | C | |
| 干燥 | A | A | A | C | C | C | C | |
*：pH调节量
实施例1～3的洗发水对头皮的头皮屑、疥疮、丘疹、干燥的抑制效果优异。因此，不含有消炎剂的比较例1对疥疮或干燥的改善效果特别差。不含有成分(A)的有机酸而使用柠檬酸的比较例2特别是对丘疹或干燥的改善效果不能确定。含有成分(A)的有机酸但pH高的比较例3对头皮屑、疥疮、丘疹、干燥的改善效果不能确定。使用在pH5以上使用的通用抗菌剂氧巯基吡啶锌的比较例4对丘疹或干燥的抑制效果差。
实施例4透明洗发水
(重量％)
甘草酸二钾 0.1
聚氧乙烯(2)月桂醚硫酸钠 13.5
椰子油脂肪酸单乙醇胺 0.4
月桂酰胺丙基甜菜碱 1.5
聚氧乙烯(16)月桂醚 2.0
阳离子化纤维素 0.5
苹果酸 0.8
48重量％氢氧化钠水溶液 适量
香料 适量
精制水 余量
上述洗发水(pH＝3.7)对头皮的头皮屑、疥疮、丘疹、干燥的抑制效果优异。
实施例5珍珠外观洗发水
(重量％)
甘草酸二钾 0.1
聚氧乙烯(2)月桂醚硫酸钠 13.5
椰子油脂肪酸单乙醇胺 0.5
月桂酰胺丙基甜菜碱 1.5
聚氧乙烯(16)月桂醚 2.0
乙二醇二硬脂酸酯 2.0
阳离子化纤维素 0.5
高分子量甲基聚硅氧烷(聚合度1000～2700) 1.0
甲基聚硅氧烷(聚合度50～300) 1.4
苹果酸 0.8
氯化钠 0.2
48重量％氢氧化钠水溶液 适量
香料 适量
精制水 余量
上述洗发水(pH＝3.7)对头皮的头皮屑、疥疮、丘疹、干燥的抑制效果优异。
Claims (4)
1.一种毛发洗净剂组合物，其特征在于，
含有以下成分(A)、(B)和(C)，用水稀释20重量倍时在25℃的pH值为1～5，
(A)可以具有羟基的有机二羧酸或羟基单羧酸或其盐 0.1～20重量％，
(B)至少一种消炎剂 0.001～10重量％，
(C)阴离子表面活性剂 0.5～60重量％。
2.根据权利要求1所述的毛发洗净剂组合物，其特征在于，
成分(B)的消炎剂为选自甘草次酸、甘草酸、以及它们的衍生物的至少1种的抗炎症剂。
3.根据权利要求1或2所述的毛发洗净剂组合物，其特征在于，
所述毛发洗净剂组合物为抗头皮屑洗发剂。
4.一种丘疹、干燥的改善方法，其特征在于，
将含有以下成分(A)、(B)和(C)并且用水稀释20重量倍时在25℃的pH值为1～5的毛发洗净剂组合物适用于头皮后进行清洗，
(A)可以具有羟基的有机二羧酸或羟基单羧酸或其盐 0.1～20重量％，
(B)选自甘草次酸、甘草酸、以及它们的衍生物的至少1种的消炎剂 0.001～10重量％，
(C)阴离子表面活性剂 0.5～60重量％。
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| CN102361628A (zh) * | 2009-03-31 | 2012-02-22 | 花王株式会社 | 水性毛发清洗剂 |
| CN102361627A (zh) * | 2009-03-31 | 2012-02-22 | 花王株式会社 | 水性毛发清洗剂 |
| CN108697909A (zh) * | 2016-03-03 | 2018-10-23 | 宝洁公司 | 使用低pH毛发护理组合物清洁毛发的方法 |
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| JP5426213B2 (ja) * | 2009-03-31 | 2014-02-26 | 花王株式会社 | 水性毛髪洗浄剤 |
| JP5426212B2 (ja) * | 2009-03-31 | 2014-02-26 | 花王株式会社 | 水性毛髪洗浄剤 |
| JP2020536885A (ja) | 2017-10-10 | 2020-12-17 | ザ プロクター アンド ギャンブル カンパニーＴｈｅ Ｐｒｏｃｔｅｒ ＆ Ｇａｍｂｌｅ Ｃｏｍｐａｎｙ | 無機塩低含有の、サルフェートを含まないパーソナルクレンジング組成物 |
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| CN116568263A (zh) | 2020-12-04 | 2023-08-08 | 宝洁公司 | 包含恶臭减少材料的毛发护理组合物 |
| CN112704657A (zh) * | 2021-01-15 | 2021-04-27 | 拉芳家化股份有限公司 | 一种含竹提取物复合制剂的洗发香波 |
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| CN102361628A (zh) * | 2009-03-31 | 2012-02-22 | 花王株式会社 | 水性毛发清洗剂 |
| CN102361627A (zh) * | 2009-03-31 | 2012-02-22 | 花王株式会社 | 水性毛发清洗剂 |
| CN102361628B (zh) * | 2009-03-31 | 2013-07-10 | 花王株式会社 | 水性毛发清洗剂 |
| CN102361627B (zh) * | 2009-03-31 | 2013-11-13 | 花王株式会社 | 水性毛发清洗剂 |
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| CN108697909A (zh) * | 2016-03-03 | 2018-10-23 | 宝洁公司 | 使用低pH毛发护理组合物清洁毛发的方法 |
| CN108697909B (zh) * | 2016-03-03 | 2021-12-17 | 宝洁公司 | 使用低pH毛发护理组合物清洁毛发的方法 |
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| EP1842572A3 (en) | 2009-04-22 |
| EP1842572B1 (en) | 2013-10-30 |
| JP5075345B2 (ja) | 2012-11-21 |
| JP2007254355A (ja) | 2007-10-04 |
| TW200800279A (en) | 2008-01-01 |
| US20070224152A1 (en) | 2007-09-27 |
| EP1842572A2 (en) | 2007-10-10 |
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