CN1184950C - 洗涤化妆品组合物及其应用 - Google Patents
洗涤化妆品组合物及其应用 Download PDFInfo
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- CN1184950C CN1184950C CNB998128910A CN99812891A CN1184950C CN 1184950 C CN1184950 C CN 1184950C CN B998128910 A CNB998128910 A CN B998128910A CN 99812891 A CN99812891 A CN 99812891A CN 1184950 C CN1184950 C CN 1184950C
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- 229940045870 sodium palmitate Drugs 0.000 description 1
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- PUVAFTRIIUSGLK-UHFFFAOYSA-M trimethyl(oxiran-2-ylmethyl)azanium;chloride Chemical compound [Cl-].C[N+](C)(C)CC1CO1 PUVAFTRIIUSGLK-UHFFFAOYSA-M 0.000 description 1
- 125000002948 undecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000004417 unsaturated alkyl group Chemical group 0.000 description 1
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- 229920001285 xanthan gum Polymers 0.000 description 1
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- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
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- A61Q5/02—Preparations for cleaning the hair
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
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Abstract
本发明涉及新的发用洗涤和调理组合物,其中在化妆上可接受的介质中含有(A)洗涤基质和(B)至少一种C4-C6羧酸和C12-C26醇的酯。本发明适用于清洗和护理头发。
Description
本发明涉及新的具有改进特性、兼用于清洗和调理角质物质如头发的化妆品组合物,并且在化妆上可接受的含水载体中含有由具去污能力的表面活性剂组成的洗涤基质,该基质中还存在至少一种C4-C6羧酸和C12-C26醇的酯作为调理剂。本发明也涉及该组合物在上述化妆品中的应用。
通常使用主要基于特别是阴离子、非离子和/或两性类型的标准表面活性剂,更特别是阴离子型表面活性剂的洗涤剂组合物(例如香波)来清洁和/或洗涤角质纤维如头发。这些组合物涂敷在湿头发上,并且在用水漂洗后,用手揉搓产生出的皂泡除去了最初存在于头发上的多种污物。
这些基本组合物当然具有良好的洗涤能力,然而与它们有关的内生化妆特性仍然相当低劣,这特别归因于此类清洗处理的相对侵害性最终会对发纤维产生或多或少的明显损害这一事实,这种损害尤其与纤维中或表面上脂质或蛋白的逐渐消除有关。
所以,为了改进上述洗发组合物的化妆性质,特别是头发在敏感头发(即头发已被损害或变脆,特别是在气雾试剂(agentsatmosphériques)和/或美发处理如长效卷发、染色或脱色的化学作用下)上施用的那些性质,目前通常是在这些组合物中加入其他称作调理剂的化妆品试剂,这些调理剂的作用主要是对发质纤维或多或少反复遭受的多种处理或侵害所引起的有害或不利影响进行修复或限制。显然,这些调理剂也可以改进天然头发的化妆特性。
鉴于这个目标,已推荐使用聚硅氧烷类化合物,特别是在漂洗过程中可沉积在角质物质上的不溶性聚硅氧烷类化合物。然而,聚硅氧烷的缺点是难于在介质中保持为均匀分散体。
油如动植物油或脂肪酸酯已被建议作为调理剂应用。然而,常规组合物具有的洗涤和发泡性质无法令人满意。此外,用这些组合物处理过的角质物质常常具有不可接受的油腻触感。
本发明旨在提出所述调理和洗涤组合物克服上述缺陷,所述组合物发泡充分,具有良好的调理特性,特别是梳理、柔软和光泽特性,而不产生油腻性。
所以,在进行了大量有关这方面的研究之后,本申请人目前已发现,通过应用洗涤基质和至少一种含有4-6个碳原子的羧酸和含有12-26个碳原子的醇的液体酯,能够获得稳定的洗涤剂组合物,该组合物具有优异的功能性,例如良好的特质洗涤力和良好的发泡性(泡沫丰富度和耐久性,以及引发起泡)。此外,组合物具有较好的化妆特性,特别是使被处理头发易于成型、保持形状、生动并且饱满。
在漂洗后,本发明的组合物赋予头发一种显著的处理效果,其特别表现为易于梳理,并且提高了饱满度、光亮度、光滑度、柔软度和顺从度,同时没有任何粘腻感。
所以,本发明的一个目的是新的洗涤和调理美发组合物,其特征在于在其化妆上可接受的含水介质中含有(A)洗涤基质和(B)至少一种含有4-6个碳原子的羧酸和含有12-26个碳原子的醇的液体酯。
本发明的一个目的还在于上述组合物在清洁和/或调理头发中的化妆应用。
A-洗涤基质:
本发明的组合物必须含有洗涤基质,其通常含水。
组成所述洗涤基质的一种或多种表面活性剂独立地选自单独或作为混合物的阴离子、两性、非离子和阳离子表面活性剂。
然而,根据本发明,洗涤基质优选含有阴离子表面活性剂或阴离子表面活性剂与两性表面活性剂或非离子表面活性剂的混合物。
所以,根据本发明,洗涤基质可以占最终组合物总重量的4%-50%重量,优选6%-35%重量并且更优选8%-25%重量。
适合实施本发明的表面活性剂特别是下列物质:
(i)
阴离子表面活性剂
在本发明的范围中,它们的性质并不是非常关键的特征。
所以,在可单独或作为混合物用于本发明中的阴离子表面活性剂的实例中,特别可提及(非限定性列出)下列化合物的盐(碱性盐,尤其是钠盐、铵盐、胺盐、氨基醇盐或镁盐):烷基硫酸盐,烷基醚硫酸盐,烷基酰氨基醚硫酸盐,烷芳基聚醚硫酸盐,一甘油酯硫酸盐;烷基磺酸盐,烷基磷酸盐,烷基酰胺磺酸盐,烷芳基磺酸盐,α-烯属磺酸盐,石蜡磺酸盐;烷基磺基琥珀酸盐,烷基醚磺基琥珀酸盐,烷基酰胺磺基琥珀酸盐;烷基磺基琥珀酰胺酸盐;烷基磺基乙酸盐,烷基醚磷酸盐;酰基肌氨酸盐;酰基羟乙基磺酸盐,酰基谷氨酸盐和N-酰基牛磺酸盐,所有这些化合物的烷基或酰基优选含有12-20个碳原子,并且芳基优选表示苯基或苄基。在可使用的阴离子表面活性剂中,还可提及脂肪酸的盐,例如油酸、蓖麻酸、棕榈酸和硬脂酸,椰油酸或氢化椰油酸的盐;酰基乳酸盐,其中酰基含有8-20个碳原子。也可采用弱阴离子表面活性剂,例如烷基-D-半乳糖醛酸类化合物及其盐,以及聚氧化烯烷基(C6-C24)醚羧酸,聚氧化烯烷基(C6-C24)芳基醚羧酸,聚氧化烯烷基(C6-C24)酰氨基醚羧酸及其盐,特别是含有2-50氧化乙烯基的那些,和它们的混合物。
在阴离子表面活性剂中,本发明优选采用烷基硫酸盐和烷基醚硫酸盐和它们的混合物。
(ii)
非离子表面活性剂:
所述非离子表面活性剂是本身已知的化合物(特别参见M.R.Porter,的“表面活性剂手册”,Blackie & Son出版(Glasgow &London),1991,116-178页),在本发明范围中,它们的性质不是关键的特征。所以,它们可特别选自(非限定性列出)聚乙氧基化、聚丙氧基化或聚甘油化的醇、α-二元醇、烷基酚或脂肪酸,其具有含有例如8-18个碳原子的脂肪链,氧化乙烯基或氧化丙烯基的数目特别是在2-50的范围内,并且甘油基的数目特别是在2-30的范围内。还可提及氧化乙烯和氧化丙烯的共聚物,氧化乙烯和氧化丙烯与脂肪醇的缩合物;具有2-30mol氧化乙烯的聚乙氧基化脂肪酰胺,含有平均1-5和特别是1.5-4甘油基的聚甘油化脂肪酰胺;优选具有2-30mol氧化乙烯的聚乙氧基化脂肪胺;具有2-30mol氧化乙烯的脱水山梨糖醇氧乙烯脂肪酸酯;蔗糖的脂肪酸酯,聚乙二醇的脂肪酸酯,烷基聚葡糖苷,N-烷基葡糖胺衍生物,氧化胺如(C10-C24)烷基氧化胺或N-酰基氨基丙基吗啉氧化物。应注意,烷基聚葡糖苷构成的非离子表面活性剂特别适合于本发明。
(iii)
两性表面活性剂:
两性表面活性剂的性质在本发明范围中并不是关键特征,其特别可以是(非限定性列出)脂族仲或叔胺衍生物,其中脂族基团是含有8-22个碳原子的直链或支链并且含有至少一个水溶性阴离子基团(例如羧酸盐,磺酸盐、硫酸盐、磷酸盐或膦酸盐);也可以提及(C8-C20)烷基甜菜碱类,磺基甜菜碱类,(C8-C20)烷基酰氨基(C1-C6)烷基甜菜碱或(C8-C20)烷基酰氨基(C1-C6)烷基磺基甜菜碱类。
在这些胺类衍生物中,可提及的是以商品名Miranol出售的产品,公开在美国专利2528378和2781354中并且具有结构:
R2-CONHCH2CH2-N(R3)(R4)(CH2COO-) (2)
其中:R2代表由存在于水解椰油中的酸R2-COOH衍生的烷基,庚基,壬基或十一烷基,R3代表β-羟乙基和R4是羧甲基;和
R2’-CONHCH2CH2-N(B)(C) (3)
其中:
B代表-CH2CH2OX’,C代表-(CH2)z-Y’,同时
z=1或2,
X’代表-CH2CH2-COOH或氢原子,
Y’代表-COOH或-CH2-CHOH-SO3H,
R2’代表存在于椰油或水解亚麻子油中的酸R9-COOH的烷基,烷基,特别是C7、C9、C11或C13烷基,C17烷基及其异构形式,或不饱和C17基团。
这些化合物在CTFA辞典(第5版,1993)中被分类,命名为椰油两性二乙酸二钠,月桂两性二乙酸二钠,辛基(Capryl)两性二乙酸二钠,辛酰基(Caprylo)两性二乙酸二钠,椰油两性二丙酸二钠,月桂两性二丙酸二钠,辛基两性二丙酸二钠,辛酰基两性二丙酸二钠,月桂两性二丙酸,椰油两性二丙酸。例如,值得一提的是由RhodiaChimie公司以商品名MiranolC2M浓缩物出售的椰油两性二乙酸盐。
在本发明的组合物中,优选采用表面活性剂的混合物,特别是阴离子表面活性剂与两性或非离子表面活性剂的混合物。特别优选的一种混合物是由至少一种阴离子表面活性剂和至少一种两性表面活性剂构成的混合物。
优选应用选自如下的阴离子表面活性剂:(C12-C24)烷基硫酸钠、三乙醇胺或铵盐,用2.2mol氧化乙烯进行氧乙烯化的(C12-C14)烷基醚硫酸钠盐,椰油基羟乙磺酸钠和α-(C14-C16)烯属磺酸钠,以及它们与下列的混合物:
-两性表面活性剂,例如称作椰油两性二丙酸二钠或椰油两性丙酸钠的胺类衍生物,由Rhodia Chimie公司以商品名“MiranolC2M浓缩物”作为含有38%活性原料的水溶液或以MiranolC32出售;
-或两性离子型两性表面活性剂,例如烷基甜菜碱类,特别是由Henkel公司以商品名“DehytonAB 30”作为含有32%MA水溶液出售的椰油基甜菜碱;或烷基酰氨基烷基甜菜碱类,例如由Goldschmidt公司出售的TegobetaineF50;
(iv)
阳离子表面活性剂:
在阳离子表面活性剂中,特别值得一提的是(非限定性列出):任选聚氧化烯化的伯、仲或叔脂肪胺盐;季铵盐,例如四烷基铵、烷基酰氨基烷基三烷基铵、三烷基苄基铵、三烷基羟烷基铵或烷基吡啶鎓的氯化物或溴化物;咪唑啉衍生物;或阳离子性质的氧化胺类。
应注意,不排除使用的阳离子表面活性剂不构成实施本发明的优选表面活性剂。
B-液体酯类
本发明的组合物必须含有至少一种含有4-6个碳原子的羧酸与含有12-26个碳原子的醇的液体酯。这些酯类化合物不溶于水,在25℃时的浓度大于0.1%。它们在低于30℃的室温下呈液态。
本发明的液体酯优选具有下列通式:
R1COOR2 (I)
其中:
R1代表含有3-5个碳原子的直链或支链、任选地单或多羟基化含烃基团,
R2代表直链或支链、任选地单或多羟基化含烃基团,该基团含有12-26个碳原子并且优选含有16-22个碳原子,
R1优选代表含有3-5个碳原子的支链烷基,并且更具体是叔丁基,
R2优选代表含有12-26个碳原子的饱和或不饱和烷基,特别是支链基团,并且更具体选自十三烷基、异鲸蜡基、异硬脂基、辛基十二烷基和异二十烷基。
所述液体酯特别优选是新戊酸异硬脂基酯(式(I),其中R1=叔丁基和R2=异硬脂基),新戊酸十三烷基酯,新戊酸异鲸蜡基酯和新戊酸异二十烷酯。
定义如上的液体酯在本发明组合物中使用时的浓度一般是该组合物总重量的0.1%至20%重量并且优选0.2%至10%重量,特别是0.5%至5%重量。
化妆上可接受的水介质可以仅仅由水组成,或者是水和化妆上可接受溶剂的混合物,所述化妆上可接受溶剂例如是C1-C4低级醇,如乙醇、异丙醇、叔丁醇、正丁醇;亚烷基二醇,如丙二醇;或二醇醚类。
本发明的洗涤剂组合物具有的最终pH通常为3至10。优选该pH为5至8。一般通过向组合物中加入碱(有机或无机)将pH调节至预定值,所述碱例如是氨水或伯、仲或叔(聚)胺,如单乙醇胺,二乙醇胺,三乙醇胺,异丙醇胺或1,3-丙二胺,或另外通过加入无机或有机酸将pH调节至预定值,优选羧酸,如柠檬酸。
除了定义如上的联合形式以外,本发明的组合物可以含有粘度调节剂,如电解质或增稠剂。特别值得一提的是氯化钠,二甲苯磺酸钠,紫胶葡聚糖(scléroglucane),黄原胶,脂肪酸烷醇酰胺,任选地被至多5mol氧化乙烯进行氧乙烯化的烷基醚羧酸烷醇酰胺,例如由Chem Y公司以名称“Aminol A15”出售的产品,交联聚丙烯酸和交联的丙烯酸/C10-C30丙烯酸烷基酯共聚物。这些粘度调节剂在本发明组合物中的使用比例至多是该组合物总重量的10%重量。
本发明的组合物也可以含有高达5%的所属领域熟知的珠光剂或遮光剂,例如C16高级脂肪醇,棕榈酸钠或镁,硬脂酸钠或镁和羟基硬脂酸钠或镁;脂肪链酰基衍生物,如乙二醇或聚乙二醇的单硬脂酸酯或二硬脂酸酯;和脂肪链醚,如二硬脂基醚或1-(十六烷氧基)-2-十八烷醇。
本发明的组合物还可以任选地含有其他试剂,其作用是改进头发或皮肤的美容特性但不对组合物的稳定性产生不利影响。这方面可提及阳离子表面活性剂,阴离子、非离子、阳离子或两性聚合物,蛋白质,蛋白水解产物,神经酰胺类,假神经酰胺类;含有直链或支链C16-C40链的脂肪酸,如18-甲基二十烷酸;羟基酸,维生素类,泛醇,挥发性或非挥发性聚硅氧烷,它们可溶于或不溶性所述介质中,植物油和合成油,以及它们的混合物。
可用于本发明中的阳离子聚合物类调理剂可选自任何本身已知的那些调理剂,用于改善用洗涤剂组合物处理过头发的美容特性,即,特别是公开在专利申请EP-A-0 337 354和法国专利申请FR-A-2270 846、FR-A-2383 660,FR-A-2598 611,FR-A-2 470 596和FR-A-2519 863中的那些。
鉴于本发明的目的,广义上来说,术语“阳离子聚合物”表示含有任何阳离子基团和/或可以电离生成阳离子基团的聚合物。
在可用于本发明的阳离子聚合物中,优选采用季化纤维素醚衍生物,如由联合碳化物公司(Union Carbide Corporation)以名称“JR400”出售的产品;共聚物,特别是二烯丙基二甲基铵盐均聚物和二烯丙基二甲基铵盐与丙烯酰胺的共聚物,特别是氯化物,由Merck公司以名称“Merquat 100”、“Merquat 550”和“Merquat S”出售的产品;和用2,3-环氧丙基三甲基氯化铵,例如Meyhall公司以名称“Jaguar C13S”出售的产品。
根据本发明,阳离子聚合物可以是最终组合物总重量的0.001%至10%重量,优选0.05%至5%重量并且特别优选0.01%至3%重量。
本发明的组合物也可以含有泡沫增效剂,例如C10-C18的1,2-烷二醇或由单或二乙醇胺衍生的脂肪烷醇酰胺。
显然,所属领域普通技术人员应谨慎选择这种或这些任选的补充化合物和/或其用量,从而经其预计的加入不会或基本上不会对与本发明联合形式(洗涤基质+本发明所述的酯)有关的特定优越特性造成不利影响。
这些组合物可以是稠度不同的液体、霜剂或凝胶的形式,并且主要适用于洗涤和护理头发。
当本发明的组合物作为标准香波使用时,直接将它们涂敷在湿头发上并且用手揉搓出泡沫,在头发上保持任选的一段时间后,随后通过在水中漂洗可除去泡沫,可以将这种操作反复一次或多次。
本发明的一个目的还在于一种洗涤和调理的方法,其包括将有效量的如上定义的组合物涂敷在温的头发上,在保留任选的一段时间后,用水漂洗它们。
现将给出具体但不是限定性的实施例来举例说明本发明。
实施例1
两种香波组合物制备如下,一种是本发明的组合物(组合物A),另一组合物是对照组合物(组合物B):
A
B
本发明 对照
-含有2.2mol氧化乙烯的月桂基醚硫 12.6gMA 12.6gMA
酸钠(70/30 C12/C14)(含有70%MA的
水溶液)
(MA=活性物质)
-椰油两性二乙酸二钠 2.7gMA 2.7gMA
(Miranol C2M浓缩物。(NP*)(含有
38%MA的水溶液)
-新戊酸异硬脂基酯 1g -
-阳离子纤维素胶 0.2g 0.2g
(Union Carbide提供的聚合物JR 400)
-乙二醇二硬脂酸酯 1.5g 1.5g
-NaCl 1.1g 1.1g
-鲸蜡基硬脂基硫酸钠 0.7gMA 0.7gMA
(Cétéarylsulfate de sodium)(90%
MA)
-椰酸单异丙醇酰胺 1.5g 1.5g
-香料,防腐剂 适量 适量
-柠檬酸 0.6g 0.6g
-去离子水 适量 100g 100g
(*)Rhodia Chimie出售的Miranol C2M浓缩物。
R代表基于椰子衍生的C8-C18烷基混合物,M代表Na。
洗发是将约12g的组合物A涂敷在预先打湿的敏感头发上。香波产生泡沫,随后用水彻底漂洗。
采用对照组合物B进行与上述相同的操作过程。
一组专业人员评定两种组合物的发泡性质和美容特性。
专家指出,本发明的组合物A非常容易引发泡沫并且泡沫更加轻盈。
用组合物A处理的湿发容易梳理并且更加柔顺。干发更光滑并且更加膨松和易整理。
实施例2
本发明的一种香波组合物制备如下:
-含有2.2mol氧化乙烯的月桂基醚硫酸钠 12.6gMA
(70/30 C12/C14)(含有70%MA的水溶液)
(MA=活性物质)
-椰油两性二乙酸二钠 2.7gMA
(Miranol C2M浓缩物。(NP*)(含有38%MA
的水溶液)
-新戊酸十三烷酯 1.5g
-阳离子纤维素胶 0.2g
(Union Carbide提供的聚合物JR 400)
-乙二醇二硬脂酸酯 1.5g
-鲸蜡基硬脂基硫酸钠(Cétéarylsulfate de 0.7gAM
sodium)(90%MA)
-椰酸单异丙醇酰胺 4g
-香料,防腐剂 适量
-NaOH 0.1g
-柠檬酸 0.55g
-去离子水 适量 100g
(*)Rhodia Chimie出售的Miranol C2M浓缩物。
R代表基于椰子衍生的C8-C18烷基混合物,M代表Na。
洗发是将约12g的组合物A涂敷在预先打湿的敏感头发上。香波产生泡沫,随后用水彻底漂洗。
泡沫非常容易引发并且泡沫更加轻盈。
用组合物处理的湿发容易梳理并且更加柔顺。干发光滑并且膨松和易整理。
Claims (8)
1.洗涤和调理美发组合物,其特征在于在化妆上可接受的介质中含有(A)含量是该组合物总重量的4%至50%重量的洗涤基质,所述洗涤基质含有一种或多种表面活性剂,选自阴离子、两性、非离子表面活性剂,和它们的混合物;和(B)至少一种液体酯,所述酯具有下式:
R1COOR2 (I)
其中:
R1代表含有3-5个碳原子的支链烷基,
R2代表含有12-26个碳原子的烷基;
所述酯存在的浓度是该组合物总重量的0.1%-20%重量。
2.根据权利要求1的组合物,其特征在于R1代表叔丁基。
3.根据权利要求1的组合物,其特征在于R2选自十三烷基、异鲸蜡基、异硬脂基、辛基十二烷基和异二十烷基。
4.根据权利要求1的组合物,其特征在于还含有一种或多种选自如下的辅剂:阳离子表面活性剂,阴离子或非离子或阳离子或两性的聚合物,蛋白质,神经酰胺,假神经酰胺,聚硅氧烷,植物油,合成油,羟基酸,维生素和泛醇,以及它们的混合物。
5.根据权利要求4的组合物,其特征在于所述阳离子聚合物选自季化纤维素醚衍生物,二烯丙基二甲基铵盐均聚物,二烯丙基二甲基铵盐和丙烯酰胺的共聚物,阳离子多糖。
6.根据权利要求5的组合物,其特征在于所述阳离子聚合物占该组合物总重量的0.001%-10%重量。
7.权利要求1-6任一项定义的组合物在清洁和/或调理头发中的应用。
8.清洗和调理头发的方法,其中包括将有效量的权利要求1-6任一项定义的组合物涂敷在湿的头发上,在保留任选的一段时间后,用水漂洗。
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FR9813865A FR2785181B1 (fr) | 1998-11-04 | 1998-11-04 | Compositions cosmetiques detergentes et utilisation |
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EP (1) | EP1126817B1 (zh) |
JP (1) | JP3807483B2 (zh) |
KR (1) | KR100462249B1 (zh) |
CN (1) | CN1184950C (zh) |
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ES (1) | ES2288027T3 (zh) |
FR (1) | FR2785181B1 (zh) |
PL (1) | PL199430B1 (zh) |
PT (1) | PT1126817E (zh) |
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JP2005515215A (ja) * | 2001-12-21 | 2005-05-26 | ローディア インコーポレイティド | 成分を懸濁させるための安定な界面活性剤組成物 |
JP4116918B2 (ja) * | 2003-04-17 | 2008-07-09 | 花王株式会社 | 毛髪化粧料 |
FR2883744B1 (fr) * | 2005-03-30 | 2009-07-03 | Oreal | Compositions cosmetiques detergentes comprenant trois tensioactifs et un ester gras et utilisation |
US8147813B2 (en) * | 2005-03-30 | 2012-04-03 | L'oreal S.A. | Detergent cosmetic compositions comprising three surfactants and at least one fatty ester, and use thereof |
US20070104669A1 (en) * | 2005-10-26 | 2007-05-10 | Rainer Muller | Cosmetic composition comprising at least one ester, at least one acrylic polymer, at least one cyclodextrin and at least one surfactant, and uses thereof |
FR2900336B1 (fr) * | 2006-04-28 | 2008-07-18 | Oreal | Composition de lavage des matieres keratiniques et procede de traitement cosmetique mettant en oeuvre ladite composition |
FR2920974B1 (fr) * | 2007-09-14 | 2010-02-12 | Oreal | Compositions cosmetiques contenant un copolymere cationique acrylique, un ester gras liquide et un polymere cationique et leurs utilisations |
FR2933613B1 (fr) | 2008-07-08 | 2010-11-12 | Oreal | Compositions cosmetiques detergentes comprenant une silicone aminee et utilisation |
FR2933612B1 (fr) | 2008-07-08 | 2010-11-12 | Oreal | Compositions cosmetiques detergentes comprenant une silicone aminee et utilisation |
WO2013014951A1 (ja) | 2011-07-28 | 2013-01-31 | 花王株式会社 | 水性毛髪洗浄剤 |
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US2528378A (en) | 1947-09-20 | 1950-10-31 | John J Mccabe Jr | Metal salts of substituted quaternary hydroxy cycloimidinic acid metal alcoholates and process for preparation of same |
US2781354A (en) | 1956-03-26 | 1957-02-12 | John J Mccabe Jr | Imidazoline derivatives and process |
CH611156A5 (zh) | 1974-05-16 | 1979-05-31 | Oreal | |
US5196189A (en) | 1974-05-16 | 1993-03-23 | Societe Anonyme Dite: L'oreal | Quaternized polymer for use as a cosmetic agent in cosmetic compositions for the hair and skin |
GB1555796A (en) * | 1976-10-15 | 1979-11-14 | Unilever Ltd | Composition for treating acne |
LU76955A1 (zh) | 1977-03-15 | 1978-10-18 | ||
FR2470596A1 (fr) | 1979-11-28 | 1981-06-12 | Oreal | Composition destinee au traitement des fibres keratiniques a base de polymeres amphoteres et de polymeres cationiques |
LU83876A1 (fr) | 1982-01-15 | 1983-09-02 | Oreal | Composition cosmetique destinee au traitement des fibres keratiniques et procede de traitement de celles-ci |
US5139037A (en) | 1982-01-15 | 1992-08-18 | L'oreal | Cosmetic composition for treating keratin fibres, and process for treating the latter |
LU86429A1 (fr) | 1986-05-16 | 1987-12-16 | Oreal | Compositions cosmetiques renfermant un polymere cationique et un polymere anionique comme agent epaississant |
US5013763A (en) * | 1987-11-30 | 1991-05-07 | The Andrew Jergens Company | Wash-off-resistant skin preparation |
MY105119A (en) | 1988-04-12 | 1994-08-30 | Kao Corp | Low irritation detergent composition. |
ES2076784T3 (es) * | 1991-10-07 | 1995-11-01 | Nephin | Barra solida para el aseo. |
US5635469A (en) * | 1993-06-10 | 1997-06-03 | The Procter & Gamble Company | Foaming cleansing products |
US5656280A (en) | 1994-12-06 | 1997-08-12 | Helene Curtis, Inc. | Water-in-oil-in-water compositions |
GB9507130D0 (en) * | 1995-04-06 | 1995-05-31 | Unilever Plc | Hair treatment composition |
FR2740331B1 (fr) * | 1995-10-25 | 1997-12-19 | Sederma Sa | Nouvelles compositions cosmetiques pour le traitement des cheveux et du cuir chevelu |
FR2755851B1 (fr) * | 1996-11-15 | 1998-12-24 | Oreal | Compositions cosmetiques detergentes et utilisation |
US5916575A (en) * | 1997-01-27 | 1999-06-29 | The Procter & Gamble Company | Cleaning products |
US5882661A (en) * | 1997-03-12 | 1999-03-16 | Elizabeth Arden Co., Division Of Conopco, Inc. | Composition and method for topical application to skin, hair and nails |
US6143286A (en) * | 1998-08-05 | 2000-11-07 | Revlon Consumer Products Corporation | Method for improving the fade resistance of hair and related compositions |
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CA2345374A1 (fr) | 2000-05-11 |
KR20010075686A (ko) | 2001-08-09 |
KR100462249B1 (ko) | 2004-12-17 |
DE69936266T2 (de) | 2008-02-28 |
JP2002528478A (ja) | 2002-09-03 |
CN1325295A (zh) | 2001-12-05 |
JP3807483B2 (ja) | 2006-08-09 |
ATE363924T1 (de) | 2007-06-15 |
WO2000025735A1 (fr) | 2000-05-11 |
BR9914763A (pt) | 2001-11-06 |
AU6346299A (en) | 2000-05-22 |
EP1126817A1 (fr) | 2001-08-29 |
AU748347B2 (en) | 2002-06-06 |
RU2204985C2 (ru) | 2003-05-27 |
US6726902B1 (en) | 2004-04-27 |
DE69936266D1 (de) | 2007-07-19 |
DK1126817T3 (da) | 2007-07-02 |
FR2785181B1 (fr) | 2006-06-02 |
US7179452B2 (en) | 2007-02-20 |
PL347227A1 (en) | 2002-03-25 |
PT1126817E (pt) | 2007-07-27 |
ES2288027T3 (es) | 2007-12-16 |
PL199430B1 (pl) | 2008-09-30 |
FR2785181A1 (fr) | 2000-05-05 |
US20040170593A1 (en) | 2004-09-02 |
EP1126817B1 (fr) | 2007-06-06 |
BR9914763B1 (pt) | 2010-09-08 |
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