JP5075345B2 - 毛髪洗浄剤組成物 - Google Patents
毛髪洗浄剤組成物 Download PDFInfo
- Publication number
- JP5075345B2 JP5075345B2 JP2006080782A JP2006080782A JP5075345B2 JP 5075345 B2 JP5075345 B2 JP 5075345B2 JP 2006080782 A JP2006080782 A JP 2006080782A JP 2006080782 A JP2006080782 A JP 2006080782A JP 5075345 B2 JP5075345 B2 JP 5075345B2
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- Prior art keywords
- acid
- weight
- dandruff
- fatty acid
- hair
- Prior art date
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- 239000000203 mixture Substances 0.000 title claims description 24
- 238000004140 cleaning Methods 0.000 title description 6
- -1 glyceryl glycinate Chemical compound 0.000 claims description 39
- 208000001840 Dandruff Diseases 0.000 claims description 30
- 239000002453 shampoo Substances 0.000 claims description 16
- 150000003839 salts Chemical class 0.000 claims description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 8
- 239000003945 anionic surfactant Substances 0.000 claims description 7
- 229940121363 anti-inflammatory agent Drugs 0.000 claims description 7
- 239000002260 anti-inflammatory agent Substances 0.000 claims description 7
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 claims description 5
- MPDGHEJMBKOTSU-YKLVYJNSSA-N 18beta-glycyrrhetic acid Chemical compound C([C@H]1C2=CC(=O)[C@H]34)[C@@](C)(C(O)=O)CC[C@]1(C)CC[C@@]2(C)[C@]4(C)CC[C@@H]1[C@]3(C)CC[C@H](O)C1(C)C MPDGHEJMBKOTSU-YKLVYJNSSA-N 0.000 claims description 5
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 claims description 5
- 239000001630 malic acid Substances 0.000 claims description 5
- 235000011090 malic acid Nutrition 0.000 claims description 5
- BIVBRWYINDPWKA-VLQRKCJKSA-L Glycyrrhizinate dipotassium Chemical compound [K+].[K+].O([C@@H]1[C@@H](O)[C@H](O)[C@H](O[C@@H]1O[C@H]1CC[C@]2(C)[C@H]3C(=O)C=C4[C@@H]5C[C@](C)(CC[C@@]5(CC[C@@]4(C)[C@]3(C)CC[C@H]2C1(C)C)C)C(O)=O)C([O-])=O)[C@@H]1O[C@H](C([O-])=O)[C@@H](O)[C@H](O)[C@H]1O BIVBRWYINDPWKA-VLQRKCJKSA-L 0.000 claims description 4
- 229940101029 dipotassium glycyrrhizinate Drugs 0.000 claims description 4
- VTAJIXDZFCRWBR-UHFFFAOYSA-N Licoricesaponin B2 Natural products C1C(C2C(C3(CCC4(C)CCC(C)(CC4C3=CC2)C(O)=O)C)(C)CC2)(C)C2C(C)(C)CC1OC1OC(C(O)=O)C(O)C(O)C1OC1OC(C(O)=O)C(O)C(O)C1O VTAJIXDZFCRWBR-UHFFFAOYSA-N 0.000 claims description 3
- LPLVUJXQOOQHMX-UHFFFAOYSA-N glycyrrhetinic acid glycoside Natural products C1CC(C2C(C3(CCC4(C)CCC(C)(CC4C3=CC2=O)C(O)=O)C)(C)CC2)(C)C2C(C)(C)C1OC1OC(C(O)=O)C(O)C(O)C1OC1OC(C(O)=O)C(O)C(O)C1O LPLVUJXQOOQHMX-UHFFFAOYSA-N 0.000 claims description 3
- 239000001685 glycyrrhizic acid Substances 0.000 claims description 3
- 229960004949 glycyrrhizic acid Drugs 0.000 claims description 3
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- 235000019410 glycyrrhizin Nutrition 0.000 claims description 3
- LPLVUJXQOOQHMX-QWBHMCJMSA-N glycyrrhizinic acid Chemical compound O([C@@H]1[C@@H](O)[C@H](O)[C@H](O[C@@H]1O[C@@H]1C([C@H]2[C@]([C@@H]3[C@@]([C@@]4(CC[C@@]5(C)CC[C@@](C)(C[C@H]5C4=CC3=O)C(O)=O)C)(C)CC2)(C)CC1)(C)C)C(O)=O)[C@@H]1O[C@H](C(O)=O)[C@@H](O)[C@H](O)[C@H]1O LPLVUJXQOOQHMX-QWBHMCJMSA-N 0.000 claims description 3
- MPDGHEJMBKOTSU-UHFFFAOYSA-N Glycyrrhetinsaeure Natural products C12C(=O)C=C3C4CC(C)(C(O)=O)CCC4(C)CCC3(C)C1(C)CCC1C2(C)CCC(O)C1(C)C MPDGHEJMBKOTSU-UHFFFAOYSA-N 0.000 claims description 2
- ILRKKHJEINIICQ-OOFFSTKBSA-N Monoammonium glycyrrhizinate Chemical compound N.O([C@@H]1[C@@H](O)[C@H](O)[C@H](O[C@@H]1O[C@H]1CC[C@]2(C)[C@H]3C(=O)C=C4[C@@H]5C[C@](C)(CC[C@@]5(CC[C@@]4(C)[C@]3(C)CC[C@H]2C1(C)C)C)C(O)=O)C(O)=O)[C@@H]1O[C@H](C(O)=O)[C@@H](O)[C@H](O)[C@H]1O ILRKKHJEINIICQ-OOFFSTKBSA-N 0.000 claims description 2
- KPQJOKRSYYJJEL-VLQRKCJKSA-K [Na+].[Na+].CC1(C)[C@H](CC[C@@]2(C)[C@H]1CC[C@]1(C)[C@@H]2C(=O)C=C2[C@@H]3C[C@](C)(CC[C@]3(C)CC[C@@]12C)C([O-])=O)O[C@H]1O[C@@H]([C@@H](O)[C@H](O)[C@H]1O[C@@H]1O[C@@H]([C@@H](O)[C@H](O)[C@H]1O)C([O-])=O)C([O-])=O Chemical compound [Na+].[Na+].CC1(C)[C@H](CC[C@@]2(C)[C@H]1CC[C@]1(C)[C@@H]2C(=O)C=C2[C@@H]3C[C@](C)(CC[C@]3(C)CC[C@@]12C)C([O-])=O)O[C@H]1O[C@@H]([C@@H](O)[C@H](O)[C@H]1O[C@@H]1O[C@@H]([C@@H](O)[C@H](O)[C@H]1O)C([O-])=O)C([O-])=O KPQJOKRSYYJJEL-VLQRKCJKSA-K 0.000 claims description 2
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- WNIFXKPDILJURQ-JKPOUOEOSA-N octadecyl (2s,4as,6ar,6as,6br,8ar,10s,12as,14br)-10-hydroxy-2,4a,6a,6b,9,9,12a-heptamethyl-13-oxo-3,4,5,6,6a,7,8,8a,10,11,12,14b-dodecahydro-1h-picene-2-carboxylate Chemical compound C1C[C@H](O)C(C)(C)[C@@H]2CC[C@@]3(C)[C@]4(C)CC[C@@]5(C)CC[C@@](C(=O)OCCCCCCCCCCCCCCCCCC)(C)C[C@H]5C4=CC(=O)[C@@H]3[C@]21C WNIFXKPDILJURQ-JKPOUOEOSA-N 0.000 claims description 2
- WNIFXKPDILJURQ-UHFFFAOYSA-N stearyl glycyrrhizinate Natural products C1CC(O)C(C)(C)C2CCC3(C)C4(C)CCC5(C)CCC(C(=O)OCCCCCCCCCCCCCCCCCC)(C)CC5C4=CC(=O)C3C21C WNIFXKPDILJURQ-UHFFFAOYSA-N 0.000 claims description 2
- CCXAYLQLOLXXKE-DWJAGBRCSA-K trisodium;(2s,3s,4s,5r,6r)-6-[(2s,3r,4s,5s,6s)-2-[[(3s,4ar,6ar,6bs,8as,11s,12ar,14ar,14bs)-11-carboxylato-4,4,6a,6b,8a,11,14b-heptamethyl-14-oxo-2,3,4a,5,6,7,8,9,10,12,12a,14a-dodecahydro-1h-picen-3-yl]oxy]-6-carboxylato-4,5-dihydroxyoxan-3-yl]oxy-3,4,5-t Chemical compound [Na+].[Na+].[Na+].O([C@@H]1[C@@H](O)[C@H](O)[C@H](O[C@@H]1O[C@H]1CC[C@]2(C)[C@H]3C(=O)C=C4[C@@H]5C[C@](C)(CC[C@@]5(CC[C@@]4(C)[C@]3(C)CC[C@H]2C1(C)C)C)C([O-])=O)C([O-])=O)[C@@H]1O[C@H](C([O-])=O)[C@@H](O)[C@H](O)[C@H]1O CCXAYLQLOLXXKE-DWJAGBRCSA-K 0.000 claims description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 33
- 239000000194 fatty acid Substances 0.000 description 33
- 229930195729 fatty acid Natural products 0.000 description 33
- 150000004665 fatty acids Chemical class 0.000 description 24
- 229920001296 polysiloxane Polymers 0.000 description 21
- 208000003251 Pruritus Diseases 0.000 description 18
- 230000007803 itching Effects 0.000 description 17
- 230000000694 effects Effects 0.000 description 16
- 210000004761 scalp Anatomy 0.000 description 15
- 206010000496 acne Diseases 0.000 description 13
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 12
- KWIUHFFTVRNATP-UHFFFAOYSA-O N,N,N-trimethylglycinium Chemical compound C[N+](C)(C)CC(O)=O KWIUHFFTVRNATP-UHFFFAOYSA-O 0.000 description 12
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 12
- 229960003237 betaine Drugs 0.000 description 12
- 238000011156 evaluation Methods 0.000 description 11
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 9
- 239000003921 oil Substances 0.000 description 9
- 235000019198 oils Nutrition 0.000 description 9
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 8
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- 125000004432 carbon atom Chemical group C* 0.000 description 8
- 229920001577 copolymer Polymers 0.000 description 8
- 239000002253 acid Substances 0.000 description 7
- 208000024891 symptom Diseases 0.000 description 7
- KIWBPDUYBMNFTB-UHFFFAOYSA-N Ethyl hydrogen sulfate Chemical compound CCOS(O)(=O)=O KIWBPDUYBMNFTB-UHFFFAOYSA-N 0.000 description 6
- 239000004166 Lanolin Substances 0.000 description 6
- 229920006317 cationic polymer Polymers 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- 230000003750 conditioning effect Effects 0.000 description 6
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 6
- 235000019388 lanolin Nutrition 0.000 description 6
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- 239000004094 surface-active agent Substances 0.000 description 6
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 5
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- 239000003795 chemical substances by application Substances 0.000 description 5
- 239000003240 coconut oil Substances 0.000 description 5
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- 230000006866 deterioration Effects 0.000 description 5
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 4
- 125000000217 alkyl group Chemical group 0.000 description 4
- 230000003247 decreasing effect Effects 0.000 description 4
- 235000011187 glycerol Nutrition 0.000 description 4
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 4
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 4
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- 150000007524 organic acids Chemical class 0.000 description 4
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 4
- CMCBDXRRFKYBDG-UHFFFAOYSA-N 1-dodecoxydodecane Chemical compound CCCCCCCCCCCCOCCCCCCCCCCCC CMCBDXRRFKYBDG-UHFFFAOYSA-N 0.000 description 3
- 239000005639 Lauric acid Substances 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
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- PRAKJMSDJKAYCZ-UHFFFAOYSA-N dodecahydrosqualene Natural products CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 3
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- GEYJUFBPCGDENK-UHFFFAOYSA-M sodium;3,8-dimethyl-5-propan-2-ylazulene-1-sulfonate Chemical compound [Na+].CC(C)C1=CC=C(C)C2=C(S([O-])(=O)=O)C=C(C)C2=C1 GEYJUFBPCGDENK-UHFFFAOYSA-M 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 229940032094 squalane Drugs 0.000 description 1
- 229940031439 squalene Drugs 0.000 description 1
- TUHBEKDERLKLEC-UHFFFAOYSA-N squalene Natural products CC(=CCCC(=CCCC(=CCCC=C(/C)CCC=C(/C)CC=C(C)C)C)C)C TUHBEKDERLKLEC-UHFFFAOYSA-N 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- SFVFIFLLYFPGHH-UHFFFAOYSA-M stearalkonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 SFVFIFLLYFPGHH-UHFFFAOYSA-M 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 229940012831 stearyl alcohol Drugs 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
- GYDJEQRTZSCIOI-LJGSYFOKSA-N tranexamic acid Chemical compound NC[C@H]1CC[C@H](C(O)=O)CC1 GYDJEQRTZSCIOI-LJGSYFOKSA-N 0.000 description 1
- 229960000401 tranexamic acid Drugs 0.000 description 1
- NRLLZRJXDKUVHM-UHFFFAOYSA-N tridecyl 7-methyloctanoate Chemical class CCCCCCCCCCCCCOC(=O)CCCCCC(C)C NRLLZRJXDKUVHM-UHFFFAOYSA-N 0.000 description 1
- SZEMGTQCPRNXEG-UHFFFAOYSA-M trimethyl(octadecyl)azanium;bromide Chemical compound [Br-].CCCCCCCCCCCCCCCCCC[N+](C)(C)C SZEMGTQCPRNXEG-UHFFFAOYSA-M 0.000 description 1
- 229940045136 urea Drugs 0.000 description 1
- 239000004034 viscosity adjusting agent Substances 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
- A61K8/365—Hydroxycarboxylic acids; Ketocarboxylic acids
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/63—Steroids; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
- A61P17/00—Drugs for dermatological disorders
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/006—Antidandruff preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Emergency Medicine (AREA)
- Dermatology (AREA)
- Bioinformatics & Cheminformatics (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Medicinal Chemistry (AREA)
- Nuclear Medicine, Radiotherapy & Molecular Imaging (AREA)
- Organic Chemistry (AREA)
- Pharmacology & Pharmacy (AREA)
- Engineering & Computer Science (AREA)
- Cosmetics (AREA)
Description
(B) 少なくとも1種の消炎剤 0.001〜10重量%
(C) アニオン界面活性剤 0.5〜60重量%
R2O-SO3M (2)
R3(CH3)2SiO−[(CH3)2SiO]b-Si(CH3)2R3
〔式中、R3はメチル基又はヒドロキシ基を示し、bは3〜20000の数を示す。〕
各種のアミノ変性シリコーンが使用できるが、特に平均分子量が約3000〜100000の、アモジメチコーン(Amodimethicone)の名称でCTFA辞典(米国,Cosmetic Ingredient Dictionary)第3版中に記載されているものが好ましい。このアミノ変性シリコーンは水性乳濁液として用いるのが好ましく、市販品としては、SM8704C〔東レ・ダウコーニング(株)〕、DC 929〔ダウ・コーニング社〕等が挙げられる。
上記以外に、ポリエーテル変性シリコーン、メチルフェニルポリシロキサン、脂肪酸変性シリコーン、アルコール変性シリコーン、アルコキシ変性シリコーン、エポキシ変性シリコーン、フッ素変性シリコーン、環状シリコーン、アルキル変性シリコーン等が挙げられる。
表1に示すシャンプーを調製し、その評価を行った。
20〜40代の一般男女から、目視により頭皮にフケと吹き出物症状の見られる群40名(男性20名、女性20名)の被験者を選抜した。これら被験者に対し、1ヶ月間、コントロールシャンプーを使用させた後、試験シャンプーを約6週間使用させ、その前後の頭皮状態変化を目視により評価した。
フケ症状は、頭皮を12の領域に分け、各領域ごとにレベル0〜6の7段階、合計0〜72の段階にレベル分けをし、レベル10以上をフケ群の対象とした。吹き出物症状は、頭皮全体の吹き出物数が3個以上を吹き出物群の対象とした。健常群は、フケ及び吹き出物の症状が、フケ群、吹き出物群の基準未満である場合とした。
フケ及び吹き出物の評価は、ダブルブラインドの条件下で熟練した研究員により行い、使用前後のフケレベル、吹き出物個数の変化量の平均からランク分けし、表1に示した。
かゆみ、かさつきの評価は、被験者に記入式5段階(改善5点、やや改善4点、変化なし3点、やや悪化2点、悪化1点)のアンケートを行い、評価点の平均(小数点以下第2位を四捨五入)からランク分けし、表1に示した。なお、コントロールシャンプー処方を以下に示す。
ポリオキシエチレン(2)ラウリルエーテル硫酸ナトリウム 13.5
ヤシ油脂肪酸モノエタノールアミド 0.5
ポリオキシエチレン(16)ラウリルエーテル 2
ラウリン酸アミドプロピルベタイン 1.5
カチオン化セルロース 0.5
pH調整剤(クエン酸,48重量%水酸化ナトリウム水溶液) pH5.5*に調整
精製水 残量
*:水にて20重量倍希釈時,25℃
◎(有効) :使用前後で平均フケレベルが10以上減少
○(やや有効):使用前後で平均フケレベルが5以上減少
△(変化なし):使用前後で平均フケレベルが±5未満の変化
×(悪化) :使用前後で平均フケレベルが5以上増加
◎(有効) :使用前後で平均吹き出物数が5個以上減少
○(やや有効):使用前後で平均吹き出物数が3個以上減少
△(変化なし):使用前後で平均吹き出物数が±3個未満の変化
×(悪化) :使用前後で平均吹き出物数が3個以上増加
◎(有効) :平均評価点が3.5以上
○(やや有効):平均評価点が3.2〜3.4
△(変化なし):平均評価点が2.8〜3.1
×(悪化) :平均評価点が2.7以下
◎(有効) :平均評価点が3.5以上
○(やや有効):平均評価点が3.2〜3.4
△(変化なし):平均評価点が2.8〜3.1
×(悪化) :平均評価点が2.7以下
(重量%)
グリチルリチン酸ジカリウム 0.1
ポリオキシエチレン(2)ラウリルエーテル硫酸ナトリウム 13.5
ヤシ油脂肪酸モノエタノールアミド 0.4
ラウリン酸アミドプロピルベタイン 1.5
ポリオキシエチレン(16)ラウリルエーテル 2.0
カチオン化セルロース 0.5
リンゴ酸 0.8
48重量%水酸化ナトリウム水溶液 適量
香料 適量
精製水 バランス
(重量%)
グリチルリチン酸ジカリウム 0.1
ポリオキシエチレン(2)ラウリルエーテル硫酸ナトリウム 13.5
ヤシ油脂肪酸モノエタノールアミド 0.5
ラウリン酸アミドプロピルベタイン 1.5
ポリオキシエチレン(16)ラウリルエーテル 2.0
エチレングリコールジステアレート 2.0
カチオン化セルロース 0.5
高分子量メチルポリシロキサン(重合度1000〜2700) 1.0
メチルポリシロキサン(重合度50〜300) 1.4
リンゴ酸 0.8
塩化ナトリウム 0.2
48重量%水酸化ナトリウム水溶液 適量
香料 適量
精製水 バランス
Claims (2)
- 次の成分(A)、(B)及び(C)を含有し、水で20重量倍希釈したときの25℃におけるpHが2〜4である毛髪洗浄剤組成物。
(A) リンゴ酸又はその塩 0.1〜20重量%
(B) グリチルレチン酸、グリチルリチン酸、グリチルリチン酸ジカリウム、グリチルリチン酸二ナトリウム、グリチルリチン酸三ナトリウム、グリチルリチン酸モノアンモニウム、グリチルレチン酸グリセリン及びグリチルレチン酸ステアリルから選ばれる少なくとも1種の抗炎症剤 0.001〜10重量%
(C) アニオン界面活性剤 0.5〜60重量% - 抗フケシャンプーである請求項1記載の毛髪洗浄剤組成物。
Priority Applications (5)
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JP2006080782A JP5075345B2 (ja) | 2006-03-23 | 2006-03-23 | 毛髪洗浄剤組成物 |
US11/687,190 US20070224152A1 (en) | 2006-03-23 | 2007-03-16 | Hair cleansing composition |
CNA2007100883762A CN101040825A (zh) | 2006-03-23 | 2007-03-16 | 毛发洗净剂组合物 |
EP07005569.4A EP1842572B1 (en) | 2006-03-23 | 2007-03-19 | Hair cleansing composition |
TW096109867A TW200800279A (en) | 2006-03-23 | 2007-03-22 | Hair cleansing composition |
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JP2006080782A JP5075345B2 (ja) | 2006-03-23 | 2006-03-23 | 毛髪洗浄剤組成物 |
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JP2007254355A JP2007254355A (ja) | 2007-10-04 |
JP5075345B2 true JP5075345B2 (ja) | 2012-11-21 |
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US (1) | US20070224152A1 (ja) |
EP (1) | EP1842572B1 (ja) |
JP (1) | JP5075345B2 (ja) |
CN (1) | CN101040825A (ja) |
TW (1) | TW200800279A (ja) |
Families Citing this family (15)
Publication number | Priority date | Publication date | Assignee | Title |
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ITMI20080444A1 (it) * | 2008-03-17 | 2009-09-18 | Giuliani Spa | Agenti per contrastare e ridurre l'azione irritante dei tensioattivi in composizioni da applicare sulla pelle per la cura o la detersione del viso e del corpo |
JP5426213B2 (ja) * | 2009-03-31 | 2014-02-26 | 花王株式会社 | 水性毛髪洗浄剤 |
US20120022037A1 (en) * | 2009-03-31 | 2012-01-26 | Kao Corporation | Aqueous hair cleansing agent |
JP2010235523A (ja) * | 2009-03-31 | 2010-10-21 | Kao Corp | 水性毛髪洗浄剤 |
JP5426212B2 (ja) * | 2009-03-31 | 2014-02-26 | 花王株式会社 | 水性毛髪洗浄剤 |
CN108697909B (zh) * | 2016-03-03 | 2021-12-17 | 宝洁公司 | 使用低pH毛发护理组合物清洁毛发的方法 |
JP2020536885A (ja) | 2017-10-10 | 2020-12-17 | ザ プロクター アンド ギャンブル カンパニーThe Procter & Gamble Company | 無機塩低含有の、サルフェートを含まないパーソナルクレンジング組成物 |
WO2021113583A1 (en) | 2019-12-06 | 2021-06-10 | The Procter & Gamble Company | Sulfate free composition with enhanced deposition of scalp active |
CN111407697A (zh) * | 2020-04-14 | 2020-07-14 | 广东润洁日化有限公司 | 一组去屑组合物 |
CN116568263A (zh) | 2020-12-04 | 2023-08-08 | 宝洁公司 | 包含恶臭减少材料的毛发护理组合物 |
CN112704657A (zh) * | 2021-01-15 | 2021-04-27 | 拉芳家化股份有限公司 | 一种含竹提取物复合制剂的洗发香波 |
US20220378684A1 (en) | 2021-05-14 | 2022-12-01 | The Procter & Gamble Company | Shampoo Compositions Containing a Sulfate-Free Surfactant System and Sclerotium Gum Thickener |
US11986543B2 (en) | 2021-06-01 | 2024-05-21 | The Procter & Gamble Company | Rinse-off compositions with a surfactant system that is substantially free of sulfate-based surfactants |
US20230190606A1 (en) * | 2021-12-09 | 2023-06-22 | The Procter & Gamble Company | Sulfate free personal cleansing composition comprising effective preservation |
CN116251032A (zh) * | 2021-12-09 | 2023-06-13 | 高露洁-棕榄公司 | 个人护理组合物 |
Family Cites Families (17)
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JPS6322506A (ja) * | 1986-07-14 | 1988-01-30 | Shiseido Co Ltd | 皮膚外用剤 |
JPS6360909A (ja) * | 1986-09-01 | 1988-03-17 | Shiseido Co Ltd | 皮膚外用剤 |
EP0587797B1 (en) * | 1991-06-07 | 1995-03-01 | Minnesota Mining And Manufacturing Company | Disinfecting shampoo composition for animals |
JP3309915B2 (ja) * | 1992-03-31 | 2002-07-29 | カネボウ株式会社 | 養毛料 |
JPH07157415A (ja) * | 1993-12-03 | 1995-06-20 | Shiseido Co Ltd | 頭髪化粧料 |
DE19504914C1 (de) * | 1995-02-15 | 1995-11-16 | Goldwell Gmbh | Haarwaschmittel |
US5523090A (en) * | 1995-02-24 | 1996-06-04 | Chesebrough-Pond's Usa Co., Division Of Conopco, Inc. | Skin treatment composition |
DE19720366A1 (de) * | 1997-05-15 | 1998-11-19 | Wella Ag | Haarreinigungsmittel mit glanzverbessernden Eigenschaften |
KR20010013377A (ko) * | 1997-06-04 | 2001-02-26 | 데이비드 엠 모이어 | 마일드한 잔류성 항균 조성물 |
US6495126B1 (en) * | 1999-07-20 | 2002-12-17 | Mary Kay Inc. | Treatment and composition for achieving skin anti-aging benefits by corneum protease activation |
JP3843020B2 (ja) * | 2002-01-21 | 2006-11-08 | 花王株式会社 | 毛髪洗浄剤 |
JP3813515B2 (ja) * | 2002-02-25 | 2006-08-23 | 花王株式会社 | 洗い流し型化粧料 |
JP3683537B2 (ja) * | 2002-03-01 | 2005-08-17 | 花王株式会社 | 毛髪洗浄剤 |
JP4127777B2 (ja) * | 2002-08-09 | 2008-07-30 | 花王株式会社 | 毛髪洗浄剤組成物 |
JP3843051B2 (ja) * | 2002-08-09 | 2006-11-08 | 花王株式会社 | シャンプー組成物 |
JP2006524187A (ja) * | 2003-01-31 | 2006-10-26 | ザ プロクター アンド ギャンブル カンパニー | 哺乳類のケラチン組織の外観を改善する手段 |
JP2005187398A (ja) * | 2003-12-25 | 2005-07-14 | Kao Corp | 毛髪化粧料 |
-
2006
- 2006-03-23 JP JP2006080782A patent/JP5075345B2/ja active Active
-
2007
- 2007-03-16 CN CNA2007100883762A patent/CN101040825A/zh active Pending
- 2007-03-16 US US11/687,190 patent/US20070224152A1/en not_active Abandoned
- 2007-03-19 EP EP07005569.4A patent/EP1842572B1/en active Active
- 2007-03-22 TW TW096109867A patent/TW200800279A/zh unknown
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EP1842572A3 (en) | 2009-04-22 |
EP1842572B1 (en) | 2013-10-30 |
JP2007254355A (ja) | 2007-10-04 |
TW200800279A (en) | 2008-01-01 |
US20070224152A1 (en) | 2007-09-27 |
CN101040825A (zh) | 2007-09-26 |
EP1842572A2 (en) | 2007-10-10 |
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Free format text: JAPANESE INTERMEDIATE CODE: R250 |
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R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
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R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |