CN100528829C - 信息素或其成分的复分解合成 - Google Patents

信息素或其成分的复分解合成 Download PDF

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CN100528829C
CN100528829C CNB008181101A CN00818110A CN100528829C CN 100528829 C CN100528829 C CN 100528829C CN B008181101 A CNB008181101 A CN B008181101A CN 00818110 A CN00818110 A CN 00818110A CN 100528829 C CN100528829 C CN 100528829C
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catalyst
metathesis
acetate
dichloro
ruthenium
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CN1423629A (zh
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R·L·佩德森
R·H·格拉布斯
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/50—Organo-phosphines
    • C07F9/505—Preparation; Separation; Purification; Stabilisation
    • C07F9/5086—Preparation; Separation; Purification; Stabilisation from phosphonium salts as starting materials
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/09—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis
    • C07C29/095—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrolysis of esters of organic acids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/44—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring increasing the number of carbon atoms by addition reactions, i.e. reactions involving at least one carbon-to-carbon double or triple bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/51—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition
    • C07C45/511—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition involving transformation of singly bound oxygen functional groups to >C = O groups
    • C07C45/515—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition involving transformation of singly bound oxygen functional groups to >C = O groups the singly bound functional group being an acetalised, ketalised hemi-acetalised, or hemi-ketalised hydroxyl group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
    • C07C6/02—Metathesis reactions at an unsaturated carbon-to-carbon bond
    • C07C6/04—Metathesis reactions at an unsaturated carbon-to-carbon bond at a carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/12—Preparation of carboxylic acid esters from asymmetrical anhydrides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/28—Preparation of carboxylic acid esters by modifying the hydroxylic moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/293—Preparation of carboxylic acid esters by modifying the hydroxylic moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/28—Preparation of carboxylic acid esters by modifying the hydroxylic moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/297—Preparation of carboxylic acid esters by modifying the hydroxylic moiety of the ester, such modification not being an introduction of an ester group by splitting-off hydrogen or functional groups; by hydrogenolysis of functional groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/333—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton
    • C07C67/343—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/475—Preparation of carboxylic acid esters by splitting of carbon-to-carbon bonds and redistribution, e.g. disproportionation or migration of groups between different molecules
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
    • C07F5/02—Boron compounds
    • C07F5/025—Boronic and borinic acid compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
    • C07F5/02—Boron compounds
    • C07F5/04—Esters of boric acids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B2200/00—Indexing scheme relating to specific properties of organic compounds
    • C07B2200/09—Geometrical isomers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
  • Pyrane Compounds (AREA)
CNB008181101A 1999-11-18 2000-11-17 信息素或其成分的复分解合成 Expired - Lifetime CN100528829C (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US16654399P 1999-11-18 1999-11-18
WO60/166,543 1999-11-18
US60/166,543 1999-11-18

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CN1423629A CN1423629A (zh) 2003-06-11
CN100528829C true CN100528829C (zh) 2009-08-19

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EP (1) EP1230207B1 (https=)
JP (2) JP4943612B2 (https=)
CN (1) CN100528829C (https=)
AT (1) ATE298318T1 (https=)
AU (1) AU1921201A (https=)
BR (1) BR0015712B1 (https=)
CA (1) CA2392049C (https=)
DE (1) DE60020987T2 (https=)
IL (2) IL149720A0 (https=)
WO (1) WO2001036368A2 (https=)
ZA (1) ZA200204712B (https=)

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EP1373170A4 (en) * 2001-03-30 2007-03-21 California Inst Of Techn CROSS-METATHESIS REACTION OF FUNCTIONALIZED AND SUBSTITUTED OLEFINS USING GROUP 8 METAL TRANSITION CARBENE COMPLEXES AS METATHESIS CATALYSTS
CA2512815A1 (en) 2003-01-13 2004-07-29 Cargill, Incorporated Method for making industrial chemicals
US8685118B2 (en) 2005-01-10 2014-04-01 Elevance Renewable Sciences, Inc. Candle and candle wax containing metathesis and metathesis-like products
RU2435778C2 (ru) * 2005-07-04 2011-12-10 Заннан Сайтех Ко., Лтд. Лиганд комплекса рутения, комплекс рутения, катализатор комплекса рутения и способы его получения и применения
WO2007081987A2 (en) * 2006-01-10 2007-07-19 Elevance Renewable Sciences, Inc. Method of making hydrogenated metathesis products
WO2007103460A2 (en) 2006-03-07 2007-09-13 Elevance Renewable Sciences, Inc. Colorant compositions comprising metathesized unsaturated polyol esters
CN102525829B (zh) 2006-03-07 2014-08-06 埃莱文斯可更新科学公司 含有复分解不饱和多元醇酯的组合物
WO2008008420A1 (en) 2006-07-12 2008-01-17 Elevance Renewable Sciences, Inc. Hot melt adhesive compositions comprising metathesized unsaturated polyol ester wax
WO2008010961A2 (en) 2006-07-13 2008-01-24 Elevance Renewable Sciences, Inc. Synthesis of terminal alkenes from internal alkenes and ethylene via olefin metathesis
CN101129138B (zh) * 2006-08-25 2010-06-23 北京中捷四方生物科技有限公司 一种思茅松毛虫性引诱剂和诱芯及其制备方法
WO2008140468A2 (en) 2006-10-13 2008-11-20 Elevance Renewable Sciences, Inc. METHODS OF MAKING α, ω -DICARBOXYLIC ACID ALKENE DERIVATIVES BY METATHESIS
WO2008046106A2 (en) 2006-10-13 2008-04-17 Elevance Renewable Sciences, Inc. Synthesis of terminal alkenes from internal alkenes via olefin metathesis
WO2008063322A2 (en) 2006-10-13 2008-05-29 Elevance Renewable Sciences, Inc. Metathesis methods involving hydrogenation and compositions relating to same
WO2008048520A2 (en) 2006-10-13 2008-04-24 Elevance Renewable Sciences, Inc. Methods of making organic compounds by metathesis and hydrocyanation
EP2183205A4 (en) * 2007-08-09 2013-10-02 Elevance Renewable Sciences CHEMICAL PROCESSES FOR TREATING METATHESIS RAW MATERIAL
FR2921363B1 (fr) * 2007-09-20 2009-11-06 Arkema France Procedes de synthese de diacides gras par metathese de diacides insatures obtenus par fermentation d'acides gras naturels
JP4594371B2 (ja) 2007-11-30 2010-12-08 信越化学工業株式会社 （ｅ３，ｚ５）−３，５−アルカジエニルアセタートの製造方法
CN101502262B (zh) * 2009-03-20 2012-06-20 中国农业科学院草原研究所 草地螟性诱剂的合成及其应用
JP2013503908A (ja) * 2009-09-04 2013-02-04 ユナイテッド パラゴン アソシエイツ インコーポレイテッド ニューロキニン２受容体活性に関連する障害または疾患を治療するための化合物
US9169447B2 (en) 2009-10-12 2015-10-27 Elevance Renewable Sciences, Inc. Methods of refining natural oils, and methods of producing fuel compositions
US9382502B2 (en) 2009-10-12 2016-07-05 Elevance Renewable Sciences, Inc. Methods of refining and producing isomerized fatty acid esters and fatty acids from natural oil feedstocks
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JP7153937B2 (ja) * 2017-02-17 2022-10-17 プロビビ インコーポレイテッド オレフィンメタセシスによるフェロモンおよび関連材料の合成方法
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CN112782309B (zh) * 2020-12-29 2022-10-28 常州大学 一种稳定长链不饱和烯醛的方法
CN114507122B (zh) * 2022-01-28 2024-07-05 宜都市华阳化工有限责任公司 3-(4-甲基苯亚甲基)-樟脑合成副产物的回收利用方法
KR102473703B1 (ko) 2022-07-12 2022-12-01 전종열 사피엔산과 그 트랜스 이성질체 및 사피엔산 에스터를 제조하는 방법
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ZA200204712B (en) 2004-04-08
JP2011178789A (ja) 2011-09-15
JP5687114B2 (ja) 2015-03-18
WO2001036368A3 (en) 2002-01-10
ATE298318T1 (de) 2005-07-15
EP1230207B1 (en) 2005-06-22
AU1921201A (en) 2001-05-30
DE60020987D1 (de) 2005-07-28
BR0015712B1 (pt) 2011-01-25
CN1423629A (zh) 2003-06-11
CA2392049C (en) 2012-01-31
JP2003531818A (ja) 2003-10-28
IL149720A (en) 2008-03-20
JP4943612B2 (ja) 2012-05-30
EP1230207A2 (en) 2002-08-14
IL149720A0 (en) 2002-11-10
BR0015712A (pt) 2004-04-27
WO2001036368A2 (en) 2001-05-25
CA2392049A1 (en) 2001-05-25
DE60020987T2 (de) 2006-05-11

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