CN100430349C - 由甲醇或二甲醚生产丙烯的方法 - Google Patents

由甲醇或二甲醚生产丙烯的方法 Download PDF

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Publication number
CN100430349C
CN100430349C CNB2005100288096A CN200510028809A CN100430349C CN 100430349 C CN100430349 C CN 100430349C CN B2005100288096 A CNB2005100288096 A CN B2005100288096A CN 200510028809 A CN200510028809 A CN 200510028809A CN 100430349 C CN100430349 C CN 100430349C
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CN
China
Prior art keywords
methanol
reactor
reaction
propylene
catalyst
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
CNB2005100288096A
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English (en)
Chinese (zh)
Other versions
CN1915931A (zh
Inventor
谢在库
钟思青
刘俊涛
陈晓峰
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
China Petroleum and Chemical Corp
Sinopec Shanghai Research Institute of Petrochemical Technology
Original Assignee
China Petroleum and Chemical Corp
Sinopec Shanghai Research Institute of Petrochemical Technology
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by China Petroleum and Chemical Corp, Sinopec Shanghai Research Institute of Petrochemical Technology filed Critical China Petroleum and Chemical Corp
Priority to CNB2005100288096A priority Critical patent/CN100430349C/zh
Priority to JP2006221173A priority patent/JP5180449B2/ja
Priority to SG200605506-5A priority patent/SG130151A1/en
Priority to TW095129911A priority patent/TW200808682A/zh
Priority to US11/503,913 priority patent/US7692056B2/en
Priority to KR1020060076996A priority patent/KR101336115B1/ko
Publication of CN1915931A publication Critical patent/CN1915931A/zh
Application granted granted Critical
Publication of CN100430349C publication Critical patent/CN100430349C/zh
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C4/00—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms
    • C07C4/02—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms by cracking a single hydrocarbon or a mixture of individually defined hydrocarbons or a normally gaseous hydrocarbon fraction
    • C07C4/06—Catalytic processes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00—Aliphatic unsaturated hydrocarbons
    • C07C11/02—Alkenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00002—Chemical plants
    • B01J2219/00027—Process aspects
    • B01J2219/0004—Processes in series
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/40—Ethylene production

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CNB2005100288096A 2005-08-15 2005-08-15 由甲醇或二甲醚生产丙烯的方法 Expired - Lifetime CN100430349C (zh)

Priority Applications (6)

Application Number Priority Date Filing Date Title
CNB2005100288096A CN100430349C (zh) 2005-08-15 2005-08-15 由甲醇或二甲醚生产丙烯的方法
JP2006221173A JP5180449B2 (ja) 2005-08-15 2006-08-14 メタノールまたはジメチルエーテルから低級オレフィンを製造する方法
SG200605506-5A SG130151A1 (en) 2005-08-15 2006-08-14 Process for producing lower olefins from methanol or dimethylether
TW095129911A TW200808682A (en) 2005-08-15 2006-08-15 Method to produce low-carbon olefin from methanol or DME
US11/503,913 US7692056B2 (en) 2005-08-15 2006-08-15 Process for producing lower olefins from methanol or dimethylether
KR1020060076996A KR101336115B1 (ko) 2005-08-15 2006-08-16 메탄올 또는 디메틸에테르로 저급 올레핀을 제조하는 방법

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CNB2005100288096A CN100430349C (zh) 2005-08-15 2005-08-15 由甲醇或二甲醚生产丙烯的方法

Publications (2)

Publication Number Publication Date
CN1915931A CN1915931A (zh) 2007-02-21
CN100430349C true CN100430349C (zh) 2008-11-05

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
CNB2005100288096A Expired - Lifetime CN100430349C (zh) 2005-08-15 2005-08-15 由甲醇或二甲醚生产丙烯的方法

Country Status (6)

Country Link
US (1) US7692056B2 (https=)
JP (1) JP5180449B2 (https=)
KR (1) KR101336115B1 (https=)
CN (1) CN100430349C (https=)
SG (1) SG130151A1 (https=)
TW (1) TW200808682A (https=)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7919660B2 (en) 2007-12-21 2011-04-05 Uop Llc Methods of converting methanol feedstock to olefins
CN101407441B (zh) * 2008-11-25 2012-06-27 上海应用技术学院 由甲醇制备丙烯的方法
US20130197288A1 (en) * 2012-01-31 2013-08-01 Linde Ag Process for the conversion of synthesis gas to olefins
WO2015082368A1 (en) * 2013-12-02 2015-06-11 Shell Internationale Research Maatschappij B.V. A process for converting oxygenates to olefins
CN105585396B (zh) * 2014-10-20 2018-03-20 中国石油化工股份有限公司 一种由含氧化合物制取低碳烯烃的方法
CN107032944B (zh) * 2016-02-03 2019-12-17 中石化广州工程有限公司 一种甲醇转化为丙烯的方法
CN116606188B (zh) * 2023-04-14 2024-03-29 浙江大学 一种甲醇制烯烃的方法

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1065853C (zh) * 1996-05-24 2001-05-16 中国科学院大连化学物理研究所 一种由甲醇或二甲醚制取乙烯、丙烯等低碳烯烃方法
CN1174945C (zh) * 1995-08-10 2004-11-10 环球油品公司 从甲烷和/或乙烷制备轻烯烃的三步工艺

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US405857A (en) * 1889-06-25 Spring-vehicle
US4058576A (en) * 1974-08-09 1977-11-15 Mobil Oil Corporation Conversion of methanol to gasoline components
US4404414A (en) * 1982-09-28 1983-09-13 Mobil Oil Corporation Conversion of methanol to gasoline
JPS60248629A (ja) * 1984-05-23 1985-12-09 Agency Of Ind Science & Technol 低級オレフインの製法
DE4009459A1 (de) * 1990-03-23 1991-09-26 Metallgesellschaft Ag Verfahren zur erzeugung von niederen olefinen
EP0568913A3 (en) * 1992-05-03 1995-03-22 Dalian Chemical Physics Inst Process for the conversion of methanol to light olefins and catalysts used therefor.
DE10117248A1 (de) * 2000-05-31 2002-10-10 Mg Technologies Ag Verfahren zum Erzeugen von Propylen aus Methanol
US6797851B2 (en) * 2001-08-30 2004-09-28 Exxonmobil Chemical Patents Inc. Two catalyst process for making olefin
US7396971B2 (en) * 2002-08-01 2008-07-08 Exxonmobil Chemical Patents Inc. Two stage hydrocarbon conversion reaction system

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1174945C (zh) * 1995-08-10 2004-11-10 环球油品公司 从甲烷和/或乙烷制备轻烯烃的三步工艺
CN1065853C (zh) * 1996-05-24 2001-05-16 中国科学院大连化学物理研究所 一种由甲醇或二甲醚制取乙烯、丙烯等低碳烯烃方法

Non-Patent Citations (6)

* Cited by examiner, † Cited by third party
Title
Methanol to propylene MTP-Lurgis way. Rothaeme，M，Holtmann，H，D.[J].Erdol Erdgas Kohle，第5期. 2002
Methanol to propylene MTP-Lurgis way. Rothaeme，M，Holtmann，H，D.[J].Erdol Erdgas Kohle，第5期. 2002 *
ZSM-5上甲醇制烯烃反应中低碳烯烃的成因. 徐柏庆，梁娟，陈国权.催化学报，第4期. 1991
ZSM-5上甲醇制烯烃反应中低碳烯烃的成因. 徐柏庆，梁娟，陈国权.催化学报，第4期. 1991 *
甲醇制烯烃(MTO)和MTP工艺. 白尔铮，金国林.化学世界，第12期. 2003
甲醇制烯烃(MTO)和MTP工艺. 白尔铮，金国林.化学世界，第12期. 2003 *

Also Published As

Publication number Publication date
CN1915931A (zh) 2007-02-21
TW200808682A (en) 2008-02-16
SG130151A1 (en) 2007-03-20
JP2007063270A (ja) 2007-03-15
US20070038011A1 (en) 2007-02-15
TWI342306B (https=) 2011-05-21
KR101336115B1 (ko) 2013-12-03
JP5180449B2 (ja) 2013-04-10
KR20070020356A (ko) 2007-02-21
US7692056B2 (en) 2010-04-06

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Granted publication date: 20081105