CN100402143C - 烷烃和烯烃氨氧化用的催化剂组合物及其制造和使用方法 - Google Patents

烷烃和烯烃氨氧化用的催化剂组合物及其制造和使用方法 Download PDF

Info

Publication number
CN100402143C
CN100402143C CNB021399654A CN02139965A CN100402143C CN 100402143 C CN100402143 C CN 100402143C CN B021399654 A CNB021399654 A CN B021399654A CN 02139965 A CN02139965 A CN 02139965A CN 100402143 C CN100402143 C CN 100402143C
Authority
CN
China
Prior art keywords
compound
antimony
solution
hydroxide
vanadium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CNB021399654A
Other languages
English (en)
Chinese (zh)
Other versions
CN1426834A (zh
Inventor
E·A·马梅多夫
K·A·贝思科
S·N·谢克赫
A·阿劳乔
N·K·库卡尼
A·克霍达科夫
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Saudi Basic Industries Corp
Original Assignee
Saudi Basic Industries Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Saudi Basic Industries Corp filed Critical Saudi Basic Industries Corp
Publication of CN1426834A publication Critical patent/CN1426834A/zh
Application granted granted Critical
Publication of CN100402143C publication Critical patent/CN100402143C/zh
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C253/00Preparation of carboxylic acid nitriles
    • C07C253/24Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002Mixed oxides other than spinels, e.g. perovskite
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/18Arsenic, antimony or bismuth
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/20Vanadium, niobium or tantalum
    • B01J23/22Vanadium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/847Vanadium, niobium or tantalum or polonium
    • B01J23/8472Vanadium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00Constitutive chemical elements of heterogeneous catalysts
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/52Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CNB021399654A 2001-12-21 2002-12-20 烷烃和烯烃氨氧化用的催化剂组合物及其制造和使用方法 Expired - Fee Related CN100402143C (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US10/036,866 US6710011B2 (en) 2001-12-21 2001-12-21 Catalyst compositions for the ammoxidation of alkanes and olefins, methods of making and of using same
US10/036866 2001-12-21

Publications (2)

Publication Number Publication Date
CN1426834A CN1426834A (zh) 2003-07-02
CN100402143C true CN100402143C (zh) 2008-07-16

Family

ID=21891089

Family Applications (1)

Application Number Title Priority Date Filing Date
CNB021399654A Expired - Fee Related CN100402143C (zh) 2001-12-21 2002-12-20 烷烃和烯烃氨氧化用的催化剂组合物及其制造和使用方法

Country Status (5)

Country Link
US (1) US6710011B2 (enExample)
EP (1) EP1321458A1 (enExample)
JP (2) JP4515703B2 (enExample)
KR (1) KR100783247B1 (enExample)
CN (1) CN100402143C (enExample)

Families Citing this family (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6710011B2 (en) * 2001-12-21 2004-03-23 Saudi Basic Industries Corporatioin Catalyst compositions for the ammoxidation of alkanes and olefins, methods of making and of using same
US7576233B2 (en) * 2002-06-04 2009-08-18 Tessenderlo Chemie S.A. Method for the preparation of halogenated benzonitriles
BRPI0500616A (pt) * 2004-03-10 2007-07-10 Rohm & Haas processos para aperfeiçoar uma ou mais caracterìsticas de desempenho de um ou mais catalisadores de óxido metálico, e para produzir ácidos carboxìlicos insaturados
BRPI0500609A (pt) * 2004-03-10 2007-07-10 Rohm & Haas processos para preparar um ou mais catalisadores modificados, e, para a criotrituração de um ou mais catalisadores de óxido metálico
BRPI0500615B1 (pt) * 2004-03-10 2015-07-14 Rohm And Haas Company Catalisador modificado, e, sistema de catalisador modificado
US7186670B2 (en) * 2004-09-30 2007-03-06 Saudi Basic Industries Corporation Process for the ammoxidation of alkanes and olefins
US7405246B2 (en) * 2005-04-05 2008-07-29 Momentive Performance Materials Inc. Cure system, adhesive system, electronic device
US7446136B2 (en) * 2005-04-05 2008-11-04 Momentive Performance Materials Inc. Method for producing cure system, adhesive system, and electronic device
KR100671978B1 (ko) * 2005-07-19 2007-01-24 한국과학기술연구원 탈질환원촉매
US7919428B2 (en) * 2007-12-04 2011-04-05 Ineos Usa Llc Method of making mixed metal oxide catalysts for ammoxidation and/or oxidation of lower alkane hydrocarbons
CN102458654B (zh) * 2009-06-11 2014-12-31 三菱瓦斯化学株式会社 氨氧化催化剂及使用该催化剂的腈化合物的制造方法
CN102218334B (zh) * 2010-04-15 2013-04-03 中国石油化工股份有限公司 含锑的氨氧化催化剂
JP6029412B2 (ja) * 2012-10-05 2016-11-24 コスモ石油株式会社 酸化脱水素触媒及びその製造方法、並びにアルカジエンの製造方法
CN104549261B (zh) * 2013-10-28 2017-07-14 中国石油化工股份有限公司 烷烃制不饱和腈的催化剂
CN103772235B (zh) * 2013-12-25 2016-04-27 中国石油集团东北炼化工程有限公司吉林设计院 一种丙烯腈生产工艺
CN105195165B (zh) * 2015-10-23 2017-09-29 中海油天津化工研究设计院有限公司 一种烯烃氨氧化制不饱和腈的流化床催化剂及其制备方法
MY193099A (en) * 2016-07-26 2022-09-26 Basf Corp Supported catalyst, monolithic selective catalytic reduction (scr) catalyst, preparation method therefor, and method for nitrogen oxides removal
US11909046B2 (en) 2017-03-07 2024-02-20 The Research Foundation For The State University Of New York Synthetic methods for crystallite size control of bimetallic polyanionic battery compositions
CN109473666A (zh) * 2018-11-07 2019-03-15 北京理工大学 一种石墨烯支撑的SbVO4纳米颗粒复合材料及其制备方法
CN111135829B (zh) * 2020-01-02 2022-09-20 万华化学集团股份有限公司 一种氨氧化催化剂及其制备方法和应用
CN114247429A (zh) * 2021-11-09 2022-03-29 暨南大学 一种硬脂酸衍生物有机臭味除臭系统
CN114956814B (zh) * 2022-05-16 2023-08-18 昆明理工大学 一种抗烧结强抗cmas腐蚀高熵钽/铌陶瓷及其制备方法

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1134854A (zh) * 1995-01-24 1996-11-06 罗纳·布朗克纤维和树脂中间体公司 氨氧化反应的催化剂及其制备方法

Family Cites Families (37)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1336136A (en) 1970-03-24 1973-11-07 Power Gas Ltd Catalytic ammoxidation of alkanes
US3860534A (en) 1971-03-24 1975-01-14 Power Gas Ltd Method of making an antimony-vanadium catalyst
US4388248A (en) * 1978-01-03 1983-06-14 Monsanto Company Ammoxidation processes
US4405498A (en) * 1979-12-17 1983-09-20 Monsanto Company Oxidation and ammoxidation catalysts
CA1145728A (en) * 1981-04-21 1983-05-03 Antonio Gozzi Three or four stage gas compressor
US4746641A (en) 1984-08-22 1988-05-24 Standard Oil Company Ammoxidation of paraffins and catalysts therefor
US4873215A (en) 1986-10-15 1989-10-10 The Standard Oil Company Catalyst for ammoxidation of paraffins
US4888438A (en) 1987-04-20 1989-12-19 The Standard Oil Company Method for ammoxidation of paraffins and catalyst system therefor
US4797381A (en) 1987-07-30 1989-01-10 The Standard Oil Company Preparation of abrasion resistant alumina-supported vanadium-antimony oxidic catalysts
US4784979A (en) 1987-12-07 1988-11-15 The Standard Oil Company Catalyst and catalyst precursor containing vanadium and antimony
US4871706A (en) 1987-12-16 1989-10-03 The Standard Oil Company Catalyst for the ammoxidation of paraffins
US4879264A (en) 1988-11-14 1989-11-07 The Standard Oil Company Method of making catalyst and catalyst precursor containing vanadium and antimony
US5008427A (en) 1988-12-23 1991-04-16 The Standard Oil Company Ammoxidation of paraffins
US5079207A (en) 1990-12-03 1992-01-07 The Standard Oil Company Catalyst for ammoxidation of paraffins
US5094989A (en) 1990-12-21 1992-03-10 The Standard Oil Company Process for activation of catalysts
FR2687144B1 (fr) 1992-02-06 1995-05-19 Rhone Poulenc Chimie Procede d'ammoxydation d'hydrocarbures satures.
FR2687670B1 (fr) 1992-02-20 1995-05-19 Rhone Poulenc Chimie Procede d'ammoxydation d'hydrocarbures satures.
US5214016A (en) 1992-04-02 1993-05-25 The Standard Oil Company Method of making catalysts containing vanadium, antimony and tin
US5258543A (en) * 1992-06-26 1993-11-02 The Standard Oil Company Method for ammoxidation of olefins
WO1995005895A1 (en) * 1993-08-26 1995-03-02 Bp America, Inc. Method of improving oxidation and ammoxidation catalysts
JP3376105B2 (ja) * 1994-06-09 2003-02-10 三菱レイヨン株式会社 鉄・アンチモン・リン含有金属酸化物触媒の再生方法
US5498588A (en) 1994-09-09 1996-03-12 The Standard Oil Company Surface modification and promotion of vanadium antimony oxide catalysts
DE19504283A1 (de) * 1995-02-09 1996-08-14 Degussa Verfahren zur Herstellung von Cyanopyridinen und dafür geeignete Katalysatoren
US5576469A (en) 1995-06-05 1996-11-19 The Standard Oil Co. Paraffin ammoxidation using vanadium antimony oxide based catalysts with halide promoters
US5693587A (en) 1995-06-06 1997-12-02 The Standard Oil Company Method for preparing vanadium antimony oxide based oxidation and ammoxidation catalysts
FR2739373B1 (fr) 1995-09-29 1997-10-31 Rhone Poulenc Fibres Procede de preparation de catalyseurs d'ammoxydation
US5750760A (en) * 1995-10-05 1998-05-12 Mitsubishi Chemical Corporation Method for producing a nitrile
US5854172A (en) 1997-01-17 1998-12-29 The Standard Oil Company Preparation of vanadium antimonate based catalysts using SnO2 ·xH2 O
JP3209960B2 (ja) * 1998-03-04 2001-09-17 三菱レイヨン株式会社 不飽和ニトリルの製造法
US6156920A (en) 1998-03-26 2000-12-05 The Standard Oil Company Molybdenum promoted vanadium-antimony-oxide based catalyst for selective paraffin ammoxidation
US5994259A (en) 1998-07-29 1999-11-30 The Standard Oil Company Catalysts for the ammoxidation of alkanes
WO2000012208A1 (en) 1998-08-31 2000-03-09 E.I. Du Pont De Nemours And Company High surface area sol-gel route prepared oxidation catalysts
US6162760A (en) 1999-02-08 2000-12-19 The Standard Oil Company Arsenic promoted vanadium-antimony-oxide based catalyst for selective paraffin ammoxidation
US6171571B1 (en) * 1999-05-10 2001-01-09 Uop Llc Crystalline multinary metal oxide compositions, process for preparing and processes for using the composition
US6235678B1 (en) * 1999-06-11 2001-05-22 Saudi Basic Industries Corporation Catalyst system for oxidative dehydrogenation of paraffins
JP4413368B2 (ja) * 2000-04-03 2010-02-10 旭化成ケミカルズ株式会社 酸化またはアンモ酸化用触媒
US6710011B2 (en) * 2001-12-21 2004-03-23 Saudi Basic Industries Corporatioin Catalyst compositions for the ammoxidation of alkanes and olefins, methods of making and of using same

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1134854A (zh) * 1995-01-24 1996-11-06 罗纳·布朗克纤维和树脂中间体公司 氨氧化反应的催化剂及其制备方法

Non-Patent Citations (5)

* Cited by examiner, † Cited by third party
Title
. .
. .;Ammoxidation of propane over modified V-Sb-Al-oxides-therole of acidity and redox properties of the catalysts. ZANTHOFF H W等.Applied Catalysis A:General,Elsevier Science,Amsterdam,Nl,Vol.164 No.1-2. 1997 *
Ammoxidation of propane over modified V-Sb-Al-oxides-therole of acidity and redox properties of the catalysts. ZANTHOFF H W等.Applied Catalysis A:General,Elsevier Science,Amsterdam,Nl,Vol.164 No.1-2. 1997
Kinetics and reaction netwok in propane ammoxidation toacrylonitril on V-Sb-Al based mixed oxides. CATANI. R等.Industrial and Engineering Chemistry Research,Vol.31 . 1992
Kinetics and reaction netwok in propane ammoxidation toacrylonitril on V-Sb-Al based mixed oxides. CATANI. R等.Industrial and Engineering Chemistry Research,Vol.31 . 1992 *

Also Published As

Publication number Publication date
CN1426834A (zh) 2003-07-02
KR20030053000A (ko) 2003-06-27
JP4515703B2 (ja) 2010-08-04
US20030144539A1 (en) 2003-07-31
JP2003260354A (ja) 2003-09-16
US6710011B2 (en) 2004-03-23
EP1321458A1 (en) 2003-06-25
KR100783247B1 (ko) 2007-12-06
JP2009142815A (ja) 2009-07-02

Similar Documents

Publication Publication Date Title
CN100402143C (zh) 烷烃和烯烃氨氧化用的催化剂组合物及其制造和使用方法
US4049575A (en) Process of producing antimony-containing oxide catalysts
KR100905842B1 (ko) 가암모니아 산화용 촉매의 제조 방법
JP2950851B2 (ja) 鉄・アンチモン・リン含有金属酸化物触媒組成物およびその製法
JP3142549B2 (ja) 鉄・アンチモン・モリブデン含有酸化物触媒組成物およびその製法
US10479760B2 (en) Synthetic methods for the preparation of propylene ammoxidation catalysts
JP5011176B2 (ja) アクリロニトリル合成用触媒およびアクリロニトリルの製造方法
JP3371112B2 (ja) 鉄・アンチモン含有金属酸化物触媒組成物およびその製法
JP4204327B2 (ja) 反応帯域中で分子酸素を用いてプロペンを不均一系触媒により気相酸化することによりアクリル酸を製造する方法
US4767739A (en) Catalyst system for ammoxidation of paraffins
JP3819192B2 (ja) アクリロニトリルの製造法
JPH0441454A (ja) メタクロレインの製造方法
US4877764A (en) Catalyst system for ammoxidation of paraffins
US7229945B2 (en) Process of making mixed metal oxide catalysts for the production of unsaturated aldehydes from olefins
JP2004008834A (ja) メタクリル酸製造用触媒の製造方法
CN112547082B (zh) 用于丙烯醛氧化制丙烯酸的催化剂及其制备方法和应用
US4888438A (en) Method for ammoxidation of paraffins and catalyst system therefor
JP2000037631A (ja) モリブデン―ビスマス―鉄含有複合酸化物触媒の調製法
JP2002306970A (ja) メタクリル酸製造用触媒、その製造方法、および、メタクリル酸の製造方法
US4788173A (en) Catalytic mixtures for ammoxidation of paraffins
WO2006072447A9 (de) Phosphor-behandelte multimetalloxidmassen
CN101340974A (zh) 用于烷烃的氨氧化的不含锑或钼的催化剂组合物,其制造方法和使用方法
JPS6113701B2 (enExample)
JPH05301051A (ja) モリブデン含有流動床触媒の製造方法
JP2003001111A (ja) メタクリル酸合成用触媒の製造方法

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20080716

Termination date: 20201220

CF01 Termination of patent right due to non-payment of annual fee