CN100400739C - 具有催化活性的金属酞菁负载纤维及制备方法 - Google Patents
具有催化活性的金属酞菁负载纤维及制备方法 Download PDFInfo
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- CN100400739C CN100400739C CNB2006100524587A CN200610052458A CN100400739C CN 100400739 C CN100400739 C CN 100400739C CN B2006100524587 A CNB2006100524587 A CN B2006100524587A CN 200610052458 A CN200610052458 A CN 200610052458A CN 100400739 C CN100400739 C CN 100400739C
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- Prior art keywords
- fiber
- metal phthalocyanine
- fabric
- reaction
- fibre
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000000835 fiber Substances 0.000 title claims abstract description 109
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 title claims abstract description 89
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 83
- 239000002184 metal Substances 0.000 title claims abstract description 83
- 230000003197 catalytic effect Effects 0.000 title claims abstract description 20
- 238000000034 method Methods 0.000 title claims description 14
- 239000004744 fabric Substances 0.000 claims abstract description 51
- 238000006243 chemical reaction Methods 0.000 claims abstract description 38
- 238000005406 washing Methods 0.000 claims abstract description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 17
- JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical group C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 claims abstract description 12
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 4
- 239000007864 aqueous solution Substances 0.000 claims abstract description 4
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 4
- 230000009257 reactivity Effects 0.000 claims abstract description 4
- 229910052701 rubidium Inorganic materials 0.000 claims abstract description 4
- 238000003756 stirring Methods 0.000 claims abstract description 4
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 4
- 229910001428 transition metal ion Inorganic materials 0.000 claims abstract description 3
- 239000000243 solution Substances 0.000 claims description 27
- 239000003513 alkali Substances 0.000 claims description 14
- 238000004140 cleaning Methods 0.000 claims description 12
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical class C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 10
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 9
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 6
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 6
- 229920000297 Rayon Polymers 0.000 claims description 6
- 229920003043 Cellulose fiber Polymers 0.000 claims description 5
- 229920000742 Cotton Polymers 0.000 claims description 4
- 230000015572 biosynthetic process Effects 0.000 claims description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims description 3
- 229920002972 Acrylic fiber Polymers 0.000 claims description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 3
- 235000010469 Glycine max Nutrition 0.000 claims description 3
- 244000068988 Glycine max Species 0.000 claims description 3
- 239000004952 Polyamide Substances 0.000 claims description 3
- 229920002978 Vinylon Polymers 0.000 claims description 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 3
- 239000004411 aluminium Substances 0.000 claims description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 3
- 229920006231 aramid fiber Polymers 0.000 claims description 3
- 229910017052 cobalt Inorganic materials 0.000 claims description 3
- 239000010941 cobalt Substances 0.000 claims description 3
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 3
- 229910052802 copper Inorganic materials 0.000 claims description 3
- 239000010949 copper Substances 0.000 claims description 3
- QKSIFUGZHOUETI-UHFFFAOYSA-N copper;azane Chemical compound N.N.N.N.[Cu+2] QKSIFUGZHOUETI-UHFFFAOYSA-N 0.000 claims description 3
- 239000003365 glass fiber Substances 0.000 claims description 3
- 239000003292 glue Substances 0.000 claims description 3
- 229910052742 iron Inorganic materials 0.000 claims description 3
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- 229920002647 polyamide Polymers 0.000 claims description 3
- 239000005020 polyethylene terephthalate Substances 0.000 claims description 3
- 102000004169 proteins and genes Human genes 0.000 claims description 3
- 108090000623 proteins and genes Proteins 0.000 claims description 3
- 230000001105 regulatory effect Effects 0.000 claims description 3
- IGLNJRXAVVLDKE-UHFFFAOYSA-N rubidium atom Chemical compound [Rb] IGLNJRXAVVLDKE-UHFFFAOYSA-N 0.000 claims description 3
- 229920002994 synthetic fiber Polymers 0.000 claims description 3
- 239000012209 synthetic fiber Substances 0.000 claims description 3
- 210000002268 wool Anatomy 0.000 claims description 3
- 239000002759 woven fabric Substances 0.000 claims description 3
- 239000011701 zinc Substances 0.000 claims description 3
- 229920004933 Terylene® Polymers 0.000 claims description 2
- 239000004568 cement Substances 0.000 claims description 2
- 238000007385 chemical modification Methods 0.000 claims description 2
- 239000002131 composite material Substances 0.000 claims description 2
- 239000011159 matrix material Substances 0.000 claims 1
- 238000002360 preparation method Methods 0.000 abstract description 8
- 239000003518 caustics Substances 0.000 abstract 1
- 238000010276 construction Methods 0.000 abstract 1
- 238000001035 drying Methods 0.000 abstract 1
- -1 naphthalene nucleus compounds Chemical class 0.000 description 10
- 238000005303 weighing Methods 0.000 description 10
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 8
- 238000001291 vacuum drying Methods 0.000 description 8
- HTSVYUUXJSMGQC-UHFFFAOYSA-N 2-chloro-1,3,5-triazine Chemical class ClC1=NC=NC=N1 HTSVYUUXJSMGQC-UHFFFAOYSA-N 0.000 description 6
- 239000002585 base Substances 0.000 description 6
- 239000003054 catalyst Substances 0.000 description 6
- 238000006555 catalytic reaction Methods 0.000 description 5
- UCFZBOCMNGFLQX-UHFFFAOYSA-N [Co]N Chemical compound [Co]N UCFZBOCMNGFLQX-UHFFFAOYSA-N 0.000 description 4
- ZMXDDKWLCZADIW-UHFFFAOYSA-N dimethylformamide Substances CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 4
- 239000012535 impurity Substances 0.000 description 4
- 238000005096 rolling process Methods 0.000 description 4
- 239000000758 substrate Substances 0.000 description 4
- MWUXSHHQAYIFBG-UHFFFAOYSA-N Nitric oxide Chemical compound O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- 229910052717 sulfur Inorganic materials 0.000 description 3
- 239000011593 sulfur Substances 0.000 description 3
- KMHSUNDEGHRBNV-UHFFFAOYSA-N 2,4-dichloropyrimidine-5-carbonitrile Chemical compound ClC1=NC=C(C#N)C(Cl)=N1 KMHSUNDEGHRBNV-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 229920000049 Carbon (fiber) Polymers 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- MPMSMUBQXQALQI-UHFFFAOYSA-N cobalt phthalocyanine Chemical compound [Co+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 MPMSMUBQXQALQI-UHFFFAOYSA-N 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000000539 dimer Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- 239000004745 nonwoven fabric Substances 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000002791 soaking Methods 0.000 description 2
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical class [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229920004934 Dacron® Polymers 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 150000001339 alkali metal compounds Chemical class 0.000 description 1
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 150000001491 aromatic compounds Chemical class 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 239000004567 concrete Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000006356 dehydrogenation reaction Methods 0.000 description 1
- 238000006477 desulfuration reaction Methods 0.000 description 1
- 230000023556 desulfurization Effects 0.000 description 1
- 238000003487 electrochemical reaction Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 125000002534 ethynyl group Chemical group [H]C#C* 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 230000000640 hydroxylating effect Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 238000006053 organic reaction Methods 0.000 description 1
- 230000000505 pernicious effect Effects 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 238000005191 phase separation Methods 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 238000006722 reduction reaction Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
Landscapes
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Catalysts (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
Description
Claims (6)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CNB2006100524587A CN100400739C (zh) | 2006-07-14 | 2006-07-14 | 具有催化活性的金属酞菁负载纤维及制备方法 |
Applications Claiming Priority (1)
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CNB2006100524587A CN100400739C (zh) | 2006-07-14 | 2006-07-14 | 具有催化活性的金属酞菁负载纤维及制备方法 |
Publications (2)
Publication Number | Publication Date |
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CN1900411A CN1900411A (zh) | 2007-01-24 |
CN100400739C true CN100400739C (zh) | 2008-07-09 |
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CNB2006100524587A Expired - Fee Related CN100400739C (zh) | 2006-07-14 | 2006-07-14 | 具有催化活性的金属酞菁负载纤维及制备方法 |
Country Status (1)
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CN (1) | CN100400739C (zh) |
Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101579640A (zh) * | 2008-05-15 | 2009-11-18 | 赵鹏雷 | 一种非均相氧化催化剂的制备方法与使用方法 |
CN102302954B (zh) * | 2011-08-26 | 2013-01-09 | 浙江理工大学 | 一种蜂窝结构酞菁催化功能材料的制备方法 |
CN103721747B (zh) * | 2013-12-13 | 2016-06-08 | 浙江理工大学 | 一种催化碳纤维及制备方法 |
CN104624237B (zh) * | 2015-01-03 | 2017-06-16 | 浙江理工大学 | 具有高催化活性的仿生催化碳纤维材料及制备方法 |
CN104607244B (zh) * | 2015-01-03 | 2017-06-16 | 浙江理工大学 | 具有催化功能的碳纤维材料及其制备方法 |
CN104607247B (zh) * | 2015-01-03 | 2017-06-16 | 浙江理工大学 | 一种高活性催化碳纤维材料及制备方法 |
CN104594021A (zh) * | 2015-02-13 | 2015-05-06 | 武汉大学 | 基于软硬酸碱理论的巯基棉后修饰材料及其制备与应用 |
CN105536872B (zh) * | 2016-01-15 | 2018-01-02 | 河北工程大学 | 纳米线铁酞菁/碳纳米纤维异质结复合材料的制备方法 |
CN109021210A (zh) * | 2018-07-17 | 2018-12-18 | 成都市水泷头化工科技有限公司 | 一种去甲醛、可降解的汽车内饰泡沫塑料及制备方法 |
CN116971175B (zh) * | 2023-09-21 | 2023-11-24 | 广州吉胜纺织有限公司 | 一种三防易打理梭织面料及其制备方法 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS62186778A (ja) * | 1986-02-13 | 1987-08-15 | Aasu Clean:Kk | 鮮度保持シ−ト |
JPS6468578A (en) * | 1987-09-02 | 1989-03-14 | Daiwa Spinning Co Ltd | Fiber having excellent washing fastness and deodorizing function |
US20050241075A1 (en) * | 2004-04-22 | 2005-11-03 | Aude Livoreil | Composition for permanently reshaping the hair comprising at least one reducing agent and at least one photo-oxidizing agent complexed with at least one metal |
-
2006
- 2006-07-14 CN CNB2006100524587A patent/CN100400739C/zh not_active Expired - Fee Related
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS62186778A (ja) * | 1986-02-13 | 1987-08-15 | Aasu Clean:Kk | 鮮度保持シ−ト |
JPS6468578A (en) * | 1987-09-02 | 1989-03-14 | Daiwa Spinning Co Ltd | Fiber having excellent washing fastness and deodorizing function |
US20050241075A1 (en) * | 2004-04-22 | 2005-11-03 | Aude Livoreil | Composition for permanently reshaping the hair comprising at least one reducing agent and at least one photo-oxidizing agent complexed with at least one metal |
Non-Patent Citations (6)
Title |
---|
催化氧化型消臭蚕丝纤维的研究. 姚玉元,陈文兴,张利,潘勇.纺织学报,第25卷第3期. 2004 |
催化氧化型消臭蚕丝纤维的研究. 姚玉元,陈文兴,张利,潘勇.纺织学报,第25卷第3期. 2004 * |
负载酞菁纤维素纤维的消臭性能及机理. 余志成,陈文兴,陈海相.纺织学报,第23卷第06期. 2002 |
负载酞菁纤维素纤维的消臭性能及机理. 余志成,陈文兴,陈海相.纺织学报,第23卷第06期. 2002 * |
金属酞菁接枝纤维素纤维及其消臭性能. 汪进前,魏莉莉,吕素芳,张利,陈文兴.纺织学报,第27卷第6期. 2006 |
金属酞菁接枝纤维素纤维及其消臭性能. 汪进前,魏莉莉,吕素芳,张利,陈文兴.纺织学报,第27卷第6期. 2006 * |
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CN1900411A (zh) | 2007-01-24 |
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Assignee: Zhejiang Hailide New Material Co., Ltd. Assignor: Zhejiang Sci-Tech University Contract fulfillment period: 2008.7.15 to 2014.7.14 contract change Contract record no.: 2008330000309 Denomination of invention: Metal phthalocyanine loaded fiber with catalytic activity and preparing method Granted publication date: 20080709 License type: Exclusive license Record date: 2008.8.28 |
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