CN100370001C - 高Tg聚合物乳液和用作压敏粘合剂的压敏粘合剂聚合物乳液的共混物 - Google Patents
高Tg聚合物乳液和用作压敏粘合剂的压敏粘合剂聚合物乳液的共混物 Download PDFInfo
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Abstract
Description
涂料/粘合剂胶乳 | Tg,℃ | LDPE剥离附着力,<sup>1</sup>pli | 环形粘性,<sup>2</sup>pli | 耐剪切性,<sup>3</sup>小时 | 低温附着力,<sup>4</sup>pli |
PBA/MMA Lepizzera<sup>a</sup> | -29 | 0.06 | 0.83 | 14.9 | 0.01 |
PBA Cavaillé1991<sup>b</sup> | -55 | 0.01 | 0.91 | 1.6 | 0.26 |
Flexcryl 1625 | -55 | 0.7 | 2.8 | 11.5 | 0.90 |
Flexcryl 1624 | -58 | 0.46 | 2.5 | 0.5 | 1.83 |
Flexcryl LC-31 | -40 | 0.93 | 2.92 | 0.37 | 1.31 |
操作# | 添加剂的Tg,℃ | 添加剂聚合物种类 | 粒径nm | LDPE剥离附着力(1),pli | 环形粘性(2),pli | 耐剪切性(3),小时 | 低温附着力(4),pli |
丙烯酸胶乳A系列585ppm DDMDn=236nm | |||||||
1 | 无 | 0.66 | 2.62 | 0.20 | 1.37 | ||
2 | 110 | PMMA | 211 | 0.97 | 2.28 | 1.62 | 0.39 |
3 | 110 | PMMA | 164 | 1.48 | 2.22 | 3.0 | 0.25 |
4 | 110 | PMMA | 155 | 1.33 | 2.81 | 2.7 | 0.30 |
5 | 110 | PMMA/MAA | 143 | 1.44 | 2.16 | 3.32 | 0.25 |
6 | 110 | PMMA | 135 | 1.61 | 2.44 | 10.44 | 0.14 |
7 | 110 | PMMA | 109 | 1.78 | 2.70 | 12.86 | 0.11 |
8 | 105 | PS | 134 | 0.96 | 1.67 | 4.42 | 30%精选纤维 |
9 | 39 | PBA/MMA | 109 | 0.07 | 0.98 | 0.45 | 0 |
10 | 38 | PBA/MMA | 180 | 0.14 | 0.71 | 0.63 | 0 |
丙烯酸胶乳B系列(90.9/7.3/1.8EHA/MMA/MAA)573ppmDDMDn=123nm | |||||||
11 | 无 | 0.86 | 2.4 | 0.28 | 1.28 | ||
12 | 110 | PMMA | 135 | 0.98 | 1.96 | 9.60 | 0.15 |
13 | 110 | PMMA | 76 | 0.98 | 1.71 | 29.9 | 0 |
14 | 110 | PMMA | 91 | 0.51 | 1.72 | 39.3 | 0.02 |
15 | 39 | PBA/MMA | 109 | 0.13 | 0.80 | 9.1 | 0 |
丙烯酸胶乳C系列1463ppmDDMDn=134nm | |||||||
16 | 无 | 1.0 | 3.5 | 0.05 | 2.2 | ||
17 | 110 | PMM | 155 | 1.42 | 0.14 | 0.57 | |
18 | 110 | PMMA | 211 | 1.16 | 0.09 | 0.87 | |
19 | 78 | PVC | 201 | 0.63 | 1.82 | 0.10 | 0.67 |
20 | 18 | PBA/VAc | 250 | 0.02 | 0 | ||
21 | 40 | PVAc | 164 | 0.03 | 0 | ||
丙烯酸胶乳D系列1024ppmDDMDn=142nm | |||||||
22 | 无 | 0.5 | 2.42 | 0.09 | 1.59 | ||
23 | 110 | PMMA | 211 | 0.71 | 3.31 | 0.51 | 0.23 |
24(增粘剂)(5) | 110 | PMMA | 211 | 1.21 | 3.06 | 0.6 | 0.36 |
25 | 78 | PVC | 201 | 0.48 | 1.55 | 0.38 | 0.89 |
操作# | 添加剂的Tg,℃ | 添加剂聚合物种类 | 粒径nm | LDPE剥离附着力(1),pli | 环形粘性(2),pli | 耐剪切性(3A),小时 | 低温附着力(4),pli |
丙烯酸胶乳E系列1024ppmDDMDn=219nm | |||||||
26 | 无 | 0.97 | 2.31 | 0.32 | 1.81 | ||
27 | 105 | PS/MMA | 80 | 1036 | 4.17 | 1.36 | |
28 | 105 | PS/MMA | 179 | 0.71 | 1.48 | 1.21 | |
29 | 39 | PBA/MMA | 109 | 0.24 | 1.68 | 6.14 | 0.40 |
30 | 38 | PBA/MMA | 180 | 0.54 | 2.31 | 2.3 | 0.85 |
丙烯酸胶乳F系列1024ppmDDMDn=149nm | |||||||
31 | 无 | 1.39 | 2.29 | 0.27 | 2.06 | ||
32 | 105 | PS/MMA | 80 | 1.51 | 1.45 | 1.51 | |
33 | 105 | PS/MMA | 179 | 0.82 | 0.90 | 1.38 | |
丙烯酸胶乳G系列1024ppmDDMDn=94.7nm | |||||||
34 | 无 | 0.99 | 2.37 | 0.33 | 2.14 | ||
35 | 105 | PS/MMA | 80 | 1.35 | 0.80 | 0.96 | |
36 | 105 | PS/MMA | 179 | 0.90 | 0.66 | 1.14 |
操作# | 添加剂的Tg,℃ | 添加剂聚合物种类 | 粒径nm | LDPE剥离附着力(1),pli | 环形粘性(2),pli | 耐剪切性,小时 | 低温附着力(4),pli |
丙烯酸胶乳C系列1463ppm DDMDn=134nm | |||||||
37 | 无 | 1.0 | 3.5 | 0.05(3) | 2.2 | ||
38 | 40 | PVAc | 164 | 1.2 | 2.69 | 0.06(3) | 1.96 |
39 | 40 | PVAc | 293 | 0.88 | 2.91 | 0.06(3) | 2.12 |
40 | 38 | PVAc | 191 | 0.9 | 3.29 | 0.09(3) | 1.94 |
Flexcryl 1624 | |||||||
41 | 无 | 0.5 | 7.2(3A) | 2.2 | |||
42 | 40 | PVAc | 164 | 1.0 | 22.9(3A) | 0.9 | |
43(6) | 40 | PVAc | 164 | 1.4 | 17.8(3A) | 1.1 |
操作# | PSA组分 | 低Tg/高Tg混合比 | T-剥离附着力,PET,pli | T-剥离附着力,MPET,pli | T-剥离附着力,OPP,pli | 耐剪切性,小时 |
44 | Flexcryl 1624 | 100/0 | 0.20 | 0.35 | 0.08 | 0.56 |
45 | 85/15 | 0.19 | 0.33 | 0.10 | ||
46 | 70/30 | 0.23 | 0.31 | 0.11 | 2.07 | |
47 | Flexcryl 1625 | 100/0 | 0.91 | 1.62 | 0.22 | 8.88 |
48 | 85/15 | 0.75 | 1.18 | 0.29 | ||
49 | 70/30 | 0.91 | 0.99 | 0.32 | >50 | |
50 | 50/50 | 0.59 | 0.25 | 0.26 | ||
51 | Flexcryl 1614 | 100/0 | 1.06 | 1.00 | 0.94 | 0.46 |
52 | 70/30 | 0.63 | 0.22 | 0.65 | 7.80 | |
53 | 增粘Rovene9410<sup>*</sup> | 100/0 | 0.22 | 0.72 | 0.16 | |
54 | 70/30 | 0.31 | 0.78 | 0.14 | ||
55 | 增粘Hartex101<sup>*</sup> | 100/0 | 0.06 | 0.03 | 0.08 | |
56 | 70/30 | 0.20 | 0.09 | 0.25 | ||
57 | 增粘DisperxollC74<sup>*</sup> | 100/0 | 0.78 | 0.20 | 0.31 | |
58 | 70/30 | 0.51 | 0.24 | 0.40 |
操作# | 添加剂Tg,℃ | 添加剂聚合物种类 | 粒径nm | LDPE剥离附着力(1),pli | 环状粘性(2),pli | 耐剪切性(3),小时 | 低温附着力(4),pli |
丙烯酸胶乳D系列 | |||||||
59 | 无 | 0.5 | 2.42 | 0.09 | 1.58 | ||
60 | 78 | VinnolitP70F,PVC粉末 | 1000 | 0.25 | 1.18 | 0.24 | 0.23 |
操作# | 添加剂Tg,℃ | 添加剂聚合物种类 | 粒径nm | LDPE剥离粘合力(1),pli | 环状粘性(2),pli | 耐剪切性(3),小时 |
丙烯酸胶乳B系列 | ||||||
61 | 无 | 0.86 | 2.4 | 0.28 | ||
62 | 105 | 三种PS胶乳:计算Dn(掺合物)=113.8 | Dn1=91.8Dn2=115.4Dn3=134.2 | 0.86 | 1.63 | 13.5 |
Claims (16)
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Application Number | Priority Date | Filing Date | Title |
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US09/900351 | 2001-07-06 | ||
US09/900,351 US20030077443A1 (en) | 2001-07-06 | 2001-07-06 | Blends of high Tg polymer emulsions and pressure sensitive adhesive polymer emulsions useful as pressure sensitive adhesives |
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CN1396229A CN1396229A (zh) | 2003-02-12 |
CN100370001C true CN100370001C (zh) | 2008-02-20 |
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CNB021411263A Expired - Fee Related CN100370001C (zh) | 2001-07-06 | 2002-07-05 | 高Tg聚合物乳液和用作压敏粘合剂的压敏粘合剂聚合物乳液的共混物 |
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US (1) | US20030077443A1 (zh) |
EP (1) | EP1273643A1 (zh) |
KR (1) | KR100512358B1 (zh) |
CN (1) | CN100370001C (zh) |
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US20050095436A1 (en) * | 1998-06-18 | 2005-05-05 | Story Harold G. | Synthetic based self seal adhesive system for packaging |
US20030143409A1 (en) * | 2001-07-06 | 2003-07-31 | Di Stefano Frank Vito | Blends of high Tg polymer emulsions and pressure sensitive adhesive polymer emulsions useful as pressure sensitive adhesives |
KR101012833B1 (ko) * | 2003-06-19 | 2011-02-08 | 주식회사 포스코 | 권취기용 유압기의 잔압 제거장치 |
US20050282961A1 (en) * | 2004-06-18 | 2005-12-22 | Hsienkun Tsai | Pressure-sensitive label laminates with improved convertability and broad temperature adhesion performance |
KR100810947B1 (ko) * | 2005-01-28 | 2008-03-10 | 롬 앤드 하아스 컴패니 | 에멀젼 폴리머로부터 제조된 의료용 필름 및 제품 |
EP1911771A1 (en) * | 2006-10-09 | 2008-04-16 | Cytec Surface Specialties, S.A. | Acqueous polymer dispersion and process |
EP1923438A1 (en) * | 2006-11-16 | 2008-05-21 | Rohm and Haas France SAS | Emulsion based adhesive |
EP1923439A1 (en) * | 2006-11-16 | 2008-05-21 | Rohm and Haas France SAS | Emulsion based adhesive product |
EP1923441B2 (en) * | 2006-11-16 | 2016-01-06 | Rohm And Haas Company | Emulsion based adhesive |
EP1923440B2 (en) * | 2006-11-16 | 2016-01-06 | Rohm and Haas Company | Emulsion based adhesive product |
US7921470B2 (en) * | 2008-06-18 | 2011-04-12 | Kuffco, Llc | Sleeve holder |
EP2147935B1 (en) * | 2008-07-02 | 2011-12-28 | Rohm and Haas Company | Emulsion Polymer Adhesives |
JP5242331B2 (ja) | 2008-10-16 | 2013-07-24 | 日東電工株式会社 | 粘着剤組成物およびその利用 |
JP5448409B2 (ja) * | 2008-10-16 | 2014-03-19 | 日東電工株式会社 | 粘着剤組成物および粘着シート |
WO2010107697A1 (en) | 2009-03-16 | 2010-09-23 | Interlock Industries, Inc. | Multi-purpose adhesives and methods of making and using thereof |
CN101935501B (zh) * | 2009-10-15 | 2012-11-28 | 上海紫丹印务有限公司 | 一种高耐抗纸包装材料的生产方法 |
US20110226416A1 (en) * | 2010-03-18 | 2011-09-22 | Basf Se | Polymer film with multiphase film morphology |
CN102803418B (zh) * | 2010-03-18 | 2014-02-19 | 巴斯夫欧洲公司 | 具有多相膜形态的聚合物膜 |
JP5959867B2 (ja) * | 2011-07-07 | 2016-08-02 | 日東電工株式会社 | 水分散型粘着剤組成物、粘着剤及び粘着シート |
US9570751B2 (en) * | 2013-02-26 | 2017-02-14 | Samsung Sdi Co., Ltd. | Binder composition for secondary battery, anode including the binder composition, and lithium battery including the anode |
JP6898970B2 (ja) * | 2014-12-18 | 2021-07-07 | ヘンケルジャパン株式会社 | 水系粘着剤 |
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JP6183821B2 (ja) * | 2015-01-16 | 2017-08-23 | サイデン化学株式会社 | エマルション型粘着剤組成物 |
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CA3064101A1 (en) | 2018-12-06 | 2020-06-06 | National Gypsum Properties, Llc | Sound damping gypsum board and method of constructing a sound damping gypsum board |
US11772372B2 (en) | 2020-06-05 | 2023-10-03 | Gold Bond Building Products, Llc | Sound damping gypsum board and method of constructing a sound damping gypsum board |
WO2023105120A1 (en) * | 2021-12-10 | 2023-06-15 | Upm Raflatac Oy | Linerless adhesive label |
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EP0554832A1 (en) * | 1992-02-03 | 1993-08-11 | Minnesota Mining And Manufacturing Company | High solids moisture resistant latex pressure-sensitive adhesive |
JPH05247420A (ja) * | 1992-03-05 | 1993-09-24 | Mitsui Toatsu Chem Inc | 表面保護粘着フィルム |
JPH05271645A (ja) * | 1992-03-27 | 1993-10-19 | Mitsui Toatsu Chem Inc | 粘着剤樹脂組成物 |
EP0574803A2 (de) * | 1992-06-16 | 1993-12-22 | BASF Aktiengesellschaft | Verwendung von wässrigen Dispersionen als Heisssiegelkleber |
CN1233260A (zh) * | 1996-09-09 | 1999-10-27 | 巴斯福股份公司 | 聚合物水分散体的制备方法 |
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EP0586966A3 (en) * | 1992-09-10 | 1994-06-15 | Nat Starch Chem Invest | High cohesion waterborne pressure sensitive adhesives |
JP2001207146A (ja) * | 2000-01-26 | 2001-07-31 | Saiden Chemical Industry Co Ltd | 水性粘着剤組成物 |
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2001
- 2001-07-06 US US09/900,351 patent/US20030077443A1/en not_active Abandoned
-
2002
- 2002-07-01 EP EP02014073A patent/EP1273643A1/en not_active Withdrawn
- 2002-07-04 KR KR10-2002-0038529A patent/KR100512358B1/ko not_active IP Right Cessation
- 2002-07-05 CN CNB021411263A patent/CN100370001C/zh not_active Expired - Fee Related
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
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EP0554832A1 (en) * | 1992-02-03 | 1993-08-11 | Minnesota Mining And Manufacturing Company | High solids moisture resistant latex pressure-sensitive adhesive |
JPH05247420A (ja) * | 1992-03-05 | 1993-09-24 | Mitsui Toatsu Chem Inc | 表面保護粘着フィルム |
JPH05271645A (ja) * | 1992-03-27 | 1993-10-19 | Mitsui Toatsu Chem Inc | 粘着剤樹脂組成物 |
EP0574803A2 (de) * | 1992-06-16 | 1993-12-22 | BASF Aktiengesellschaft | Verwendung von wässrigen Dispersionen als Heisssiegelkleber |
CN1233260A (zh) * | 1996-09-09 | 1999-10-27 | 巴斯福股份公司 | 聚合物水分散体的制备方法 |
Also Published As
Publication number | Publication date |
---|---|
EP1273643A1 (en) | 2003-01-08 |
CN1396229A (zh) | 2003-02-12 |
US20030077443A1 (en) | 2003-04-24 |
KR100512358B1 (ko) | 2005-09-02 |
KR20030008139A (ko) | 2003-01-24 |
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