CN100369844C - 玻璃用水溶性防热辐射涂料,防热辐射玻璃,和防止热辐射的方法 - Google Patents
玻璃用水溶性防热辐射涂料,防热辐射玻璃,和防止热辐射的方法 Download PDFInfo
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- CN100369844C CN100369844C CNB038100592A CN03810059A CN100369844C CN 100369844 C CN100369844 C CN 100369844C CN B038100592 A CNB038100592 A CN B038100592A CN 03810059 A CN03810059 A CN 03810059A CN 100369844 C CN100369844 C CN 100369844C
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- glass
- thermal radiation
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- 230000005855 radiation Effects 0.000 title claims abstract description 324
- 239000011521 glass Substances 0.000 title claims abstract description 258
- 238000000576 coating method Methods 0.000 title claims abstract description 66
- 239000011248 coating agent Substances 0.000 title claims abstract description 65
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 46
- 238000000034 method Methods 0.000 title claims abstract description 40
- 239000000463 material Substances 0.000 title abstract description 41
- 239000006087 Silane Coupling Agent Substances 0.000 claims abstract description 47
- 239000008367 deionised water Substances 0.000 claims abstract description 21
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 21
- SCPYDCQAZCOKTP-UHFFFAOYSA-N silanol Chemical compound [SiH3]O SCPYDCQAZCOKTP-UHFFFAOYSA-N 0.000 claims abstract description 16
- 238000006460 hydrolysis reaction Methods 0.000 claims abstract description 11
- 230000007062 hydrolysis Effects 0.000 claims abstract description 10
- 238000002834 transmittance Methods 0.000 claims description 49
- 238000001228 spectrum Methods 0.000 claims description 38
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- 230000015572 biosynthetic process Effects 0.000 claims description 11
- 238000001035 drying Methods 0.000 claims description 9
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 6
- 241000282326 Felis catus Species 0.000 claims description 4
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 4
- 229920002554 vinyl polymer Chemical group 0.000 claims description 4
- 125000000217 alkyl group Chemical group 0.000 claims description 3
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- 239000000758 substrate Substances 0.000 abstract 2
- 150000001450 anions Chemical class 0.000 abstract 1
- VTYYLEPIZMXCLO-UHFFFAOYSA-L calcium carbonate Substances [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 abstract 1
- 229910000019 calcium carbonate Inorganic materials 0.000 abstract 1
- 239000000243 solution Substances 0.000 description 22
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- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 12
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- 230000005540 biological transmission Effects 0.000 description 7
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
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- 150000001768 cations Chemical class 0.000 description 5
- 239000012286 potassium permanganate Substances 0.000 description 5
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- 239000004411 aluminium Substances 0.000 description 4
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- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- 235000014113 dietary fatty acids Nutrition 0.000 description 4
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- 229920001296 polysiloxane Polymers 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 238000012545 processing Methods 0.000 description 4
- 238000003860 storage Methods 0.000 description 4
- 125000000022 2-aminoethyl group Chemical group [H]C([*])([H])C([H])([H])N([H])[H] 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 3
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- PHQOGHDTIVQXHL-UHFFFAOYSA-N n'-(3-trimethoxysilylpropyl)ethane-1,2-diamine Chemical compound CO[Si](OC)(OC)CCCNCCN PHQOGHDTIVQXHL-UHFFFAOYSA-N 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
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- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 2
- 229910004298 SiO 2 Inorganic materials 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
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- 230000002950 deficient Effects 0.000 description 2
- PKTOVQRKCNPVKY-UHFFFAOYSA-N dimethoxy(methyl)silicon Chemical compound CO[Si](C)OC PKTOVQRKCNPVKY-UHFFFAOYSA-N 0.000 description 2
- WHGNXNCOTZPEEK-UHFFFAOYSA-N dimethoxy-methyl-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical compound CO[Si](C)(OC)CCCOCC1CO1 WHGNXNCOTZPEEK-UHFFFAOYSA-N 0.000 description 2
- 150000002118 epoxides Chemical group 0.000 description 2
- FWDBOZPQNFPOLF-UHFFFAOYSA-N ethenyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)C=C FWDBOZPQNFPOLF-UHFFFAOYSA-N 0.000 description 2
- NKSJNEHGWDZZQF-UHFFFAOYSA-N ethenyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C=C NKSJNEHGWDZZQF-UHFFFAOYSA-N 0.000 description 2
- SBRXLTRZCJVAPH-UHFFFAOYSA-N ethyl(trimethoxy)silane Chemical compound CC[Si](OC)(OC)OC SBRXLTRZCJVAPH-UHFFFAOYSA-N 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- 125000005843 halogen group Chemical group 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 229920000151 polyglycol Polymers 0.000 description 2
- 239000010695 polyglycol Substances 0.000 description 2
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 230000009257 reactivity Effects 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 230000000630 rising effect Effects 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- FZHAPNGMFPVSLP-UHFFFAOYSA-N silanamine Chemical compound [SiH3]N FZHAPNGMFPVSLP-UHFFFAOYSA-N 0.000 description 2
- 229910000077 silane Inorganic materials 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 239000004577 thatch Substances 0.000 description 2
- 230000008719 thickening Effects 0.000 description 2
- GQIUQDDJKHLHTB-UHFFFAOYSA-N trichloro(ethenyl)silane Chemical compound Cl[Si](Cl)(Cl)C=C GQIUQDDJKHLHTB-UHFFFAOYSA-N 0.000 description 2
- JXUKBNICSRJFAP-UHFFFAOYSA-N triethoxy-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical compound CCO[Si](OCC)(OCC)CCCOCC1CO1 JXUKBNICSRJFAP-UHFFFAOYSA-N 0.000 description 2
- DQZNLOXENNXVAD-UHFFFAOYSA-N trimethoxy-[2-(7-oxabicyclo[4.1.0]heptan-4-yl)ethyl]silane Chemical compound C1C(CC[Si](OC)(OC)OC)CCC2OC21 DQZNLOXENNXVAD-UHFFFAOYSA-N 0.000 description 2
- 239000005050 vinyl trichlorosilane Substances 0.000 description 2
- 238000009736 wetting Methods 0.000 description 2
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical compound OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 description 1
- SRFACLNNATVRAT-YUDCMIJISA-N (2s)-2-[[(e)-2-carboxyethenyl]amino]-3-methyl-3-sulfinobutanoic acid Chemical compound OS(=O)C(C)(C)[C@H](C(O)=O)N\C=C\C(O)=O SRFACLNNATVRAT-YUDCMIJISA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 241000272525 Anas platyrhynchos Species 0.000 description 1
- ZTQSAGDEMFDKMZ-UHFFFAOYSA-N Butyraldehyde Chemical compound CCCC=O ZTQSAGDEMFDKMZ-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
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- 229930006000 Sucrose Natural products 0.000 description 1
- 229920013701 VORANOL™ Polymers 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
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- 238000004378 air conditioning Methods 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- 125000005370 alkoxysilyl group Chemical group 0.000 description 1
- 125000005037 alkyl phenyl group Chemical group 0.000 description 1
- 125000005336 allyloxy group Chemical group 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 230000003373 anti-fouling effect Effects 0.000 description 1
- 125000004104 aryloxy group Chemical group 0.000 description 1
- 229960000686 benzalkonium chloride Drugs 0.000 description 1
- 230000031709 bromination Effects 0.000 description 1
- 238000005893 bromination reaction Methods 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000005341 cation exchange Methods 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 238000005660 chlorination reaction Methods 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 238000005253 cladding Methods 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000003292 diminished effect Effects 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- ICIWUVCWSCSTAQ-UHFFFAOYSA-M iodate Chemical compound [O-]I(=O)=O ICIWUVCWSCSTAQ-UHFFFAOYSA-M 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
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- 239000007769 metal material Substances 0.000 description 1
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- 235000010270 methyl p-hydroxybenzoate Nutrition 0.000 description 1
- 239000004292 methyl p-hydroxybenzoate Substances 0.000 description 1
- LXCFILQKKLGQFO-UHFFFAOYSA-N methylparaben Chemical compound COC(=O)C1=CC=C(O)C=C1 LXCFILQKKLGQFO-UHFFFAOYSA-N 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- HOSQZKZVJBFALN-UHFFFAOYSA-N n'-benzyl-n-(3-trimethoxysilylpropyl)ethane-1,2-diamine;hydron;chloride Chemical compound Cl.CO[Si](OC)(OC)CCCNCCNCC1=CC=CC=C1 HOSQZKZVJBFALN-UHFFFAOYSA-N 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 125000000962 organic group Chemical group 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 230000010287 polarization Effects 0.000 description 1
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- 229920000642 polymer Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 239000008213 purified water Substances 0.000 description 1
- 230000000191 radiation effect Effects 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000013049 sediment Substances 0.000 description 1
- 150000004819 silanols Chemical class 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 239000002195 soluble material Substances 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 235000014347 soups Nutrition 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 238000004544 sputter deposition Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 238000004448 titration Methods 0.000 description 1
- 125000005270 trialkylamine group Chemical group 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/28—Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material
- C03C17/30—Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material with silicon-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/04—Polysiloxanes
- C09D183/08—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen, and oxygen
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/32—Radiation-absorbing paints
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/14—Polysiloxanes containing silicon bound to oxygen-containing groups
- C08G77/16—Polysiloxanes containing silicon bound to oxygen-containing groups to hydroxyl groups
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S428/00—Stock material or miscellaneous articles
- Y10S428/92—Fire or heat protection feature
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
- Y10T428/31609—Particulate metal or metal compound-containing
- Y10T428/31612—As silicone, silane or siloxane
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31652—Of asbestos
- Y10T428/31663—As siloxane, silicone or silane
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Wood Science & Technology (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Surface Treatment Of Glass (AREA)
- Laminated Bodies (AREA)
- Paints Or Removers (AREA)
Abstract
Description
硅烷偶合剂 | 总阴离子含量51.3mgCaCO<sub>3</sub>/L | 总阴离子含量102.7mgCaCO<sub>3</sub>/L | 总阴离子含量302.5mgCaCO<sub>3</sub>/L | 总阴离子含量558.9mgCaCO<sub>3</sub>/L | 总阴离子含量750mgCaCO<sub>3</sub>/L |
0.001% | ◎ | ◎ | ◎ | ◎ | △ |
0.005% | ◎ | ◎ | ◎ | ◎ | △ |
0.01% | ◎ | ◎ | ◎ | ◎ | △ |
0.1% | ◎ | ◎ | ◎ | ◎ | △ |
1.0% | ◎ | ◎ | ◎ | ◎ | × |
3.0% | ◎ | ◎ | ◎ | ◎ | × |
5.0% | ◎ | ◎ | ◎ | ◎ | × |
6.0% | ◎ | ◎ | ◎ | ◎ | × |
硅烷偶合剂 | 总阴离子含量51.3mgCaCO<sub>3</sub>/L | 总阴离子含量102.7mgCaCO<sub>3</sub>/L | 总阴离子含量302.5mgCaCO<sub>3</sub>/L | 总阴离子含量558.9mgCaCO<sub>3</sub>/L | 总阴离子含量750mgCaCO<sub>3</sub>/L |
0.001% | ◎ | ◎ | ◎ | ◎ | ◎ |
0.005% | ◎ | ◎ | ◎ | ◎ | ◎ |
0.01% | ◎ | ◎ | ◎ | ◎ | ◎ |
0.1% | ◎ | ◎ | ◎ | ◎ | ◎ |
1.0% | ◎ | ◎ | ◎ | ◎ | ◎ |
3.0% | ◎ | ◎ | ◎ | ◎ | △ |
5.0% | ◎ | ◎ | ◎ | ◎ | △ |
6.0% | ◎ | ◎ | ◎ | ◎ | △ |
硅烷偶合剂 | 总阴离子含量51.3mgCaCO<sub>3</sub>/L | 总阴离子含量102.7mgCaCO<sub>3</sub>/L | 总阴离子含量302.5mgCaCO<sub>3</sub>/L | 总阴离子含量558.9mgCaCO<sub>3</sub>/L | 总阴离子含量750mgCaCO<sub>3</sub>/L |
0.001% | ◎ | ◎ | ◎ | ◎ | △ |
0.005% | ◎ | ◎ | ◎ | ◎ | △ |
0.01% | ◎ | ◎ | ◎ | ◎ | △ |
0.1% | ◎ | ◎ | ◎ | ◎ | △ |
1.0% | ◎ | ◎ | ◎ | ◎ | △ |
3.0% | ◎ | ◎ | ◎ | ◎ | △ |
5.0% | ◎ | ◎ | ◎ | ◎ | × |
6.0% | ◎ | ◎ | ◎ | ◎ | × |
测试样品 | 涂膜的太阳辐射热吸收率(%) | 在常温下热辐射波长谱带中的辐射热吸收率(%) | 涂膜的可见光透光率(%) | 箱子内部的平均温度(℃) |
0.01%溶液 | 0.08 | 0.12 | 99.9 | 50.3 |
0.1%溶液 | 0.11 | 0.55 | 99.8 | 50.5 |
1.0%溶液 | 0.19 | 3.24 | 99.8 | 50.3 |
3.0%溶液 | 0.24 | 4.21 | 99.8 | 50.4 |
5.0%溶液 | 0.25 | 4.78 | 99.8 | 50.4 |
仅玻璃 | 11.1<sup>*1</sup> | 89.9<sup>*1</sup> | 89.1<sup>*1</sup> | 52.3 |
Claims (11)
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JP2002111573 | 2002-04-15 | ||
JP111573/2002 | 2002-04-15 |
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CN1703379A CN1703379A (zh) | 2005-11-30 |
CN100369844C true CN100369844C (zh) | 2008-02-20 |
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US (1) | US7858196B2 (zh) |
JP (1) | JP4421902B2 (zh) |
KR (1) | KR100966248B1 (zh) |
CN (1) | CN100369844C (zh) |
AU (1) | AU2003236361A1 (zh) |
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JP2007106918A (ja) * | 2005-10-14 | 2007-04-26 | Oshino Denki Seisakusho:Kk | 断熱塗膜材 |
US8186113B2 (en) * | 2007-07-09 | 2012-05-29 | Raytheon Canada Limited | Building window having a visible-light-reflective optical interference coating thereon |
CN103122163B (zh) * | 2011-11-18 | 2015-04-08 | 攀钢集团研究院有限公司 | 一种金属防护涂料和热镀金属材料 |
US20160069070A1 (en) * | 2014-09-10 | 2016-03-10 | United States Gypsum Company | Two-layer glass fiber mat composite |
CN106642032A (zh) * | 2017-03-06 | 2017-05-10 | 湖州明朔光电科技有限公司 | 防高温防热辐射层结构及工矿用灯 |
CN106978051B (zh) * | 2017-04-13 | 2019-05-31 | 江苏大使同丰涂料有限公司 | 一种玻璃用防热辐射涂料及其制备方法 |
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JP2002012601A (ja) * | 2000-06-30 | 2002-01-15 | Saiden Chemical Industry Co Ltd | 塗料用水性重合体分散液の製造方法及びその分散液 |
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US4658059A (en) * | 1983-12-30 | 1987-04-14 | Union Oil Company Of California | Methods for removing biuret from urea by ion exchange |
US5411585A (en) * | 1991-02-15 | 1995-05-02 | S. C. Johnson & Son, Inc. | Production of stable hydrolyzable organosilane solutions |
US5783264A (en) * | 1991-12-16 | 1998-07-21 | Howes; Stephen Edwin | Decorative windows with contoured plastic resin laminated to glass |
US5250185A (en) * | 1992-05-01 | 1993-10-05 | Texaco Inc. | Reducing aqueous boron concentrations with reverse osmosis membranes operating at a high pH |
US5363994A (en) * | 1992-06-26 | 1994-11-15 | Tremco, Inc. | Aqueous silane coupling agent solution for use as a sealant primer |
US5873931A (en) * | 1992-10-06 | 1999-02-23 | Minnesota Mining And Manufacturing Company | Coating composition having anti-reflective and anti-fogging properties |
GB9400319D0 (en) * | 1994-01-10 | 1994-03-09 | Pilkington Glass Ltd | Coatings on glass |
DE69522483T2 (de) * | 1994-03-01 | 2002-04-25 | Mitsubishi Chem Corp | Methode zur Demineralisierung von Wasser oder einer wässerigen Flüssigkeit |
JP3200301B2 (ja) * | 1994-07-22 | 2001-08-20 | オルガノ株式会社 | 純水又は超純水の製造方法及び製造装置 |
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US6001163A (en) * | 1997-04-17 | 1999-12-14 | Sdc Coatings, Inc. | Composition for providing an abrasion resistant coating on a substrate |
JP2000319588A (ja) * | 1999-05-10 | 2000-11-21 | Sony Corp | 熱吸収膜用塗料、熱吸収膜およびカラー陰極線管 |
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- 2003-04-03 CN CNB038100592A patent/CN100369844C/zh not_active Expired - Fee Related
- 2003-04-03 JP JP2003583963A patent/JP4421902B2/ja not_active Expired - Lifetime
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US5907015A (en) * | 1994-08-02 | 1999-05-25 | Lord Corporation | Aqueous silane adhesive compositions |
JP2002012601A (ja) * | 2000-06-30 | 2002-01-15 | Saiden Chemical Industry Co Ltd | 塗料用水性重合体分散液の製造方法及びその分散液 |
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WO2003087003A1 (fr) | 2003-10-23 |
JPWO2003087003A1 (ja) | 2005-08-18 |
HK1084655A1 (en) | 2006-08-04 |
CN1703379A (zh) | 2005-11-30 |
KR20050007295A (ko) | 2005-01-17 |
AU2003236361A1 (en) | 2003-10-27 |
JP4421902B2 (ja) | 2010-02-24 |
KR100966248B1 (ko) | 2010-06-28 |
US7858196B2 (en) | 2010-12-28 |
US20050214544A1 (en) | 2005-09-29 |
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