CH629507A5 - Process for the polymerisation of mono- and di-olefinic compounds - Google Patents
Process for the polymerisation of mono- and di-olefinic compounds Download PDFInfo
- Publication number
- CH629507A5 CH629507A5 CH1415177A CH1415177A CH629507A5 CH 629507 A5 CH629507 A5 CH 629507A5 CH 1415177 A CH1415177 A CH 1415177A CH 1415177 A CH1415177 A CH 1415177A CH 629507 A5 CH629507 A5 CH 629507A5
- Authority
- CH
- Switzerland
- Prior art keywords
- reaction
- carried out
- process according
- pia
- polymerization
- Prior art date
Links
- 150000001875 compounds Chemical class 0.000 title claims description 17
- 238000000034 method Methods 0.000 title claims description 13
- 238000006116 polymerization reaction Methods 0.000 claims description 18
- 238000006243 chemical reaction Methods 0.000 claims description 13
- 125000005234 alkyl aluminium group Chemical class 0.000 claims description 7
- 229930195733 hydrocarbon Natural products 0.000 claims description 6
- 239000004215 Carbon black (E152) Substances 0.000 claims description 5
- 150000004678 hydrides Chemical class 0.000 claims description 5
- 229910052723 transition metal Inorganic materials 0.000 claims description 5
- 150000003624 transition metals Chemical class 0.000 claims description 5
- 230000003197 catalytic effect Effects 0.000 claims description 3
- 239000000178 monomer Substances 0.000 claims description 3
- 125000003118 aryl group Chemical group 0.000 claims description 2
- 150000001993 dienes Chemical class 0.000 claims description 2
- 150000005673 monoalkenes Chemical class 0.000 claims description 2
- 239000002904 solvent Substances 0.000 claims description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 12
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 12
- 229920000642 polymer Polymers 0.000 description 12
- 229910052782 aluminium Inorganic materials 0.000 description 9
- 239000007787 solid Substances 0.000 description 7
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 6
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 5
- IMNFDUFMRHMDMM-UHFFFAOYSA-N anhydrous n-heptane Natural products CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 5
- 229910002056 binary alloy Inorganic materials 0.000 description 5
- 239000003054 catalyst Substances 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 4
- 239000005977 Ethylene Substances 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical class [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
- 229910003074 TiCl4 Inorganic materials 0.000 description 3
- 125000000217 alkyl group Chemical group 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 description 3
- 238000006467 substitution reaction Methods 0.000 description 3
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 3
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
- 230000003993 interaction Effects 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 229920001195 polyisoprene Polymers 0.000 description 2
- 239000011541 reaction mixture Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 150000003623 transition metal compounds Chemical class 0.000 description 2
- 238000011282 treatment Methods 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- -1 aluminum compound Chemical class 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 238000005660 chlorination reaction Methods 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 125000001309 chloro group Chemical group Cl* 0.000 description 1
- 230000000536 complexating effect Effects 0.000 description 1
- 238000010668 complexation reaction Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT29602/76A IT1064496B (it) | 1976-11-22 | 1976-11-22 | Processo per la polimerizzazione di composti mono e diolefinici |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CH629507A5 true CH629507A5 (en) | 1982-04-30 |
Family
ID=11228082
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CH1415177A CH629507A5 (en) | 1976-11-22 | 1977-11-18 | Process for the polymerisation of mono- and di-olefinic compounds |
Country Status (20)
| Country | Link |
|---|---|
| JP (1) | JPS6055526B2 (cg-RX-API-DMAC7.html) |
| AU (1) | AU510549B2 (cg-RX-API-DMAC7.html) |
| BE (1) | BE861062A (cg-RX-API-DMAC7.html) |
| CA (1) | CA1106543A (cg-RX-API-DMAC7.html) |
| CH (1) | CH629507A5 (cg-RX-API-DMAC7.html) |
| CS (1) | CS203177B2 (cg-RX-API-DMAC7.html) |
| DD (1) | DD133334A5 (cg-RX-API-DMAC7.html) |
| DE (1) | DE2751919C2 (cg-RX-API-DMAC7.html) |
| DK (1) | DK149127C (cg-RX-API-DMAC7.html) |
| FR (1) | FR2371464A1 (cg-RX-API-DMAC7.html) |
| GB (1) | GB1587659A (cg-RX-API-DMAC7.html) |
| HU (1) | HU176874B (cg-RX-API-DMAC7.html) |
| IL (1) | IL53366A (cg-RX-API-DMAC7.html) |
| IT (1) | IT1064496B (cg-RX-API-DMAC7.html) |
| LU (1) | LU78555A1 (cg-RX-API-DMAC7.html) |
| NL (1) | NL180012C (cg-RX-API-DMAC7.html) |
| NO (1) | NO149924C (cg-RX-API-DMAC7.html) |
| SE (1) | SE440362B (cg-RX-API-DMAC7.html) |
| YU (1) | YU39055B (cg-RX-API-DMAC7.html) |
| ZA (1) | ZA776811B (cg-RX-API-DMAC7.html) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62127088U (cg-RX-API-DMAC7.html) * | 1986-02-05 | 1987-08-12 | ||
| BE1007698A3 (fr) * | 1993-11-04 | 1995-10-03 | Solvay | Systeme catalytique utilisable pour la polymerisation des alpha-olefines et procede pour cette polymerisation. |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3901862A (en) * | 1972-12-20 | 1975-08-26 | Snam Progetti | Process for the preparation of ethylene-butadiene copolymers |
| FR2237911A1 (en) * | 1973-07-04 | 1975-02-14 | Okktinskoe Mauchno Proizv | High yield ethylene(-propylene)polymer prepn. - using titanium chloride and polyalkylalumoxane reactn. prod. as catalyst system |
| IT1019677B (it) * | 1974-07-01 | 1977-11-30 | Snam Progetti | Composti polimerici dell allumi nio di natura poliiminica procedi mento per la loro preparazione e loro impiego come componenti di sistemi catalitici per la poli merizzazione di composti insaturi |
-
1976
- 1976-11-22 IT IT29602/76A patent/IT1064496B/it active
-
1977
- 1977-11-09 AU AU30478/77A patent/AU510549B2/en not_active Expired
- 1977-11-09 CA CA290,496A patent/CA1106543A/en not_active Expired
- 1977-11-13 IL IL53366A patent/IL53366A/xx unknown
- 1977-11-15 ZA ZA00776811A patent/ZA776811B/xx unknown
- 1977-11-18 NO NO773949A patent/NO149924C/no unknown
- 1977-11-18 CH CH1415177A patent/CH629507A5/it not_active IP Right Cessation
- 1977-11-21 GB GB48445/77A patent/GB1587659A/en not_active Expired
- 1977-11-21 DE DE2751919A patent/DE2751919C2/de not_active Expired
- 1977-11-21 SE SE7713140A patent/SE440362B/xx not_active IP Right Cessation
- 1977-11-21 CS CS777645A patent/CS203177B2/cs unknown
- 1977-11-21 DK DK516077A patent/DK149127C/da not_active IP Right Cessation
- 1977-11-21 YU YU02770/77A patent/YU39055B/xx unknown
- 1977-11-21 LU LU78555A patent/LU78555A1/xx unknown
- 1977-11-21 JP JP52139027A patent/JPS6055526B2/ja not_active Expired
- 1977-11-21 FR FR7734946A patent/FR2371464A1/fr active Granted
- 1977-11-22 BE BE182820A patent/BE861062A/xx not_active IP Right Cessation
- 1977-11-22 NL NLAANVRAGE7712876,A patent/NL180012C/xx not_active IP Right Cessation
- 1977-11-22 DD DD7700202190A patent/DD133334A5/xx unknown
- 1977-12-21 HU HU77SA3076A patent/HU176874B/hu unknown
Also Published As
| Publication number | Publication date |
|---|---|
| CS203177B2 (en) | 1981-02-27 |
| NL180012C (nl) | 1986-12-16 |
| SE440362B (sv) | 1985-07-29 |
| JPS6055526B2 (ja) | 1985-12-05 |
| ZA776811B (en) | 1978-09-27 |
| NL7712876A (nl) | 1978-05-24 |
| FR2371464B1 (cg-RX-API-DMAC7.html) | 1980-05-16 |
| HU176874B (en) | 1981-05-28 |
| DE2751919A1 (de) | 1978-05-24 |
| NL180012B (nl) | 1986-07-16 |
| IL53366A0 (en) | 1978-01-31 |
| SE7713140L (sv) | 1978-05-23 |
| IL53366A (en) | 1981-03-31 |
| BE861062A (fr) | 1978-05-22 |
| JPS5365382A (en) | 1978-06-10 |
| NO773949L (no) | 1978-05-23 |
| DK149127C (da) | 1986-07-14 |
| CA1106543A (en) | 1981-08-04 |
| IT1064496B (it) | 1985-02-18 |
| YU277077A (en) | 1982-06-30 |
| DK149127B (da) | 1986-02-03 |
| AU510549B2 (en) | 1980-07-03 |
| YU39055B (en) | 1984-02-29 |
| AU3047877A (en) | 1979-06-28 |
| GB1587659A (en) | 1981-04-08 |
| DD133334A5 (de) | 1978-12-27 |
| NO149924B (no) | 1984-04-09 |
| FR2371464A1 (fr) | 1978-06-16 |
| LU78555A1 (cg-RX-API-DMAC7.html) | 1978-04-13 |
| DE2751919C2 (de) | 1982-11-25 |
| DK516077A (da) | 1978-05-23 |
| NO149924C (no) | 1984-08-01 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PL | Patent ceased | ||
| PL | Patent ceased |