CH539001A - Procédé de purification électrolytique des eaux résiduelles - Google Patents
Procédé de purification électrolytique des eaux résiduellesInfo
- Publication number
- CH539001A CH539001A CH592572A CH592572A CH539001A CH 539001 A CH539001 A CH 539001A CH 592572 A CH592572 A CH 592572A CH 592572 A CH592572 A CH 592572A CH 539001 A CH539001 A CH 539001A
- Authority
- CH
- Switzerland
- Prior art keywords
- mercury
- solution
- iron
- chromium
- electrodes
- Prior art date
Links
- 238000000746 purification Methods 0.000 title claims description 12
- 239000002351 wastewater Substances 0.000 title description 3
- 238000000034 method Methods 0.000 claims description 38
- 230000008569 process Effects 0.000 claims description 23
- 229910001868 water Inorganic materials 0.000 claims description 21
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 17
- ZCDOYSPFYFSLEW-UHFFFAOYSA-N chromate(2-) Chemical class [O-][Cr]([O-])(=O)=O ZCDOYSPFYFSLEW-UHFFFAOYSA-N 0.000 claims description 16
- 229910052739 hydrogen Inorganic materials 0.000 claims description 15
- 239000001257 hydrogen Substances 0.000 claims description 15
- 239000000463 material Substances 0.000 claims description 13
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 12
- 150000002730 mercury Chemical class 0.000 claims description 11
- 229910052799 carbon Inorganic materials 0.000 claims description 10
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 9
- 239000007788 liquid Substances 0.000 claims description 9
- 238000005192 partition Methods 0.000 claims description 2
- 239000000843 powder Substances 0.000 claims description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 65
- 239000000243 solution Substances 0.000 description 42
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 32
- 229910052742 iron Inorganic materials 0.000 description 27
- 229910052753 mercury Inorganic materials 0.000 description 26
- 239000011701 zinc Substances 0.000 description 24
- 229910052751 metal Inorganic materials 0.000 description 22
- 239000011651 chromium Substances 0.000 description 21
- 238000006243 chemical reaction Methods 0.000 description 19
- 239000010949 copper Substances 0.000 description 19
- 239000002184 metal Substances 0.000 description 19
- 239000002253 acid Substances 0.000 description 18
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 16
- 229910052804 chromium Inorganic materials 0.000 description 16
- 238000011282 treatment Methods 0.000 description 15
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 description 14
- 229910052802 copper Inorganic materials 0.000 description 13
- 229910052725 zinc Inorganic materials 0.000 description 13
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 12
- 229910000510 noble metal Inorganic materials 0.000 description 12
- 230000015572 biosynthetic process Effects 0.000 description 11
- 229940008718 metallic mercury Drugs 0.000 description 11
- 150000003839 salts Chemical class 0.000 description 9
- 239000000725 suspension Substances 0.000 description 9
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 8
- 229910002651 NO3 Inorganic materials 0.000 description 8
- JOPOVCBBYLSVDA-UHFFFAOYSA-N chromium(6+) Chemical compound [Cr+6] JOPOVCBBYLSVDA-UHFFFAOYSA-N 0.000 description 8
- 230000009467 reduction Effects 0.000 description 8
- 235000010344 sodium nitrate Nutrition 0.000 description 7
- 229910000497 Amalgam Inorganic materials 0.000 description 6
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 6
- 239000003792 electrolyte Substances 0.000 description 6
- 150000002500 ions Chemical class 0.000 description 6
- 239000007791 liquid phase Substances 0.000 description 6
- 150000007513 acids Chemical class 0.000 description 5
- 230000008901 benefit Effects 0.000 description 5
- 239000010802 sludge Substances 0.000 description 5
- PXLIDIMHPNPGMH-UHFFFAOYSA-N sodium chromate Chemical compound [Na+].[Na+].[O-][Cr]([O-])(=O)=O PXLIDIMHPNPGMH-UHFFFAOYSA-N 0.000 description 5
- 239000004317 sodium nitrate Substances 0.000 description 5
- 229910000831 Steel Inorganic materials 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- 150000001447 alkali salts Chemical class 0.000 description 4
- 239000011575 calcium Substances 0.000 description 4
- VQWFNAGFNGABOH-UHFFFAOYSA-K chromium(iii) hydroxide Chemical class [OH-].[OH-].[OH-].[Cr+3] VQWFNAGFNGABOH-UHFFFAOYSA-K 0.000 description 4
- 238000004090 dissolution Methods 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 150000002739 metals Chemical class 0.000 description 4
- -1 nitrate ions Chemical class 0.000 description 4
- 239000002244 precipitate Substances 0.000 description 4
- 239000010959 steel Substances 0.000 description 4
- 235000011149 sulphuric acid Nutrition 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- DOBUSJIVSSJEDA-UHFFFAOYSA-L 1,3-dioxa-2$l^{6}-thia-4-mercuracyclobutane 2,2-dioxide Chemical class [Hg+2].[O-]S([O-])(=O)=O DOBUSJIVSSJEDA-UHFFFAOYSA-L 0.000 description 3
- 229910003556 H2 SO4 Inorganic materials 0.000 description 3
- 229910018487 Ni—Cr Inorganic materials 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 230000002378 acidificating effect Effects 0.000 description 3
- 238000007792 addition Methods 0.000 description 3
- 238000005267 amalgamation Methods 0.000 description 3
- 150000001450 anions Chemical class 0.000 description 3
- 238000005119 centrifugation Methods 0.000 description 3
- 150000001844 chromium Chemical class 0.000 description 3
- VNNRSPGTAMTISX-UHFFFAOYSA-N chromium nickel Chemical compound [Cr].[Ni] VNNRSPGTAMTISX-UHFFFAOYSA-N 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- 238000005189 flocculation Methods 0.000 description 3
- 230000016615 flocculation Effects 0.000 description 3
- 229910001385 heavy metal Inorganic materials 0.000 description 3
- 238000009434 installation Methods 0.000 description 3
- 235000014413 iron hydroxide Nutrition 0.000 description 3
- NCNCGGDMXMBVIA-UHFFFAOYSA-L iron(ii) hydroxide Chemical class [OH-].[OH-].[Fe+2] NCNCGGDMXMBVIA-UHFFFAOYSA-L 0.000 description 3
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 150000002823 nitrates Chemical class 0.000 description 3
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 3
- 230000001590 oxidative effect Effects 0.000 description 3
- 239000003643 water by type Substances 0.000 description 3
- IKHGUXGNUITLKF-UHFFFAOYSA-N Acetaldehyde Chemical compound CC=O IKHGUXGNUITLKF-UHFFFAOYSA-N 0.000 description 2
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 description 2
- 239000010405 anode material Substances 0.000 description 2
- 229910001424 calcium ion Inorganic materials 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 239000010406 cathode material Substances 0.000 description 2
- 150000001768 cations Chemical class 0.000 description 2
- RCTYPNKXASFOBE-UHFFFAOYSA-M chloromercury Chemical compound [Hg]Cl RCTYPNKXASFOBE-UHFFFAOYSA-M 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 150000001879 copper Chemical class 0.000 description 2
- 125000002534 ethynyl group Chemical group [H]C#C* 0.000 description 2
- 230000007062 hydrolysis Effects 0.000 description 2
- 238000006460 hydrolysis reaction Methods 0.000 description 2
- 229910000370 mercury sulfate Inorganic materials 0.000 description 2
- 150000004692 metal hydroxides Chemical class 0.000 description 2
- 230000007935 neutral effect Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 239000012071 phase Substances 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 2
- 229910000368 zinc sulfate Inorganic materials 0.000 description 2
- 239000011686 zinc sulphate Substances 0.000 description 2
- 235000009529 zinc sulphate Nutrition 0.000 description 2
- WWSJZGAPAVMETJ-UHFFFAOYSA-N 2-[4-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]-3-ethoxypyrazol-1-yl]-1-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethanone Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)C=1C(=NN(C=1)CC(=O)N1CC2=C(CC1)NN=N2)OCC WWSJZGAPAVMETJ-UHFFFAOYSA-N 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 229910007541 Zn O Inorganic materials 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229940101006 anhydrous sodium sulfite Drugs 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000008346 aqueous phase Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 159000000007 calcium salts Chemical class 0.000 description 1
- 150000001721 carbon Chemical class 0.000 description 1
- 238000005255 carburizing Methods 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 230000000536 complexating effect Effects 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 229910001448 ferrous ion Inorganic materials 0.000 description 1
- 239000011790 ferrous sulphate Substances 0.000 description 1
- 235000003891 ferrous sulphate Nutrition 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000003517 fume Substances 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- GPRLSGONYQIRFK-UHFFFAOYSA-N hydron Chemical compound [H+] GPRLSGONYQIRFK-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- LWJROJCJINYWOX-UHFFFAOYSA-L mercury dichloride Chemical compound Cl[Hg]Cl LWJROJCJINYWOX-UHFFFAOYSA-L 0.000 description 1
- 229910000372 mercury(II) sulfate Inorganic materials 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 230000020477 pH reduction Effects 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000012549 training Methods 0.000 description 1
- 150000003751 zinc Chemical class 0.000 description 1
- UGZADUVQMDAIAO-UHFFFAOYSA-L zinc hydroxide Chemical compound [OH-].[OH-].[Zn+2] UGZADUVQMDAIAO-UHFFFAOYSA-L 0.000 description 1
- 229910021511 zinc hydroxide Inorganic materials 0.000 description 1
- 229940007718 zinc hydroxide Drugs 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/70—Treatment of water, waste water, or sewage by reduction
- C02F1/705—Reduction by metals
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
- C02F1/461—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
- C02F1/46104—Devices therefor; Their operating or servicing
- C02F1/46176—Galvanic cells
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
- C02F2101/20—Heavy metals or heavy metal compounds
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
- C02F2101/20—Heavy metals or heavy metal compounds
- C02F2101/22—Chromium or chromium compounds, e.g. chromates
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/02—Non-contaminated water, e.g. for industrial water supply
- C02F2103/023—Water in cooling circuits
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Water Supply & Treatment (AREA)
- Environmental & Geological Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Electrochemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Water Treatment By Electricity Or Magnetism (AREA)
- Removal Of Specific Substances (AREA)
- Treatment Of Water By Oxidation Or Reduction (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Water Treatment By Sorption (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
IT2354971 | 1971-04-23 | ||
IT2420571 | 1971-05-07 |
Publications (1)
Publication Number | Publication Date |
---|---|
CH539001A true CH539001A (fr) | 1973-07-15 |
Family
ID=26328395
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CH592572A CH539001A (fr) | 1971-04-23 | 1972-04-22 | Procédé de purification électrolytique des eaux résiduelles |
Country Status (24)
Country | Link |
---|---|
JP (1) | JPS5235945B1 (cs) |
AT (1) | AT324969B (cs) |
BE (1) | BE782358A (cs) |
CA (1) | CA1028278A (cs) |
CH (1) | CH539001A (cs) |
CS (1) | CS178869B2 (cs) |
DD (1) | DD96694A5 (cs) |
DE (1) | DE2219095A1 (cs) |
DK (1) | DK142049C (cs) |
ES (1) | ES402789A1 (cs) |
FI (1) | FI62810C (cs) |
FR (1) | FR2133922B1 (cs) |
GB (1) | GB1376998A (cs) |
HU (1) | HU164830B (cs) |
IE (1) | IE36316B1 (cs) |
IL (1) | IL39131A (cs) |
LU (1) | LU65207A1 (cs) |
NL (1) | NL153829B (cs) |
NO (1) | NO139679C (cs) |
PL (1) | PL83655B1 (cs) |
RO (1) | RO63778A (cs) |
SE (1) | SE386153B (cs) |
TR (1) | TR17282A (cs) |
YU (1) | YU36674B (cs) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2430848C2 (de) * | 1974-06-27 | 1986-02-27 | Levrini, Valter, Castellarano | Verfahren zur chemischen Reinigung von Abwässern |
CH649976A5 (de) * | 1981-03-05 | 1985-06-28 | Hans Lueber | Vorrichtung zur kalksteinverhinderung in wasserbehaeltern. |
US4525254A (en) * | 1982-10-07 | 1985-06-25 | Gosudarstvenny Nauchno-Issledovatelsky I Proektny Institut Po Obogascheniju Rud Tsvetnykh Metallov "Kazmekhanobr" | Process and apparatus for purifying effluents and liquors |
DE10005681B4 (de) * | 2000-02-07 | 2005-06-16 | Atc Dr. Mann E.K. | Verfahren und Vorrichtung zur Dekontamination metallhaltiger Wässer |
CN115418483B (zh) * | 2022-08-30 | 2023-06-30 | 中南大学 | 含铬废液制备铬铁合金的方法 |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1459451A1 (de) * | 1962-05-29 | 1968-12-19 | Asendorf Dr Erich | Verfahren zum Entkupfern von schwefelsauren und salpetersauren Abwaessern unter gleichzeitiger Vernichtung wasserunloeslicher Kupferverbindungen |
AT240059B (de) * | 1963-08-02 | 1965-05-10 | Donau Chemie Ag | Verfahren zur elektrolytischen Abscheidung von sulfosalzbildenden Metallen |
US3392102A (en) * | 1967-03-16 | 1968-07-09 | Koch Rudolf | Galvanic action water purifier |
-
1972
- 1972-04-03 IL IL39131A patent/IL39131A/xx unknown
- 1972-04-19 YU YU1051/72A patent/YU36674B/xx unknown
- 1972-04-19 NO NO1361/72A patent/NO139679C/no unknown
- 1972-04-19 DE DE19722219095 patent/DE2219095A1/de active Pending
- 1972-04-20 BE BE782358A patent/BE782358A/xx not_active IP Right Cessation
- 1972-04-20 FR FR7213901A patent/FR2133922B1/fr not_active Expired
- 1972-04-21 PL PL1972154899A patent/PL83655B1/pl unknown
- 1972-04-21 FI FI1138/72A patent/FI62810C/fi active
- 1972-04-21 IE IE532/72A patent/IE36316B1/xx unknown
- 1972-04-21 CA CA140,318A patent/CA1028278A/en not_active Expired
- 1972-04-21 SE SE7205294A patent/SE386153B/xx unknown
- 1972-04-21 RO RO7200070638A patent/RO63778A/ro unknown
- 1972-04-21 DK DK197372A patent/DK142049C/da not_active IP Right Cessation
- 1972-04-21 DD DD162482A patent/DD96694A5/xx unknown
- 1972-04-21 HU HUSA2348A patent/HU164830B/hu unknown
- 1972-04-21 CS CS7200002717A patent/CS178869B2/cs unknown
- 1972-04-21 GB GB1874072A patent/GB1376998A/en not_active Expired
- 1972-04-21 LU LU65207D patent/LU65207A1/xx unknown
- 1972-04-22 CH CH592572A patent/CH539001A/fr not_active IP Right Cessation
- 1972-04-22 ES ES402789A patent/ES402789A1/es not_active Expired
- 1972-04-24 AT AT360072A patent/AT324969B/de not_active IP Right Cessation
- 1972-04-24 JP JP47040486A patent/JPS5235945B1/ja active Pending
- 1972-04-24 NL NL727205539A patent/NL153829B/xx not_active IP Right Cessation
- 1972-04-24 TR TR17282A patent/TR17282A/xx unknown
Also Published As
Publication number | Publication date |
---|---|
AT324969B (de) | 1975-09-25 |
NL153829B (nl) | 1977-07-15 |
RO63778A (fr) | 1978-10-15 |
IE36316B1 (en) | 1976-10-13 |
NO139679B (no) | 1979-01-15 |
DK142049C (da) | 1981-01-12 |
FI62810B (fi) | 1982-11-30 |
SE386153B (sv) | 1976-08-02 |
GB1376998A (en) | 1974-12-11 |
IE36316L (en) | 1972-10-23 |
FI62810C (fi) | 1983-03-10 |
CA1028278A (en) | 1978-03-21 |
CS178869B2 (en) | 1977-10-31 |
IL39131A (en) | 1975-08-31 |
DE2219095A1 (de) | 1972-11-16 |
HU164830B (cs) | 1974-04-11 |
FR2133922B1 (cs) | 1974-10-18 |
PL83655B1 (cs) | 1975-12-31 |
FR2133922A1 (cs) | 1972-12-01 |
BE782358A (fr) | 1972-08-16 |
IL39131A0 (en) | 1972-06-28 |
ES402789A1 (es) | 1975-10-16 |
DK142049B (da) | 1980-08-18 |
NO139679C (no) | 1979-04-25 |
YU36674B (en) | 1984-08-31 |
NL7205539A (cs) | 1972-10-25 |
TR17282A (tr) | 1975-03-24 |
DD96694A5 (cs) | 1973-04-05 |
YU105172A (en) | 1982-02-25 |
JPS5235945B1 (cs) | 1977-09-12 |
LU65207A1 (cs) | 1972-07-13 |
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