CH361133A - Verfahren zur Herstellung von Polystyrol - Google Patents
Verfahren zur Herstellung von PolystyrolInfo
- Publication number
- CH361133A CH361133A CH361133DA CH361133A CH 361133 A CH361133 A CH 361133A CH 361133D A CH361133D A CH 361133DA CH 361133 A CH361133 A CH 361133A
- Authority
- CH
- Switzerland
- Prior art keywords
- polystyrene
- styrene
- catalyst
- polymerization
- production
- Prior art date
Links
- 239000004793 Polystyrene Substances 0.000 title claims description 10
- 229920002223 polystyrene Polymers 0.000 title claims description 10
- 238000000034 method Methods 0.000 title claims description 7
- 238000004519 manufacturing process Methods 0.000 title claims description 3
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 22
- 239000003054 catalyst Substances 0.000 claims description 14
- 229910052736 halogen Inorganic materials 0.000 claims description 4
- 150000002367 halogens Chemical class 0.000 claims description 4
- 125000003545 alkoxy group Chemical group 0.000 claims description 2
- 125000000217 alkyl group Chemical group 0.000 claims description 2
- 229920006395 saturated elastomer Polymers 0.000 claims description 2
- 125000004432 carbon atom Chemical group C* 0.000 claims 2
- 125000000547 substituted alkyl group Chemical group 0.000 claims 1
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 9
- 238000006116 polymerization reaction Methods 0.000 description 7
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 239000000203 mixture Substances 0.000 description 5
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- XWMCJIOSNAXGAT-UHFFFAOYSA-L [Cl-].[Cl-].C[Ti+2]C Chemical compound [Cl-].[Cl-].C[Ti+2]C XWMCJIOSNAXGAT-UHFFFAOYSA-L 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 239000003999 initiator Substances 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 238000010505 homolytic fission reaction Methods 0.000 description 2
- VXWPONVCMVLXBW-UHFFFAOYSA-M magnesium;carbanide;iodide Chemical compound [CH3-].[Mg+2].[I-] VXWPONVCMVLXBW-UHFFFAOYSA-M 0.000 description 2
- IUYHWZFSGMZEOG-UHFFFAOYSA-M magnesium;propane;chloride Chemical compound [Mg+2].[Cl-].C[CH-]C IUYHWZFSGMZEOG-UHFFFAOYSA-M 0.000 description 2
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical group [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- XVUQPESXTGAQTC-UHFFFAOYSA-N CC(C)O[Ti](C)(C)OC(C)C Chemical compound CC(C)O[Ti](C)(C)OC(C)C XVUQPESXTGAQTC-UHFFFAOYSA-N 0.000 description 1
- NOKXNDKMAPFVBB-UHFFFAOYSA-N CC(C)[Ti] Chemical compound CC(C)[Ti] NOKXNDKMAPFVBB-UHFFFAOYSA-N 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical group [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Chemical group BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- FPCJKVGGYOAWIZ-UHFFFAOYSA-N butan-1-ol;titanium Chemical compound [Ti].CCCCO.CCCCO.CCCCO.CCCCO FPCJKVGGYOAWIZ-UHFFFAOYSA-N 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 125000001309 chloro group Chemical group Cl* 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 150000002222 fluorine compounds Chemical class 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical group II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000012985 polymerization agent Substances 0.000 description 1
- 239000002685 polymerization catalyst Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 1
- VXUYXOFXAQZZMF-UHFFFAOYSA-N titanium(IV) isopropoxide Chemical compound CC(C)O[Ti](OC(C)C)(OC(C)C)OC(C)C VXUYXOFXAQZZMF-UHFFFAOYSA-N 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F12/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F12/02—Monomers containing only one unsaturated aliphatic radical
- C08F12/04—Monomers containing only one unsaturated aliphatic radical containing one ring
- C08F12/06—Hydrocarbons
- C08F12/08—Styrene
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerization Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US59734256A | 1956-07-12 | 1956-07-12 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CH361133A true CH361133A (de) | 1962-03-31 |
Family
ID=48792192
Family Applications (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CH361133D CH361133A (de) | 1956-07-12 | 1957-07-09 | Verfahren zur Herstellung von Polystyrol |
| CH360206D CH360206A (de) | 1956-07-12 | 1957-07-09 | Verfahren zum Polymerisieren von Olefinen |
| CH361134D CH361134A (de) | 1956-07-12 | 1957-07-09 | Verfahren zur Herstellung von Polystyrol |
Family Applications After (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CH360206D CH360206A (de) | 1956-07-12 | 1957-07-09 | Verfahren zum Polymerisieren von Olefinen |
| CH361134D CH361134A (de) | 1956-07-12 | 1957-07-09 | Verfahren zur Herstellung von Polystyrol |
Country Status (5)
| Country | Link |
|---|---|
| BE (2) | BE559046A (enrdf_load_stackoverflow) |
| CH (3) | CH361133A (enrdf_load_stackoverflow) |
| DE (2) | DE1118461B (enrdf_load_stackoverflow) |
| FR (2) | FR1176834A (enrdf_load_stackoverflow) |
| GB (2) | GB856434A (enrdf_load_stackoverflow) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL267208A (enrdf_load_stackoverflow) * | 1960-08-02 | |||
| CA967583A (en) * | 1969-05-28 | 1975-05-13 | Imperial Chemical Industries Limited | Organo-metallic compounds and uses thereof |
| JP3846507B2 (ja) * | 1995-03-10 | 2006-11-15 | 日産化学工業株式会社 | チタン触媒、有機チタン反応試剤及びそれらの製造法並びにそれらを用いた反応方法 |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2721189A (en) * | 1954-08-30 | 1955-10-18 | Du Pont | Polymeric bicyclo-(2, 2, 1)-2-heptene |
| BE553478A (enrdf_load_stackoverflow) | 1955-12-16 |
-
1957
- 1957-06-21 FR FR1176834D patent/FR1176834A/fr not_active Expired
- 1957-06-28 FR FR1177632D patent/FR1177632A/fr not_active Expired
- 1957-07-01 GB GB2075857D patent/GB856434A/en not_active Expired
- 1957-07-02 GB GB2090457A patent/GB855202A/en not_active Expired
- 1957-07-08 DE DE1957T0013844 patent/DE1118461B/de active Pending
- 1957-07-08 BE BE559046D patent/BE559046A/xx unknown
- 1957-07-08 DE DE1957T0013845 patent/DE1032924B/de active Pending
- 1957-07-08 BE BE8071957A patent/BE559047A/xx unknown
- 1957-07-09 CH CH361133D patent/CH361133A/de unknown
- 1957-07-09 CH CH360206D patent/CH360206A/de unknown
- 1957-07-09 CH CH361134D patent/CH361134A/de unknown
Also Published As
| Publication number | Publication date |
|---|---|
| FR1177632A (fr) | 1959-04-28 |
| FR1176834A (fr) | 1959-04-16 |
| GB855202A (en) | 1960-11-30 |
| CH361134A (de) | 1962-03-31 |
| BE559047A (enrdf_load_stackoverflow) | 1957-07-31 |
| DE1032924B (de) | 1958-06-26 |
| CH360206A (de) | 1962-02-15 |
| BE559046A (enrdf_load_stackoverflow) | 1957-07-31 |
| GB856434A (en) | 1960-12-14 |
| DE1118461B (de) | 1961-11-30 |
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