CA3055297C - High nitrogen, multi-principal element, high entropy corrosion resistant alloy - Google Patents
High nitrogen, multi-principal element, high entropy corrosion resistant alloy Download PDFInfo
- Publication number
- CA3055297C CA3055297C CA3055297A CA3055297A CA3055297C CA 3055297 C CA3055297 C CA 3055297C CA 3055297 A CA3055297 A CA 3055297A CA 3055297 A CA3055297 A CA 3055297A CA 3055297 C CA3055297 C CA 3055297C
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- CA
- Canada
- Prior art keywords
- alloy
- corrosion resistant
- mol
- high entropy
- resistant alloy
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 229910045601 alloy Inorganic materials 0.000 title claims abstract description 114
- 239000000956 alloy Substances 0.000 title claims abstract description 114
- 238000005260 corrosion Methods 0.000 title claims abstract description 43
- 230000007797 corrosion Effects 0.000 title claims abstract description 43
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 title claims description 31
- 229910052757 nitrogen Inorganic materials 0.000 title claims description 19
- 239000006104 solid solution Substances 0.000 claims abstract description 21
- 229910052721 tungsten Inorganic materials 0.000 claims abstract description 12
- 229910052720 vanadium Inorganic materials 0.000 claims abstract description 10
- 239000012535 impurity Substances 0.000 claims abstract description 4
- 229910052750 molybdenum Inorganic materials 0.000 claims description 15
- 229910052742 iron Inorganic materials 0.000 claims description 9
- 239000010949 copper Substances 0.000 claims description 8
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 7
- 229910052802 copper Inorganic materials 0.000 claims description 7
- 229910052748 manganese Inorganic materials 0.000 claims description 7
- 238000005275 alloying Methods 0.000 claims description 4
- 230000002411 adverse Effects 0.000 abstract description 10
- 239000000203 mixture Substances 0.000 abstract description 9
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 25
- 239000003570 air Substances 0.000 description 16
- 239000011651 chromium Substances 0.000 description 16
- 238000012360 testing method Methods 0.000 description 16
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical group [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 14
- 238000009835 boiling Methods 0.000 description 14
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 12
- 229910052804 chromium Inorganic materials 0.000 description 12
- 229910052759 nickel Inorganic materials 0.000 description 12
- 229910017052 cobalt Inorganic materials 0.000 description 10
- 239000010941 cobalt Substances 0.000 description 10
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 10
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 8
- 239000011733 molybdenum Substances 0.000 description 8
- 239000011572 manganese Substances 0.000 description 7
- 238000002156 mixing Methods 0.000 description 7
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 6
- 239000000243 solution Substances 0.000 description 6
- 238000007792 addition Methods 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 5
- 238000001556 precipitation Methods 0.000 description 5
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
- 239000000470 constituent Substances 0.000 description 4
- 238000007654 immersion Methods 0.000 description 4
- 230000009467 reduction Effects 0.000 description 4
- 239000011780 sodium chloride Substances 0.000 description 4
- 238000010998 test method Methods 0.000 description 4
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 229910017604 nitric acid Inorganic materials 0.000 description 3
- 235000011007 phosphoric acid Nutrition 0.000 description 3
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 3
- 239000010937 tungsten Substances 0.000 description 3
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 3
- 229910000851 Alloy steel Inorganic materials 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 230000014509 gene expression Effects 0.000 description 2
- 150000004767 nitrides Chemical class 0.000 description 2
- 238000005482 strain hardening Methods 0.000 description 2
- 238000009864 tensile test Methods 0.000 description 2
- -1 Chromium nitrides Chemical class 0.000 description 1
- 108091006629 SLC13A2 Proteins 0.000 description 1
- 239000003929 acidic solution Substances 0.000 description 1
- 229910000905 alloy phase Inorganic materials 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 239000012080 ambient air Substances 0.000 description 1
- 229910001566 austenite Inorganic materials 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229910001325 element alloy Inorganic materials 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- 210000003127 knee Anatomy 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910052758 niobium Inorganic materials 0.000 description 1
- 238000005191 phase separation Methods 0.000 description 1
- 230000010287 polarization Effects 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 229910001256 stainless steel alloy Inorganic materials 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 230000004580 weight loss Effects 0.000 description 1
- 229910000859 α-Fe Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C30/00—Alloys containing less than 50% by weight of each constituent
- C22C30/02—Alloys containing less than 50% by weight of each constituent containing copper
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C30/00—Alloys containing less than 50% by weight of each constituent
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C19/00—Alloys based on nickel or cobalt
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/42—Ferrous alloys, e.g. steel alloys containing chromium with nickel with copper
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/44—Ferrous alloys, e.g. steel alloys containing chromium with nickel with molybdenum or tungsten
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/52—Ferrous alloys, e.g. steel alloys containing chromium with nickel with cobalt
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/58—Ferrous alloys, e.g. steel alloys containing chromium with nickel with more than 1.5% by weight of manganese
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C2200/00—Crystalline structure
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Heat Treatment Of Steel (AREA)
- Powder Metallurgy (AREA)
- Turbine Rotor Nozzle Sealing (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201762468600P | 2017-03-08 | 2017-03-08 | |
| US62/468,600 | 2017-03-08 | ||
| PCT/US2018/021461 WO2018165369A1 (en) | 2017-03-08 | 2018-03-08 | High nitrogen, multi-principal element, high entropy corrosion resistant alloy |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA3055297A1 CA3055297A1 (en) | 2018-09-13 |
| CA3055297C true CA3055297C (en) | 2021-04-13 |
Family
ID=61768494
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA3055297A Active CA3055297C (en) | 2017-03-08 | 2018-03-08 | High nitrogen, multi-principal element, high entropy corrosion resistant alloy |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US20180340245A1 (ko) |
| EP (1) | EP3592877A1 (ko) |
| JP (1) | JP2020510139A (ko) |
| KR (1) | KR20190127808A (ko) |
| CN (1) | CN110651057A (ko) |
| BR (1) | BR112019017951A2 (ko) |
| CA (1) | CA3055297C (ko) |
| IL (1) | IL268904A (ko) |
| MX (1) | MX2019010538A (ko) |
| RU (1) | RU2731924C1 (ko) |
| WO (1) | WO2018165369A1 (ko) |
Families Citing this family (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109097708B (zh) * | 2018-09-06 | 2021-02-09 | 中国石油大学(华东) | 一种提高单相高熵合金表面性能的方法 |
| CN110106428B (zh) * | 2019-05-27 | 2020-10-09 | 河北工业大学 | 一种具有带状析出相高熵合金及其制备方法 |
| CN110284042B (zh) * | 2019-08-05 | 2020-05-05 | 西安工业大学 | 超塑性高熵合金、板材及其制备方法 |
| US20210106729A1 (en) * | 2019-10-14 | 2021-04-15 | Abbott Cardiovascular Systems, Inc. | Methods for manufacturing radiopaque intraluminal stents comprising cobalt-based alloys with supersaturated tungsten content |
| US11353117B1 (en) | 2020-01-17 | 2022-06-07 | Vulcan Industrial Holdings, LLC | Valve seat insert system and method |
| US11421680B1 (en) | 2020-06-30 | 2022-08-23 | Vulcan Industrial Holdings, LLC | Packing bore wear sleeve retainer system |
| US11421679B1 (en) | 2020-06-30 | 2022-08-23 | Vulcan Industrial Holdings, LLC | Packing assembly with threaded sleeve for interaction with an installation tool |
| US12049889B2 (en) | 2020-06-30 | 2024-07-30 | Vulcan Industrial Holdings, LLC | Packing bore wear sleeve retainer system |
| US11384756B1 (en) | 2020-08-19 | 2022-07-12 | Vulcan Industrial Holdings, LLC | Composite valve seat system and method |
| USD997992S1 (en) | 2020-08-21 | 2023-09-05 | Vulcan Industrial Holdings, LLC | Fluid end for a pumping system |
| USD986928S1 (en) | 2020-08-21 | 2023-05-23 | Vulcan Industrial Holdings, LLC | Fluid end for a pumping system |
| USD980876S1 (en) | 2020-08-21 | 2023-03-14 | Vulcan Industrial Holdings, LLC | Fluid end for a pumping system |
| US11391374B1 (en) | 2021-01-14 | 2022-07-19 | Vulcan Industrial Holdings, LLC | Dual ring stuffing box |
| US12055221B2 (en) | 2021-01-14 | 2024-08-06 | Vulcan Industrial Holdings, LLC | Dual ring stuffing box |
| KR102509526B1 (ko) * | 2021-03-08 | 2023-03-10 | 포항공과대학교 산학협력단 | 바나듐 석출물을 포함하는 석출경화형 고 엔트로피 합금 |
| CN114231765B (zh) * | 2021-11-26 | 2022-06-21 | 北冶功能材料(江苏)有限公司 | 一种高温合金棒材的制备方法与应用 |
| US11434900B1 (en) * | 2022-04-25 | 2022-09-06 | Vulcan Industrial Holdings, LLC | Spring controlling valve |
| US11920684B1 (en) | 2022-05-17 | 2024-03-05 | Vulcan Industrial Holdings, LLC | Mechanically or hybrid mounted valve seat |
| CN115449692B (zh) * | 2022-10-14 | 2023-06-23 | 长沙理工大学 | 一种具有twip效应的高阻尼高熵钢板材及其制备方法 |
| CN116005150B (zh) * | 2022-12-07 | 2023-09-19 | 哈尔滨工业大学 | 一种耐高温摩擦磨损的高熵合金涂层及其制备方法 |
| CN116043091B (zh) * | 2022-12-28 | 2023-09-01 | 北京理工大学 | 一种TiZrNb基高熵合金及其制备方法 |
| CN118272743B (zh) * | 2024-03-14 | 2024-09-10 | 西安工业大学 | 一种微合金化的高性能高熵非晶合金及其制备方法 |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20020159914A1 (en) * | 2000-11-07 | 2002-10-31 | Jien-Wei Yeh | High-entropy multielement alloys |
| JP4190720B2 (ja) * | 2000-11-29 | 2008-12-03 | 國立清華大學 | 多元合金 |
| CN103556146B (zh) * | 2013-11-06 | 2016-01-20 | 四川建筑职业技术学院 | 制备高熵合金涂层的方法 |
| US20150368770A1 (en) * | 2014-06-20 | 2015-12-24 | Huntington Alloys Corporation | Nickel-Chromium-Iron-Molybdenum Corrosion Resistant Alloy and Article of Manufacture and Method of Manufacturing Thereof |
| CN105671392B (zh) * | 2014-11-19 | 2017-11-03 | 北京科技大学 | 一种氮强化的TiZrHfNb基高熵合金及其制备方法 |
| CN105671404B (zh) * | 2014-11-19 | 2017-11-03 | 北京科技大学 | 一种氮氧共合金化的TiZrHfNb基高熵合金及其制备方法 |
| KR101708763B1 (ko) * | 2015-05-04 | 2017-03-08 | 한국과학기술연구원 | 고온 중성자 조사 손상에 강한 엔트로피 제어 bcc 합금 |
| CN105296836B (zh) * | 2015-11-17 | 2017-12-08 | 北京科技大学 | 一种具有形状记忆效应的NxMy高熵合金及其制备方法 |
| KR101684856B1 (ko) * | 2016-01-29 | 2016-12-09 | 서울대학교 산학협력단 | 하이엔트로피 합금 폼 및 이의 제조방법 |
| KR101748836B1 (ko) * | 2016-02-15 | 2017-07-03 | 서울대학교 산학협력단 | Ｔｗｉｐ/ｔｒｉｐ 특성을 가진 하이엔트로피 합금 및 그 제조방법 |
| TWI595098B (zh) * | 2016-06-22 | 2017-08-11 | 國立清華大學 | 高熵超合金 |
-
2018
- 2018-03-08 US US15/915,145 patent/US20180340245A1/en not_active Abandoned
- 2018-03-08 KR KR1020197029679A patent/KR20190127808A/ko not_active Application Discontinuation
- 2018-03-08 EP EP18713500.9A patent/EP3592877A1/en not_active Withdrawn
- 2018-03-08 RU RU2019130857A patent/RU2731924C1/ru active
- 2018-03-08 WO PCT/US2018/021461 patent/WO2018165369A1/en unknown
- 2018-03-08 CN CN201880016595.6A patent/CN110651057A/zh active Pending
- 2018-03-08 CA CA3055297A patent/CA3055297C/en active Active
- 2018-03-08 MX MX2019010538A patent/MX2019010538A/es unknown
- 2018-03-08 JP JP2019548668A patent/JP2020510139A/ja active Pending
- 2018-03-08 BR BR112019017951A patent/BR112019017951A2/pt not_active Application Discontinuation
-
2019
- 2019-08-25 IL IL26890419A patent/IL268904A/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| JP2020510139A (ja) | 2020-04-02 |
| CN110651057A (zh) | 2020-01-03 |
| RU2731924C1 (ru) | 2020-09-09 |
| MX2019010538A (es) | 2019-10-15 |
| KR20190127808A (ko) | 2019-11-13 |
| IL268904A (en) | 2019-10-31 |
| BR112019017951A2 (pt) | 2020-05-19 |
| CA3055297A1 (en) | 2018-09-13 |
| US20180340245A1 (en) | 2018-11-29 |
| WO2018165369A1 (en) | 2018-09-13 |
| EP3592877A1 (en) | 2020-01-15 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request |
Effective date: 20190903 |