CA2853318A1 - Use of comb or block copolymers as soil antiredeposition agents and soil release agents in laundry processes - Google Patents
Use of comb or block copolymers as soil antiredeposition agents and soil release agents in laundry processes Download PDFInfo
- Publication number
- CA2853318A1 CA2853318A1 CA2853318A CA2853318A CA2853318A1 CA 2853318 A1 CA2853318 A1 CA 2853318A1 CA 2853318 A CA2853318 A CA 2853318A CA 2853318 A CA2853318 A CA 2853318A CA 2853318 A1 CA2853318 A1 CA 2853318A1
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- CA
- Canada
- Prior art keywords
- comb
- mol
- primary
- polymer
- soil
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
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- 239000008187 granular material Substances 0.000 description 1
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- 229910001385 heavy metal Inorganic materials 0.000 description 1
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- 150000002391 heterocyclic compounds Chemical class 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 1
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- 125000000654 isopropylidene group Chemical group C(C)(C)=* 0.000 description 1
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- 238000010412 laundry washing Methods 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- HNEGQIOMVPPMNR-NSCUHMNNSA-N mesaconic acid Chemical compound OC(=O)C(/C)=C/C(O)=O HNEGQIOMVPPMNR-NSCUHMNNSA-N 0.000 description 1
- 108010003855 mesentericopeptidase Proteins 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- XJRBAMWJDBPFIM-UHFFFAOYSA-N methyl vinyl ether Chemical compound COC=C XJRBAMWJDBPFIM-UHFFFAOYSA-N 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- 229960002900 methylcellulose Drugs 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- HNEGQIOMVPPMNR-UHFFFAOYSA-N methylfumaric acid Natural products OC(=O)C(C)=CC(O)=O HNEGQIOMVPPMNR-UHFFFAOYSA-N 0.000 description 1
- 108010020132 microbial serine proteinases Proteins 0.000 description 1
- 235000013336 milk Nutrition 0.000 description 1
- 239000008267 milk Substances 0.000 description 1
- 210000004080 milk Anatomy 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- VSEAAEQOQBMPQF-UHFFFAOYSA-N morpholin-3-one Chemical class O=C1COCCN1 VSEAAEQOQBMPQF-UHFFFAOYSA-N 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 150000002832 nitroso derivatives Chemical class 0.000 description 1
- SRSFOMHQIATOFV-UHFFFAOYSA-N octanoyl octaneperoxoate Chemical compound CCCCCCCC(=O)OOC(=O)CCCCCCC SRSFOMHQIATOFV-UHFFFAOYSA-N 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- QRMPKOFEUHIBNM-UHFFFAOYSA-N p-dimethylcyclohexane Natural products CC1CCC(C)CC1 QRMPKOFEUHIBNM-UHFFFAOYSA-N 0.000 description 1
- 239000002540 palm oil Substances 0.000 description 1
- 150000002976 peresters Chemical class 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 125000000864 peroxy group Chemical group O(O*)* 0.000 description 1
- JRKICGRDRMAZLK-UHFFFAOYSA-L persulfate group Chemical group S(=O)(=O)([O-])OOS(=O)(=O)[O-] JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 1
- VVTMNCICAIKIRN-UHFFFAOYSA-N phenyl benzoate;sodium Chemical compound [Na].C=1C=CC=CC=1C(=O)OC1=CC=CC=C1 VVTMNCICAIKIRN-UHFFFAOYSA-N 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- IWELDVXSEVIIGI-UHFFFAOYSA-N piperazin-2-one Chemical class O=C1CNCCN1 IWELDVXSEVIIGI-UHFFFAOYSA-N 0.000 description 1
- JTHRRMFZHSDGNJ-UHFFFAOYSA-N piperazine-2,3-dione Chemical class O=C1NCCNC1=O JTHRRMFZHSDGNJ-UHFFFAOYSA-N 0.000 description 1
- 150000003053 piperidines Chemical class 0.000 description 1
- 229920002006 poly(N-vinylimidazole) polymer Polymers 0.000 description 1
- 229920002239 polyacrylonitrile Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 108010064470 polyaspartate Proteins 0.000 description 1
- 229920000151 polyglycol Polymers 0.000 description 1
- 239000010695 polyglycol Substances 0.000 description 1
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- 229920000193 polymethacrylate Polymers 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
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- 229920002223 polystyrene Polymers 0.000 description 1
- 229920000166 polytrimethylene carbonate Polymers 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- BWJUFXUULUEGMA-UHFFFAOYSA-N propan-2-yl propan-2-yloxycarbonyloxy carbonate Chemical compound CC(C)OC(=O)OOC(=O)OC(C)C BWJUFXUULUEGMA-UHFFFAOYSA-N 0.000 description 1
- LLHKCFNBLRBOGN-UHFFFAOYSA-N propylene glycol methyl ether acetate Chemical compound COCC(C)OC(C)=O LLHKCFNBLRBOGN-UHFFFAOYSA-N 0.000 description 1
- 235000018102 proteins Nutrition 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 150000003219 pyrazolines Chemical class 0.000 description 1
- 229920005604 random copolymer Polymers 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229910021647 smectite Inorganic materials 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 235000019832 sodium triphosphate Nutrition 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 description 1
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- 239000000375 suspending agent Substances 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- 108010075550 termamyl Proteins 0.000 description 1
- OPQYOFWUFGEMRZ-UHFFFAOYSA-N tert-butyl 2,2-dimethylpropaneperoxoate Chemical compound CC(C)(C)OOC(=O)C(C)(C)C OPQYOFWUFGEMRZ-UHFFFAOYSA-N 0.000 description 1
- KHJNXCATZZIGAX-UHFFFAOYSA-N tert-butyl 2-ethyl-2-methylheptaneperoxoate Chemical compound CCCCCC(C)(CC)C(=O)OOC(C)(C)C KHJNXCATZZIGAX-UHFFFAOYSA-N 0.000 description 1
- PFBLRDXPNUJYJM-UHFFFAOYSA-N tert-butyl 2-methylpropaneperoxoate Chemical compound CC(C)C(=O)OOC(C)(C)C PFBLRDXPNUJYJM-UHFFFAOYSA-N 0.000 description 1
- GJBRNHKUVLOCEB-UHFFFAOYSA-N tert-butyl benzenecarboperoxoate Chemical compound CC(C)(C)OOC(=O)C1=CC=CC=C1 GJBRNHKUVLOCEB-UHFFFAOYSA-N 0.000 description 1
- SWAXTRYEYUTSAP-UHFFFAOYSA-N tert-butyl ethaneperoxoate Chemical compound CC(=O)OOC(C)(C)C SWAXTRYEYUTSAP-UHFFFAOYSA-N 0.000 description 1
- CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 description 1
- UZVUJVFQFNHRSY-OUTKXMMCSA-J tetrasodium;(2s)-2-[bis(carboxylatomethyl)amino]pentanedioate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CC[C@@H](C([O-])=O)N(CC([O-])=O)CC([O-])=O UZVUJVFQFNHRSY-OUTKXMMCSA-J 0.000 description 1
- GTZCVFVGUGFEME-UHFFFAOYSA-N trans-aconitic acid Natural products OC(=O)CC(C(O)=O)=CC(O)=O GTZCVFVGUGFEME-UHFFFAOYSA-N 0.000 description 1
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- GSEJCLTVZPLZKY-UHFFFAOYSA-O triethanolammonium Chemical class OCC[NH+](CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-O 0.000 description 1
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 1
- OHOTVSOGTVKXEL-UHFFFAOYSA-K trisodium;2-[bis(carboxylatomethyl)amino]propanoate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)C(C)N(CC([O-])=O)CC([O-])=O OHOTVSOGTVKXEL-UHFFFAOYSA-K 0.000 description 1
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- 239000008096 xylene Substances 0.000 description 1
- PAPBSGBWRJIAAV-UHFFFAOYSA-N ε-Caprolactone Chemical compound O=C1CCCCCO1 PAPBSGBWRJIAAV-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0036—Soil deposition preventing compositions; Antiredeposition agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3788—Graft polymers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/12—Soft surfaces, e.g. textile
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
- Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
- Graft Or Block Polymers (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201161550936P | 2011-10-25 | 2011-10-25 | |
| EP11186446 | 2011-10-25 | ||
| US61/550,936 | 2011-10-25 | ||
| EP11186446.8 | 2011-10-25 | ||
| PCT/EP2012/071020 WO2013060708A1 (en) | 2011-10-25 | 2012-10-24 | Use of comb or block copolymers as soil antiredeposition agents and soil release agents in laundry processes |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA2853318A1 true CA2853318A1 (en) | 2013-05-02 |
Family
ID=48167152
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2853318A Abandoned CA2853318A1 (en) | 2011-10-25 | 2012-10-24 | Use of comb or block copolymers as soil antiredeposition agents and soil release agents in laundry processes |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US20140298591A1 (en:Method) |
| EP (1) | EP2771445B1 (en:Method) |
| JP (1) | JP2014532770A (en:Method) |
| KR (1) | KR102004562B1 (en:Method) |
| CN (1) | CN104105786A (en:Method) |
| BR (1) | BR112014009967A8 (en:Method) |
| CA (1) | CA2853318A1 (en:Method) |
| IN (1) | IN2014CN03743A (en:Method) |
| MX (1) | MX2014004939A (en:Method) |
| PL (1) | PL2771445T3 (en:Method) |
| RU (1) | RU2014120925A (en:Method) |
| WO (1) | WO2013060708A1 (en:Method) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2013060708A1 (en) * | 2011-10-25 | 2013-05-02 | Basf Se | Use of comb or block copolymers as soil antiredeposition agents and soil release agents in laundry processes |
| EP2978786A1 (en) | 2013-03-27 | 2016-02-03 | Basf Se | Block copolymers as soil release agents in laundry processes |
| DE102015212611A1 (de) * | 2015-07-06 | 2017-01-12 | Henkel Ag & Co. Kgaa | Stern-Block-Kamm-Polymere als bioaktive Trägermatrices für die wirkstofffreisetzende semipermanente Beschichtung von Oberflächen |
| CN109069872B (zh) * | 2015-12-09 | 2021-07-13 | 得克萨斯州大学系统董事会 | 用于治疗疾病的聚合物药物递送系统 |
| DE102016223588A1 (de) | 2016-11-28 | 2018-05-30 | Clariant International Ltd | Copolymere und deren verwendung in reinigungsmittel-zusammensetzungen |
| DE102016223586A1 (de) | 2016-11-28 | 2018-05-30 | Clariant International Ltd | Copolymere und deren verwendung in reinigungsmittel-zusammensetzungen |
| DE102016223590A1 (de) | 2016-11-28 | 2018-05-30 | Clariant International Ltd | Copolymer enthaltende reinigungsmittelzusammensetzungen |
| DE102016223585A1 (de) | 2016-11-28 | 2018-05-30 | Clariant International Ltd | Copolymere und deren verwendung in waschmittel-zusammensetzungen |
| DE102016223584A1 (de) | 2016-11-28 | 2018-05-30 | Clariant International Ltd | Copolymer enthaltende waschmittelzusammensetzungen |
| CN110314561A (zh) * | 2018-03-29 | 2019-10-11 | 东华大学 | 一种聚合物膜材料及其制备方法 |
| CN115380054B (zh) * | 2020-04-14 | 2025-05-13 | 巴斯夫欧洲公司 | 胺改性聚合物、用于其制备的可控自由基聚合及其实施 |
Family Cites Families (87)
| Publication number | Priority date | Publication date | Assignee | Title |
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| KR930000892B1 (ko) | 1983-07-11 | 1993-02-11 | 커몬웰스 사이언티픽 앤드 인더스트리얼 리셔치 오가니제이숀 | 신규의 개시제를 사용하여 중합체 또는 공중합체를 제조하는방법 |
| JPH0246640B2 (ja) * | 1986-06-27 | 1990-10-16 | Kao Corp | Iryoyoekitaisenzaisoseibutsu |
| US4972037A (en) * | 1989-08-07 | 1990-11-20 | Minnesota Mining And Manufacturing Company | Polysiloxane-grafted copolymer topical binder composition with novel fluorochemical comonomer and method of coating therewith |
| DE4006093A1 (de) * | 1990-02-27 | 1991-08-29 | Goldschmidt Ag Th | Polyacrylsaeureester mit langkettigen alkoxylierten kohlenwasserstoffoxy-gruppen und deren verwendung in der kosmetik und koerperpflege |
| DE4008761A1 (de) * | 1990-03-19 | 1991-09-26 | Goldschmidt Ag Th | Polyacrylsaeureester mit ammoniumsalzgruppen |
| DE69125309T2 (de) | 1990-05-21 | 1997-07-03 | Unilever Nv | Bleichmittelaktivierung |
| DE4236337C1 (de) * | 1992-10-28 | 1994-01-27 | Goldschmidt Ag Th | Verwendung von Polyacrylsäureestern als Dispergiermittel |
| US5322912A (en) | 1992-11-16 | 1994-06-21 | Xerox Corporation | Polymerization processes and toner compositions therefrom |
| JPH07138316A (ja) * | 1993-11-15 | 1995-05-30 | Kuraray Co Ltd | ポリ（メタ）アクリル酸エステルの製造方法 |
| AU3077495A (en) | 1994-08-19 | 1996-03-14 | Unilever Plc | Detergent bleach composition |
| DE19502294A1 (de) | 1995-01-26 | 1996-08-01 | Basf Ag | Verwendung von Trisäuren auf Basis alkoxylierter teriärer Amine als Komplexbildner |
| FR2730240A1 (fr) | 1995-02-07 | 1996-08-09 | Atochem Elf Sa | Stabilisation d'un polymere par un radical libre stable |
| DE19529905A1 (de) | 1995-08-15 | 1997-02-20 | Henkel Kgaa | Aktivatorkomplexe für Persauerstoffverbindungen |
| DE19530786A1 (de) | 1995-08-22 | 1997-02-27 | Hoechst Ag | Bleichmittelzusammensetzung enthaltend Polyoxometallate als Bleichkatalysator |
| WO1997024177A1 (en) | 1995-12-29 | 1997-07-10 | Allied Colloids Limited | Enzyme-containing particles and liquid detergent concentrate |
| DE19600159A1 (de) | 1996-01-04 | 1997-07-10 | Hoechst Ag | Bleichmittelsysteme enthaltend Bis- und Tris-(mu-oxo)-di-Mangan-Komplexsalze |
| WO1997036986A1 (de) | 1996-04-01 | 1997-10-09 | Henkel Kommanditgesellschaft Auf Aktien | Reinigungsmittel mit oligoamminaktivatorkomplexen für persauerstoffverbindungen |
| US5693603A (en) | 1996-04-30 | 1997-12-02 | Lever Brothers Company, Division Of Conopco, Inc. | Sulfanimines as bleach catalysts |
| DE19620267A1 (de) | 1996-05-20 | 1997-11-27 | Henkel Kgaa | Katalytisch wirksame Aktivatorkomplexe mit N¶4¶-Liganden für Persauerstoffverbindungen |
| US5876625A (en) | 1996-07-22 | 1999-03-02 | Carnegie Mellon University | Metal ligand containing bleaching compositions |
| EP1038946A3 (en) | 1996-08-23 | 2000-10-25 | Unilever Plc | N-acylimines as bleach catalysts |
| WO1998013392A1 (en) | 1996-09-25 | 1998-04-02 | Akzo Nobel N.V. | No-compounds for pseudo-living radical polymerization |
| EP0832969B1 (de) | 1996-09-26 | 2004-11-17 | Henkel Kommanditgesellschaft auf Aktien | Katalytisch aktive Wirkstoffkombination zur Verstärkung der Bleichwirkung |
| DE19639603A1 (de) | 1996-09-26 | 1998-04-02 | Henkel Kgaa | Übergangsmetall-Aktivatorkomplexe für Persauerstoffverbindungen |
| EP0951485B1 (en) | 1997-01-10 | 2003-04-02 | E.I. Du Pont De Nemours And Company | Method of controlling polymer molecular weight and structure |
| ES2201441T3 (es) | 1997-03-07 | 2004-03-16 | THE PROCTER & GAMBLE COMPANY | Composiciones de blanqueantes que contienen un catalizador metalico del blanqueante, y activadores de blanqueantes y/o acidos percarboxilicos organicos. |
| US6281311B1 (en) | 1997-03-31 | 2001-08-28 | Pmd Holdings Corp. | Controlled free radical polymerization process |
| DE19714122A1 (de) | 1997-04-05 | 1998-10-08 | Clariant Gmbh | Bleichaktive Metall-Komplexe |
| DE19719397A1 (de) | 1997-05-07 | 1998-11-12 | Clariant Gmbh | Bleichaktive Metall-Komplexe |
| DE19721886A1 (de) | 1997-05-26 | 1998-12-03 | Henkel Kgaa | Bleichsystem |
| DE69812633T2 (de) | 1997-07-15 | 2003-10-23 | Ciba Speciality Chemicals Holding Inc., Basel | Von nitrone- oder nitroso-verbindungen abgeleitete alkoxyaminverbindungen-enthaltende polymerisierbare zusammensetzungen |
| CA2248476A1 (en) | 1997-10-01 | 1999-04-01 | Unilever Plc | Bleach activation |
| WO1999033947A1 (de) | 1997-12-24 | 1999-07-08 | Henkel Kommanditgesellschaft Auf Aktien | Verwendung von übergangsmetallkomplexen mit dendrimer-liganden zur verstärkung der bleichwirkung von persauerstoffverbindungen |
| SG82601A1 (en) | 1998-03-09 | 2001-08-21 | Ciba Sc Holding Ag | 1-alkoxy-polyalkyl-piperidine derivatives and their use as polymerization regulators |
| ES2196878T3 (es) | 1998-06-15 | 2003-12-16 | Unilever Nv | Catalizadores de blanqueo y formulaciones que los contienen. |
| TWI246519B (en) | 1998-06-25 | 2006-01-01 | Ciba Sc Holding Ag | Use of 2,2,6,6 tetraalkylpiperidine-N-oxyl radicals having long alkyl chains as polymerization regulators |
| DE69916455T2 (de) | 1998-07-31 | 2004-09-09 | Ciba Specialty Chemicals Holding Inc. | Offenkettige alkoxyaminverbindungen und ihrer anwendung als polymerisationsregler |
| TWI225483B (en) | 1998-10-16 | 2004-12-21 | Ciba Sc Holding Ag | Heterocyclic alkoxyamines as regulators in controlled radical polymerization process |
| ES2206853T3 (es) | 1998-11-10 | 2004-05-16 | Unilever N.V. | Catalizadores de blanqueo y oxidacion. |
| DE19855607A1 (de) | 1998-12-02 | 2000-06-08 | Henkel Kgaa | Verwendung von Übergangsmetallkomplexen mit stickstoffhaltigen heterocyclischen Liganden zur Verstärkung der Bleichwirkung von Persauerstoffverbindungen |
| AU4061900A (en) | 1999-04-01 | 2000-10-23 | Procter & Gamble Company, The | Transition metal bleaching agents |
| JP4666447B2 (ja) | 1999-07-14 | 2011-04-06 | チバ ホールディング インコーポレーテッド | 三脚状配位子の金属錯体 |
| KR20010026522A (ko) | 1999-09-07 | 2001-04-06 | 윤종용 | 인터넷폰의 콜백을 위한 시스템 및 그 방법 |
| US6476996B1 (en) | 2000-02-15 | 2002-11-05 | Western Digital Technologies, Inc. | Disk drive comprising an actuator driver circuit for retracting a head independent of a servo microprocessor when a spindle speed fault mode is detected |
| BR0108772A (pt) | 2000-02-29 | 2002-11-26 | Unilever Nv | Composição alvejante, método para alvejar um substrato, e, ligando |
| TW541303B (en) | 2000-03-22 | 2003-07-11 | Ciba Sc Holding Ag | 2,2,6,6 diethyl-dimethyl-1-alkoxy-piperidine compounds and their corresponding 1-oxides |
| DE10019878A1 (de) | 2000-04-20 | 2001-10-25 | Clariant Gmbh | Bleichaktive Dendrimer-Liganden und deren Metall-Komplexe |
| US20030104969A1 (en) * | 2000-05-11 | 2003-06-05 | Caswell Debra Sue | Laundry system having unitized dosing |
| GB0011527D0 (en) | 2000-05-12 | 2000-06-28 | Unilever Plc | Bleach catalyst and composition and method for bleaching a substrate |
| PL358806A1 (en) | 2000-07-04 | 2004-08-23 | Ciba Specialty Chemicals Holding Inc. | Method for treating textile fibre materials or leather |
| DE10037162A1 (de) | 2000-07-21 | 2002-02-07 | F Ekkehardt Hahn | Bleich- und Oxidationsmittel und ihre Verwendung |
| US20050098759A1 (en) * | 2000-09-07 | 2005-05-12 | Frankenbach Gayle M. | Methods for improving the performance of fabric wrinkle control compositions |
| TW557305B (en) | 2000-12-14 | 2003-10-11 | Ciba Sc Holding Ag | N-alkoxy-4,4-dioxy-polyalkyl-piperidine compounds, their corresponding n-oxides and controlled radical polymerization therewith |
| TWI274053B (en) | 2000-12-14 | 2007-02-21 | Ciba Sc Holding Ag | N-alkoxy-4,4-dioxy-polyalkyl-piperidine compounds, with glycidyl or alkylcarbonyl groups as functional initiators for controlled radical polymerization |
| GB0030673D0 (en) | 2000-12-15 | 2001-01-31 | Unilever Plc | Ligand and complex for catalytically bleaching a substrate |
| GB0102826D0 (en) | 2001-02-05 | 2001-03-21 | Unilever Plc | Composition and method for bleaching a substrate |
| US6833343B2 (en) | 2001-03-30 | 2004-12-21 | Kao Corporation | Bleaching detergent formulation |
| US7161005B2 (en) | 2001-04-30 | 2007-01-09 | Ciba Specialty Chemicals Corporation | Use of metal complex compounds as oxidation catalysts |
| US6849679B2 (en) * | 2001-05-21 | 2005-02-01 | Ciba Specialty Chemicals Corporation | Pigment compositions with modified block copolymer dispersants |
| CN1249035C (zh) | 2001-06-13 | 2006-04-05 | 西巴特殊化学品控股有限公司 | 4－亚氨基－n－烷氧基或氧基－多烷基－哌啶化合物以及它们作为聚合调节剂的用途 |
| DE10163331A1 (de) | 2001-12-21 | 2003-07-10 | Henkel Kgaa | Trägerfixierte Bleichkatalysatorkomplexverbindungen geeignet als Katalysatoren für Persauerstoffverbindungen |
| GB0207744D0 (en) * | 2002-04-03 | 2002-05-15 | Unilever Plc | Fabric care composition |
| DE10230834A1 (de) | 2002-07-09 | 2004-01-22 | Robert Bosch Gmbh | Verfahren zum Betreiben einer Brennkraftmaschine |
| EP1521820B1 (en) | 2002-07-11 | 2006-03-22 | Ciba SC Holding AG | Use of metal complex compounds as oxidation catalysts |
| DE10236133A1 (de) * | 2002-08-07 | 2004-02-26 | Byk-Chemie Gmbh | Verwendung von Gradientencopolymeren als Dispergiermittel zur Behandlung von Pigmenten und Feststoffen |
| DE10304131A1 (de) | 2003-02-03 | 2004-08-05 | Clariant Gmbh | Verwendung von Übergangsmetallkomplexen als Bleichkatalysatoren |
| DE10345273A1 (de) | 2003-09-30 | 2005-04-21 | Clariant Gmbh | Verwendung von Übergangsmetallkomplexen mit Lactamliganden als Bleichkatalysatoren |
| DE102004003710A1 (de) | 2004-01-24 | 2005-08-11 | Clariant Gmbh | Verwendung von Übergangsmetallkomplexen als Bleichkatalysatoren in Wasch- und Reinigungsmitteln |
| WO2005074515A2 (en) * | 2004-01-30 | 2005-08-18 | Huntsman Petrochemical Corporation | Surface-active polymers as detergents |
| JP2008505089A (ja) | 2004-07-01 | 2008-02-21 | メルク エンド カムパニー インコーポレーテッド | 有糸分裂キネシン阻害剤 |
| EP1861429B1 (en) * | 2005-01-11 | 2013-03-13 | Basf Se | Process for the post-modification of homo and copolymers prepared by controlled free radical polymerization processes |
| DE102005026522B4 (de) * | 2005-06-08 | 2007-04-05 | Henkel Kgaa | Verstärkung der Reinigungsleistung von Waschmitteln durch Polymer |
| JP5270843B2 (ja) * | 2006-01-31 | 2013-08-21 | 株式会社日本触媒 | （メタ）アクリル酸系共重合体、その製造方法およびこれを用いてなる洗剤組成物 |
| KR20090128443A (ko) * | 2007-04-03 | 2009-12-15 | 헨켈 아게 운트 코. 카게아아 | 항-그레이 세제 |
| DE102007017656A1 (de) | 2007-04-12 | 2008-10-16 | Henkel Ag & Co. Kgaa | Biheteroaryl-Metallkomplexe als Bleichkatalysatoren |
| DE102007017654A1 (de) | 2007-04-12 | 2008-10-16 | Henkel Ag & Co. Kgaa | Bis(hydroxychinolin)-Metallkomplexe als Bleichkatalysatoren |
| DE102007017657A1 (de) | 2007-04-12 | 2008-10-16 | Henkel Ag & Co. Kgaa | Tris/heterocyclyl)-Metallkomplexe als Bleichkatalysatoren |
| WO2009019225A2 (de) * | 2007-08-03 | 2009-02-12 | Basf Se | Assoziativverdicker-dispersion |
| CN101861340A (zh) * | 2007-11-14 | 2010-10-13 | 巴斯夫欧洲公司 | 制备增稠剂分散体的方法 |
| WO2010003783A1 (en) * | 2008-07-11 | 2010-01-14 | Unilever Nv | Copolymers and detergent compositions |
| JP2010209134A (ja) * | 2009-03-06 | 2010-09-24 | Nippon Shokubai Co Ltd | ポリオキシアルキレン系重合体およびその製造方法 |
| JP2011074096A (ja) * | 2009-09-29 | 2011-04-14 | Nippon Shokubai Co Ltd | ポリオキシアルキレン系共重合体およびその製造方法 |
| JP5637678B2 (ja) | 2009-11-17 | 2014-12-10 | 株式会社日本触媒 | 新規重合体およびその製造方法 |
| RU2013103600A (ru) * | 2010-06-29 | 2014-08-10 | Басф Се | Способ улучшения свойств текучести расплавов полимеров |
| WO2013060708A1 (en) * | 2011-10-25 | 2013-05-02 | Basf Se | Use of comb or block copolymers as soil antiredeposition agents and soil release agents in laundry processes |
| US8623151B2 (en) * | 2012-03-23 | 2014-01-07 | Ecolab Usa Inc. | Terpolymer containing maleic acid, vinyl acetate, and alkyl acrylate monomers for aluminum protection |
| EP2978786A1 (en) * | 2013-03-27 | 2016-02-03 | Basf Se | Block copolymers as soil release agents in laundry processes |
-
2012
- 2012-10-24 WO PCT/EP2012/071020 patent/WO2013060708A1/en not_active Ceased
- 2012-10-24 KR KR1020147013605A patent/KR102004562B1/ko not_active Expired - Fee Related
- 2012-10-24 MX MX2014004939A patent/MX2014004939A/es unknown
- 2012-10-24 PL PL12775510T patent/PL2771445T3/pl unknown
- 2012-10-24 RU RU2014120925/04A patent/RU2014120925A/ru not_active Application Discontinuation
- 2012-10-24 CA CA2853318A patent/CA2853318A1/en not_active Abandoned
- 2012-10-24 JP JP2014537590A patent/JP2014532770A/ja active Pending
- 2012-10-24 IN IN3743CHN2014 patent/IN2014CN03743A/en unknown
- 2012-10-24 EP EP12775510.6A patent/EP2771445B1/en not_active Not-in-force
- 2012-10-24 CN CN201280064119.4A patent/CN104105786A/zh active Pending
- 2012-10-24 BR BR112014009967A patent/BR112014009967A8/pt not_active IP Right Cessation
- 2012-10-24 US US14/354,008 patent/US20140298591A1/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| EP2771445B1 (en) | 2018-12-12 |
| US20140298591A1 (en) | 2014-10-09 |
| JP2014532770A (ja) | 2014-12-08 |
| BR112014009967A2 (pt) | 2017-05-30 |
| MX2014004939A (es) | 2014-07-30 |
| IN2014CN03743A (en:Method) | 2015-09-25 |
| BR112014009967A8 (pt) | 2017-12-19 |
| EP2771445A1 (en) | 2014-09-03 |
| CN104105786A (zh) | 2014-10-15 |
| WO2013060708A1 (en) | 2013-05-02 |
| PL2771445T3 (pl) | 2019-05-31 |
| RU2014120925A (ru) | 2015-12-10 |
| KR102004562B1 (ko) | 2019-07-26 |
| KR20140091561A (ko) | 2014-07-21 |
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Legal Events
| Date | Code | Title | Description |
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| FZDE | Discontinued |
Effective date: 20181024 |