CA2851494A1 - Catalyst electrodes, and methods of making and using the same - Google Patents
Catalyst electrodes, and methods of making and using the same Download PDFInfo
- Publication number
- CA2851494A1 CA2851494A1 CA2851494A CA2851494A CA2851494A1 CA 2851494 A1 CA2851494 A1 CA 2851494A1 CA 2851494 A CA2851494 A CA 2851494A CA 2851494 A CA2851494 A CA 2851494A CA 2851494 A1 CA2851494 A1 CA 2851494A1
- Authority
- CA
- Canada
- Prior art keywords
- catalyst
- membrane
- whiskers
- alternating layers
- multiple alternating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 239000003054 catalyst Substances 0.000 title claims abstract description 107
- 238000000034 method Methods 0.000 title claims abstract description 103
- 229910052697 platinum Inorganic materials 0.000 claims abstract description 57
- 229910052741 iridium Inorganic materials 0.000 claims abstract description 51
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 25
- 238000004544 sputter deposition Methods 0.000 claims abstract description 22
- 239000012528 membrane Substances 0.000 claims description 76
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 33
- 239000001301 oxygen Substances 0.000 claims description 33
- 229910052760 oxygen Inorganic materials 0.000 claims description 33
- 229910052707 ruthenium Inorganic materials 0.000 claims description 31
- 239000001257 hydrogen Substances 0.000 claims description 24
- 229910052739 hydrogen Inorganic materials 0.000 claims description 24
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 22
- 238000000137 annealing Methods 0.000 claims description 22
- 230000005855 radiation Effects 0.000 claims description 15
- 238000004519 manufacturing process Methods 0.000 claims description 14
- 239000002253 acid Substances 0.000 claims description 12
- 239000012535 impurity Substances 0.000 claims description 10
- 150000001768 cations Chemical class 0.000 claims description 9
- 238000005406 washing Methods 0.000 claims description 8
- 239000010409 thin film Substances 0.000 claims description 6
- 239000010410 layer Substances 0.000 description 175
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical group [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 86
- 210000004027 cell Anatomy 0.000 description 31
- 238000000576 coating method Methods 0.000 description 23
- 239000000758 substrate Substances 0.000 description 21
- 239000011248 coating agent Substances 0.000 description 20
- 229910052751 metal Inorganic materials 0.000 description 20
- 239000002184 metal Substances 0.000 description 20
- 229910045601 alloy Inorganic materials 0.000 description 17
- 239000000956 alloy Substances 0.000 description 17
- 201000000760 cerebral cavernous malformation Diseases 0.000 description 17
- 239000000463 material Substances 0.000 description 17
- 239000000446 fuel Substances 0.000 description 16
- 229920000557 Nafion® Polymers 0.000 description 12
- 230000000052 comparative effect Effects 0.000 description 12
- 239000000203 mixture Substances 0.000 description 11
- 230000008569 process Effects 0.000 description 11
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 10
- 238000006243 chemical reaction Methods 0.000 description 10
- 238000000151 deposition Methods 0.000 description 10
- 238000011068 loading method Methods 0.000 description 10
- 229920000642 polymer Polymers 0.000 description 10
- 238000012360 testing method Methods 0.000 description 10
- 239000012530 fluid Substances 0.000 description 9
- 238000007429 general method Methods 0.000 description 9
- 230000010287 polarization Effects 0.000 description 9
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 8
- 230000008021 deposition Effects 0.000 description 8
- 239000003792 electrolyte Substances 0.000 description 8
- 239000002657 fibrous material Substances 0.000 description 8
- 238000005224 laser annealing Methods 0.000 description 8
- 229910052799 carbon Inorganic materials 0.000 description 7
- 230000003197 catalytic effect Effects 0.000 description 7
- 238000009826 distribution Methods 0.000 description 7
- 239000010408 film Substances 0.000 description 7
- 239000007789 gas Substances 0.000 description 7
- 238000000859 sublimation Methods 0.000 description 7
- 230000008022 sublimation Effects 0.000 description 7
- 238000012546 transfer Methods 0.000 description 7
- 239000005518 polymer electrolyte Substances 0.000 description 6
- 229920000049 Carbon (fiber) Polymers 0.000 description 5
- 239000004917 carbon fiber Substances 0.000 description 5
- 229920001940 conductive polymer Polymers 0.000 description 5
- ZZSIDSMUTXFKNS-UHFFFAOYSA-N perylene red Chemical compound CC(C)C1=CC=CC(C(C)C)=C1N(C(=O)C=1C2=C3C4=C(OC=5C=CC=CC=5)C=1)C(=O)C2=CC(OC=1C=CC=CC=1)=C3C(C(OC=1C=CC=CC=1)=CC1=C2C(C(N(C=3C(=CC=CC=3C(C)C)C(C)C)C1=O)=O)=C1)=C2C4=C1OC1=CC=CC=C1 ZZSIDSMUTXFKNS-UHFFFAOYSA-N 0.000 description 5
- 229910052723 transition metal Inorganic materials 0.000 description 5
- 150000003624 transition metals Chemical class 0.000 description 5
- 229910052786 argon Inorganic materials 0.000 description 4
- 230000008901 benefit Effects 0.000 description 4
- 239000002322 conducting polymer Substances 0.000 description 4
- -1 hydrogen ions Chemical class 0.000 description 4
- 238000003475 lamination Methods 0.000 description 4
- 239000002121 nanofiber Substances 0.000 description 4
- 229920001721 polyimide Polymers 0.000 description 4
- 239000001054 red pigment Substances 0.000 description 4
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 4
- 238000000429 assembly Methods 0.000 description 3
- 230000000712 assembly Effects 0.000 description 3
- 125000004429 atom Chemical group 0.000 description 3
- 238000010276 construction Methods 0.000 description 3
- 238000009792 diffusion process Methods 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 238000001755 magnetron sputter deposition Methods 0.000 description 3
- 239000011159 matrix material Substances 0.000 description 3
- 150000002739 metals Chemical class 0.000 description 3
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- 239000000049 pigment Substances 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 238000001771 vacuum deposition Methods 0.000 description 3
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- 239000004642 Polyimide Substances 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 238000003491 array Methods 0.000 description 2
- 239000002041 carbon nanotube Substances 0.000 description 2
- 229910021393 carbon nanotube Inorganic materials 0.000 description 2
- 238000009833 condensation Methods 0.000 description 2
- 230000005494 condensation Effects 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 238000005137 deposition process Methods 0.000 description 2
- 238000009713 electroplating Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 125000000524 functional group Chemical group 0.000 description 2
- 230000008570 general process Effects 0.000 description 2
- 229910052737 gold Inorganic materials 0.000 description 2
- 229920000554 ionomer Polymers 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 229910052748 manganese Inorganic materials 0.000 description 2
- 229910001092 metal group alloy Inorganic materials 0.000 description 2
- 239000002086 nanomaterial Substances 0.000 description 2
- 239000011368 organic material Substances 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 2
- 239000004810 polytetrafluoroethylene Substances 0.000 description 2
- 238000006722 reduction reaction Methods 0.000 description 2
- 230000002441 reversible effect Effects 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 229910052715 tantalum Inorganic materials 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- 238000011282 treatment Methods 0.000 description 2
- 229910052720 vanadium Inorganic materials 0.000 description 2
- 229910052726 zirconium Inorganic materials 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 229910052684 Cerium Inorganic materials 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- 229920003935 Flemion® Polymers 0.000 description 1
- WLLGXSLBOPFWQV-UHFFFAOYSA-N MGK 264 Chemical compound C1=CC2CC1C1C2C(=O)N(CC(CC)CCCC)C1=O WLLGXSLBOPFWQV-UHFFFAOYSA-N 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 239000002033 PVDF binder Substances 0.000 description 1
- 239000004696 Poly ether ether ketone Substances 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- 239000004809 Teflon Substances 0.000 description 1
- 229920006362 Teflon® Polymers 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- GLLRIXZGBQOFLM-UHFFFAOYSA-N Xanthorin Natural products C1=C(C)C=C2C(=O)C3=C(O)C(OC)=CC(O)=C3C(=O)C2=C1O GLLRIXZGBQOFLM-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 238000005275 alloying Methods 0.000 description 1
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- 125000003368 amide group Chemical group 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- JUPQTSLXMOCDHR-UHFFFAOYSA-N benzene-1,4-diol;bis(4-fluorophenyl)methanone Chemical compound OC1=CC=C(O)C=C1.C1=CC(F)=CC=C1C(=O)C1=CC=C(F)C=C1 JUPQTSLXMOCDHR-UHFFFAOYSA-N 0.000 description 1
- 238000005513 bias potential Methods 0.000 description 1
- 229910002056 binary alloy Inorganic materials 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 125000002843 carboxylic acid group Chemical group 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 238000000541 cathodic arc deposition Methods 0.000 description 1
- 210000000170 cell membrane Anatomy 0.000 description 1
- 238000005229 chemical vapour deposition Methods 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000011247 coating layer Substances 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 230000001143 conditioned effect Effects 0.000 description 1
- 238000004320 controlled atmosphere Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 229910001882 dioxygen Inorganic materials 0.000 description 1
- 238000003618 dip coating Methods 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 239000010411 electrocatalyst Substances 0.000 description 1
- 239000007772 electrode material Substances 0.000 description 1
- 238000004070 electrodeposition Methods 0.000 description 1
- 238000007772 electroless plating Methods 0.000 description 1
- 238000001523 electrospinning Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 229920000295 expanded polytetrafluoroethylene Polymers 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000007888 film coating Substances 0.000 description 1
- 238000009501 film coating Methods 0.000 description 1
- 229920002313 fluoropolymer Polymers 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229910052735 hafnium Inorganic materials 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 125000005462 imide group Chemical group 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 238000007735 ion beam assisted deposition Methods 0.000 description 1
- 239000003014 ion exchange membrane Substances 0.000 description 1
- 229920003303 ion-exchange polymer Polymers 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 239000002346 layers by function Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 239000006262 metallic foam Substances 0.000 description 1
- 239000013528 metallic particle Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000000877 morphologic effect Effects 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229910052758 niobium Inorganic materials 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 150000004767 nitrides Chemical class 0.000 description 1
- 230000006911 nucleation Effects 0.000 description 1
- 238000010899 nucleation Methods 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000012860 organic pigment Substances 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 238000005240 physical vapour deposition Methods 0.000 description 1
- 229920001643 poly(ether ketone) Polymers 0.000 description 1
- 229920000052 poly(p-xylylene) Polymers 0.000 description 1
- 229920003223 poly(pyromellitimide-1,4-diphenyl ether) Polymers 0.000 description 1
- 229920001197 polyacetylene Polymers 0.000 description 1
- 229920002530 polyetherether ketone Polymers 0.000 description 1
- 229920002959 polymer blend Polymers 0.000 description 1
- 229920005597 polymer membrane Polymers 0.000 description 1
- 229920000307 polymer substrate Polymers 0.000 description 1
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 239000008213 purified water Substances 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 239000002964 rayon Substances 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 229910052702 rhenium Inorganic materials 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- 238000001878 scanning electron micrograph Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000004528 spin coating Methods 0.000 description 1
- 238000005477 sputtering target Methods 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 125000000542 sulfonic acid group Chemical group 0.000 description 1
- 150000003460 sulfonic acids Chemical class 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 229910002058 ternary alloy Inorganic materials 0.000 description 1
- 238000007738 vacuum evaporation Methods 0.000 description 1
- 238000002061 vacuum sublimation Methods 0.000 description 1
- 238000001947 vapour-phase growth Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/22—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
- C23C14/34—Sputtering
- C23C14/3407—Cathode assembly for sputtering apparatus, e.g. Target
- C23C14/3414—Metallurgical or chemical aspects of target preparation, e.g. casting, powder metallurgy
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
- C23C14/14—Metallic material, boron or silicon
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
- C23C14/14—Metallic material, boron or silicon
- C23C14/20—Metallic material, boron or silicon on organic substrates
- C23C14/205—Metallic material, boron or silicon on organic substrates by cathodic sputtering
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/58—After-treatment
- C23C14/5806—Thermal treatment
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/58—After-treatment
- C23C14/5806—Thermal treatment
- C23C14/5813—Thermal treatment using lasers
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/02—Hydrogen or oxygen
- C25B1/04—Hydrogen or oxygen by electrolysis of water
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
- C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
- C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
- C25B11/042—Electrodes formed of a single material
- C25B11/049—Photocatalysts
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
- C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
- C25B11/051—Electrodes formed of electrocatalysts on a substrate or carrier
- C25B11/073—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material
- C25B11/091—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material consisting of at least one catalytic element and at least one catalytic compound; consisting of two or more catalytic elements or catalytic compounds
- C25B11/097—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material consisting of at least one catalytic element and at least one catalytic compound; consisting of two or more catalytic elements or catalytic compounds comprising two or more noble metals or noble metal alloys
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
- C25B9/17—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof
- C25B9/19—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof with diaphragms
- C25B9/23—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof with diaphragms comprising ion-exchange membranes in or on which electrode material is embedded
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Electrochemistry (AREA)
- Mechanical Engineering (AREA)
- Physics & Mathematics (AREA)
- Inorganic Chemistry (AREA)
- Thermal Sciences (AREA)
- Optics & Photonics (AREA)
- Catalysts (AREA)
- Inert Electrodes (AREA)
- Electrodes For Compound Or Non-Metal Manufacture (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
- Fuel Cell (AREA)
- Physical Vapour Deposition (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201161545409P | 2011-10-10 | 2011-10-10 | |
| US61/545,409 | 2011-10-10 | ||
| PCT/US2012/057897 WO2013055533A1 (en) | 2011-10-10 | 2012-09-28 | Catalyst electrodes, and methods of making and using the same |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA2851494A1 true CA2851494A1 (en) | 2013-04-18 |
Family
ID=47018561
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2851494A Abandoned CA2851494A1 (en) | 2011-10-10 | 2012-09-28 | Catalyst electrodes, and methods of making and using the same |
Country Status (6)
| Country | Link |
|---|---|
| US (2) | US20140246304A1 (enExample) |
| EP (2) | EP2766515B1 (enExample) |
| JP (2) | JP6050367B2 (enExample) |
| CN (1) | CN103857831B (enExample) |
| CA (1) | CA2851494A1 (enExample) |
| WO (1) | WO2013055533A1 (enExample) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US11094953B2 (en) | 2015-05-26 | 2021-08-17 | 3M Innovative Properties Company | Electrode membrane assembly having an oxygen evolution catalyst electrodes, and methods of making and using the same |
Families Citing this family (38)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103857831B (zh) | 2011-10-10 | 2016-08-17 | 3M创新有限公司 | 催化剂电极及其制备和使用方法 |
| WO2014058984A2 (en) * | 2012-10-09 | 2014-04-17 | Brookhaven Science Associates, Llc | Gas diffusion electrodes and methods for fabricating and testing same |
| EP2989672A1 (en) * | 2013-04-23 | 2016-03-02 | 3M Innovative Properties Company | Catalyst electrodes and method of making it |
| WO2016097217A1 (en) * | 2014-12-19 | 2016-06-23 | Industrie De Nora S.P.A. | Electrode for electrochemical cells and composition thereof |
| CN105088153B (zh) * | 2015-08-17 | 2017-09-26 | 宁波中车时代传感技术有限公司 | 半导体硅锗薄膜的制备方法 |
| BE1023867B1 (fr) * | 2016-02-23 | 2017-08-25 | H2Win S.A. | Dispositif pour la production d'hydrogène gazeux |
| CN109923716A (zh) | 2016-10-26 | 2019-06-21 | 3M创新有限公司 | 催化剂 |
| JP7055971B2 (ja) | 2016-10-26 | 2022-04-19 | スリーエム イノベイティブ プロパティズ カンパニー | 燃料電池用pt-ni-ir触媒 |
| KR20190069524A (ko) * | 2016-10-26 | 2019-06-19 | 쓰리엠 이노베이티브 프로퍼티즈 캄파니 | 연료 전지용 Pt-Ni-Ir 촉매 |
| US11196055B2 (en) | 2016-10-26 | 2021-12-07 | 3M Innovative Properties Company | Nanoporous oxygen reduction catalyst material |
| WO2018185616A1 (en) | 2017-04-03 | 2018-10-11 | 3M Innovative Properties Company | Water electrolyzers |
| CN110475907B (zh) * | 2017-04-03 | 2022-08-23 | 3M创新有限公司 | 水电解槽 |
| WO2018185617A1 (en) | 2017-04-03 | 2018-10-11 | 3M Innovative Properties Company | Water electrolyzers |
| CN108070877B (zh) * | 2017-11-09 | 2020-07-07 | 江苏安凯特科技股份有限公司 | 一种用于电解生产的阴极及其制备方法 |
| CN111511958A (zh) * | 2017-12-22 | 2020-08-07 | 3M创新有限公司 | 用于电解槽的含有分散催化剂的阳极组合物 |
| JP7003016B2 (ja) * | 2018-03-22 | 2022-01-20 | 株式会社東芝 | 水電解の陽極に用いる酸素発生用触媒、陽極、膜電極複合体、水電解用セル、スタック及び水電解装置 |
| WO2019193460A1 (en) * | 2018-04-04 | 2019-10-10 | 3M Innovative Properties Company | Catalyst comprising pt, ni, and ru |
| WO2019193458A1 (en) * | 2018-04-04 | 2019-10-10 | 3M Innovative Properties Company | Catalyst comprising pt, ni, and ta |
| EP3776701A1 (en) | 2018-04-04 | 2021-02-17 | 3M Innovative Properties Company | Catalyst |
| WO2019193461A1 (en) * | 2018-04-04 | 2019-10-10 | 3M Innovative Properties Company | Catalyst comprising pt, ni, and cr |
| WO2019198029A1 (en) * | 2018-04-13 | 2019-10-17 | 3M Innovative Properties Company | Catalyst |
| WO2019198033A1 (en) * | 2018-04-13 | 2019-10-17 | 3M Innovative Properties Company | Catalyst |
| WO2019198031A1 (en) | 2018-04-13 | 2019-10-17 | 3M Innovative Properties Company | Catalyst |
| US11560632B2 (en) | 2018-09-27 | 2023-01-24 | 3M Innovative Properties Company | Membrane, membrane electrode assembly, and water electrolyzer including the same |
| CN112771212A (zh) * | 2018-09-28 | 2021-05-07 | 3M创新有限公司 | 氢燃料系统 |
| EP3899100B1 (en) | 2018-12-19 | 2023-01-25 | 3M Innovative Properties Company | Water electrolyzers |
| CN118932412A (zh) * | 2019-02-08 | 2024-11-12 | Agc株式会社 | 膜电极接合体、水电解装置 |
| EP3927868B1 (en) | 2019-02-21 | 2023-11-15 | Tribotecc GmbH | Use of sulfidic compositions |
| CN112439418B (zh) * | 2019-08-15 | 2021-09-24 | 中国科学院化学研究所 | 一种金属纳米颗粒内嵌类石墨烯及其制备方法与应用 |
| JP7218263B2 (ja) | 2019-09-18 | 2023-02-06 | 株式会社東芝 | 積層触媒、電極、膜電極複合体、電気化学セル、スタック、燃料電池及び水電解の可逆装置、車両及び飛翔体 |
| US11894566B2 (en) | 2020-05-12 | 2024-02-06 | Robert Bosch Gmbh | Catalyst materials for a fuel cell stack |
| WO2021257985A1 (en) * | 2020-06-19 | 2021-12-23 | Headwaters Inc. | Ionizers having carbon nanotube ion emitting heads |
| EP4282019A4 (en) * | 2021-01-21 | 2024-10-02 | Hydrolite Ltd | Fabrication of membrane electrode assemblies and reversible electrochemical devices |
| US11888196B2 (en) | 2021-06-16 | 2024-01-30 | Hydrolite Ltd | Self-refueling power-generating systems |
| US20220407086A1 (en) * | 2021-06-16 | 2022-12-22 | Robert Bosch Gmbh | Anode catalyst materials for electrochemical cells |
| US12206115B2 (en) | 2021-10-07 | 2025-01-21 | Robert Bosch Gmbh | Platinum-based alloy catalyst materials and computational methods relating thereto |
| US12378683B2 (en) | 2022-10-18 | 2025-08-05 | Plug Power Inc. | Sputtering-based catalyst deposition on particles for membrane electrode assembly (MEA) catalyst layer |
| CN120905722A (zh) * | 2025-10-13 | 2025-11-07 | 山东赛克赛斯氢能源有限公司 | 一种铱基pem电解水阳极催化剂及其制备方法与应用 |
Family Cites Families (46)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1645655A (en) | 1923-10-24 | 1927-10-18 | Mccathran William Reed | Intermittent inductive train-control system |
| NL128866C (enExample) * | 1965-05-12 | |||
| US4039409A (en) * | 1975-12-04 | 1977-08-02 | General Electric Company | Method for gas generation utilizing platinum metal electrocatalyst containing 5 to 60% ruthenium |
| US4340276A (en) | 1978-11-01 | 1982-07-20 | Minnesota Mining And Manufacturing Company | Method of producing a microstructured surface and the article produced thereby |
| JPS57131376A (en) * | 1981-02-06 | 1982-08-14 | Japan Atom Energy Res Inst | Electrolyzing method for water |
| US4568598A (en) | 1984-10-30 | 1986-02-04 | Minnesota Mining And Manufacturing Company | Article with reduced friction polymer sheet support |
| US5039561A (en) | 1986-08-25 | 1991-08-13 | Minnesota Mining And Manufacturing Company | Method for preparing an article having surface layer of uniformly oriented, crystalline, organic microstructures |
| US4812352A (en) | 1986-08-25 | 1989-03-14 | Minnesota Mining And Manufacturing Company | Article having surface layer of uniformly oriented, crystalline, organic microstructures |
| US5338430A (en) | 1992-12-23 | 1994-08-16 | Minnesota Mining And Manufacturing Company | Nanostructured electrode membranes |
| US6136412A (en) | 1997-10-10 | 2000-10-24 | 3M Innovative Properties Company | Microtextured catalyst transfer substrate |
| US6042959A (en) * | 1997-10-10 | 2000-03-28 | 3M Innovative Properties Company | Membrane electrode assembly and method of its manufacture |
| US5879827A (en) | 1997-10-10 | 1999-03-09 | Minnesota Mining And Manufacturing Company | Catalyst for membrane electrode assembly and method of making |
| US5879828A (en) | 1997-10-10 | 1999-03-09 | Minnesota Mining And Manufacturing Company | Membrane electrode assembly |
| US5910378A (en) * | 1997-10-10 | 1999-06-08 | Minnesota Mining And Manufacturing Company | Membrane electrode assemblies |
| US6300000B1 (en) * | 1999-06-18 | 2001-10-09 | Gore Enterprise Holdings | Fuel cell membrane electrode assemblies with improved power outputs and poison resistance |
| US6641948B1 (en) * | 1999-11-17 | 2003-11-04 | Neah Power Systems Inc | Fuel cells having silicon substrates and/or sol-gel derived support structures |
| US6482763B2 (en) | 1999-12-29 | 2002-11-19 | 3M Innovative Properties Company | Suboxide fuel cell catalyst for enhanced reformate tolerance |
| EP1327276A2 (en) * | 2000-09-27 | 2003-07-16 | Proton Energy Systems, Inc. | Apparatus and method for maintaining compression of the active area in an electrochemical cell |
| KR20020063020A (ko) | 2001-01-26 | 2002-08-01 | 한국과학기술연구원 | 미세 섬유상 고분자웹의 제조 방법 |
| US6617283B2 (en) * | 2001-06-22 | 2003-09-09 | Ut-Battelle, Llc | Method of depositing an electrically conductive oxide buffer layer on a textured substrate and articles formed therefrom |
| JP3571680B2 (ja) * | 2001-10-11 | 2004-09-29 | 本田技研工業株式会社 | 固体高分子型燃料電池用電極 |
| CA2407202C (en) | 2001-10-11 | 2009-11-03 | Honda Giken Kogyo Kabushiki Kaisha | Electrode for polymer electrolyte fuel cell |
| US6946362B2 (en) | 2002-09-06 | 2005-09-20 | Hewlett-Packard Development Company, L.P. | Method and apparatus for forming high surface area material films and membranes |
| US6624328B1 (en) | 2002-12-17 | 2003-09-23 | 3M Innovative Properties Company | Preparation of perfluorinated vinyl ethers having a sulfonyl fluoride end-group |
| US20040116742A1 (en) | 2002-12-17 | 2004-06-17 | 3M Innovative Properties Company | Selective reaction of hexafluoropropylene oxide with perfluoroacyl fluorides |
| US7348088B2 (en) | 2002-12-19 | 2008-03-25 | 3M Innovative Properties Company | Polymer electrolyte membrane |
| US7338692B2 (en) | 2003-09-12 | 2008-03-04 | 3M Innovative Properties Company | Microporous PVDF films |
| KR100696463B1 (ko) * | 2003-09-27 | 2007-03-19 | 삼성에스디아이 주식회사 | 고농도 탄소 담지 촉매, 그 제조방법, 상기 촉매를 이용한촉매전극 및 이를 이용한 연료전지 |
| US7419741B2 (en) * | 2003-09-29 | 2008-09-02 | 3M Innovative Properties Company | Fuel cell cathode catalyst |
| US20090081500A1 (en) * | 2003-10-10 | 2009-03-26 | Ohio University | Fuel cell utilizing ammonia, ethanol or combinations thereof |
| CA2542313C (en) * | 2003-10-10 | 2012-12-04 | Ohio University | Electro-catalysts for the oxidation of ammonia in alkaline media |
| WO2005049199A1 (en) | 2003-10-29 | 2005-06-02 | Umicore Ag & Co Kg | Precious metal oxide catalyst for water electrolysis |
| US7901829B2 (en) | 2005-09-13 | 2011-03-08 | 3M Innovative Properties Company | Enhanced catalyst interface for membrane electrode assembly |
| US7790304B2 (en) | 2005-09-13 | 2010-09-07 | 3M Innovative Properties Company | Catalyst layers to enhance uniformity of current density in membrane electrode assemblies |
| US20080020923A1 (en) | 2005-09-13 | 2008-01-24 | Debe Mark K | Multilayered nanostructured films |
| KR101102905B1 (ko) * | 2006-04-14 | 2012-01-11 | 어플라이드 머티어리얼스, 인코포레이티드 | 신뢰할 수 있는 연료 전지 전극 설계 |
| US7923660B2 (en) * | 2007-08-15 | 2011-04-12 | Applied Materials, Inc. | Pulsed laser anneal system architecture |
| WO2009024158A1 (de) | 2007-08-17 | 2009-02-26 | Bühler AG | Rührwerksmühle |
| US8481214B2 (en) * | 2008-02-25 | 2013-07-09 | Catalyst Power Technologies | Electrodes including support filament with collar stop |
| US8049862B2 (en) * | 2008-08-08 | 2011-11-01 | Apple Inc. | Indium tin oxide (ITO) layer forming |
| US8637193B2 (en) * | 2008-08-25 | 2014-01-28 | 3M Innovative Properties Company | Fuel cell nanocatalyst with voltage reversal tolerance |
| JP5207244B2 (ja) * | 2008-09-30 | 2013-06-12 | 凸版印刷株式会社 | 水素製造装置 |
| US20100279210A1 (en) * | 2009-04-23 | 2010-11-04 | 3M Innovative Properties Company | Catalyst property control with intermixed inorganics |
| CN102947989B (zh) | 2010-04-26 | 2015-12-16 | 3M创新有限公司 | 退火纳米结构化薄膜催化剂 |
| WO2011149732A2 (en) | 2010-05-25 | 2011-12-01 | 3M Innovative Properties Company | Reinforced electrolyte membrane |
| CN103857831B (zh) | 2011-10-10 | 2016-08-17 | 3M创新有限公司 | 催化剂电极及其制备和使用方法 |
-
2012
- 2012-09-28 CN CN201280049628.XA patent/CN103857831B/zh not_active Expired - Fee Related
- 2012-09-28 WO PCT/US2012/057897 patent/WO2013055533A1/en not_active Ceased
- 2012-09-28 US US14/350,290 patent/US20140246304A1/en not_active Abandoned
- 2012-09-28 EP EP12772668.5A patent/EP2766515B1/en not_active Not-in-force
- 2012-09-28 CA CA2851494A patent/CA2851494A1/en not_active Abandoned
- 2012-09-28 EP EP16203586.9A patent/EP3222752B1/en active Active
- 2012-09-28 JP JP2014535741A patent/JP6050367B2/ja not_active Expired - Fee Related
-
2016
- 2016-11-18 JP JP2016225200A patent/JP6334652B2/ja active Active
-
2017
- 2017-09-14 US US15/704,741 patent/US10927448B2/en active Active
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US11094953B2 (en) | 2015-05-26 | 2021-08-17 | 3M Innovative Properties Company | Electrode membrane assembly having an oxygen evolution catalyst electrodes, and methods of making and using the same |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103857831A (zh) | 2014-06-11 |
| EP2766515A1 (en) | 2014-08-20 |
| US20140246304A1 (en) | 2014-09-04 |
| WO2013055533A1 (en) | 2013-04-18 |
| EP2766515B1 (en) | 2018-08-08 |
| EP3222752A1 (en) | 2017-09-27 |
| US20180002807A1 (en) | 2018-01-04 |
| US10927448B2 (en) | 2021-02-23 |
| JP6334652B2 (ja) | 2018-05-30 |
| JP6050367B2 (ja) | 2016-12-21 |
| EP3222752B1 (en) | 2019-11-06 |
| JP2017095800A (ja) | 2017-06-01 |
| CN103857831B (zh) | 2016-08-17 |
| JP2015501374A (ja) | 2015-01-15 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US10927448B2 (en) | Catalyst electrodes, and methods of making and using the same | |
| EP3303657B1 (en) | Oxygen evolution catalyst electrodes, and methods of making and using the same | |
| EP3607113B1 (en) | Water electrolyzers | |
| JP6126130B2 (ja) | 電気化学電池電極 | |
| US11560632B2 (en) | Membrane, membrane electrode assembly, and water electrolyzer including the same | |
| US11414770B2 (en) | Water electrolyzers | |
| US20200017980A1 (en) | Water electrolyzers | |
| US11404702B2 (en) | Catalyst comprising Pt, Ni, and Cr | |
| US20210008528A1 (en) | Catalyst comprising pt, ni, and ru | |
| US20210066724A1 (en) | Catalyst |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request |
Effective date: 20170920 |
|
| FZDE | Discontinued |
Effective date: 20200930 |