CA2660634C - Method for producing methanol, dimethyl ether, derived synthetic hydrocarbons and their products from carbon dioxide and water (moisture) of the air as sole source material - Google Patents
Method for producing methanol, dimethyl ether, derived synthetic hydrocarbons and their products from carbon dioxide and water (moisture) of the air as sole source material Download PDFInfo
- Publication number
- CA2660634C CA2660634C CA2660634A CA2660634A CA2660634C CA 2660634 C CA2660634 C CA 2660634C CA 2660634 A CA2660634 A CA 2660634A CA 2660634 A CA2660634 A CA 2660634A CA 2660634 C CA2660634 C CA 2660634C
- Authority
- CA
- Canada
- Prior art keywords
- carbon dioxide
- water
- air
- methanol
- under conditions
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 title claims abstract description 174
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 title claims abstract description 152
- 229910002092 carbon dioxide Inorganic materials 0.000 title claims abstract description 76
- 239000001569 carbon dioxide Substances 0.000 title claims abstract description 60
- 229910001868 water Inorganic materials 0.000 title claims abstract description 52
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 title claims abstract description 50
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 48
- 229930195733 hydrocarbon Natural products 0.000 title claims abstract description 22
- 150000002430 hydrocarbons Chemical class 0.000 title claims abstract description 22
- 239000000463 material Substances 0.000 title claims abstract description 18
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 14
- VUZPPFZMUPKLLV-UHFFFAOYSA-N methane;hydrate Chemical compound C.O VUZPPFZMUPKLLV-UHFFFAOYSA-N 0.000 title claims description 13
- 238000000034 method Methods 0.000 claims abstract description 45
- 239000001257 hydrogen Substances 0.000 claims abstract description 20
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 20
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 19
- 239000002250 absorbent Substances 0.000 claims abstract description 7
- 230000002745 absorbent Effects 0.000 claims abstract description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 5
- 238000005868 electrolysis reaction Methods 0.000 claims abstract description 5
- 229920002873 Polyethylenimine Polymers 0.000 claims abstract description 4
- 238000005984 hydrogenation reaction Methods 0.000 claims abstract description 4
- TZIHFWKZFHZASV-UHFFFAOYSA-N methyl formate Chemical compound COC=O TZIHFWKZFHZASV-UHFFFAOYSA-N 0.000 claims description 18
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 10
- 238000006243 chemical reaction Methods 0.000 claims description 10
- 229920000642 polymer Polymers 0.000 claims description 9
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 8
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 8
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 8
- 239000005977 Ethylene Substances 0.000 claims description 8
- 229910002091 carbon monoxide Inorganic materials 0.000 claims description 8
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 8
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 8
- 238000007791 dehumidification Methods 0.000 claims description 7
- 239000000126 substance Substances 0.000 claims description 7
- 239000003463 adsorbent Substances 0.000 claims description 6
- 238000003776 cleavage reaction Methods 0.000 claims description 5
- 238000010438 heat treatment Methods 0.000 claims description 5
- 229910052757 nitrogen Inorganic materials 0.000 claims description 5
- 108090000623 proteins and genes Proteins 0.000 claims description 5
- 102000004169 proteins and genes Human genes 0.000 claims description 5
- 230000007017 scission Effects 0.000 claims description 5
- 239000002594 sorbent Substances 0.000 claims description 5
- 238000010521 absorption reaction Methods 0.000 claims description 4
- 239000007789 gas Substances 0.000 claims description 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 3
- 229910021529 ammonia Inorganic materials 0.000 claims description 3
- 239000003054 catalyst Substances 0.000 claims description 3
- 230000003197 catalytic effect Effects 0.000 claims description 3
- 239000012528 membrane Substances 0.000 claims description 3
- 238000010926 purge Methods 0.000 claims description 3
- 238000000926 separation method Methods 0.000 claims description 3
- 238000001179 sorption measurement Methods 0.000 claims description 3
- 238000006555 catalytic reaction Methods 0.000 claims description 2
- 230000002906 microbiologic effect Effects 0.000 claims description 2
- 239000005350 fused silica glass Substances 0.000 claims 2
- 150000003863 ammonium salts Chemical class 0.000 claims 1
- 239000000446 fuel Substances 0.000 abstract description 15
- 150000001875 compounds Chemical class 0.000 abstract description 6
- 229910021485 fumed silica Inorganic materials 0.000 abstract description 3
- 239000002816 fuel additive Substances 0.000 abstract description 2
- 239000000047 product Substances 0.000 description 16
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 15
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 10
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 5
- 238000009903 catalytic hydrogenation reaction Methods 0.000 description 5
- 235000019253 formic acid Nutrition 0.000 description 5
- 239000002803 fossil fuel Substances 0.000 description 5
- 239000004215 Carbon black (E152) Substances 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 239000007858 starting material Substances 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- IEJIGPNLZYLLBP-UHFFFAOYSA-N dimethyl carbonate Chemical compound COC(=O)OC IEJIGPNLZYLLBP-UHFFFAOYSA-N 0.000 description 2
- -1 dimethyl ether Chemical compound 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 108010027322 single cell proteins Proteins 0.000 description 2
- 239000012736 aqueous medium Substances 0.000 description 1
- 150000001491 aromatic compounds Chemical class 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 238000010612 desalination reaction Methods 0.000 description 1
- 230000003467 diminishing effect Effects 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000004146 energy storage Methods 0.000 description 1
- 230000003203 everyday effect Effects 0.000 description 1
- 239000003546 flue gas Substances 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 230000000116 mitigating effect Effects 0.000 description 1
- 239000002086 nanomaterial Substances 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 235000015097 nutrients Nutrition 0.000 description 1
- 238000005832 oxidative carbonylation reaction Methods 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000013535 sea water Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
- C07C41/01—Preparation of ethers
- C07C41/09—Preparation of ethers by dehydration of compounds containing hydroxy groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B61/00—Other general methods
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
- C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
- C07C29/147—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof
- C07C29/149—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof with hydrogen or hydrogen-containing gases
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
- C07C31/02—Monohydroxylic acyclic alcohols
- C07C31/04—Methanol
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P30/00—Technologies relating to oil refining and petrochemical industry
- Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P30/00—Technologies relating to oil refining and petrochemical industry
- Y02P30/40—Ethylene production
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Carbon And Carbon Compounds (AREA)
- Gas Separation By Absorption (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US83727306P | 2006-08-10 | 2006-08-10 | |
| US60/837,273 | 2006-08-10 | ||
| US11/780,171 | 2007-07-19 | ||
| US11/780,171 US7378561B2 (en) | 2006-08-10 | 2007-07-19 | Method for producing methanol, dimethyl ether, derived synthetic hydrocarbons and their products from carbon dioxide and water (moisture) of the air as sole source material |
| PCT/US2007/074601 WO2008021698A2 (en) | 2006-08-10 | 2007-07-27 | Method for producing methanol, dimethyl ether, derived synthetic hydrocarbons and their products from carbon dioxide and water (moisture) of the air as sole source material |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2660634A1 CA2660634A1 (en) | 2008-02-21 |
| CA2660634C true CA2660634C (en) | 2013-07-16 |
Family
ID=38956389
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2660634A Expired - Fee Related CA2660634C (en) | 2006-08-10 | 2007-07-27 | Method for producing methanol, dimethyl ether, derived synthetic hydrocarbons and their products from carbon dioxide and water (moisture) of the air as sole source material |
Country Status (8)
| Country | Link |
|---|---|
| US (2) | US7378561B2 (enExample) |
| EP (1) | EP2054364A2 (enExample) |
| JP (1) | JP2010500362A (enExample) |
| KR (2) | KR20130043694A (enExample) |
| CN (1) | CN101500975B (enExample) |
| AU (1) | AU2007284226B2 (enExample) |
| CA (1) | CA2660634C (enExample) |
| WO (1) | WO2008021698A2 (enExample) |
Families Citing this family (82)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7608743B2 (en) * | 2005-04-15 | 2009-10-27 | University Of Southern California | Efficient and selective chemical recycling of carbon dioxide to methanol, dimethyl ether and derived products |
| CA2604569C (en) * | 2005-04-15 | 2014-08-26 | University Of Southern California | Efficient and selective conversion of carbon dioxide to methanol, dimethyl ether and derived products |
| US20080234523A1 (en) * | 2006-12-01 | 2008-09-25 | Leo Ernest Manzer | Process for making isooctenes from aqueous 2-butanol |
| US8584468B2 (en) * | 2007-02-09 | 2013-11-19 | Dale Robert Lutz | Reliable carbon-neutral power generation system |
| US9557057B2 (en) | 2007-02-09 | 2017-01-31 | Dale Robert Lutz | Reliable carbon-neutral power generation system |
| GB2448685A (en) * | 2007-04-23 | 2008-10-29 | David Andrew Johnston | Carbon dioxide absorbed from air and hydrogen from electrolysis of water, for production of carbon monoxide, alcohols, Fischer-Tropsch hydrocarbons & fuels |
| US8277631B2 (en) * | 2007-05-04 | 2012-10-02 | Principle Energy Solutions, Inc. | Methods and devices for the production of hydrocarbons from carbon and hydrogen sources |
| WO2009001777A1 (ja) * | 2007-06-26 | 2008-12-31 | Taiko Pharmaceutical Co., Ltd. | 二酸化塩素の製造方法、及び該方法に用いる二酸化塩素製造用アルカリ組成物 |
| EP2293864A4 (en) * | 2008-05-16 | 2011-10-26 | Univ Southern California | REDUCING OR ELIMINATING THE IMMUNE IMPRESSION OF HUMAN ACTIVITIES |
| CA2728322A1 (en) * | 2008-06-26 | 2009-12-30 | University Of Southern California | Stockpiling methanol and/or dimethyl ether for fuel and energy reserves |
| US8791166B2 (en) * | 2008-07-24 | 2014-07-29 | University Of Southern California | Producing methanol and its products exclusively from geothermal sources and their energy |
| WO2010088524A2 (en) | 2009-01-29 | 2010-08-05 | Princeton University | Conversion of carbon dioxide to organic products |
| KR101187267B1 (ko) * | 2009-02-12 | 2012-10-02 | 포항공과대학교 산학협력단 | 염기성 고분자를 이용한 이산화탄소 제거 방법 |
| EP2417091A1 (en) * | 2009-04-10 | 2012-02-15 | University Of Southern California | Rendering natural gas as an environmentally carbon dioxide neutral fuel and a regenerative carbon source |
| EP2417081A1 (en) | 2009-04-10 | 2012-02-15 | University Of Southern California | Rendering coal as an environmentally carbon dioxide neutral fuel and a regenerative carbon source |
| CA2757577A1 (en) * | 2009-04-10 | 2010-10-14 | University Of Southern California | Rendering petroleum oil as an environmentally carbon dioxide neutral source material for fuels, derived products and as a regenerative carbon source |
| US8470074B2 (en) * | 2009-12-22 | 2013-06-25 | Exxonmobil Research And Engineering Company | Carbon dioxide sorbents |
| US8845877B2 (en) | 2010-03-19 | 2014-09-30 | Liquid Light, Inc. | Heterocycle catalyzed electrochemical process |
| US8500987B2 (en) | 2010-03-19 | 2013-08-06 | Liquid Light, Inc. | Purification of carbon dioxide from a mixture of gases |
| US8721866B2 (en) | 2010-03-19 | 2014-05-13 | Liquid Light, Inc. | Electrochemical production of synthesis gas from carbon dioxide |
| CN101841051A (zh) * | 2010-03-24 | 2010-09-22 | 苏州大学 | 基于二氧化碳的新型储能方法及装置 |
| US10173169B2 (en) | 2010-03-26 | 2019-01-08 | Dioxide Materials, Inc | Devices for electrocatalytic conversion of carbon dioxide |
| US9790161B2 (en) | 2010-03-26 | 2017-10-17 | Dioxide Materials, Inc | Process for the sustainable production of acrylic acid |
| US20130015064A1 (en) | 2011-06-29 | 2013-01-17 | Masel Richard I | Sensors For Carbon Dioxide And Other End Uses |
| US8956990B2 (en) | 2010-03-26 | 2015-02-17 | Dioxide Materials, Inc. | Catalyst mixtures |
| US9012345B2 (en) | 2010-03-26 | 2015-04-21 | Dioxide Materials, Inc. | Electrocatalysts for carbon dioxide conversion |
| US9566574B2 (en) | 2010-07-04 | 2017-02-14 | Dioxide Materials, Inc. | Catalyst mixtures |
| US9193593B2 (en) | 2010-03-26 | 2015-11-24 | Dioxide Materials, Inc. | Hydrogenation of formic acid to formaldehyde |
| WO2016064440A1 (en) | 2014-10-21 | 2016-04-28 | Dioxide Materials | Electrolyzer and membranes |
| US9957624B2 (en) | 2010-03-26 | 2018-05-01 | Dioxide Materials, Inc. | Electrochemical devices comprising novel catalyst mixtures |
| US9815021B2 (en) | 2010-03-26 | 2017-11-14 | Dioxide Materials, Inc. | Electrocatalytic process for carbon dioxide conversion |
| US20110237830A1 (en) | 2010-03-26 | 2011-09-29 | Dioxide Materials Inc | Novel catalyst mixtures |
| CN101844986A (zh) * | 2010-05-27 | 2010-09-29 | 浙江师范大学 | 利用二氧化碳制备碳酸二甲酯的方法 |
| US8524066B2 (en) * | 2010-07-29 | 2013-09-03 | Liquid Light, Inc. | Electrochemical production of urea from NOx and carbon dioxide |
| US8845878B2 (en) | 2010-07-29 | 2014-09-30 | Liquid Light, Inc. | Reducing carbon dioxide to products |
| EP2624949B1 (en) * | 2010-10-04 | 2015-12-09 | University Of Southern California | Recycling carbon dioxide via capture and temporary storage to produce renewable fuels and derived products |
| US8961774B2 (en) | 2010-11-30 | 2015-02-24 | Liquid Light, Inc. | Electrochemical production of butanol from carbon dioxide and water |
| US8568581B2 (en) | 2010-11-30 | 2013-10-29 | Liquid Light, Inc. | Heterocycle catalyzed carbonylation and hydroformylation with carbon dioxide |
| US9090976B2 (en) | 2010-12-30 | 2015-07-28 | The Trustees Of Princeton University | Advanced aromatic amine heterocyclic catalysts for carbon dioxide reduction |
| US8562811B2 (en) | 2011-03-09 | 2013-10-22 | Liquid Light, Inc. | Process for making formic acid |
| CA2841062A1 (en) | 2011-07-06 | 2013-01-10 | Liquid Light, Inc. | Reduction of carbon dioxide to carboxylic acids, glycols, and carboxylates |
| BR112013033326A2 (pt) | 2011-07-06 | 2017-01-31 | Liquid Light Inc | captura de dióxido de carbono e conversão para produtos orgânicos |
| EP2610235B1 (en) | 2011-12-28 | 2014-05-21 | King Saud University | Method for conversion of carbon dioxide into hydrocarbons |
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| US9963411B2 (en) | 2015-12-02 | 2018-05-08 | King Abdullah University Of Science And Technology | Utilization and recycling of emitted carbon dioxide |
| JP6585859B2 (ja) | 2016-04-04 | 2019-10-02 | ダイオキサイド マテリアルズ，インコーポレイティド | イオン伝導膜 |
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| EP3440238B1 (en) | 2016-04-04 | 2021-10-27 | Dioxide Materials, Inc. | Electrolyzers having catalyst layers |
| US9840670B2 (en) * | 2016-05-12 | 2017-12-12 | M. K. Carter | Chemical conversion of carbon dioxide and water to hydrocarbon fuels |
| US9873650B2 (en) * | 2016-05-26 | 2018-01-23 | X Development Llc | Method for efficient CO2 degasification |
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| DE2743113C3 (de) * | 1977-09-24 | 1980-09-04 | Chemische Werke Huels Ag, 4370 Marl | Verfahren zur Herstellung von Gemischen aus Formaldehyd und Methanol durch partielle Oxidation von Methan |
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- 2007-07-27 CA CA2660634A patent/CA2660634C/en not_active Expired - Fee Related
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| CA2660634A1 (en) | 2008-02-21 |
| JP2010500362A (ja) | 2010-01-07 |
| AU2007284226A1 (en) | 2008-02-21 |
| CN101500975A (zh) | 2009-08-05 |
| KR20130043694A (ko) | 2013-04-30 |
| US7378561B2 (en) | 2008-05-27 |
| US20080039538A1 (en) | 2008-02-14 |
| AU2007284226B2 (en) | 2011-12-08 |
| KR20090057240A (ko) | 2009-06-04 |
| CN101500975B (zh) | 2013-05-29 |
| US20080220480A1 (en) | 2008-09-11 |
| WO2008021698A3 (en) | 2008-07-10 |
| EP2054364A2 (en) | 2009-05-06 |
| WO2008021698A2 (en) | 2008-02-21 |
| US7459590B2 (en) | 2008-12-02 |
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