CA2607223C - Polyolefinic molding composition having improved resistance to thermooxidative degradation and its use for the production of pipes - Google Patents
Polyolefinic molding composition having improved resistance to thermooxidative degradation and its use for the production of pipes Download PDFInfo
- Publication number
- CA2607223C CA2607223C CA2607223A CA2607223A CA2607223C CA 2607223 C CA2607223 C CA 2607223C CA 2607223 A CA2607223 A CA 2607223A CA 2607223 A CA2607223 A CA 2607223A CA 2607223 C CA2607223 C CA 2607223C
- Authority
- CA
- Canada
- Prior art keywords
- use according
- molding composition
- pipes
- weight
- range
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 32
- 238000000465 moulding Methods 0.000 title claims abstract description 29
- 230000015556 catabolic process Effects 0.000 title claims abstract description 4
- 238000006731 degradation reaction Methods 0.000 title claims abstract description 4
- 238000004519 manufacturing process Methods 0.000 title abstract description 4
- -1 polyoxy Polymers 0.000 claims abstract description 24
- 150000001875 compounds Chemical class 0.000 claims abstract description 19
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 claims abstract description 8
- 239000000645 desinfectant Substances 0.000 claims abstract description 8
- 229920002397 thermoplastic olefin Polymers 0.000 claims abstract description 8
- 230000001590 oxidative effect Effects 0.000 claims abstract description 7
- 239000000654 additive Substances 0.000 claims abstract description 5
- 230000007774 longterm Effects 0.000 claims abstract description 4
- 239000007788 liquid Substances 0.000 claims abstract description 3
- 239000004698 Polyethylene Substances 0.000 claims description 15
- 229920000573 polyethylene Polymers 0.000 claims description 15
- 239000002202 Polyethylene glycol Substances 0.000 claims description 8
- 239000004743 Polypropylene Substances 0.000 claims description 8
- 229920001223 polyethylene glycol Polymers 0.000 claims description 8
- 229920001155 polypropylene Polymers 0.000 claims description 8
- 239000000126 substance Substances 0.000 claims description 6
- 125000004432 carbon atom Chemical group C* 0.000 claims description 5
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 4
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 claims description 4
- 125000000217 alkyl group Chemical group 0.000 claims description 3
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 3
- 229920001577 copolymer Polymers 0.000 claims description 3
- 239000012760 heat stabilizer Substances 0.000 claims description 3
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 3
- 239000000178 monomer Substances 0.000 claims description 3
- 125000001424 substituent group Chemical group 0.000 claims description 3
- 239000006096 absorbing agent Substances 0.000 claims description 2
- 239000003963 antioxidant agent Substances 0.000 claims description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 2
- 239000004611 light stabiliser Substances 0.000 claims description 2
- 239000006078 metal deactivator Substances 0.000 claims description 2
- 229920001195 polyisoprene Polymers 0.000 claims description 2
- 229920003245 polyoctenamer Polymers 0.000 claims description 2
- 229920001451 polypropylene glycol Polymers 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 10
- 238000000034 method Methods 0.000 abstract description 5
- 230000000996 additive effect Effects 0.000 abstract description 2
- 239000000155 melt Substances 0.000 description 9
- 238000004132 cross linking Methods 0.000 description 6
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 5
- 239000000460 chlorine Substances 0.000 description 5
- 229910052801 chlorine Inorganic materials 0.000 description 5
- VSAWBBYYMBQKIK-UHFFFAOYSA-N 4-[[3,5-bis[(3,5-ditert-butyl-4-hydroxyphenyl)methyl]-2,4,6-trimethylphenyl]methyl]-2,6-ditert-butylphenol Chemical compound CC1=C(CC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)C(C)=C(CC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)C(C)=C1CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 VSAWBBYYMBQKIK-UHFFFAOYSA-N 0.000 description 4
- 239000003054 catalyst Substances 0.000 description 4
- 238000010894 electron beam technology Methods 0.000 description 4
- 238000006116 polymerization reaction Methods 0.000 description 4
- 229920000098 polyolefin Polymers 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- 238000001125 extrusion Methods 0.000 description 3
- 229920001519 homopolymer Polymers 0.000 description 3
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- OSVXSBDYLRYLIG-UHFFFAOYSA-N dioxidochlorine(.) Chemical compound O=Cl=O OSVXSBDYLRYLIG-UHFFFAOYSA-N 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 150000001451 organic peroxides Chemical class 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- ZKQDCIXGCQPQNV-UHFFFAOYSA-N Calcium hypochlorite Chemical compound [Ca+2].Cl[O-].Cl[O-] ZKQDCIXGCQPQNV-UHFFFAOYSA-N 0.000 description 1
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 description 1
- 239000004155 Chlorine dioxide Substances 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- FBPFZTCFMRRESA-KVTDHHQDSA-N D-Mannitol Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-KVTDHHQDSA-N 0.000 description 1
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 1
- 229930195725 Mannitol Natural products 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 1
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 1
- 238000007792 addition Methods 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 238000004061 bleaching Methods 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 235000019398 chlorine dioxide Nutrition 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000004811 fluoropolymer Substances 0.000 description 1
- 229920002313 fluoropolymer Polymers 0.000 description 1
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000012685 gas phase polymerization Methods 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 239000000594 mannitol Substances 0.000 description 1
- 235000010355 mannitol Nutrition 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000010525 oxidative degradation reaction Methods 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 239000002530 phenolic antioxidant Substances 0.000 description 1
- 239000011990 phillips catalyst Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920005604 random copolymer Polymers 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000010557 suspension polymerization reaction Methods 0.000 description 1
- 229940113165 trimethylolpropane Drugs 0.000 description 1
- UKRDPEFKFJNXQM-UHFFFAOYSA-N vinylsilane Chemical class [SiH3]C=C UKRDPEFKFJNXQM-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/05—Alcohols; Metal alcoholates
- C08K5/053—Polyhydroxylic alcohols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/06—Ethers; Acetals; Ketals; Ortho-esters
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing atoms other than carbon or hydrogen
- C08L23/0892—Copolymers of ethene with unsaturated hydrocarbons containing atoms other than carbon or hydrogen with monomers containing atoms other than carbon, hydrogen or oxygen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L71/00—Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L71/00—Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
- C08L71/02—Polyalkylene oxides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Rigid Pipes And Flexible Pipes (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Injection Moulding Of Plastics Or The Like (AREA)
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102005023040.7 | 2005-05-13 | ||
| DE102005023040A DE102005023040A1 (de) | 2005-05-13 | 2005-05-13 | Polyolefinische Formmasse mit verbesserter Beständigkeit gegen thermo-oxidativen Abbau und ihre Verwendung für das Herstellen von Rohren |
| US68839705P | 2005-06-08 | 2005-06-08 | |
| US60/688,397 | 2005-06-08 | ||
| PCT/EP2006/004251 WO2006119935A1 (en) | 2005-05-13 | 2006-05-06 | Polyolefinic molding composition having improved resistance to thermooxidative degradation and its use for the production of pipes |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2607223A1 CA2607223A1 (en) | 2006-11-16 |
| CA2607223C true CA2607223C (en) | 2013-07-09 |
Family
ID=37295474
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2607223A Expired - Fee Related CA2607223C (en) | 2005-05-13 | 2006-05-06 | Polyolefinic molding composition having improved resistance to thermooxidative degradation and its use for the production of pipes |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US8728370B2 (enExample) |
| EP (1) | EP1879954B1 (enExample) |
| JP (2) | JP2008540746A (enExample) |
| KR (1) | KR101328412B1 (enExample) |
| CN (1) | CN101175805B (enExample) |
| AU (1) | AU2006246010A1 (enExample) |
| BR (1) | BRPI0608803A2 (enExample) |
| CA (1) | CA2607223C (enExample) |
| DE (1) | DE102005023040A1 (enExample) |
| ES (1) | ES2429899T3 (enExample) |
| RU (1) | RU2416622C2 (enExample) |
| WO (1) | WO2006119935A1 (enExample) |
Families Citing this family (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2039719A1 (en) * | 2007-09-21 | 2009-03-25 | Total Petrochemicals Research Feluy | Pipes for transporting water containing chlorine dioxide. |
| US7855246B2 (en) * | 2007-12-05 | 2010-12-21 | Uponor Innovation Ab | Plastic pipe made of polyolefin |
| JP5481854B2 (ja) * | 2008-12-16 | 2014-04-23 | Ｔｄｋ株式会社 | 電子部品 |
| EP2199328A1 (en) * | 2008-12-22 | 2010-06-23 | Borealis AG | Polyolefin composition for water pipes with improved chlorine resistance |
| JP2010180395A (ja) | 2009-01-09 | 2010-08-19 | Sumitomo Chemical Co Ltd | ポリマー安定剤及び該安定剤を含有するポリマー組成物 |
| WO2010149607A1 (en) * | 2009-06-22 | 2010-12-29 | Borealis Ag | Chlorine dioxide resistant polyethylene pipes, their preparation and use |
| JP2013158708A (ja) * | 2012-02-06 | 2013-08-19 | Nippon Rensui Co Ltd | 水処理装置および水処理方法 |
| JP2013158709A (ja) * | 2012-02-06 | 2013-08-19 | Nippon Rensui Co Ltd | 陰イオン交換樹脂および陰イオン交換樹脂の処理方法 |
| EP2746324A1 (en) * | 2012-12-21 | 2014-06-25 | Borealis AG | Use of pigments and additives for improving pipe stability against desinfectant containing water |
| EP3356467B1 (en) | 2015-10-01 | 2019-07-03 | SABIC Global Technologies B.V. | Pipe produced with a polymer composition comprising a polyolefin |
| CN105622922B (zh) * | 2016-04-06 | 2018-04-20 | 苏州博纳化学科技有限公司 | 一种亲水性双羟基化合物的制备方法 |
| EP3378890A1 (en) | 2017-03-22 | 2018-09-26 | Songwon Industrial Co., Ltd. | Polyolefin stabilizers with reduced fragmentation |
| EP3421529A1 (en) | 2017-06-29 | 2019-01-02 | Songwon Industrial Co., Ltd. | Polyolefin articles with improved resistance against chlorine dioxide |
| CN111836721A (zh) * | 2017-11-14 | 2020-10-27 | Eos有限公司电镀光纤系统 | 用于增材制造方法的组合物 |
| DE102018105936A1 (de) | 2018-03-14 | 2019-09-19 | Fachhochschule Münster | Beschichtete Photokatalysatoren |
| US12340506B2 (en) * | 2019-04-30 | 2025-06-24 | The Trustees Of Dartmouth College | System and method for attention-based classification of high-resolution microscopy images |
| KR20230083306A (ko) * | 2020-10-09 | 2023-06-09 | 다우 글로벌 테크놀로지스 엘엘씨 | 향상된 에이징 및 감소된 쉬링크백 중합체성 조성물 |
| EP4408925A1 (en) | 2021-09-30 | 2024-08-07 | ExxonMobil Chemical Patents Inc. | Polyethylene glycol-based polymer processing aid masterbatches |
| EP4408921A1 (en) | 2021-09-30 | 2024-08-07 | ExxonMobil Chemical Patents Inc. | Fluoropolymer-free processing aids for ethylene-based polymers |
| WO2023149985A1 (en) | 2022-02-07 | 2023-08-10 | Exxonmobil Chemical Patents Inc. | Polyethylene glycol-based polymer processing aids |
| WO2023154744A1 (en) | 2022-02-14 | 2023-08-17 | Exxonmobil Chemical Patents Inc. | Polyethylene glycol-based polymer processing aids |
Family Cites Families (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3222314A (en) * | 1956-06-20 | 1965-12-07 | Du Pont | Polyethylene resin containing a solid polyethylene glycol |
| US3902532A (en) * | 1972-03-13 | 1975-09-02 | Phillips Petroleum Co | High hoop-stress pipe |
| US4186123A (en) * | 1974-10-02 | 1980-01-29 | Johns-Manville Corporation | Filled polymeric composition |
| US4013622A (en) * | 1975-06-23 | 1977-03-22 | Cities Service Company | Method of reducing breakdown in polyethylene film |
| IL75719A (en) * | 1984-07-18 | 1988-11-30 | Du Pont Canada | Polyolefin blends containing reactive agents |
| DE3731067A1 (de) * | 1987-09-16 | 1989-04-06 | Basf Ag | Eingedickte formmassen |
| JPH01172439A (ja) * | 1987-12-28 | 1989-07-07 | Nippon Petrochem Co Ltd | 難燃性オレフィン系重合体樹脂組成物 |
| JP2593678B2 (ja) * | 1988-01-27 | 1997-03-26 | 三ツ星ベルト株式会社 | 超高分子量ポリエチレン系組成物 |
| US4855360A (en) * | 1988-04-15 | 1989-08-08 | Minnesota Mining And Manufacturing Company | Extrudable thermoplastic hydrocarbon polymer composition |
| US5378747A (en) * | 1992-12-28 | 1995-01-03 | Phillips Petroleum Company | Ethylene polymer compositions |
| JP3574689B2 (ja) * | 1994-11-16 | 2004-10-06 | 日本ユニカー株式会社 | ダイスカスの発生を防止する方法 |
| US5459187A (en) * | 1995-02-13 | 1995-10-17 | Novacor Chemicals Ltd. | Polyethylene with reduced melt fracture |
| JPH09143318A (ja) | 1995-11-20 | 1997-06-03 | Nippon Unicar Co Ltd | パイプのダイスカス発生を防止する方法 |
| EP0781803A1 (en) * | 1995-12-29 | 1997-07-02 | General Electric Company | Stabilized thermoplastic polymer compositions |
| US6362258B1 (en) * | 1995-12-29 | 2002-03-26 | General Electric Company | Stabilized thermoplastic polymer composition |
| KR100563428B1 (ko) * | 1997-07-04 | 2006-03-22 | 교와 가가꾸고교 가부시키가이샤 | 내열열화성을 갖는 합성수지 조성물 및 이의 성형품 |
| CN1273592A (zh) * | 1997-08-27 | 2000-11-15 | 陶氏化学公司 | α烯烃与乙烯基芳族单体的共聚物的流变改性方法 |
| US6294604B1 (en) * | 1998-03-06 | 2001-09-25 | Dyneon Llc | Polymer processing additive having improved stability |
| JP4577917B2 (ja) * | 1998-08-20 | 2010-11-10 | 三井・デュポンポリケミカル株式会社 | 高周波発熱性樹脂組成物、及び該樹脂組成物からなる高周波融着性成形体 |
| JP2000072860A (ja) * | 1998-08-31 | 2000-03-07 | Nippon Zeon Co Ltd | パイプ |
| JP2001064457A (ja) * | 1999-08-31 | 2001-03-13 | Du Pont Mitsui Polychem Co Ltd | エチレン系樹脂組成物 |
| GB0004436D0 (en) * | 2000-02-25 | 2000-04-12 | Clariant Int Ltd | Synergistic stabilizer compositions for thermoplastic polymers in prolonged contact with water |
| WO2001090230A1 (en) | 2000-05-26 | 2001-11-29 | Nkt Research A/S | Self-lubricating polymers |
| CA2442789A1 (en) * | 2003-09-26 | 2005-03-26 | Nova Chemicals Corporation | High molecular weight polyethylene glycol as polymer process aids |
-
2005
- 2005-05-13 DE DE102005023040A patent/DE102005023040A1/de not_active Withdrawn
-
2006
- 2006-05-06 CN CN2006800165811A patent/CN101175805B/zh not_active Expired - Fee Related
- 2006-05-06 AU AU2006246010A patent/AU2006246010A1/en not_active Abandoned
- 2006-05-06 JP JP2008510469A patent/JP2008540746A/ja not_active Withdrawn
- 2006-05-06 CA CA2607223A patent/CA2607223C/en not_active Expired - Fee Related
- 2006-05-06 BR BRPI0608803-1A patent/BRPI0608803A2/pt not_active IP Right Cessation
- 2006-05-06 US US11/920,310 patent/US8728370B2/en active Active
- 2006-05-06 EP EP06724744.5A patent/EP1879954B1/en not_active Not-in-force
- 2006-05-06 ES ES06724744T patent/ES2429899T3/es active Active
- 2006-05-06 KR KR1020077026281A patent/KR101328412B1/ko not_active Expired - Fee Related
- 2006-05-06 WO PCT/EP2006/004251 patent/WO2006119935A1/en not_active Ceased
- 2006-05-06 RU RU2007145916/05A patent/RU2416622C2/ru not_active IP Right Cessation
-
2012
- 2012-10-19 JP JP2012231966A patent/JP5721685B2/ja not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| BRPI0608803A2 (pt) | 2011-03-15 |
| AU2006246010A1 (en) | 2006-11-16 |
| WO2006119935A1 (en) | 2006-11-16 |
| CN101175805A (zh) | 2008-05-07 |
| RU2416622C2 (ru) | 2011-04-20 |
| DE102005023040A1 (de) | 2006-11-16 |
| JP2013057069A (ja) | 2013-03-28 |
| CN101175805B (zh) | 2011-11-30 |
| RU2007145916A (ru) | 2009-06-20 |
| EP1879954B1 (en) | 2013-07-31 |
| JP5721685B2 (ja) | 2015-05-20 |
| ES2429899T3 (es) | 2013-11-18 |
| JP2008540746A (ja) | 2008-11-20 |
| KR20080007253A (ko) | 2008-01-17 |
| EP1879954A1 (en) | 2008-01-23 |
| US8728370B2 (en) | 2014-05-20 |
| CA2607223A1 (en) | 2006-11-16 |
| US20090069477A1 (en) | 2009-03-12 |
| KR101328412B1 (ko) | 2013-11-14 |
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