CA2543499C - Process for cleaning gases from gasification units - Google Patents
Process for cleaning gases from gasification units Download PDFInfo
- Publication number
- CA2543499C CA2543499C CA2543499A CA2543499A CA2543499C CA 2543499 C CA2543499 C CA 2543499C CA 2543499 A CA2543499 A CA 2543499A CA 2543499 A CA2543499 A CA 2543499A CA 2543499 C CA2543499 C CA 2543499C
- Authority
- CA
- Canada
- Prior art keywords
- steam
- gas
- sorbent
- process according
- solid sulphur
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000007789 gas Substances 0.000 title claims abstract description 119
- 238000002309 gasification Methods 0.000 title claims abstract description 57
- 238000000034 method Methods 0.000 title claims abstract description 43
- 230000008569 process Effects 0.000 title claims abstract description 42
- 238000004140 cleaning Methods 0.000 title claims abstract description 17
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 65
- 239000005864 Sulphur Substances 0.000 claims abstract description 63
- 239000002594 sorbent Substances 0.000 claims abstract description 61
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 claims abstract description 47
- 230000015572 biosynthetic process Effects 0.000 claims abstract description 35
- 238000003786 synthesis reaction Methods 0.000 claims abstract description 31
- 239000007787 solid Substances 0.000 claims abstract description 25
- 238000006243 chemical reaction Methods 0.000 claims abstract description 23
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims abstract description 21
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 19
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000000446 fuel Substances 0.000 claims abstract description 11
- 229910002092 carbon dioxide Inorganic materials 0.000 claims abstract description 10
- 229910002091 carbon monoxide Inorganic materials 0.000 claims abstract description 10
- 239000001257 hydrogen Substances 0.000 claims abstract description 9
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 9
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000001569 carbon dioxide Substances 0.000 claims abstract description 6
- 230000001172 regenerating effect Effects 0.000 claims abstract description 6
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000011575 calcium Substances 0.000 claims abstract description 5
- 229910052791 calcium Inorganic materials 0.000 claims abstract description 5
- 150000001875 compounds Chemical class 0.000 claims abstract description 4
- 230000003197 catalytic effect Effects 0.000 claims abstract description 3
- 150000002366 halogen compounds Chemical class 0.000 claims abstract description 3
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical group [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 21
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 claims description 14
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 12
- 229910052736 halogen Inorganic materials 0.000 claims description 10
- 150000002367 halogens Chemical class 0.000 claims description 10
- 229910001887 tin oxide Inorganic materials 0.000 claims description 10
- 239000011787 zinc oxide Substances 0.000 claims description 10
- 229910052751 metal Inorganic materials 0.000 claims description 8
- 239000002184 metal Substances 0.000 claims description 8
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 6
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 6
- 229910052759 nickel Inorganic materials 0.000 claims description 6
- 239000000428 dust Substances 0.000 claims description 5
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 4
- 239000003054 catalyst Substances 0.000 claims description 4
- 229910052802 copper Inorganic materials 0.000 claims description 4
- 239000010949 copper Substances 0.000 claims description 4
- QHGNHLZPVBIIPX-UHFFFAOYSA-N tin(ii) oxide Chemical class [Sn]=O QHGNHLZPVBIIPX-UHFFFAOYSA-N 0.000 claims description 4
- 150000004760 silicates Chemical class 0.000 claims description 3
- 229910021532 Calcite Inorganic materials 0.000 claims description 2
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 2
- 229910052750 molybdenum Inorganic materials 0.000 claims description 2
- 239000011733 molybdenum Substances 0.000 claims description 2
- 229910017052 cobalt Inorganic materials 0.000 claims 1
- 239000010941 cobalt Substances 0.000 claims 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims 1
- 229910000514 dolomite Inorganic materials 0.000 claims 1
- 239000010459 dolomite Substances 0.000 claims 1
- 230000008929 regeneration Effects 0.000 description 25
- 238000011069 regeneration method Methods 0.000 description 25
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 19
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical group [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 18
- AGVJBLHVMNHENQ-UHFFFAOYSA-N Calcium sulfide Chemical compound [S-2].[Ca+2] AGVJBLHVMNHENQ-UHFFFAOYSA-N 0.000 description 16
- 239000003245 coal Substances 0.000 description 16
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 15
- 239000001301 oxygen Substances 0.000 description 15
- 229910052760 oxygen Inorganic materials 0.000 description 15
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 12
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 12
- 239000002250 absorbent Substances 0.000 description 9
- 230000002745 absorbent Effects 0.000 description 9
- 229910000019 calcium carbonate Inorganic materials 0.000 description 9
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 8
- 239000000203 mixture Substances 0.000 description 8
- 239000004291 sulphur dioxide Substances 0.000 description 8
- 235000010269 sulphur dioxide Nutrition 0.000 description 8
- 230000009102 absorption Effects 0.000 description 7
- 238000010521 absorption reaction Methods 0.000 description 7
- QGJOPFRUJISHPQ-UHFFFAOYSA-N Carbon disulfide Chemical compound S=C=S QGJOPFRUJISHPQ-UHFFFAOYSA-N 0.000 description 6
- 229940105305 carbon monoxide Drugs 0.000 description 6
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 6
- ODINCKMPIJJUCX-UHFFFAOYSA-N Calcium oxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 238000002360 preparation method Methods 0.000 description 5
- 238000011084 recovery Methods 0.000 description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- 229910021529 ammonia Inorganic materials 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 239000010763 heavy fuel oil Substances 0.000 description 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 4
- 239000010742 number 1 fuel oil Substances 0.000 description 4
- 230000008901 benefit Effects 0.000 description 3
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 3
- 239000000292 calcium oxide Substances 0.000 description 3
- 239000001175 calcium sulphate Substances 0.000 description 3
- 235000011132 calcium sulphate Nutrition 0.000 description 3
- 229910002090 carbon oxide Inorganic materials 0.000 description 3
- 239000012876 carrier material Substances 0.000 description 3
- 239000012535 impurity Substances 0.000 description 3
- 239000000543 intermediate Substances 0.000 description 3
- 229910017464 nitrogen compound Inorganic materials 0.000 description 3
- 150000002830 nitrogen compounds Chemical class 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 238000010248 power generation Methods 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 230000009467 reduction Effects 0.000 description 3
- 230000003019 stabilising effect Effects 0.000 description 3
- 239000001117 sulphuric acid Substances 0.000 description 3
- 235000011149 sulphuric acid Nutrition 0.000 description 3
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 2
- 101100229708 Homo sapiens GOLT1B gene Proteins 0.000 description 2
- 102100021102 Hyaluronidase PH-20 Human genes 0.000 description 2
- 235000019738 Limestone Nutrition 0.000 description 2
- 101150055528 SPAM1 gene Proteins 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 2
- 102100024018 Vesicle transport protein GOT1B Human genes 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 229940043430 calcium compound Drugs 0.000 description 2
- 150000001674 calcium compounds Chemical class 0.000 description 2
- 239000000919 ceramic Substances 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 239000002803 fossil fuel Substances 0.000 description 2
- 239000000295 fuel oil Substances 0.000 description 2
- AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 description 2
- 239000006028 limestone Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000003345 natural gas Substances 0.000 description 2
- 229910000069 nitrogen hydride Inorganic materials 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 238000005498 polishing Methods 0.000 description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 2
- 239000011686 zinc sulphate Substances 0.000 description 2
- 235000009529 zinc sulphate Nutrition 0.000 description 2
- 239000002028 Biomass Substances 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- 229910008066 SnC12 Inorganic materials 0.000 description 1
- 229910008046 SnC14 Inorganic materials 0.000 description 1
- 229910001308 Zinc ferrite Inorganic materials 0.000 description 1
- 239000005083 Zinc sulfide Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- HHSPVTKDOHQBKF-UHFFFAOYSA-J calcium;magnesium;dicarbonate Chemical compound [Mg+2].[Ca+2].[O-]C([O-])=O.[O-]C([O-])=O HHSPVTKDOHQBKF-UHFFFAOYSA-J 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- JJWKPURADFRFRB-UHFFFAOYSA-N carbonyl sulfide Chemical compound O=C=S JJWKPURADFRFRB-UHFFFAOYSA-N 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 238000001311 chemical methods and process Methods 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000003034 coal gas Substances 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 230000001143 conditioned effect Effects 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 239000002283 diesel fuel Substances 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- 239000003502 gasoline Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 230000008676 import Effects 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000003077 lignite Substances 0.000 description 1
- 229910001510 metal chloride Inorganic materials 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 229960003903 oxygen Drugs 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 230000036647 reaction Effects 0.000 description 1
- 239000011819 refractory material Substances 0.000 description 1
- 238000005201 scrubbing Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 150000004763 sulfides Chemical class 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- -1 sulphur com-pounds Chemical class 0.000 description 1
- AFNRRBXCCXDRPS-UHFFFAOYSA-N tin(ii) sulfide Chemical compound [Sn]=S AFNRRBXCCXDRPS-UHFFFAOYSA-N 0.000 description 1
- HPGGPRDJHPYFRM-UHFFFAOYSA-J tin(iv) chloride Chemical class Cl[Sn](Cl)(Cl)Cl HPGGPRDJHPYFRM-UHFFFAOYSA-J 0.000 description 1
- 230000000699 topical effect Effects 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- WGEATSXPYVGFCC-UHFFFAOYSA-N zinc ferrite Chemical compound O=[Zn].O=[Fe]O[Fe]=O WGEATSXPYVGFCC-UHFFFAOYSA-N 0.000 description 1
- 229910000368 zinc sulfate Inorganic materials 0.000 description 1
- DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
- C10K1/00—Purifying combustible gases containing carbon monoxide
- C10K1/20—Purifying combustible gases containing carbon monoxide by treating with solids; Regenerating spent purifying masses
- C10K1/26—Regeneration of the purifying material contains also apparatus for the regeneration of the purifying material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/48—Sulfur compounds
- B01D53/50—Sulfur oxides
- B01D53/508—Sulfur oxides by treating the gases with solids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/68—Halogens or halogen compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/02—Fixed-bed gasification of lump fuel
- C10J3/06—Continuous processes
- C10J3/14—Continuous processes using gaseous heat-carriers
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/72—Other features
- C10J3/82—Gas withdrawal means
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
- C10K3/00—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide
- C10K3/02—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide by catalytic treatment
- C10K3/04—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide by catalytic treatment reducing the carbon monoxide content, e.g. water-gas shift [WGS]
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0953—Gasifying agents
- C10J2300/0973—Water
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0983—Additives
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E20/00—Combustion technologies with mitigation potential
- Y02E20/16—Combined cycle power plant [CCPP], or combined cycle gas turbine [CCGT]
- Y02E20/18—Integrated gasification combined cycle [IGCC], e.g. combined with carbon capture and storage [CCS]
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Combustion & Propulsion (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Environmental & Geological Engineering (AREA)
- Analytical Chemistry (AREA)
- Industrial Gases (AREA)
- Treating Waste Gases (AREA)
- Catalysts (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DKPA200500553 | 2005-04-15 | ||
DKPA200500553 | 2005-04-15 |
Publications (2)
Publication Number | Publication Date |
---|---|
CA2543499A1 CA2543499A1 (en) | 2006-10-15 |
CA2543499C true CA2543499C (en) | 2014-04-08 |
Family
ID=37055672
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA2543499A Expired - Fee Related CA2543499C (en) | 2005-04-15 | 2006-04-13 | Process for cleaning gases from gasification units |
Country Status (7)
Country | Link |
---|---|
US (1) | US7618558B2 (de) |
CN (1) | CN1880412B (de) |
CA (1) | CA2543499C (de) |
DE (1) | DE102006017680B4 (de) |
RU (1) | RU2417825C2 (de) |
UA (1) | UA91821C2 (de) |
ZA (1) | ZA200603020B (de) |
Families Citing this family (39)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7618606B2 (en) * | 2003-02-06 | 2009-11-17 | The Ohio State University | Separation of carbon dioxide (CO2) from gas mixtures |
CA2629829A1 (en) * | 2005-11-23 | 2007-05-31 | Shell Internationale Research Maatschappij B.V. | A process for sequestration of carbon dioxide by mineral carbonation |
EP2073914B1 (de) * | 2006-09-25 | 2020-05-06 | The Ohio State University | Calcium-looping für die herstellung von hochreinem wasserstoff |
DE602007010508D1 (de) * | 2006-12-08 | 2010-12-23 | Shell Int Research | Verfahren zur herstellung eines gereinigten synthesegasstroms |
US8328889B2 (en) * | 2007-12-12 | 2012-12-11 | Kellogg Brown & Root Llc | Efficiency of gasification processes |
US8091337B2 (en) * | 2008-02-29 | 2012-01-10 | Corning Incorporated | Exhaust treatment device having a reactive compound and conditioning the device via endothermic reaction |
US8192716B2 (en) * | 2008-04-01 | 2012-06-05 | Greatpoint Energy, Inc. | Sour shift process for the removal of carbon monoxide from a gas stream |
DE102008049579A1 (de) * | 2008-09-30 | 2010-04-01 | Uhde Gmbh | Heißgasreinigung |
US8496909B2 (en) * | 2008-10-13 | 2013-07-30 | The Ohio State University Research Foundation | Calcium looping process for high purity hydrogen production integrated with capture of carbon dioxide, sulfur and halides |
MX2011004326A (es) * | 2008-10-22 | 2011-07-28 | Southern Res Inst | Proceso para descontaminar gas de sintesis. |
WO2010075027A1 (en) * | 2008-12-15 | 2010-07-01 | Katana Energy Llc | Emissions free sulfuric acid and sodium bisulfite production for desalination from gasification acid gas |
US8343243B2 (en) * | 2009-03-31 | 2013-01-01 | General Electric Company | Method and apparatus for blending lignite and coke slurries |
JP5636048B2 (ja) * | 2009-06-30 | 2014-12-03 | シエル・インターナシヨネイル・リサーチ・マーチヤツピイ・ベー・ウイShell Internationale Research Maatschappij Beslotenvennootshap | 水素に富む気体混合物を製造する方法 |
US8314277B2 (en) | 2010-06-30 | 2012-11-20 | Uop Llc | Adsorbent for feed and products purification in benzene saturation process |
US8313641B2 (en) | 2010-06-30 | 2012-11-20 | Uop Llc | Adsorbent for feed and products purification in a reforming process |
NL2008313C2 (en) * | 2012-02-17 | 2013-09-02 | Stichting Energie | Water gas shift process. |
JP2014015499A (ja) * | 2012-07-06 | 2014-01-30 | Hitachi Ltd | ガス化方法とそのシステム、石炭ガス化複合発電方法とそのシステム。 |
FR2997414B1 (fr) * | 2012-10-31 | 2015-10-02 | Ifp Energies Now | Procede ameliore de conversion d'une charge contenant de la biomasse pour la production d'hydrocarbures par voie de synthese fischer-tropsch |
JP6025603B2 (ja) * | 2013-02-21 | 2016-11-16 | 三菱重工業株式会社 | Coシフト反応装置及びcoシフト変換方法 |
JP6496104B2 (ja) * | 2014-02-18 | 2019-04-03 | クラリアント触媒株式会社 | ハロゲン化合物吸収剤およびそれを用いた合成ガスの製造方法 |
US10773958B2 (en) | 2014-03-21 | 2020-09-15 | Chevron Phillips Chemical Company Lp | Processes for removing polysulfanes and elemental sulfur from hydrogen sulfide |
US9605220B2 (en) * | 2014-06-28 | 2017-03-28 | Saudi Arabian Oil Company | Energy efficient gasification based multi generation apparatus employing advanced process schemes and related methods |
CN104084041B (zh) * | 2014-07-17 | 2016-08-17 | 北京三聚创洁科技发展有限公司 | 一种氧化锌脱硫废剂的再生方法 |
DK3368472T3 (da) | 2015-10-29 | 2020-06-15 | Johnson Matthey Plc | Vandgasshiftkatalysator |
GB201519133D0 (en) | 2015-10-29 | 2015-12-16 | Johnson Matthey Plc | Process |
GB201519139D0 (en) | 2015-10-29 | 2015-12-16 | Johnson Matthey Plc | Process |
US9803151B2 (en) | 2016-03-24 | 2017-10-31 | General Electric Company | System and method for gasification |
RU2748547C2 (ru) * | 2016-11-01 | 2021-05-26 | Шелл Интернэшнл Рисерч Маатсхаппий Б.В. | Способ получения очищенного газового потока |
US10213730B1 (en) | 2017-08-22 | 2019-02-26 | Saudi Arabian Oil Company | Process for acid gas treatment and power generation |
CN110243992B (zh) * | 2018-03-09 | 2022-10-11 | 国家能源投资集团有限责任公司 | 催化剂评价原料气的制备方法与催化剂工业评价测试系统 |
US10464872B1 (en) | 2018-07-31 | 2019-11-05 | Greatpoint Energy, Inc. | Catalytic gasification to produce methanol |
US10344231B1 (en) | 2018-10-26 | 2019-07-09 | Greatpoint Energy, Inc. | Hydromethanation of a carbonaceous feedstock with improved carbon utilization |
US10435637B1 (en) | 2018-12-18 | 2019-10-08 | Greatpoint Energy, Inc. | Hydromethanation of a carbonaceous feedstock with improved carbon utilization and power generation |
CN111377575B (zh) * | 2018-12-28 | 2022-09-09 | 中国石油化工股份有限公司 | 一种高硫酸盐高cod有机废水的处理方法 |
CA3130873A1 (en) * | 2019-02-21 | 2020-08-27 | Teknologian Tutkimuskeskus Vtt Oy | Method and process arrangement for producing hydrocarbons and use |
US10618818B1 (en) | 2019-03-22 | 2020-04-14 | Sure Champion Investment Limited | Catalytic gasification to produce ammonia and urea |
CN112316987A (zh) * | 2019-08-05 | 2021-02-05 | 中国石油化工股份有限公司 | 一种积碳低碳烷烃脱氢催化剂的脱硫方法 |
CN110550601B (zh) * | 2019-08-08 | 2023-03-14 | 中石化宁波工程有限公司 | 一种用于高浓度co原料气的变换工艺 |
FR3112537B1 (fr) | 2020-07-14 | 2023-03-31 | Engie | Dispositif et procédé de production hybride de dihydrogène de synthèse et/ou de méthane de synthèse |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4302218A (en) * | 1980-06-16 | 1981-11-24 | Fmc Corporation | Process for controlling sulfur oxides in coal gasification |
US4769045A (en) | 1986-04-10 | 1988-09-06 | The United States Department Of Energy | Method for the desulfurization of hot product gases from coal gasifier |
DK165969C (da) * | 1989-05-29 | 1993-11-08 | Haldor Topsoe As | Fremgangsmaade til fjernelse af sulfider fra gasstroemme |
CN1024458C (zh) * | 1991-06-01 | 1994-05-11 | 王师祥 | 空气连续汽化深冷脱氮制合成氨的方法 |
EP0634471A1 (de) * | 1993-07-12 | 1995-01-18 | M. W. Kellogg Company | Kohlenvergasung und Verfahren zur Entfernung von Schwefel |
WO1996030465A1 (en) | 1995-03-30 | 1996-10-03 | Enviropower Inc. | Method for feeding regeneration offgas into a gasifier |
CN1114583C (zh) * | 1998-10-06 | 2003-07-16 | 王国良 | 利用原煤独立制造甲醇的方法 |
CN1213131C (zh) * | 2003-06-25 | 2005-08-03 | 中国科学院山西煤炭化学研究所 | 一种高温煤气脱硫除尘一体化方法及其设备 |
-
2006
- 2006-04-07 US US11/399,373 patent/US7618558B2/en not_active Expired - Fee Related
- 2006-04-12 DE DE102006017680.4A patent/DE102006017680B4/de not_active Expired - Fee Related
- 2006-04-13 CA CA2543499A patent/CA2543499C/en not_active Expired - Fee Related
- 2006-04-13 ZA ZA200603020A patent/ZA200603020B/xx unknown
- 2006-04-14 UA UAA200604176A patent/UA91821C2/ru unknown
- 2006-04-14 RU RU2006112353/05A patent/RU2417825C2/ru not_active IP Right Cessation
- 2006-04-14 CN CN2006100841854A patent/CN1880412B/zh not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
DE102006017680B4 (de) | 2016-07-14 |
CN1880412B (zh) | 2012-01-11 |
UA91821C2 (ru) | 2010-09-10 |
US7618558B2 (en) | 2009-11-17 |
DE102006017680A1 (de) | 2006-10-19 |
US20060233687A1 (en) | 2006-10-19 |
CN1880412A (zh) | 2006-12-20 |
RU2006112353A (ru) | 2007-11-10 |
CA2543499A1 (en) | 2006-10-15 |
RU2417825C2 (ru) | 2011-05-10 |
ZA200603020B (en) | 2007-06-27 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CA2543499C (en) | Process for cleaning gases from gasification units | |
US4833877A (en) | Process for the reduction of pollutant emissions from power stations with combined gas/steam turbine processes with preceding coal gasification | |
EP0487102B1 (de) | System für die Rückgewinnung und Verwendung von CO2-Gas | |
CN102413900B (zh) | 处理尾气物流的方法和设备 | |
CN112063422B (zh) | 一种高炉煤气脱硫及硫资源化利用方法和装置 | |
US7935324B2 (en) | Integrated warm gas desulfurization and gas shift for cleanup of gaseous streams | |
JP2012522090A (ja) | 精製合成ガスを製造する方法 | |
CN103657368A (zh) | 一种同时脱硫脱硝脱汞干法烟气净化方法及装置 | |
EA037523B1 (ru) | Система и способ выработки энергии с использованием процесса получения метана | |
KR20110095294A (ko) | 배출 가스 스트림 처리 방법 및 장치 | |
US4769045A (en) | Method for the desulfurization of hot product gases from coal gasifier | |
KR100278949B1 (ko) | 석탄으로부터 얻은 고온의 가스로부터 유황 화학종을 제거하는 시스템 및 방법 | |
Gangwal et al. | Hot-gas cleanup—sulfur recovery technical, environmental, and economic issues | |
JPH1180760A (ja) | ガス精製装置 | |
CA2007123C (en) | Method for purifying high-temperature reducing gas | |
Dehghani et al. | FLUE GAS DESULFURIZATION METHODS TO CONSERVE THE ENVIRONMENT. | |
GB2190683A (en) | Method for purifying high-temperature reducing gas | |
NL9102195A (nl) | Werkwijze voor het behandelen van, door kolenvergassing, residuvergassing, afvalvergassing of olievergassing verkregen gassen. | |
KR100194555B1 (ko) | 고신뢰도 고효율 석탄가스화 복합발전 시스템 및전력발생방법 | |
JP4658350B2 (ja) | 硫黄化合物の低減方法及びその装置 | |
JPH01254226A (ja) | 高温還元性ガスの精製方法 | |
JPS59184291A (ja) | 高温還元性ガスの精製方法 | |
NL8803164A (nl) | Werkwijze en inrichting voor het ontzwavelen van gas. | |
JPH01203020A (ja) | 高温還元性ガスの精製方法 | |
Colton et al. | Low and Intermediate Btu Fuel Gas Cleanup |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
EEER | Examination request | ||
MKLA | Lapsed |
Effective date: 20200831 |