CA2543499C - Process for cleaning gases from gasification units - Google Patents

Process for cleaning gases from gasification units Download PDF

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Publication number
CA2543499C
CA2543499C CA2543499A CA2543499A CA2543499C CA 2543499 C CA2543499 C CA 2543499C CA 2543499 A CA2543499 A CA 2543499A CA 2543499 A CA2543499 A CA 2543499A CA 2543499 C CA2543499 C CA 2543499C
Authority
CA
Canada
Prior art keywords
steam
gas
sorbent
process according
solid sulphur
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CA2543499A
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English (en)
French (fr)
Other versions
CA2543499A1 (en
Inventor
Poul Erik Hoejlund Nielsen
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Topsoe AS
Original Assignee
Haldor Topsoe AS
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Haldor Topsoe AS filed Critical Haldor Topsoe AS
Publication of CA2543499A1 publication Critical patent/CA2543499A1/en
Application granted granted Critical
Publication of CA2543499C publication Critical patent/CA2543499C/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10KPURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00Purifying combustible gases containing carbon monoxide
    • C10K1/20Purifying combustible gases containing carbon monoxide by treating with solids; Regenerating spent purifying masses
    • C10K1/26Regeneration of the purifying material contains also apparatus for the regeneration of the purifying material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/48Sulfur compounds
    • B01D53/50Sulfur oxides
    • B01D53/508Sulfur oxides by treating the gases with solids
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/68Halogens or halogen compounds
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/02Fixed-bed gasification of lump fuel
    • C10J3/06Continuous processes
    • C10J3/14Continuous processes using gaseous heat-carriers
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/72Other features
    • C10J3/82Gas withdrawal means
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10KPURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K3/00Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide
    • C10K3/02Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide by catalytic treatment
    • C10K3/04Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide by catalytic treatment reducing the carbon monoxide content, e.g. water-gas shift [WGS]
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/09Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953Gasifying agents
    • C10J2300/0973Water
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/09Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0983Additives
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E20/00Combustion technologies with mitigation potential
    • Y02E20/16Combined cycle power plant [CCPP], or combined cycle gas turbine [CCGT]
    • Y02E20/18Integrated gasification combined cycle [IGCC], e.g. combined with carbon capture and storage [CCS]

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Combustion & Propulsion (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Environmental & Geological Engineering (AREA)
  • Analytical Chemistry (AREA)
  • Industrial Gases (AREA)
  • Treating Waste Gases (AREA)
  • Catalysts (AREA)
CA2543499A 2005-04-15 2006-04-13 Process for cleaning gases from gasification units Expired - Fee Related CA2543499C (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DKPA200500553 2005-04-15
DKPA200500553 2005-04-15

Publications (2)

Publication Number Publication Date
CA2543499A1 CA2543499A1 (en) 2006-10-15
CA2543499C true CA2543499C (en) 2014-04-08

Family

ID=37055672

Family Applications (1)

Application Number Title Priority Date Filing Date
CA2543499A Expired - Fee Related CA2543499C (en) 2005-04-15 2006-04-13 Process for cleaning gases from gasification units

Country Status (7)

Country Link
US (1) US7618558B2 (de)
CN (1) CN1880412B (de)
CA (1) CA2543499C (de)
DE (1) DE102006017680B4 (de)
RU (1) RU2417825C2 (de)
UA (1) UA91821C2 (de)
ZA (1) ZA200603020B (de)

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US7618606B2 (en) * 2003-02-06 2009-11-17 The Ohio State University Separation of carbon dioxide (CO2) from gas mixtures
CA2629829A1 (en) * 2005-11-23 2007-05-31 Shell Internationale Research Maatschappij B.V. A process for sequestration of carbon dioxide by mineral carbonation
EP2073914B1 (de) * 2006-09-25 2020-05-06 The Ohio State University Calcium-looping für die herstellung von hochreinem wasserstoff
DE602007010508D1 (de) * 2006-12-08 2010-12-23 Shell Int Research Verfahren zur herstellung eines gereinigten synthesegasstroms
US8328889B2 (en) * 2007-12-12 2012-12-11 Kellogg Brown & Root Llc Efficiency of gasification processes
US8091337B2 (en) * 2008-02-29 2012-01-10 Corning Incorporated Exhaust treatment device having a reactive compound and conditioning the device via endothermic reaction
US8192716B2 (en) * 2008-04-01 2012-06-05 Greatpoint Energy, Inc. Sour shift process for the removal of carbon monoxide from a gas stream
DE102008049579A1 (de) * 2008-09-30 2010-04-01 Uhde Gmbh Heißgasreinigung
US8496909B2 (en) * 2008-10-13 2013-07-30 The Ohio State University Research Foundation Calcium looping process for high purity hydrogen production integrated with capture of carbon dioxide, sulfur and halides
MX2011004326A (es) * 2008-10-22 2011-07-28 Southern Res Inst Proceso para descontaminar gas de sintesis.
WO2010075027A1 (en) * 2008-12-15 2010-07-01 Katana Energy Llc Emissions free sulfuric acid and sodium bisulfite production for desalination from gasification acid gas
US8343243B2 (en) * 2009-03-31 2013-01-01 General Electric Company Method and apparatus for blending lignite and coke slurries
JP5636048B2 (ja) * 2009-06-30 2014-12-03 シエル・インターナシヨネイル・リサーチ・マーチヤツピイ・ベー・ウイShell Internationale Research Maatschappij Beslotenvennootshap 水素に富む気体混合物を製造する方法
US8314277B2 (en) 2010-06-30 2012-11-20 Uop Llc Adsorbent for feed and products purification in benzene saturation process
US8313641B2 (en) 2010-06-30 2012-11-20 Uop Llc Adsorbent for feed and products purification in a reforming process
NL2008313C2 (en) * 2012-02-17 2013-09-02 Stichting Energie Water gas shift process.
JP2014015499A (ja) * 2012-07-06 2014-01-30 Hitachi Ltd ガス化方法とそのシステム、石炭ガス化複合発電方法とそのシステム。
FR2997414B1 (fr) * 2012-10-31 2015-10-02 Ifp Energies Now Procede ameliore de conversion d'une charge contenant de la biomasse pour la production d'hydrocarbures par voie de synthese fischer-tropsch
JP6025603B2 (ja) * 2013-02-21 2016-11-16 三菱重工業株式会社 Coシフト反応装置及びcoシフト変換方法
JP6496104B2 (ja) * 2014-02-18 2019-04-03 クラリアント触媒株式会社 ハロゲン化合物吸収剤およびそれを用いた合成ガスの製造方法
US10773958B2 (en) 2014-03-21 2020-09-15 Chevron Phillips Chemical Company Lp Processes for removing polysulfanes and elemental sulfur from hydrogen sulfide
US9605220B2 (en) * 2014-06-28 2017-03-28 Saudi Arabian Oil Company Energy efficient gasification based multi generation apparatus employing advanced process schemes and related methods
CN104084041B (zh) * 2014-07-17 2016-08-17 北京三聚创洁科技发展有限公司 一种氧化锌脱硫废剂的再生方法
DK3368472T3 (da) 2015-10-29 2020-06-15 Johnson Matthey Plc Vandgasshiftkatalysator
GB201519133D0 (en) 2015-10-29 2015-12-16 Johnson Matthey Plc Process
GB201519139D0 (en) 2015-10-29 2015-12-16 Johnson Matthey Plc Process
US9803151B2 (en) 2016-03-24 2017-10-31 General Electric Company System and method for gasification
RU2748547C2 (ru) * 2016-11-01 2021-05-26 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. Способ получения очищенного газового потока
US10213730B1 (en) 2017-08-22 2019-02-26 Saudi Arabian Oil Company Process for acid gas treatment and power generation
CN110243992B (zh) * 2018-03-09 2022-10-11 国家能源投资集团有限责任公司 催化剂评价原料气的制备方法与催化剂工业评价测试系统
US10464872B1 (en) 2018-07-31 2019-11-05 Greatpoint Energy, Inc. Catalytic gasification to produce methanol
US10344231B1 (en) 2018-10-26 2019-07-09 Greatpoint Energy, Inc. Hydromethanation of a carbonaceous feedstock with improved carbon utilization
US10435637B1 (en) 2018-12-18 2019-10-08 Greatpoint Energy, Inc. Hydromethanation of a carbonaceous feedstock with improved carbon utilization and power generation
CN111377575B (zh) * 2018-12-28 2022-09-09 中国石油化工股份有限公司 一种高硫酸盐高cod有机废水的处理方法
CA3130873A1 (en) * 2019-02-21 2020-08-27 Teknologian Tutkimuskeskus Vtt Oy Method and process arrangement for producing hydrocarbons and use
US10618818B1 (en) 2019-03-22 2020-04-14 Sure Champion Investment Limited Catalytic gasification to produce ammonia and urea
CN112316987A (zh) * 2019-08-05 2021-02-05 中国石油化工股份有限公司 一种积碳低碳烷烃脱氢催化剂的脱硫方法
CN110550601B (zh) * 2019-08-08 2023-03-14 中石化宁波工程有限公司 一种用于高浓度co原料气的变换工艺
FR3112537B1 (fr) 2020-07-14 2023-03-31 Engie Dispositif et procédé de production hybride de dihydrogène de synthèse et/ou de méthane de synthèse

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Also Published As

Publication number Publication date
DE102006017680B4 (de) 2016-07-14
CN1880412B (zh) 2012-01-11
UA91821C2 (ru) 2010-09-10
US7618558B2 (en) 2009-11-17
DE102006017680A1 (de) 2006-10-19
US20060233687A1 (en) 2006-10-19
CN1880412A (zh) 2006-12-20
RU2006112353A (ru) 2007-11-10
CA2543499A1 (en) 2006-10-15
RU2417825C2 (ru) 2011-05-10
ZA200603020B (en) 2007-06-27

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Effective date: 20200831