CA2335253A1 - Oxidation and bleaching system with enzymatically produced oxidizing agents - Google Patents

Info

Publication number

CA2335253A1

CA2335253A1 CA002335253A CA2335253A CA2335253A1 CA 2335253 A1 CA2335253 A1 CA 2335253A1 CA 002335253 A CA002335253 A CA 002335253A CA 2335253 A CA2335253 A CA 2335253A CA 2335253 A1 CA2335253 A1 CA 2335253A1

Authority

CA

Canada

Prior art keywords

acid

concentration

enzyme

component

enzyme component

Prior art date

1997-06-20

Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)

Abandoned

Links

• Espacenet
• Global Dossier
• CIPO
• Discuss

• 238000004061 bleaching Methods 0.000 title claims abstract description 105
• 238000007254 oxidation reaction Methods 0.000 title claims abstract description 65
• 239000007800 oxidant agent Substances 0.000 title claims abstract description 58
• 230000003647 oxidation Effects 0.000 title claims abstract description 53
• 102000004190 Enzymes Human genes 0.000 claims abstract description 254
• 108090000790 Enzymes Proteins 0.000 claims abstract description 254
• 239000000194 fatty acid Substances 0.000 claims abstract description 76
• 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 74
• 229930195729 fatty acid Natural products 0.000 claims abstract description 74
• 150000004665 fatty acids Chemical class 0.000 claims abstract description 66
• 238000006243 chemical reaction Methods 0.000 claims abstract description 59
• 150000002576 ketones Chemical class 0.000 claims abstract description 52
• 238000004519 manufacturing process Methods 0.000 claims abstract description 13
• 239000002243 precursor Substances 0.000 claims abstract description 12
• 150000001728 carbonyl compounds Chemical class 0.000 claims abstract description 10
• 229920006395 saturated elastomer Polymers 0.000 claims abstract 3
• -1 and/or class 3.5.5.1 Proteins 0.000 claims description 108
• 229920001131 Pulp (paper) Polymers 0.000 claims description 85
• 108090001060 Lipase Proteins 0.000 claims description 84
• 229920005610 lignin Polymers 0.000 claims description 84
• 102000004882 Lipase Human genes 0.000 claims description 83
• 239000000126 substance Substances 0.000 claims description 77
• 239000002351 wastewater Substances 0.000 claims description 72
• 239000004367 Lipase Substances 0.000 claims description 71
• 235000019421 lipase Nutrition 0.000 claims description 71
• 238000000034 method Methods 0.000 claims description 68
• 238000011282 treatment Methods 0.000 claims description 65
• 230000008569 process Effects 0.000 claims description 64
• 150000001875 compounds Chemical class 0.000 claims description 59
• 239000002253 acid Substances 0.000 claims description 53
• TUNFSRHWOTWDNC-UHFFFAOYSA-N Myristic acid Natural products CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 claims description 52
• POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 claims description 50
• 230000001590 oxidative effect Effects 0.000 claims description 47
• 230000002255 enzymatic effect Effects 0.000 claims description 45
• 239000010893 paper waste Substances 0.000 claims description 42
• QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 39
• 239000012965 benzophenone Substances 0.000 claims description 39
• 239000001301 oxygen Substances 0.000 claims description 38
• 229910052760 oxygen Inorganic materials 0.000 claims description 38
• 238000005406 washing Methods 0.000 claims description 38
• XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 37
• RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 claims description 36
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• 125000003118 aryl group Chemical group 0.000 claims description 16
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• WDGFFVCWBZVLCE-UHFFFAOYSA-N purpurogallin Chemical compound C1=CC=C(O)C(=O)C2=C1C=C(O)C(O)=C2O WDGFFVCWBZVLCE-UHFFFAOYSA-N 0.000 claims description 16
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• 125000001931 aliphatic group Chemical group 0.000 claims description 13
• IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims description 13
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• 229910052757 nitrogen Inorganic materials 0.000 claims description 13
• OEGPRYNGFWGMMV-UHFFFAOYSA-N (3,4-dimethoxyphenyl)methanol Chemical compound COC1=CC=C(CO)C=C1OC OEGPRYNGFWGMMV-UHFFFAOYSA-N 0.000 claims description 12
• 239000000470 constituent Substances 0.000 claims description 12
• 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 12
• IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 12
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• LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 10
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• 239000003077 lignite Substances 0.000 claims description 9
• QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 8
• LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 8
• ZWEHNKRNPOVVGH-UHFFFAOYSA-N Methyl ethyl ketone Natural products CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 claims description 8
• 150000001408 amides Chemical class 0.000 claims description 8
• 125000005842 heteroatom Chemical group 0.000 claims description 8
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• 241000228212 Aspergillus Species 0.000 claims description 7
• WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 claims description 7
• OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 7
• AVXURJPOCDRRFD-UHFFFAOYSA-N Hydroxylamine Chemical compound ON AVXURJPOCDRRFD-UHFFFAOYSA-N 0.000 claims description 7
• 239000000853 adhesive Substances 0.000 claims description 7
• 230000001070 adhesive effect Effects 0.000 claims description 7
• 230000029087 digestion Effects 0.000 claims description 7
• 238000011065 in-situ storage Methods 0.000 claims description 7
• 150000001451 organic peroxides Chemical class 0.000 claims description 7
• AZQWKYJCGOJGHM-UHFFFAOYSA-N 1,4-benzoquinone Chemical compound O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 claims description 6
• NGSWKAQJJWESNS-UHFFFAOYSA-N 4-coumaric acid Chemical compound OC(=O)C=CC1=CC=C(O)C=C1 NGSWKAQJJWESNS-UHFFFAOYSA-N 0.000 claims description 6
• XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 6
• WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 6
• XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 6
• 108010054320 Lignin peroxidase Proteins 0.000 claims description 6
• OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 6
• DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 6
• NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 6
• 150000001336 alkenes Chemical class 0.000 claims description 6
• 150000001491 aromatic compounds Chemical class 0.000 claims description 6
• 239000002738 chelating agent Substances 0.000 claims description 6
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• 229940042795 hydrazides for tuberculosis treatment Drugs 0.000 claims description 6
• 150000003949 imides Chemical class 0.000 claims description 6
• QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 claims description 6
• VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical compound OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 claims description 6
• RPACBEVZENYWOL-XFULWGLBSA-M sodium;(2r)-2-[6-(4-chlorophenoxy)hexyl]oxirane-2-carboxylate Chemical compound [Na+].C=1C=C(Cl)C=CC=1OCCCCCC[C@]1(C(=O)[O-])CO1 RPACBEVZENYWOL-XFULWGLBSA-M 0.000 claims description 6
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• 239000011593 sulfur Chemical group 0.000 claims description 6
• 229910052717 sulfur Chemical group 0.000 claims description 6
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• GUBGYTABKSRVRQ-CUHNMECISA-N D-Cellobiose Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@H]1O[C@@H]1[C@@H](CO)OC(O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-CUHNMECISA-N 0.000 claims description 5
• KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 claims description 5
• 101710121765 Endo-1,4-beta-xylanase Proteins 0.000 claims description 5
• WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 claims description 5
• 108010059896 Manganese peroxidase Proteins 0.000 claims description 5
• QPCDCPDFJACHGM-UHFFFAOYSA-N N,N-bis{2-[bis(carboxymethyl)amino]ethyl}glycine Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(=O)O)CCN(CC(O)=O)CC(O)=O QPCDCPDFJACHGM-UHFFFAOYSA-N 0.000 claims description 5
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• 239000012190 activator Substances 0.000 claims description 5
• WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 claims description 5
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• 239000000499 gel Substances 0.000 claims description 5
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• RWSXRVCMGQZWBV-WDSKDSINSA-N glutathione Chemical compound OC(=O)[C@@H](N)CCC(=O)N[C@@H](CS)C(=O)NCC(O)=O RWSXRVCMGQZWBV-WDSKDSINSA-N 0.000 claims description 5
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