CA2224270A1 - Shaped hydrogenation catalyst and processes for their preparation and use - Google Patents

Shaped hydrogenation catalyst and processes for their preparation and use Download PDF

Info

Publication number
CA2224270A1
CA2224270A1 CA002224270A CA2224270A CA2224270A1 CA 2224270 A1 CA2224270 A1 CA 2224270A1 CA 002224270 A CA002224270 A CA 002224270A CA 2224270 A CA2224270 A CA 2224270A CA 2224270 A1 CA2224270 A1 CA 2224270A1
Authority
CA
Canada
Prior art keywords
calcium
composition
weight
catalyst
metal
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
CA002224270A
Other languages
English (en)
French (fr)
Inventor
William J. Carrick
Brian D. Roberts
Deepak S. Thakur
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF Catalysts LLC
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Publication of CA2224270A1 publication Critical patent/CA2224270A1/en
Abandoned legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D307/38—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
    • C07D307/40—Radicals substituted by oxygen atoms
    • C07D307/42—Singly bound oxygen atoms
    • C07D307/44—Furfuryl alcohol
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/16—Clays or other mineral silicates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the alkali- or alkaline earth metals or beryllium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/72—Copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/78—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with alkali- or alkaline earth metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/31—Density
    • B01J35/32—Bulk density
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B31/00—Reduction in general
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/30—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds
    • C07C209/32—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds by reduction of nitro groups
    • C07C209/36—Preparation of compounds containing amino groups bound to a carbon skeleton by reduction of nitrogen-to-oxygen or nitrogen-to-nitrogen bonds by reduction of nitro groups by reduction of nitro groups bound to carbon atoms of six-membered aromatic rings in presence of hydrogen-containing gases and a catalyst
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/14—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group
    • C07C29/141—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group with hydrogen or hydrogen-containing gases
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/143—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of ketones
    • C07C29/145—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of ketones with hydrogen or hydrogen-containing gases
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/147—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof
    • C07C29/149—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof with hydrogen or hydrogen-containing gases
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/613—10-100 m2/g

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Dispersion Chemistry (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Furan Compounds (AREA)
CA002224270A 1995-06-15 1996-04-15 Shaped hydrogenation catalyst and processes for their preparation and use Abandoned CA2224270A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US08/490,874 1995-06-15
US08/490,874 US5977010A (en) 1995-06-15 1995-06-15 Shaped hydrogenation catalyst and processes for their preparation and use

Publications (1)

Publication Number Publication Date
CA2224270A1 true CA2224270A1 (en) 1997-01-03

Family

ID=23949860

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002224270A Abandoned CA2224270A1 (en) 1995-06-15 1996-04-15 Shaped hydrogenation catalyst and processes for their preparation and use

Country Status (10)

Country Link
US (2) US5977010A (enEXAMPLES)
EP (2) EP1300192A3 (enEXAMPLES)
JP (1) JP4020430B2 (enEXAMPLES)
AT (1) ATE245053T1 (enEXAMPLES)
CA (1) CA2224270A1 (enEXAMPLES)
DE (1) DE69629115T2 (enEXAMPLES)
DK (1) DK0831967T3 (enEXAMPLES)
ES (1) ES2202435T3 (enEXAMPLES)
IN (1) IN188606B (enEXAMPLES)
WO (1) WO1997000131A1 (enEXAMPLES)

Families Citing this family (96)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5977010A (en) * 1995-06-15 1999-11-02 Engelhard Corporation Shaped hydrogenation catalyst and processes for their preparation and use
GB9808802D0 (en) * 1998-04-24 1998-06-24 Glaxo Group Ltd Pharmaceutical formulations
US6576588B2 (en) * 2000-04-07 2003-06-10 Catalytic Distillation Technologies Process for selective hydrogenation of alkynes and catalyst therefor
EP1211234A3 (en) * 2000-11-29 2003-11-26 Samsung Electronics Co., Ltd. Process for preparing 1,3-alkandiols from 3-hydroxyesters
DE10108842A1 (de) * 2001-02-23 2002-10-02 Degussa Geformter Kupfer-Katalysator
US6897175B2 (en) * 2001-10-09 2005-05-24 General Electric Catalyst and method for the alkylation of hydroxyaromatic compounds
US6580000B1 (en) 2002-06-06 2003-06-17 Ak Research Company Process for the manufacture of alkoxysilanes and alkoxy orthosilicates
JP4032248B2 (ja) * 2003-04-25 2008-01-16 本田技研工業株式会社 自動車排ガス浄化用燃焼触媒
US7081432B2 (en) * 2003-07-10 2006-07-25 General Electric Company Alkylation catalyst and method for making alkylated phenols
US7087705B2 (en) * 2004-03-31 2006-08-08 General Electric Company Process for the monoalkylation of dihydroxy aromatic compounds
US7208646B2 (en) * 2004-05-14 2007-04-24 Catalytic Distillation Technologies Selective hydrogenation of butadiene
DE102004033556A1 (de) * 2004-07-09 2006-02-16 Basf Ag Katalysatorformkörper und Verfahren zur Hydrierung von Carbonylverbindungen
US20060173224A1 (en) * 2005-02-01 2006-08-03 Catalytic Distillation Technologies Process and catalyst for selective hydrogenation of dienes and acetylenes
KR20070115991A (ko) * 2005-03-24 2007-12-06 이데미쓰 고산 가부시키가이샤 탈황제 및 이것을 이용한 탈황 방법
JP4661676B2 (ja) * 2006-04-25 2011-03-30 堺化学工業株式会社 水素化触媒とその利用とその製造方法
US7964114B2 (en) * 2007-12-17 2011-06-21 Sud-Chemie Inc. Iron-based water gas shift catalyst
US8241697B2 (en) 2007-12-20 2012-08-14 Abbott Point Of Care Inc. Formation of immobilized biological layers for sensing
US8268604B2 (en) * 2007-12-20 2012-09-18 Abbott Point Of Care Inc. Compositions for forming immobilized biological layers for sensing
DE102008001319A1 (de) * 2008-04-22 2009-10-29 Evonik Röhm Gmbh Katalysator zur Umsetzung von Carbonsäurenitrilen
US8471075B2 (en) * 2008-07-31 2013-06-25 Celanese International Corporation Processes for making ethanol from acetic acid
US8546622B2 (en) 2008-07-31 2013-10-01 Celanese International Corporation Process for making ethanol from acetic acid using acidic catalysts
US7608744B1 (en) 2008-07-31 2009-10-27 Celanese International Corporation Ethanol production from acetic acid utilizing a cobalt catalyst
US7816565B2 (en) * 2008-07-31 2010-10-19 Celanese International Corporation Direct and selective production of acetaldehyde from acetic acid utilizing a supported metal catalyst
US8309772B2 (en) 2008-07-31 2012-11-13 Celanese International Corporation Tunable catalyst gas phase hydrogenation of carboxylic acids
US8501652B2 (en) * 2008-07-31 2013-08-06 Celanese International Corporation Catalysts for making ethanol from acetic acid
US8309773B2 (en) 2010-02-02 2012-11-13 Calanese International Corporation Process for recovering ethanol
US7863489B2 (en) 2008-07-31 2011-01-04 Celanese International Corporation Direct and selective production of ethanol from acetic acid utilizing a platinum/tin catalyst
US8680317B2 (en) 2008-07-31 2014-03-25 Celanese International Corporation Processes for making ethyl acetate from acetic acid
US20100197486A1 (en) * 2008-07-31 2010-08-05 Celanese International Corporation Catalysts for making ethyl acetate from acetic acid
US8304586B2 (en) * 2010-02-02 2012-11-06 Celanese International Corporation Process for purifying ethanol
US8637714B2 (en) 2008-07-31 2014-01-28 Celanese International Corporation Process for producing ethanol over catalysts containing platinum and palladium
US8338650B2 (en) 2008-07-31 2012-12-25 Celanese International Corporation Palladium catalysts for making ethanol from acetic acid
US8178715B2 (en) * 2008-12-31 2012-05-15 Celanese International Corporation Integrated process for the production of vinyl acetate from acetic acid via acetaldehyde
US8450535B2 (en) 2009-07-20 2013-05-28 Celanese International Corporation Ethanol production from acetic acid utilizing a cobalt catalyst
BR112012009825A2 (pt) * 2009-10-26 2016-10-18 Celanese Int Corp processos para fabricar etanol a partir de ácido acético
US8710277B2 (en) * 2009-10-26 2014-04-29 Celanese International Corporation Process for making diethyl ether from acetic acid
US8680321B2 (en) * 2009-10-26 2014-03-25 Celanese International Corporation Processes for making ethanol from acetic acid using bimetallic catalysts
EP2493606A2 (en) * 2009-10-26 2012-09-05 Celanese International Corporation Catalysts for making ethanol from acetic acid
WO2011078354A1 (ja) 2009-12-25 2011-06-30 東ソー株式会社 水素化触媒とその製造方法、及びその用途
JP5966244B2 (ja) * 2009-12-25 2016-08-10 東ソー株式会社 水素化触媒とその製造方法、及びその用途
JP5747499B2 (ja) * 2009-12-25 2015-07-15 東ソー株式会社 水素化触媒とその製造方法、およびその用途
US8211821B2 (en) * 2010-02-01 2012-07-03 Celanese International Corporation Processes for making tin-containing catalysts
US8932372B2 (en) 2010-02-02 2015-01-13 Celanese International Corporation Integrated process for producing alcohols from a mixed acid feed
US8668750B2 (en) 2010-02-02 2014-03-11 Celanese International Corporation Denatured fuel ethanol compositions for blending with gasoline or diesel fuel for use as motor fuels
US8575403B2 (en) 2010-05-07 2013-11-05 Celanese International Corporation Hydrolysis of ethyl acetate in ethanol separation process
US8460405B2 (en) 2010-02-02 2013-06-11 Celanese International Corporation Ethanol compositions
US8541633B2 (en) 2010-02-02 2013-09-24 Celanese International Corporation Processes for producing anhydrous ethanol compositions
US8858659B2 (en) * 2010-02-02 2014-10-14 Celanese International Corporation Processes for producing denatured ethanol
US8747492B2 (en) 2010-02-02 2014-06-10 Celanese International Corporation Ethanol/fuel blends for use as motor fuels
TW201136660A (en) * 2010-02-02 2011-11-01 Celanese Int Corp Catalyst supports having crystalline support modifiers
US8314272B2 (en) 2010-02-02 2012-11-20 Celanese International Corporation Process for recovering ethanol with vapor separation
WO2011097222A2 (en) * 2010-02-02 2011-08-11 Celanese International Corporation Processes for producing ethanol from acetaldehyde
US8680343B2 (en) 2010-02-02 2014-03-25 Celanese International Corporation Process for purifying ethanol
US8344186B2 (en) 2010-02-02 2013-01-01 Celanese International Corporation Processes for producing ethanol from acetaldehyde
US8222466B2 (en) 2010-02-02 2012-07-17 Celanese International Corporation Process for producing a water stream from ethanol production
US8728179B2 (en) 2010-02-02 2014-05-20 Celanese International Corporation Ethanol compositions
US8569551B2 (en) 2010-05-07 2013-10-29 Celanese International Corporation Alcohol production process integrating acetic acid feed stream comprising water from carbonylation process
US8754267B2 (en) 2010-05-07 2014-06-17 Celanese International Corporation Process for separating acetaldehyde from ethanol-containing mixtures
US8680342B2 (en) 2010-05-07 2014-03-25 Celanese International Corporation Process for recovering alcohol produced by hydrogenating an acetic acid feed stream comprising water
WO2012074841A2 (en) * 2010-11-30 2012-06-07 Basf Corporation Copper chromite hydrogenation catalysts for production of fatty alcohols
US8350098B2 (en) 2011-04-04 2013-01-08 Celanese International Corporation Ethanol production from acetic acid utilizing a molybdenum carbide catalyst
US9073816B2 (en) 2011-04-26 2015-07-07 Celanese International Corporation Reducing ethyl acetate concentration in recycle streams for ethanol production processes
US8895786B2 (en) 2011-08-03 2014-11-25 Celanese International Corporation Processes for increasing alcohol production
US8536382B2 (en) 2011-10-06 2013-09-17 Celanese International Corporation Processes for hydrogenating alkanoic acids using catalyst comprising tungsten
US8658843B2 (en) 2011-10-06 2014-02-25 Celanese International Corporation Hydrogenation catalysts prepared from polyoxometalate precursors and process for using same to produce ethanol while minimizing diethyl ether formation
US8703868B2 (en) 2011-11-28 2014-04-22 Celanese International Corporation Integrated process for producing polyvinyl alcohol or a copolymer thereof and ethanol
US9000234B2 (en) 2011-12-22 2015-04-07 Celanese International Corporation Calcination of modified support to prepare hydrogenation catalysts
US9233899B2 (en) 2011-12-22 2016-01-12 Celanese International Corporation Hydrogenation catalysts having an amorphous support
JP5817507B2 (ja) * 2011-12-22 2015-11-18 東ソー株式会社 水素化触媒組成物成型体、及びその製造方法
US8575406B2 (en) 2011-12-22 2013-11-05 Celanese International Corporation Catalysts having promoter metals and process for producing ethanol
US8907142B2 (en) 2011-12-29 2014-12-09 Celanese International Corporation Process for promoting catalyst activity for ethyl acetate conversion
US9333496B2 (en) 2012-02-29 2016-05-10 Celanese International Corporation Cobalt/tin catalyst for producing ethanol
US9079172B2 (en) 2012-03-13 2015-07-14 Celanese International Corporation Promoters for cobalt-tin catalysts for reducing alkanoic acids
US8455702B1 (en) 2011-12-29 2013-06-04 Celanese International Corporation Cobalt and tin catalysts for producing ethanol
CN104039446B (zh) 2012-01-06 2016-12-28 国际人造丝公司 加氢催化剂
US9024086B2 (en) 2012-01-06 2015-05-05 Celanese International Corporation Hydrogenation catalysts with acidic sites
US8981164B2 (en) 2012-01-06 2015-03-17 Celanese International Corporation Cobalt and tin hydrogenation catalysts
US8802588B2 (en) 2012-01-23 2014-08-12 Celanese International Corporation Bismuth catalyst composition and process for manufacturing ethanol mixture
US9051235B2 (en) 2012-02-07 2015-06-09 Celanese International Corporation Process for producing ethanol using a molar excess of hydrogen
US9050585B2 (en) 2012-02-10 2015-06-09 Celanese International Corporation Chemisorption of ethyl acetate during hydrogenation of acetic acid to ethanol
US9126194B2 (en) 2012-02-29 2015-09-08 Celanese International Corporation Catalyst having support containing tin and process for manufacturing ethanol
US8927786B2 (en) 2012-03-13 2015-01-06 Celanese International Corporation Ethanol manufacturing process over catalyst having improved radial crush strength
US9073042B2 (en) 2012-03-14 2015-07-07 Celanese International Corporation Acetic acid hydrogenation over a group VIII metal calcined catalyst having a secondary promoter
US8536383B1 (en) 2012-03-14 2013-09-17 Celanese International Corporation Rhodium/tin catalysts and processes for producing ethanol
US20140051894A1 (en) * 2012-08-15 2014-02-20 Celanese International Corporation Silica Enhanced Support for Hydrogenation Catalysts and Processes for Producing Ethanol
US8962508B2 (en) * 2012-08-22 2015-02-24 Basf Se Process for treating shaped catalyst bodies and shaped catalyst bodies having increased mechanical strength
CN104602810B (zh) * 2012-09-03 2018-06-08 株式会社可乐丽 铜系催化剂前体及其制造方法、以及氢化方法
US8772553B2 (en) 2012-10-26 2014-07-08 Celanese International Corporation Hydrogenation reaction conditions for producing ethanol
WO2015137301A1 (ja) * 2014-03-11 2015-09-17 東ソー株式会社 芳香族ニトロ化合物用水素化触媒とその製造方法
WO2016025383A1 (en) * 2014-08-11 2016-02-18 Basf Corporation Hydrogenation catalysts
DE102014013530A1 (de) 2014-09-12 2016-03-17 Clariant International Ltd. Extrudierter Cu-Al-Mn-Hydrierkatalysator
WO2016154514A1 (en) * 2015-03-26 2016-09-29 Basf Corporation Hydrogenolysis catalysts with high acid tolerance
CN110871085B (zh) * 2018-08-30 2022-11-29 淄博张店东方化学股份有限公司 一种糠醛催化加氢制备糠醇的负载型催化剂及其制备方法与应用
EP3890879A1 (en) 2018-12-03 2021-10-13 Basf Corporation Highly active and highly selective copper extrudate catalysts
EP3891115B1 (en) * 2018-12-03 2024-07-24 Basf Se Process for producing 1-(4-isobutylphenyl)ethanol by hydrogenation of 1-(4-isobutyl-phenyl)ethanone in the presence of a catalyst composition comprising copper
TWI704132B (zh) * 2019-02-13 2020-09-11 台灣中油股份有限公司 苯多羧酸酯氫化反應形成脂環族多羧酸酯之氫化方法

Family Cites Families (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB888775A (en) * 1957-11-11 1962-02-07 Leuna Werke Veb Process for the production of highly active hydrogenation catalysts from carbonates and hydroxides
US3100234A (en) * 1961-05-22 1963-08-06 Monsanto Chemicals Dehydrogenation catalyst
US3779946A (en) * 1970-08-05 1973-12-18 Bayer Ag Production of transition metal-containing supported catalysts
JPS5516415B2 (enEXAMPLES) * 1973-09-06 1980-05-01
US4188365A (en) * 1976-04-16 1980-02-12 Mitsui Petrochemical Industries, Ltd. Process for catalytic vapor phase reduction of nitrogen oxides and catalyst composition used therefor
US4283581A (en) * 1978-02-24 1981-08-11 Chevron Research Company Hydrogenation process
CA1248285A (en) * 1983-07-07 1989-01-03 Vincent L. Hughes Fully saturated petroleum resin and hot melt pressure sensitive adhesive formulations utilizing same as tackifier
US4666879A (en) * 1985-09-11 1987-05-19 Harshaw/Filtrol Partnership Extruded copper chromite-alumina hydrogenation catalyst
US4762817A (en) * 1986-11-03 1988-08-09 Union Carbide Corporation Aldehyde hydrogenation catalyst
GB8808239D0 (en) * 1988-04-08 1988-05-11 Knowsley Contract Chem Ltd Catalyst & its use in alkylation & acylation
US4929777A (en) * 1989-02-13 1990-05-29 Eastman Kodak Company Catalyst compositions and the use thereof in the hydrogenation of carboxylic acid esters
US5043509A (en) * 1989-08-18 1991-08-27 Uop Shaped catalyst particles utilizable for the conversion of organic compounds
US5155086A (en) * 1989-09-12 1992-10-13 Engelhard Corporation Hydrogenation catalyst, process for preparing and process of using said catalyst
US5345005A (en) * 1989-09-12 1994-09-06 Engelhard Corporation Hydrogenation catalyst, process for preparing and process of using said catalyst
CA2026275C (en) * 1989-10-17 2000-12-05 Deepak S. Thakur Hydrogenation catalyst, process for preparing and process of using said catalyst
US5008235A (en) * 1989-12-21 1991-04-16 Union Carbide Chemicals And Plastics Technology Corporation Catalysts of Cu-Al-third metal for hydrogenation
DE4025245A1 (de) * 1990-08-09 1992-02-13 Huels Chemische Werke Ag Verfahren zur herstellung von gesaettigten alkoholen aus aldehyden
US5124295A (en) * 1990-12-13 1992-06-23 Engelhard Corporation Copper chromite catalyst and process for preparation said catalyst
US5134108A (en) * 1991-05-22 1992-07-28 Engelhard Corporation Process for preparing catalyst with copper or zinc and with chromium, molybdenum, tungsten, or vanadium, and product thereof
US5243095A (en) * 1992-04-24 1993-09-07 Engelhard Corporation Hydrogenation catalyst, process for preparing and process for using said catalyst
EP0658155A4 (en) * 1993-07-07 1996-01-24 Bp Chem Int Ltd METHOD FOR CONVERTING ACETATES IN ETHER.
DE4403187C1 (de) * 1994-02-02 1995-09-28 Degussa Geformter Kupfer-Katalysator für die selektive Hydrierung von Furfural zu Furfurylalkohol
US5977010A (en) * 1995-06-15 1999-11-02 Engelhard Corporation Shaped hydrogenation catalyst and processes for their preparation and use
US5945570A (en) * 1998-10-29 1999-08-31 Arhancet; Juan Pedro Catalyst and process for preparing 1,3-propanediol

Also Published As

Publication number Publication date
ATE245053T1 (de) 2003-08-15
EP1300192A2 (en) 2003-04-09
ES2202435T3 (es) 2004-04-01
IN188606B (enEXAMPLES) 2002-10-19
DE69629115D1 (de) 2003-08-21
DE69629115T2 (de) 2004-06-03
EP0831967B1 (en) 2003-07-16
US6049008A (en) 2000-04-11
DK0831967T3 (da) 2003-09-29
JPH11507867A (ja) 1999-07-13
WO1997000131A1 (en) 1997-01-03
EP0831967A1 (en) 1998-04-01
US5977010A (en) 1999-11-02
EP1300192A3 (en) 2006-10-11
JP4020430B2 (ja) 2007-12-12

Similar Documents

Publication Publication Date Title
US5977010A (en) Shaped hydrogenation catalyst and processes for their preparation and use
US7459571B2 (en) Catalyst extrudates based on copper oxide and their use for hydrogenating carbonyl compounds
KR101518083B1 (ko) 수소화 촉매 및 카르보닐 화합물의 수소화에 의한 알콜의 제조 방법
KR920001303B1 (ko) 개선된 알데하이드 수소화 방법
JP3271969B2 (ja) 水素化触媒、該触媒の製造方法及び使用方法
KR20010041595A (ko) 카르보닐 화합물의 수소화 방법
CN102099320B (zh) 通过裂化在制造过程中形成的高沸物来获得新戊二醇的方法
TWI490034B (zh) 製備具有增強氫化活性之經承載氫化觸媒之方法
EP0175558A1 (en) Process for the vapor phase hydrogenation of carboxylic acids to esters and alcohols
EP0563327B1 (en) Copper chromite catalyst and process for preparing said catalyst
US11077428B2 (en) Hydrogenolysis catalysts with high acid tolerance
US4666879A (en) Extruded copper chromite-alumina hydrogenation catalyst
GB2525746A (en) Hydrogenation catalyst and process for production thereof by the use of uncalcined starting material
EP3946723B1 (en) Copper extrudate catalyst and applications for hydrogenation and hydrogenolysis
KR101932780B1 (ko) 알데히드를 알코올로 수소화하기 위한 촉진된 구리/아연 촉매
US5672558A (en) Formed compositions
WO2012074841A2 (en) Copper chromite hydrogenation catalysts for production of fatty alcohols
EP3890879A1 (en) Highly active and highly selective copper extrudate catalysts
DE19726666A1 (de) Verfahren zur Addition von Hydroxylgruppen enthaltenden Verbindungen an Alkine oder Allene
WO2023246892A1 (en) Shaped catalyst body
KR20040090658A (ko) 무수프탈산으로부터 프탈라이드를 제조하는 방법

Legal Events

Date Code Title Description
FZDE Discontinued