CA2111192A1 - Supported high activity polyolefin catalyst component with regular distribution of magnesium values provided utilizing a controlled drying protocol - Google Patents

Supported high activity polyolefin catalyst component with regular distribution of magnesium values provided utilizing a controlled drying protocol

Info

Publication number
CA2111192A1
CA2111192A1 CA002111192A CA2111192A CA2111192A1 CA 2111192 A1 CA2111192 A1 CA 2111192A1 CA 002111192 A CA002111192 A CA 002111192A CA 2111192 A CA2111192 A CA 2111192A CA 2111192 A1 CA2111192 A1 CA 2111192A1
Authority
CA
Canada
Prior art keywords
support
solvent
magnesium
catalyst component
halides
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
CA002111192A
Other languages
English (en)
French (fr)
Inventor
Charles K. Buehler
Albert P. Masino
Raghu Menon
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Millennium Petrochemicals Inc
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Publication of CA2111192A1 publication Critical patent/CA2111192A1/en
Abandoned legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652—Pretreating with metals or metal-containing compounds
    • C08F4/656—Pretreating with metals or metal-containing compounds with silicon or compounds thereof
    • C08F4/6565—Pretreating with metals or metal-containing compounds with silicon or compounds thereof and magnesium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652—Pretreating with metals or metal-containing compounds
    • C08F4/656—Pretreating with metals or metal-containing compounds with silicon or compounds thereof
    • C08F4/6567—Pretreating with metals or metal-containing compounds with silicon or compounds thereof and aluminium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652—Pretreating with metals or metal-containing compounds
    • C08F4/657—Pretreating with metals or metal-containing compounds with metals or metal-containing compounds, not provided for in groups C08F4/653 - C08F4/656
    • C08F4/6578—Pretreating with metals or metal-containing compounds with metals or metal-containing compounds, not provided for in groups C08F4/653 - C08F4/656 and silicon or compounds thereof

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
CA002111192A 1991-06-20 1992-06-19 Supported high activity polyolefin catalyst component with regular distribution of magnesium values provided utilizing a controlled drying protocol Abandoned CA2111192A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US717,956 1991-06-20
US07/717,956 US5145821A (en) 1990-05-09 1991-06-20 Silica supported polymerization catalyst system

Publications (1)

Publication Number Publication Date
CA2111192A1 true CA2111192A1 (en) 1993-01-07

Family

ID=24884208

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002111192A Abandoned CA2111192A1 (en) 1991-06-20 1992-06-19 Supported high activity polyolefin catalyst component with regular distribution of magnesium values provided utilizing a controlled drying protocol

Country Status (14)

Country Link
US (1) US5145821A (enExample)
EP (1) EP0592570A4 (enExample)
JP (1) JPH06508653A (enExample)
KR (1) KR940701411A (enExample)
CN (1) CN1069739A (enExample)
AU (1) AU659660B2 (enExample)
BR (1) BR9206177A (enExample)
CA (1) CA2111192A1 (enExample)
FI (1) FI935634L (enExample)
MX (1) MX9203079A (enExample)
NO (1) NO934679L (enExample)
TW (1) TW216424B (enExample)
WO (1) WO1993000368A1 (enExample)
ZA (1) ZA924534B (enExample)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5221650A (en) * 1987-09-21 1993-06-22 Quantum Chemical Corporation Supported high activity polypropylene catalyst component with regular distribution of magnesium values provided utilizing a controlled drying protocol
US5275991A (en) * 1987-09-21 1994-01-04 Quantum Chemical Corporation Supported high activity polyolefin catalyst component with regular distribution of magnesium values provided utilizing a controlled drying protocol
US6291384B1 (en) 1991-11-06 2001-09-18 Mobil Oil Corporation High activity catalyst prepared with alkoxysilanes
US5470812A (en) * 1991-11-06 1995-11-28 Mobil Oil Corporation High activity polyethylene catalysts prepared with alkoxysilane reagents
US5939348A (en) * 1991-11-06 1999-08-17 Mobil Oil Corporation Catalyst for the manufacture of polythylene with a narrow molecular weight distribution
DE69415829T2 (de) * 1993-11-18 1999-05-20 Mobil Oil Corp., Fairfax, Va. Katalysatorzusammensetzung für die copolymerisation von ethylen
US5661097A (en) * 1994-08-12 1997-08-26 The Dow Chemical Company Supported olefin polymerization catalyst
JP3866478B2 (ja) * 2000-03-28 2007-01-10 株式会社東芝 半導体集積回路
RU2005135113A (ru) * 2003-04-15 2006-05-10 Базелль Полиолефине Итали с.р.л. (IT) Каталитические системы типа циглера-натта и способ их получения
DE10317395A1 (de) * 2003-04-15 2004-11-04 Basell Polyolefine Gmbh Katalysatorsysteme vom Typ der Ziegler-Natta-Katalysatoren und ein Verfahren zu deren Herstellung
DE102008047796A1 (de) 2008-09-17 2010-04-15 Siemens Aktiengesellschaft Vorrichtung zur Erzeugung von breitbandigem Schall im Hörbereich des Menschen
EP2643362B1 (en) 2010-11-26 2018-03-14 Saudi Basic Industries Corporation Process for making a solid catalyst component for ethylene polymerization and copolymerization
KR102053117B1 (ko) * 2012-03-05 2019-12-06 유니베이션 테크놀로지즈, 엘엘씨 촉매 조성물의 제조 방법 및 그로부터 생산된 중합체 생성물
CN105344382A (zh) * 2015-11-30 2016-02-24 南京威安新材料科技有限公司 一种高效催化剂
CN120404466B (zh) * 2025-07-03 2025-09-23 浙江华川实业集团有限公司 造纸白水中胶黏物连续监测提取系统及提取胶黏物的应用

Family Cites Families (38)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3135809A (en) * 1960-07-21 1964-06-02 Southern Res Inst Isomerization process
NL162661B (nl) * 1968-11-21 1980-01-15 Montedison Spa Werkwijze om een katalysator te bereiden voor de poly- merisatie van alkenen-1.
YU35844B (en) * 1968-11-25 1981-08-31 Montedison Spa Process for obtaining catalysts for the polymerization of olefines
US3591656A (en) * 1969-01-24 1971-07-06 Exxon Research Engineering Co Heterogeneous catalyst process
US4156063A (en) * 1971-06-25 1979-05-22 Montecanti Edison, S.p.A. Process for the stereoregular polymerization of alpha olefins
IT1054410B (it) * 1975-11-21 1981-11-10 Mitsui Petrochemical Ind Catalizzatori per la polimerizzazione delle alfa olefine
GB1603724A (en) * 1977-05-25 1981-11-25 Montedison Spa Components and catalysts for the polymerisation of alpha-olefins
US4565795A (en) * 1979-12-07 1986-01-21 Phillips Petroleum Company Polymerization and catalysts
US4530913A (en) * 1980-01-16 1985-07-23 Chemplex Company Polymerization catalyst and method
IT1132230B (it) * 1980-07-24 1986-06-25 Anic Spa Procedimento per la produzione dell'enzima colesterolo-esterasi e per idrolisi degli esteri con acidi grassi del colesterolo mediante l'impiego dell'enzima stesso
EP0052471B1 (en) * 1980-11-11 1985-09-18 Asahi Kasei Kogyo Kabushiki Kaisha Process and catalyst for polymerization of olefins
US4394291A (en) * 1981-03-04 1983-07-19 Phillips Petroleum Company Polyolefin polymerization process and catalyst
JPS58162607A (ja) * 1982-03-19 1983-09-27 Mitsui Toatsu Chem Inc α−オレフインの重合方法
CA1225080A (en) * 1983-01-28 1987-08-04 Gil R. Hawley Polyolefin polymerization process and catalyst
JPS59221309A (ja) * 1983-05-31 1984-12-12 Toa Nenryo Kogyo Kk オレフイン重合用触媒成分
US4508843A (en) * 1983-08-08 1985-04-02 Exxon Research & Engineering Co. Supported polyolefin catalyst for the polymerization of ethylene under high temperatures
US4503159A (en) * 1983-08-19 1985-03-05 Phillips Petroleum Company Polyolefin polymerization process and catalyst
US4612299A (en) * 1984-07-09 1986-09-16 Amoco Corporation Magnesium carboxylate supports
US4544716A (en) * 1984-06-22 1985-10-01 Phillips Petroleum Company Polyolefin polymerization process and catalyst
JPH0655783B2 (ja) * 1984-07-31 1994-07-27 東燃株式会社 オレフイン重合用触媒成分
JPH0674292B2 (ja) * 1984-11-30 1994-09-21 東燃株式会社 エチレン重合用触媒成分の製造法
JPH072776B2 (ja) * 1985-01-28 1995-01-18 東燃株式会社 オレフイン重合用触媒成分
CA1263370A (en) * 1985-03-25 1989-11-28 Masaaki Katao CATALYST AND PROCESS FOR PRODUCING .alpha.-OLEFIN POLYMERS USING THE SAME
DE3680394D1 (de) * 1985-06-17 1991-08-29 Idemitsu Petrochemical Co Verfahren zur herstellung von polyolefinen.
US4738942A (en) * 1985-12-23 1988-04-19 Mobil Oil Corporation Catalyst composition for polymerizing alpha-olefin polymers of relatively narrow molecular weight distribution and high melt index
EP0240254A3 (en) * 1986-03-31 1989-07-26 Exxon Chemical Patents Inc. Polymerization catalyst, production and use
JPS62256802A (ja) * 1986-04-28 1987-11-09 Sumitomo Chem Co Ltd α−オレフイン重合体の製造法
ZA882999B (en) * 1987-05-04 1988-11-01 Shell Oil Company Preparation of olefin polymerization catalyst component
DE3730022A1 (de) * 1987-09-08 1989-03-16 Basf Ag Verfahren zum herstellen von homo- und copolymerisaten des propens mittels eines ziegler-natta-katalysatorsystems
JPH0780968B2 (ja) * 1987-09-09 1995-08-30 住友化学工業株式会社 オレフィン重合体の製造法
US5034365A (en) * 1990-05-09 1991-07-23 Quantum Chemical Corporation Silica supported polymerization catalyst
US4950631A (en) * 1987-09-21 1990-08-21 Quantum Chemical Corporation Modified silica based catalyst
CA1329801C (en) * 1987-09-21 1994-05-24 Charles K. Buehler Modified silica based catalyst
US5275991A (en) * 1987-09-21 1994-01-04 Quantum Chemical Corporation Supported high activity polyolefin catalyst component with regular distribution of magnesium values provided utilizing a controlled drying protocol
US4950630A (en) * 1987-11-30 1990-08-21 Toa Nenryo Kogyo, K.K. Method for production of catalyst component for olefin polymerization
DE3819577A1 (de) * 1988-06-09 1989-12-14 Hoechst Ag Verfahren zur herstellung eines polypropylens
US5037789A (en) * 1990-03-23 1991-08-06 Quantum Chemical Corporation Non-supported catalyst
US5232998A (en) * 1990-05-09 1993-08-03 Quantum Chemical Corporation Olefin polymerization using silica supported catalyst

Also Published As

Publication number Publication date
FI935634A0 (fi) 1993-12-15
TW216424B (enExample) 1993-11-21
WO1993000368A1 (en) 1993-01-07
BR9206177A (pt) 1994-12-13
FI935634A7 (fi) 1994-02-11
CN1069739A (zh) 1993-03-10
NO934679D0 (no) 1993-12-17
ZA924534B (en) 1993-03-31
MX9203079A (es) 1994-08-31
NO934679L (no) 1994-02-04
EP0592570A1 (en) 1994-04-20
EP0592570A4 (en) 1994-11-17
JPH06508653A (ja) 1994-09-29
AU2258792A (en) 1993-01-25
US5145821A (en) 1992-09-08
KR940701411A (ko) 1994-05-28
FI935634L (fi) 1994-02-11
AU659660B2 (en) 1995-05-25

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Legal Events

Date Code Title Description
FZDE Discontinued
FZDE Discontinued

Effective date: 19970619