CA2058331A1 - Core-shell polymer - Google Patents
Core-shell polymerInfo
- Publication number
- CA2058331A1 CA2058331A1 CA002058331A CA2058331A CA2058331A1 CA 2058331 A1 CA2058331 A1 CA 2058331A1 CA 002058331 A CA002058331 A CA 002058331A CA 2058331 A CA2058331 A CA 2058331A CA 2058331 A1 CA2058331 A1 CA 2058331A1
- Authority
- CA
- Canada
- Prior art keywords
- core
- shell
- polymer
- oxygenic
- group
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 229920000642 polymer Polymers 0.000 title claims abstract description 69
- 239000011258 core-shell material Substances 0.000 title claims abstract description 38
- 229920006324 polyoxymethylene Polymers 0.000 claims abstract description 49
- 229930182556 Polyacetal Natural products 0.000 claims abstract description 43
- 239000011347 resin Substances 0.000 claims abstract description 26
- 229920005989 resin Polymers 0.000 claims abstract description 26
- 239000000203 mixture Substances 0.000 claims abstract description 22
- 239000004094 surface-active agent Substances 0.000 claims abstract description 15
- 229920001971 elastomer Polymers 0.000 claims abstract description 13
- 229920006163 vinyl copolymer Polymers 0.000 claims abstract description 12
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims abstract description 9
- 125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 claims abstract description 8
- 239000000178 monomer Substances 0.000 claims description 21
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 17
- 238000000034 method Methods 0.000 claims description 12
- 238000007720 emulsion polymerization reaction Methods 0.000 claims description 11
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 9
- 229920002554 vinyl polymer Polymers 0.000 claims description 9
- 125000000217 alkyl group Chemical group 0.000 claims description 8
- 125000004432 carbon atom Chemical group C* 0.000 claims description 6
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 claims description 6
- 239000003999 initiator Substances 0.000 claims description 6
- 239000011342 resin composition Substances 0.000 claims description 6
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 6
- 229920002818 (Hydroxyethyl)methacrylate Polymers 0.000 claims description 5
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical group CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 claims description 5
- 229920001577 copolymer Polymers 0.000 claims description 5
- 150000001993 dienes Chemical class 0.000 claims description 3
- 229920001519 homopolymer Polymers 0.000 claims description 3
- 125000005250 alkyl acrylate group Chemical group 0.000 claims description 2
- 150000002978 peroxides Chemical class 0.000 claims description 2
- 239000002954 polymerization reaction product Substances 0.000 claims 3
- 239000011541 reaction mixture Substances 0.000 claims 3
- 230000001747 exhibiting effect Effects 0.000 claims 2
- 239000002736 nonionic surfactant Substances 0.000 claims 2
- 239000000155 melt Substances 0.000 claims 1
- 239000003505 polymerization initiator Substances 0.000 claims 1
- 239000003638 chemical reducing agent Substances 0.000 abstract 1
- 150000002500 ions Chemical class 0.000 description 26
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 10
- 238000006116 polymerization reaction Methods 0.000 description 10
- -1 acryl Chemical group 0.000 description 8
- 229910021641 deionized water Inorganic materials 0.000 description 7
- 150000001450 anions Chemical class 0.000 description 6
- 238000000465 moulding Methods 0.000 description 6
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 5
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 4
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 4
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 4
- 229910052717 sulfur Inorganic materials 0.000 description 4
- 239000011593 sulfur Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 239000004925 Acrylic resin Substances 0.000 description 3
- 229920000178 Acrylic resin Polymers 0.000 description 3
- 241001093575 Alma Species 0.000 description 3
- 101100536354 Drosophila melanogaster tant gene Proteins 0.000 description 3
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 230000009467 reduction Effects 0.000 description 3
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 2
- 101150039033 Eci2 gene Proteins 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 125000000129 anionic group Chemical group 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 239000000706 filtrate Substances 0.000 description 2
- PYGSKMBEVAICCR-UHFFFAOYSA-N hexa-1,5-diene Chemical group C=CCCC=C PYGSKMBEVAICCR-UHFFFAOYSA-N 0.000 description 2
- 230000001976 improved effect Effects 0.000 description 2
- 239000011256 inorganic filler Substances 0.000 description 2
- 229910003475 inorganic filler Inorganic materials 0.000 description 2
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 2
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- 239000008188 pellet Substances 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- DNXHEGUUPJUMQT-UHFFFAOYSA-N (+)-estrone Natural products OC1=CC=C2C3CCC(C)(C(CC4)=O)C4C3CCC2=C1 DNXHEGUUPJUMQT-UHFFFAOYSA-N 0.000 description 1
- IFKPLJWIEQBPGG-QGZVFWFLSA-N (5s)-6-(dimethylamino)-5-methyl-4,4-diphenylhexan-3-one Chemical compound C=1C=CC=CC=1C([C@H](C)CN(C)C)(C(=O)CC)C1=CC=CC=C1 IFKPLJWIEQBPGG-QGZVFWFLSA-N 0.000 description 1
- FCBZNZYQLJTCKR-UHFFFAOYSA-N 1-prop-2-enoxyethanol Chemical compound CC(O)OCC=C FCBZNZYQLJTCKR-UHFFFAOYSA-N 0.000 description 1
- STMDPCBYJCIZOD-UHFFFAOYSA-N 2-(2,4-dinitroanilino)-4-methylpentanoic acid Chemical compound CC(C)CC(C(O)=O)NC1=CC=C([N+]([O-])=O)C=C1[N+]([O-])=O STMDPCBYJCIZOD-UHFFFAOYSA-N 0.000 description 1
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 1
- 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 description 1
- OZAIFHULBGXAKX-VAWYXSNFSA-N AIBN Substances N#CC(C)(C)\N=N\C(C)(C)C#N OZAIFHULBGXAKX-VAWYXSNFSA-N 0.000 description 1
- 101150106671 COMT gene Proteins 0.000 description 1
- GAWIXWVDTYZWAW-UHFFFAOYSA-N C[CH]O Chemical group C[CH]O GAWIXWVDTYZWAW-UHFFFAOYSA-N 0.000 description 1
- 101100178984 Caenorhabditis elegans hyl-2 gene Proteins 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 102100024133 Coiled-coil domain-containing protein 50 Human genes 0.000 description 1
- 229920005177 Duracon® POM Polymers 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- HSRJKNPTNIJEKV-UHFFFAOYSA-N Guaifenesin Chemical compound COC1=CC=CC=C1OCC(O)CO HSRJKNPTNIJEKV-UHFFFAOYSA-N 0.000 description 1
- 101000910772 Homo sapiens Coiled-coil domain-containing protein 50 Proteins 0.000 description 1
- 101000998897 Homo sapiens Serine protease HTRA3 Proteins 0.000 description 1
- 241000521257 Hydrops Species 0.000 description 1
- 229920006063 Lamide® Polymers 0.000 description 1
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 description 1
- 241001274660 Modulus Species 0.000 description 1
- 241000907681 Morpho Species 0.000 description 1
- 206010030113 Oedema Diseases 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- 101150012695 Procr gene Proteins 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 1
- 235000014443 Pyrus communis Nutrition 0.000 description 1
- 101150107341 RERE gene Proteins 0.000 description 1
- 102100033197 Serine protease HTRA3 Human genes 0.000 description 1
- 208000001203 Smallpox Diseases 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 1
- 241000534944 Thia Species 0.000 description 1
- 241000736892 Thujopsis dolabrata Species 0.000 description 1
- 241000870995 Variola Species 0.000 description 1
- JNDDXAUSKFKLLR-DFHCBJLBSA-N [(z)-4-[(4-amino-2-methylpyrimidin-5-yl)methyl-formylamino]-3-benzoylsulfanylpent-3-enyl] benzoate;2-ethoxybenzamide;n-(4-ethoxyphenyl)-3-hydroxybutanamide;1,3,7-trimethylpurine-2,6-dione Chemical compound CCOC1=CC=CC=C1C(N)=O.CN1C(=O)N(C)C(=O)C2=C1N=CN2C.CCOC1=CC=C(NC(=O)CC(C)O)C=C1.C=1C=CC=CC=1C(=O)OCC\C(SC(=O)C=1C=CC=CC=1)=C(/C)N(C=O)CC1=CN=C(C)N=C1N JNDDXAUSKFKLLR-DFHCBJLBSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- 125000003368 amide group Chemical group 0.000 description 1
- 229920006125 amorphous polymer Polymers 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- WDIHJSXYQDMJHN-UHFFFAOYSA-L barium chloride Chemical compound [Cl-].[Cl-].[Ba+2] WDIHJSXYQDMJHN-UHFFFAOYSA-L 0.000 description 1
- 229910001626 barium chloride Inorganic materials 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- NEHMKBQYUWJMIP-UHFFFAOYSA-N chloromethane Chemical compound ClC NEHMKBQYUWJMIP-UHFFFAOYSA-N 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 101150027734 cript gene Proteins 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- SDIXRDNYIMOKSG-UHFFFAOYSA-L disodium methyl arsenate Chemical compound [Na+].[Na+].C[As]([O-])([O-])=O SDIXRDNYIMOKSG-UHFFFAOYSA-L 0.000 description 1
- RXPRRQLKFXBCSJ-UHFFFAOYSA-N dl-Vincamin Natural products C1=CC=C2C(CCN3CCC4)=C5C3C4(CC)CC(O)(C(=O)OC)N5C2=C1 RXPRRQLKFXBCSJ-UHFFFAOYSA-N 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229920006351 engineering plastic Polymers 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- KVFIJIWMDBAGDP-UHFFFAOYSA-N ethylpyrazine Chemical compound CCC1=CN=CC=N1 KVFIJIWMDBAGDP-UHFFFAOYSA-N 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 101150032210 hel-1 gene Proteins 0.000 description 1
- ACCCMOQWYVYDOT-UHFFFAOYSA-N hexane-1,1-diol Chemical compound CCCCCC(O)O ACCCMOQWYVYDOT-UHFFFAOYSA-N 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 229920000126 latex Polymers 0.000 description 1
- AIHDCSAXVMAMJH-GFBKWZILSA-N levan Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)OC[C@@H]1[C@@H](O)[C@H](O)[C@](CO)(CO[C@@H]2[C@H]([C@H](O)[C@@](O)(CO)O2)O)O1 AIHDCSAXVMAMJH-GFBKWZILSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 125000005641 methacryl group Chemical group 0.000 description 1
- MYWUZJCMWCOHBA-VIFPVBQESA-N methamphetamine Chemical compound CN[C@@H](C)CC1=CC=CC=C1 MYWUZJCMWCOHBA-VIFPVBQESA-N 0.000 description 1
- BQJCRHHNABKAKU-KBQPJGBKSA-N morphine Chemical compound O([C@H]1[C@H](C=C[C@H]23)O)C4=C5[C@@]12CCN(C)[C@@H]3CC5=CC=C4O BQJCRHHNABKAKU-KBQPJGBKSA-N 0.000 description 1
- HVFSJXUIRWUHRG-UHFFFAOYSA-N oic acid Natural products C1CC2C3CC=C4CC(OC5C(C(O)C(O)C(CO)O5)O)CC(O)C4(C)C3CCC2(C)C1C(C)C(O)CC(C)=C(C)C(=O)OC1OC(COC(C)=O)C(O)C(O)C1OC(C(C1O)O)OC(COC(C)=O)C1OC1OC(CO)C(O)C(O)C1O HVFSJXUIRWUHRG-UHFFFAOYSA-N 0.000 description 1
- 239000012766 organic filler Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- RPQRDASANLAFCM-UHFFFAOYSA-N oxiran-2-ylmethyl prop-2-enoate Chemical compound C=CC(=O)OCC1CO1 RPQRDASANLAFCM-UHFFFAOYSA-N 0.000 description 1
- 125000005704 oxymethylene group Chemical group [H]C([H])([*:2])O[*:1] 0.000 description 1
- JRKICGRDRMAZLK-UHFFFAOYSA-L peroxydisulfate Chemical compound [O-]S(=O)(=O)OOS([O-])(=O)=O JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 1
- 229920000193 polymethacrylate Polymers 0.000 description 1
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 description 1
- 229920000136 polysorbate Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- FBCQUCJYYPMKRO-UHFFFAOYSA-N prop-2-enyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC=C FBCQUCJYYPMKRO-UHFFFAOYSA-N 0.000 description 1
- IOVGROKTTNBUGK-SJCJKPOMSA-N ritodrine Chemical compound N([C@@H](C)[C@H](O)C=1C=CC(O)=CC=1)CCC1=CC=C(O)C=C1 IOVGROKTTNBUGK-SJCJKPOMSA-N 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical class S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- QXJQHYBHAIHNGG-UHFFFAOYSA-N trimethylolethane Chemical compound OCC(C)(CO)CO QXJQHYBHAIHNGG-UHFFFAOYSA-N 0.000 description 1
- RXPRRQLKFXBCSJ-GIVPXCGWSA-N vincamine Chemical compound C1=CC=C2C(CCN3CCC4)=C5[C@@H]3[C@]4(CC)C[C@](O)(C(=O)OC)N5C2=C1 RXPRRQLKFXBCSJ-GIVPXCGWSA-N 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F279/00—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00
- C08F279/02—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00 on to polymers of conjugated dienes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
- C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
- C08F265/06—Polymerisation of acrylate or methacrylate esters on to polymers thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F291/00—Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds according to more than one of the groups C08F251/00 - C08F289/00
- C08F291/02—Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds according to more than one of the groups C08F251/00 - C08F289/00 on to elastomers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L59/00—Compositions of polyacetals; Compositions of derivatives of polyacetals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/04—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to rubbers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Graft Or Block Polymers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP40926790 | 1990-12-28 | ||
| JP409267/90 | 1990-12-28 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA2058331A1 true CA2058331A1 (en) | 1992-06-29 |
Family
ID=18518614
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002058331A Abandoned CA2058331A1 (en) | 1990-12-28 | 1991-12-23 | Core-shell polymer |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US5484845A (show.php) |
| EP (1) | EP0494534B1 (show.php) |
| JP (1) | JP2999318B2 (show.php) |
| KR (1) | KR950011900B1 (show.php) |
| BR (1) | BR9105640A (show.php) |
| CA (1) | CA2058331A1 (show.php) |
| DE (1) | DE69123341T2 (show.php) |
| MX (1) | MX9102855A (show.php) |
| TW (1) | TW221819B (show.php) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5258431A (en) * | 1991-06-20 | 1993-11-02 | Polyplastics Co., Ltd. | Weather-resistant polyacetal resin compositions exhibiting reduced surface gloss characteristics, and molded articles thereof |
| JP2561881B2 (ja) * | 1992-02-26 | 1996-12-11 | 旭化成工業株式会社 | ポリアセタール樹脂組成物 |
| TW230215B (show.php) * | 1992-03-16 | 1994-09-11 | Polyplastics Kk | |
| EP0586966A3 (en) * | 1992-09-10 | 1994-06-15 | Nat Starch Chem Invest | High cohesion waterborne pressure sensitive adhesives |
| DE4235976A1 (de) * | 1992-10-24 | 1994-04-28 | Basf Ag | Thermoplastische Formmasse |
| DE4237640A1 (de) * | 1992-11-07 | 1994-05-11 | Basf Ag | Thermoplastische Formmasse |
| JP3462888B2 (ja) * | 1993-04-19 | 2003-11-05 | ポリプラスチックス株式会社 | 耐候性ポリアセタール樹脂組成物 |
| JP4049882B2 (ja) * | 1998-04-07 | 2008-02-20 | 日本合成化学工業株式会社 | 再分散性アクリル系エマルジョン粉末及びその製造方法 |
| GB9919304D0 (en) | 1999-08-17 | 1999-10-20 | Ici Plc | Acrylic composition |
| DE10003807A1 (de) * | 2000-01-28 | 2001-08-02 | Basf Ag | Schlagzähmodifizierte Polyoxymethylene |
| CA2526218A1 (en) * | 2003-06-28 | 2005-01-13 | E.I. Du Pont De Nemours And Company | Polyacetal and polyvinylbutyral compositions and blends having enhanced surface properties and articles made therefrom |
| US20060079621A1 (en) * | 2004-06-24 | 2006-04-13 | Win-Chung Lee | Toughened polyacetal compositions and blends having low surface gloss |
| EP2054472B1 (de) * | 2006-08-18 | 2015-06-03 | Styrolution Europe GmbH | Thermoplastische formmassen auf basis von acrylnitril, styrol und butadien, sowie agglomerationsmittel enthaltend ethylacrylat und methacrylamid |
| US9296874B2 (en) | 2011-04-28 | 2016-03-29 | Ticona Llc | Polyacetal compositions and molded products made therefrom |
| JP6805863B2 (ja) * | 2017-02-13 | 2020-12-23 | 住友ゴム工業株式会社 | タイヤ用ゴム組成物及び空気入りタイヤ |
Family Cites Families (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1964156C3 (de) * | 1969-12-22 | 1978-08-24 | Basf Ag, 6700 Ludwigshafen | Thermoplastische Formmassen hoher Schlagzähigkeit |
| US3668274A (en) * | 1970-09-10 | 1972-06-06 | Rohm & Haas | Acrylic modifiers for polycarbonamides |
| US3699185A (en) * | 1970-12-21 | 1972-10-17 | Ford Motor Co | Rubber-modified acrylic copolymer thermoset |
| US3856883A (en) * | 1973-05-29 | 1974-12-24 | Ford Motor Co | Graded rubber particles having hydroxy functionality and a polymeric crosslinking agent |
| US4034013A (en) * | 1975-11-13 | 1977-07-05 | Rohm And Haas Company | Impact and melt strength improvement of poly(alkylene terephthalate) |
| US4200567A (en) * | 1977-08-22 | 1980-04-29 | Rohm And Haas Company | Synergistic impact modifier system for poly (alkylene terephthalates) |
| JPS5946382B2 (ja) * | 1979-07-20 | 1984-11-12 | 富士写真フイルム株式会社 | カラ−拡散転写法写真要素 |
| GB8321119D0 (en) * | 1982-10-01 | 1983-09-07 | Ici Plc | Polymerisation process |
| JPS59136343A (ja) * | 1983-01-04 | 1984-08-04 | ヘキスト・セラニーズ・コーポレーション | 耐衝撃性の高いポリアセタ−ル成形材料 |
| JPH0665704B2 (ja) * | 1985-02-04 | 1994-08-24 | ポリプラスチックス株式会社 | メッキ用ポリアセタ−ル樹脂組成物 |
| DE3674902D1 (de) * | 1985-06-26 | 1990-11-15 | Dow Chemical Co | Mit rubber modifizierte epoxyzusammensetzungen. |
| NL8600166A (nl) * | 1986-01-27 | 1987-08-17 | Gen Electric | Polymeermengsel, dat een polyamide, een polyfenyleenether en een middel voor het verbeteren van de slagsterkte bevat. |
| US4713414A (en) * | 1986-07-16 | 1987-12-15 | Celanese Corporation | Polyoxymethylene molding compositions exhibiting improved toughness |
| JPH0611837B2 (ja) * | 1986-09-03 | 1994-02-16 | 住友ダウ株式会社 | 熱可塑性樹脂組成物 |
| FR2619570B1 (fr) * | 1987-08-20 | 1992-02-14 | Charbonnages Ste Chimique | Procede de fabrication d'une resine thermoplastique resistante au choc, comportant une etape de transfert des particules d'un latex de renforcement dans les monomeres de la matrice, par formation de complexes interpolymeres destabilisant le latex |
| US5036120A (en) * | 1988-04-06 | 1991-07-30 | Nippon Petrochemicals Co., Ltd. | Thermoplastic resin composition and method for preparing the same |
| US4948822A (en) * | 1989-02-27 | 1990-08-14 | National Starch And Chemical Investment Holding Corporation | Laminating adhesives |
| JPH02251558A (ja) * | 1989-03-27 | 1990-10-09 | Asahi Chem Ind Co Ltd | ポリオキシメチレン樹脂組成物 |
| US5183858A (en) * | 1989-03-31 | 1993-02-02 | Takeda Chemical Industries, Ltd. | Core-shell polymer, production and use thereof |
| JPH07116347B2 (ja) * | 1989-04-25 | 1995-12-13 | 旭化成工業株式会社 | 耐衝撃性に優れるポリオキシメチレン組成物 |
| JPH07116348B2 (ja) * | 1989-05-09 | 1995-12-13 | 旭化成工業株式会社 | 耐候性に優れたポリオキシメチレン組成物 |
| US5321056A (en) * | 1992-06-19 | 1994-06-14 | Rohm And Haas Company | Amorphous, aromatic polyester containing impact modifier |
| US5346953A (en) * | 1993-02-08 | 1994-09-13 | General Electric Company | Core-shell ABS copolymers and method for their preparation |
-
1991
- 1991-12-23 DE DE69123341T patent/DE69123341T2/de not_active Expired - Lifetime
- 1991-12-23 EP EP91311963A patent/EP0494534B1/en not_active Expired - Lifetime
- 1991-12-23 CA CA002058331A patent/CA2058331A1/en not_active Abandoned
- 1991-12-24 TW TW080110061A patent/TW221819B/zh not_active IP Right Cessation
- 1991-12-26 JP JP34469491A patent/JP2999318B2/ja not_active Expired - Lifetime
- 1991-12-27 MX MX9102855A patent/MX9102855A/es not_active IP Right Cessation
- 1991-12-28 KR KR1019910024874A patent/KR950011900B1/ko not_active Expired - Lifetime
- 1991-12-30 BR BR919105640A patent/BR9105640A/pt not_active IP Right Cessation
-
1994
- 1994-10-20 US US08/326,355 patent/US5484845A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| MX9102855A (es) | 1992-06-01 |
| EP0494534A3 (en) | 1992-08-12 |
| JP2999318B2 (ja) | 2000-01-17 |
| EP0494534B1 (en) | 1996-11-27 |
| TW221819B (show.php) | 1994-03-21 |
| DE69123341T2 (de) | 1997-06-26 |
| BR9105640A (pt) | 1992-09-01 |
| DE69123341D1 (de) | 1997-01-09 |
| KR920012255A (ko) | 1992-07-25 |
| JPH05271361A (ja) | 1993-10-19 |
| EP0494534A2 (en) | 1992-07-15 |
| KR950011900B1 (ko) | 1995-10-12 |
| US5484845A (en) | 1996-01-16 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request | ||
| FZDE | Discontinued |