CA1337009C - Procede de preparation d'homo-et co-polymeres du chlorure de vinyle aptes a donner des plastisols - Google Patents
Procede de preparation d'homo-et co-polymeres du chlorure de vinyle aptes a donner des plastisolsInfo
- Publication number
- CA1337009C CA1337009C CA000544679A CA544679A CA1337009C CA 1337009 C CA1337009 C CA 1337009C CA 000544679 A CA000544679 A CA 000544679A CA 544679 A CA544679 A CA 544679A CA 1337009 C CA1337009 C CA 1337009C
- Authority
- CA
- Canada
- Prior art keywords
- latex
- vinyl chloride
- heating
- temperature
- polymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 title claims abstract description 36
- 229920001577 copolymer Polymers 0.000 title claims abstract description 18
- 239000004999 plastisol Substances 0.000 title claims abstract description 15
- 229920001944 Plastisol Polymers 0.000 title claims abstract description 14
- 238000004519 manufacturing process Methods 0.000 title description 2
- 229920001519 homopolymer Polymers 0.000 title 1
- 239000004816 latex Substances 0.000 claims abstract description 70
- 229920000126 latex Polymers 0.000 claims abstract description 70
- 238000000034 method Methods 0.000 claims abstract description 23
- 229920000642 polymer Polymers 0.000 claims abstract description 23
- 238000001694 spray drying Methods 0.000 claims abstract description 19
- 239000000178 monomer Substances 0.000 claims abstract description 11
- 238000002360 preparation method Methods 0.000 claims abstract description 9
- 239000000843 powder Substances 0.000 claims abstract description 6
- 238000012545 processing Methods 0.000 claims abstract description 5
- 230000015556 catabolic process Effects 0.000 claims abstract description 3
- 238000006731 degradation reaction Methods 0.000 claims abstract description 3
- 238000010438 heat treatment Methods 0.000 claims description 16
- 238000006116 polymerization reaction Methods 0.000 claims description 9
- 239000012530 fluid Substances 0.000 claims description 6
- 238000000889 atomisation Methods 0.000 description 11
- 239000002245 particle Substances 0.000 description 10
- 229920002554 vinyl polymer Polymers 0.000 description 9
- 238000000227 grinding Methods 0.000 description 8
- 238000003860 storage Methods 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- 239000000839 emulsion Substances 0.000 description 7
- 238000007334 copolymerization reaction Methods 0.000 description 6
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 6
- -1 for example Substances 0.000 description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- 238000004806 packaging method and process Methods 0.000 description 4
- 239000007789 gas Substances 0.000 description 3
- 229920000915 polyvinyl chloride Polymers 0.000 description 3
- 239000004800 polyvinyl chloride Substances 0.000 description 3
- YIVJZNGAASQVEM-UHFFFAOYSA-N Lauroyl peroxide Chemical compound CCCCCCCCCCCC(=O)OOC(=O)CCCCCCCCCCC YIVJZNGAASQVEM-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 238000007872 degassing Methods 0.000 description 2
- 239000008367 deionised water Substances 0.000 description 2
- 229910021641 deionized water Inorganic materials 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 239000010419 fine particle Substances 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 239000004014 plasticizer Substances 0.000 description 2
- 239000011541 reaction mixture Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 238000012546 transfer Methods 0.000 description 2
- 238000000108 ultra-filtration Methods 0.000 description 2
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- 101000577881 Homo sapiens Macrophage metalloelastase Proteins 0.000 description 1
- 239000005639 Lauric acid Substances 0.000 description 1
- 102100027998 Macrophage metalloelastase Human genes 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 229910001870 ammonium persulfate Inorganic materials 0.000 description 1
- 239000011260 aqueous acid Substances 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 238000003490 calendering Methods 0.000 description 1
- 230000001413 cellular effect Effects 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 235000009508 confectionery Nutrition 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 description 1
- 238000010981 drying operation Methods 0.000 description 1
- 125000002573 ethenylidene group Chemical group [*]=C=C([H])[H] 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000010101 extrusion blow moulding Methods 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 125000005395 methacrylic acid group Chemical group 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- 238000010899 nucleation Methods 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- 239000012429 reaction media Substances 0.000 description 1
- 238000001175 rotational moulding Methods 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- HRZFUMHJMZEROT-UHFFFAOYSA-L sodium disulfite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])(=O)=O HRZFUMHJMZEROT-UHFFFAOYSA-L 0.000 description 1
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 description 1
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 1
- 229940001584 sodium metabisulfite Drugs 0.000 description 1
- 235000010262 sodium metabisulphite Nutrition 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 238000005496 tempering Methods 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/12—Powdering or granulating
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/12—Powdering or granulating
- C08J3/122—Pulverisation by spraying
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/12—Powdering or granulating
- C08J3/16—Powdering or granulating by coagulating dispersions
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
- C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
- C08J2327/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08J2327/06—Homopolymers or copolymers of vinyl chloride
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR8612781A FR2603890B1 (fr) | 1986-09-12 | 1986-09-12 | Procede de preparation d'homo- et copolymeres du chlorure de vinyle aptes a donner des plastisols |
| FR8612781 | 1986-09-12 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1337009C true CA1337009C (fr) | 1995-09-12 |
Family
ID=9338891
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA000544679A Expired - Fee Related CA1337009C (fr) | 1986-09-12 | 1987-08-17 | Procede de preparation d'homo-et co-polymeres du chlorure de vinyle aptes a donner des plastisols |
Country Status (14)
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5155185A (en) * | 1989-02-06 | 1992-10-13 | The B. F. Goodrich Company | Process for producing dust free polyvinyl chloride resins |
| EP0596426B1 (en) * | 1992-11-04 | 1997-03-12 | Mitsubishi Chemical Corporation | Method for producing a vinyl chloride resin |
| DE4342391A1 (de) * | 1993-12-13 | 1995-06-14 | Hoechst Ag | Verfahren zur Reduzierung der Keimzahl in wäßrigen Kunstharz-haltigen Mehrphasensystemen mittels Mikrowellenstrahlen |
| US5696228A (en) * | 1996-10-03 | 1997-12-09 | Cytec Technology Corp. | Process for producing substantially dry polymer particles from aqueous dispersions |
| JP4059929B2 (ja) * | 1997-07-07 | 2008-03-12 | 新第一塩ビ株式会社 | ペースト加工用塩化ビニル樹脂顆粒およびその製造方法 |
| CN100357006C (zh) * | 2002-11-29 | 2007-12-26 | 三菱丽阳株式会社 | 聚合物的回收方法 |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2531780C3 (de) * | 1975-07-16 | 1980-02-07 | Chemische Werke Huels Ag, 4370 Marl | Verfahren zur Herstellung von verpastbaren Polymeren des Vinylchlorids |
| GB1553829A (en) * | 1975-10-13 | 1979-10-10 | Ici Ltd | Method of treating vinyl chloride polymer latices |
| DK137650B (da) * | 1976-05-12 | 1978-04-10 | Niro Atomizer As | Fremgangsmåde til fremstilling af et til plastisoldannelse egnet pulver af polyvinylchlorid eller af et vinylchlorid-copolymerisat samt tørretårn til udøvelse af fremgangsmåden. |
| FR2468619B1 (fr) * | 1979-11-06 | 1985-06-21 | Rhone Poulenc Ind | Procede de preparation d'homo- et co-polymeres du chlorure de vinyle aptes a donner des plastisols a partir d'un latex contenant deux populations de particules |
| DE3034983C2 (de) * | 1980-09-17 | 1982-06-16 | Chemische Werke Hüls AG, 4370 Marl | Verfahren zur thermischen Nachbehandlung von verpastbaren Polymerisaten des Vinylchlorids |
| JPS5887102A (ja) * | 1981-11-19 | 1983-05-24 | Kanegafuchi Chem Ind Co Ltd | 凝固ラテツクスの製造方法および装置 |
-
1986
- 1986-09-12 FR FR8612781A patent/FR2603890B1/fr not_active Expired
-
1987
- 1987-08-13 NO NO873409A patent/NO169902C/no unknown
- 1987-08-17 CA CA000544679A patent/CA1337009C/fr not_active Expired - Fee Related
- 1987-08-31 US US07/091,271 patent/US4948872A/en not_active Expired - Fee Related
- 1987-09-03 EP EP87401974A patent/EP0261014B1/fr not_active Revoked
- 1987-09-03 DE DE3752065T patent/DE3752065T2/de not_active Revoked
- 1987-09-03 ES ES87401974T patent/ES2102344T3/es not_active Expired - Lifetime
- 1987-09-10 ZA ZA876779A patent/ZA876779B/xx unknown
- 1987-09-10 JP JP62225465A patent/JPS6395204A/ja active Granted
- 1987-09-10 IN IN662/MAS/87A patent/IN170194B/en unknown
- 1987-09-11 PT PT85684A patent/PT85684B/pt not_active IP Right Cessation
- 1987-09-11 FI FI873961A patent/FI91266C/fi not_active IP Right Cessation
- 1987-09-12 CN CN87106282A patent/CN1029620C/zh not_active Expired - Fee Related
- 1987-09-12 KR KR1019870010126A patent/KR930001069B1/ko not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| DE3752065D1 (de) | 1997-06-19 |
| IN170194B (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1992-02-22 |
| FI91266B (fi) | 1994-02-28 |
| PT85684A (pt) | 1987-10-01 |
| PT85684B (pt) | 1990-05-31 |
| ZA876779B (en) | 1988-05-25 |
| KR930001069B1 (ko) | 1993-02-15 |
| FI91266C (fi) | 1994-06-10 |
| FI873961L (fi) | 1988-03-13 |
| FR2603890B1 (fr) | 1988-11-18 |
| FR2603890A1 (fr) | 1988-03-18 |
| JPH0357124B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1991-08-30 |
| EP0261014A1 (fr) | 1988-03-23 |
| NO169902C (no) | 1992-08-19 |
| FI873961A0 (fi) | 1987-09-11 |
| KR880004006A (ko) | 1988-06-01 |
| DE3752065T2 (de) | 1997-12-11 |
| NO873409D0 (no) | 1987-08-13 |
| CN1029620C (zh) | 1995-08-30 |
| ES2102344T3 (es) | 1997-08-01 |
| JPS6395204A (ja) | 1988-04-26 |
| NO873409L (no) | 1988-03-14 |
| EP0261014B1 (fr) | 1997-05-14 |
| CN87106282A (zh) | 1988-03-23 |
| NO169902B (no) | 1992-05-11 |
| US4948872A (en) | 1990-08-14 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKLA | Lapsed |