CA1088697A - Polyol blends and polyurethane prepared therefrom - Google Patents
Polyol blends and polyurethane prepared therefromInfo
- Publication number
- CA1088697A CA1088697A CA262,201A CA262201A CA1088697A CA 1088697 A CA1088697 A CA 1088697A CA 262201 A CA262201 A CA 262201A CA 1088697 A CA1088697 A CA 1088697A
- Authority
- CA
- Canada
- Prior art keywords
- polyurethane
- glycol
- poly
- chain extender
- ether
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 24
- 239000004814 polyurethane Substances 0.000 title claims abstract description 19
- 229920002635 polyurethane Polymers 0.000 title claims description 17
- 150000003077 polyols Chemical class 0.000 title description 20
- 229920005862 polyol Polymers 0.000 title description 18
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims abstract description 55
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims abstract description 26
- -1 poly(oxyethylene-oxypropylene) Polymers 0.000 claims abstract description 25
- 239000004970 Chain extender Substances 0.000 claims abstract description 13
- 125000005442 diisocyanate group Chemical group 0.000 claims abstract description 9
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical group OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 claims description 15
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical group OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 10
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 8
- 229920001400 block copolymer Polymers 0.000 claims description 7
- 238000001125 extrusion Methods 0.000 claims description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 5
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 claims description 4
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 3
- 229920001577 copolymer Polymers 0.000 claims description 3
- DHTGRDDBCWWKQJ-UHFFFAOYSA-N 2-(2,2-dihydroxyethoxy)ethane-1,1-diol Chemical group OC(O)COCC(O)O DHTGRDDBCWWKQJ-UHFFFAOYSA-N 0.000 claims description 2
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 claims description 2
- ZNOHBYNDODQXAO-UHFFFAOYSA-N C1(C2=CC=C(C(=O)OC(C(O)O1)O)C=C2)=O Chemical group C1(C2=CC=C(C(=O)OC(C(O)O1)O)C=C2)=O ZNOHBYNDODQXAO-UHFFFAOYSA-N 0.000 claims 1
- 125000003827 glycol group Chemical group 0.000 claims 1
- 229920001971 elastomer Polymers 0.000 abstract description 7
- 239000000806 elastomer Substances 0.000 abstract description 7
- 229920006311 Urethane elastomer Polymers 0.000 abstract description 2
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 abstract 1
- 229920003225 polyurethane elastomer Polymers 0.000 description 10
- 150000002334 glycols Chemical class 0.000 description 8
- 238000000034 method Methods 0.000 description 4
- 230000000704 physical effect Effects 0.000 description 4
- 229920001169 thermoplastic Polymers 0.000 description 4
- 239000004416 thermosoftening plastic Substances 0.000 description 4
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000011541 reaction mixture Substances 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 229940043375 1,5-pentanediol Drugs 0.000 description 1
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 1
- 239000004606 Fillers/Extenders Substances 0.000 description 1
- ALQSHHUCVQOPAS-UHFFFAOYSA-N Pentane-1,5-diol Chemical compound OCCCCCO ALQSHHUCVQOPAS-UHFFFAOYSA-N 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- 239000004809 Teflon Substances 0.000 description 1
- 229920006362 Teflon® Polymers 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 230000003301 hydrolyzing effect Effects 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4804—Two or more polyethers of different physical or chemical nature
- C08G18/4808—Mixtures of two or more polyetherdiols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4833—Polyethers containing oxyethylene units
- C08G18/4837—Polyethers containing oxyethylene units and other oxyalkylene units
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
- C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
- C08G18/6666—Compounds of group C08G18/48 or C08G18/52
- C08G18/667—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38
- C08G18/6674—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/3203
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2933—Coated or with bond, impregnation or core
- Y10T428/2935—Discontinuous or tubular or cellular core
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyurethanes Or Polyureas (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US05/617,655 US4010146A (en) | 1975-09-29 | 1975-09-29 | Polyol blends and polyurethane prepared therefrom |
| US617,655 | 1975-09-29 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1088697A true CA1088697A (en) | 1980-10-28 |
Family
ID=24474485
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA262,201A Expired CA1088697A (en) | 1975-09-29 | 1976-09-28 | Polyol blends and polyurethane prepared therefrom |
Country Status (4)
| Country | Link |
|---|---|
| US (2) | US4010146A (en, 2012) |
| JP (1) | JPS5242597A (en, 2012) |
| BE (1) | BE846190A (en, 2012) |
| CA (1) | CA1088697A (en, 2012) |
Families Citing this family (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| USRE31671E (en) * | 1974-09-09 | 1984-09-11 | The Upjohn Company | Thermoplastic polyurethane elastomers from polyoxypropylene polyoxyethylene block copolymers |
| DE2860517D1 (en) * | 1977-07-01 | 1981-04-09 | Du Pont | Curable polyurethane prepolymers, adhesive compositions containing them, a method of bonding using the adhesive compositions and the bonded articles so obtained |
| US4125522A (en) * | 1977-07-01 | 1978-11-14 | E. I. Du Pont De Nemours And Company | Adhesive composition |
| US4134883A (en) * | 1977-08-23 | 1979-01-16 | Westinghouse Electric Corp. | Abrasion resistant polyurethane article having a high rolling coefficient of friction |
| US4168363A (en) * | 1978-04-03 | 1979-09-18 | Minnesota Mining And Manufacturing Company | Elastomeric cable jacket repair composition |
| US4306053A (en) * | 1980-03-18 | 1981-12-15 | Minnesota Mining And Manufacturing Company | Oil and water resistant polyurethane resin and polyol composition useful to make the same |
| US4379904A (en) * | 1980-11-24 | 1983-04-12 | The Upjohn Company | Novel polyurethane product |
| IT1151544B (it) * | 1982-04-15 | 1986-12-24 | Anic Spa | Composizione a base di policarbonati alifatici contenente grupi uretanici e terminazioni acriliche o metacriliche reticolabile in presenza di iniziatori radicalici |
| US4500442A (en) * | 1983-01-28 | 1985-02-19 | The Dow Chemical Company | Compositions containing mold release agents |
| DE3405531A1 (de) * | 1984-02-16 | 1985-08-29 | Bayer Ag, 5090 Leverkusen | Verfahren zur herstellung von thermoplastischen polyurethanelastomeren und ihre verwendung |
| JPS61200114A (ja) * | 1985-02-28 | 1986-09-04 | Nippon Zeon Co Ltd | 抗血栓性ポリウレタン化合物及びその製造方法 |
| US4870150A (en) * | 1988-05-23 | 1989-09-26 | Tremco Incorporated | Polyurethanes made from blends of polypropyleneoxide polyol and polybutyleneoxide polyol intermediates |
| US5130404A (en) * | 1991-06-04 | 1992-07-14 | Azon Usa Inc. | Castable thermosetting polyurethane polymer having improved heat stability |
| WO1994015985A1 (en) * | 1992-12-31 | 1994-07-21 | The Dow Chemical Company | Thermoplastic polyurethanes and a process for their preparation |
| US5618904A (en) * | 1993-12-29 | 1997-04-08 | Essex Specialty Products Inc. | Polyurethane hot melt adhesive |
| CN1210324C (zh) * | 1995-12-08 | 2005-07-13 | 亨茨曼Ici化学品有限公司 | 聚氨酯弹性体 |
| EP1028132A1 (de) * | 1999-02-09 | 2000-08-16 | Basf Aktiengesellschaft | Verfahren zur Herstellung von thermoplastischen Polyurethanen |
| US6294638B1 (en) * | 1999-10-08 | 2001-09-25 | Bayer Corporation | Soft, transparent and processable thermoplastic polyurethane |
| US6905985B1 (en) * | 2002-11-21 | 2005-06-14 | Highland Industries, Inc. | Fabric film for automotive heaters |
| WO2015084635A1 (en) * | 2013-12-02 | 2015-06-11 | Dow Global Technologies Llc | Storage Stable Polyol Composition for Polyurethane Elastomers |
| JP2018528318A (ja) * | 2015-09-24 | 2018-09-27 | ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ | 熱可塑性ポリウレタン |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE759114A (fr) * | 1969-11-25 | 1971-05-18 | Marles Kuhlmann Wyandotte | Polymeres urethane-uree solubles dans l'eau |
| JPS4923598A (en, 2012) * | 1972-06-23 | 1974-03-02 | ||
| JPS5222018B2 (en, 2012) * | 1972-07-20 | 1977-06-14 | ||
| US3915937A (en) * | 1974-05-10 | 1975-10-28 | Uniroyal Inc | Poly(oxypropylene) glycol based polyurethane elastomers suitable for automotive body parts |
-
1975
- 1975-09-29 US US05/617,655 patent/US4010146A/en not_active Expired - Lifetime
-
1976
- 1976-07-06 US US05/702,936 patent/US4101439A/en not_active Expired - Lifetime
- 1976-09-14 BE BE170629A patent/BE846190A/xx unknown
- 1976-09-28 CA CA262,201A patent/CA1088697A/en not_active Expired
- 1976-09-28 JP JP51117919A patent/JPS5242597A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| US4010146A (en) | 1977-03-01 |
| JPS5242597A (en) | 1977-04-02 |
| BE846190A (fr) | 1976-12-31 |
| US4101439A (en) | 1978-07-18 |
| JPS625932B2 (en, 2012) | 1987-02-07 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CA1088697A (en) | Polyol blends and polyurethane prepared therefrom | |
| Coutinho et al. | Degradation profile of films cast from aqueous polyurethane dispersions | |
| MXPA00012713A (es) | Elastomeros de poliuretano que exhiben propiedades mejoradas de desmoldeo, resistencia en crudo y absorcion de agua, y polioles que no presentan turbiedad y son adecuados para la preparacion de estos elastomeros. | |
| JPH03157416A (ja) | 軟質燃料容器のためのポリウレタン | |
| RU2135524C1 (ru) | Способ получения жесткого пенополиуретана и слоистое изделие на его основе | |
| JP2000219723A (ja) | ジュレンジイソシアネ―トに基づくポリウレタンキャストエラストマ― | |
| KR920019837A (ko) | 고 성능 폴리 우레탄 도포제 조성물 및 이의 제조방법 | |
| CN113527624B (zh) | 透明聚氨酯弹性体及其制备方法 | |
| US4124574A (en) | Poly (oxyalkylene) glycol based polyurethane with improved paint adhesion properties | |
| EP2294105B1 (en) | Fiber reinforced tpu composites | |
| WO1991014726A1 (en) | Polyoxyalkylene polyols containing internal polyoxyethylene blocks and a process for preparing polyurethanes therefrom | |
| JP3311746B2 (ja) | 柔軟なポリウレタンフォーム | |
| JPS59105015A (ja) | ポリオ−ル増量剤としてポリエチレンテレフタレ−ト廃流を用いる硬質ポリウレタン及びポリイソシアヌレ−トフオ−ムの製造方法 | |
| AU5987598A (en) | New polyols and their use in polyurethane preparation | |
| JPH08176252A (ja) | 改良されたプレポリマー組成物 | |
| CN115403759A (zh) | 无卤阻燃聚醚酯多元醇及其制备方法和应用 | |
| JPH03177413A (ja) | 耐熱性かつ熱可塑性の、ポリウレタンエラストマー及びその製造法 | |
| GB2232676A (en) | Polyurethane compositions exhibiting reduced smoke density and method of preparing same | |
| JP2001098045A (ja) | 軟質ポリウレタンフォーム組成物及びその軟質ポリウレタンフォーム | |
| JPS5964620A (ja) | 親水性ポリウレタンフオ−ムの製造方法 | |
| US4599460A (en) | Polyalkylene ether glycol copolymers | |
| US4490485A (en) | Manufacture of flexible polyurethane foam containing a condensation product of polyethylene terephthalate | |
| JPS61238816A (ja) | ポリウレタン系エラストマ−の製造方法 | |
| CN1246128A (zh) | 新颖多元醇及其在制备聚氨基甲酸酯中的用途 | |
| WO1998033833A1 (en) | New polyols and their use in polyurethane preparation |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKEX | Expiry |