CA1062841A - Polyvinylidene fluoride or vinylidene fluoride copolymer compositions - Google Patents
Polyvinylidene fluoride or vinylidene fluoride copolymer compositionsInfo
- Publication number
- CA1062841A CA1062841A CA253,052A CA253052A CA1062841A CA 1062841 A CA1062841 A CA 1062841A CA 253052 A CA253052 A CA 253052A CA 1062841 A CA1062841 A CA 1062841A
- Authority
- CA
- Canada
- Prior art keywords
- copolymer
- weight
- fluoride
- percent
- alkyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920001577 copolymer Polymers 0.000 title claims abstract description 64
- 239000002033 PVDF binder Substances 0.000 title claims abstract description 42
- 229920002981 polyvinylidene fluoride Polymers 0.000 title claims abstract description 42
- 239000000203 mixture Substances 0.000 title claims abstract description 32
- 239000000463 material Substances 0.000 claims abstract description 36
- XUCNUKMRBVNAPB-UHFFFAOYSA-N fluoroethene Chemical compound FC=C XUCNUKMRBVNAPB-UHFFFAOYSA-N 0.000 claims abstract description 22
- -1 alkyl methacrylate Chemical compound 0.000 claims abstract description 13
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 11
- 125000005250 alkyl acrylate group Chemical group 0.000 claims abstract description 9
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 6
- 239000000178 monomer Substances 0.000 claims description 25
- BQCIDUSAKPWEOX-UHFFFAOYSA-N 1,1-Difluoroethene Chemical compound FC(F)=C BQCIDUSAKPWEOX-UHFFFAOYSA-N 0.000 claims description 13
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 9
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 8
- 229910052731 fluorine Inorganic materials 0.000 claims description 8
- 239000011737 fluorine Substances 0.000 claims description 8
- 125000002947 alkylene group Chemical group 0.000 claims description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 3
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 2
- HCDGVLDPFQMKDK-UHFFFAOYSA-N hexafluoropropylene Chemical group FC(F)=C(F)C(F)(F)F HCDGVLDPFQMKDK-UHFFFAOYSA-N 0.000 claims description 2
- 238000000465 moulding Methods 0.000 abstract description 9
- 238000007493 shaping process Methods 0.000 abstract description 5
- 230000000704 physical effect Effects 0.000 abstract description 3
- 238000013329 compounding Methods 0.000 abstract 1
- 238000000034 method Methods 0.000 description 24
- 238000006116 polymerization reaction Methods 0.000 description 11
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 10
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- 239000000126 substance Substances 0.000 description 8
- 229920000642 polymer Polymers 0.000 description 7
- 239000007792 gaseous phase Substances 0.000 description 5
- 238000001228 spectrum Methods 0.000 description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- 229920001519 homopolymer Polymers 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- 229920002620 polyvinyl fluoride Polymers 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- 239000012986 chain transfer agent Substances 0.000 description 3
- 238000002485 combustion reaction Methods 0.000 description 3
- 239000013078 crystal Substances 0.000 description 3
- 238000002425 crystallisation Methods 0.000 description 3
- 230000008025 crystallization Effects 0.000 description 3
- 230000006872 improvement Effects 0.000 description 3
- 238000010348 incorporation Methods 0.000 description 3
- 239000004816 latex Substances 0.000 description 3
- 229920000126 latex Polymers 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 2
- 230000005540 biological transmission Effects 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- UUAGAQFQZIEFAH-UHFFFAOYSA-N chlorotrifluoroethylene Chemical group FC(F)=C(F)Cl UUAGAQFQZIEFAH-UHFFFAOYSA-N 0.000 description 2
- 238000006731 degradation reaction Methods 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 230000001771 impaired effect Effects 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- SNGREZUHAYWORS-UHFFFAOYSA-N perfluorooctanoic acid Chemical compound OC(=O)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F SNGREZUHAYWORS-UHFFFAOYSA-N 0.000 description 2
- 229920000131 polyvinylidene Polymers 0.000 description 2
- XWGJFPHUCFXLBL-UHFFFAOYSA-M rongalite Chemical compound [Na+].OCS([O-])=O XWGJFPHUCFXLBL-UHFFFAOYSA-M 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 229920001897 terpolymer Polymers 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- NDMMKOCNFSTXRU-UHFFFAOYSA-N 1,1,2,3,3-pentafluoroprop-1-ene Chemical group FC(F)C(F)=C(F)F NDMMKOCNFSTXRU-UHFFFAOYSA-N 0.000 description 1
- MHWAJHABMBTNHS-UHFFFAOYSA-N 1,1-difluoroethene;1,1,2,2-tetrafluoroethene Chemical group FC(F)=C.FC(F)=C(F)F MHWAJHABMBTNHS-UHFFFAOYSA-N 0.000 description 1
- UPVJEODAZWTJKZ-UHFFFAOYSA-N 1,2-dichloro-1,2-difluoroethene Chemical group FC(Cl)=C(F)Cl UPVJEODAZWTJKZ-UHFFFAOYSA-N 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- 108091006629 SLC13A2 Proteins 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- WXZKPELXXQHDNS-UHFFFAOYSA-N decane-1,1-dithiol Chemical compound CCCCCCCCCC(S)S WXZKPELXXQHDNS-UHFFFAOYSA-N 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000007720 emulsion polymerization reaction Methods 0.000 description 1
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 238000010559 graft polymerization reaction Methods 0.000 description 1
- 239000012770 industrial material Substances 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000002667 nucleating agent Substances 0.000 description 1
- 239000013307 optical fiber Substances 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 229920006255 plastic film Polymers 0.000 description 1
- 239000001103 potassium chloride Substances 0.000 description 1
- 235000011164 potassium chloride Nutrition 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- YPVDWEHVCUBACK-UHFFFAOYSA-N propoxycarbonyloxy propyl carbonate Chemical compound CCCOC(=O)OOC(=O)OCCC YPVDWEHVCUBACK-UHFFFAOYSA-N 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 238000010557 suspension polymerization reaction Methods 0.000 description 1
- 238000002834 transmittance Methods 0.000 description 1
- 238000001429 visible spectrum Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/12—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
- C08L27/14—Homopolymers or copolymers of vinyl fluoride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/12—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
- C08L27/16—Homopolymers or copolymers or vinylidene fluoride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
- C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S260/00—Chemistry of carbon compounds
- Y10S260/32—Incompatible blend
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP50061571A JPS51137741A (en) | 1975-05-23 | 1975-05-23 | Molded arti cles based on polyvinylidene fluoride |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1062841A true CA1062841A (en) | 1979-09-18 |
Family
ID=13174933
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA253,052A Expired CA1062841A (en) | 1975-05-23 | 1976-05-21 | Polyvinylidene fluoride or vinylidene fluoride copolymer compositions |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US4091055A (OSRAM) |
| JP (1) | JPS51137741A (OSRAM) |
| CA (1) | CA1062841A (OSRAM) |
| DE (1) | DE2622498C3 (OSRAM) |
| FI (1) | FI64181C (OSRAM) |
| FR (1) | FR2311803A1 (OSRAM) |
| GB (1) | GB1541306A (OSRAM) |
| NO (1) | NO143972C (OSRAM) |
| SE (1) | SE411356B (OSRAM) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4348312A (en) * | 1978-11-20 | 1982-09-07 | Minnesota Mining And Manufacturing Company | Ultra-high-index glass microspheres and products made therefrom with a fluoropolymer and an ester polymer blend |
| EP0044702B1 (en) * | 1980-07-23 | 1984-12-27 | Minnesota Mining And Manufacturing Company | Piezoelectric and pyroelectric polymeric blends |
| JPS5930502A (ja) * | 1982-08-13 | 1984-02-18 | Nippon Telegr & Teleph Corp <Ntt> | プラスチツク光フアイバ |
| US4581412A (en) * | 1983-09-21 | 1986-04-08 | Daikin Kogyo Co., Ltd. | Coating composition of vinylidene fluoride copolymer and acrylic polymer |
| JPS61190546A (ja) * | 1985-02-20 | 1986-08-25 | Central Glass Co Ltd | 光学用樹脂組成物 |
| US4822122A (en) * | 1985-06-12 | 1989-04-18 | Mitsubishi Rayon Co., Ltd. | Optical transmission medium and process for producing the same based on vinylidene flouride polymers and metharylate polymers |
| FR2583914B1 (fr) * | 1985-06-21 | 1989-04-07 | Thomson Csf | Materiaux dielectriques a base de polymeres et a permittivite dielectrique elevee |
| JPS63159459A (ja) * | 1986-12-23 | 1988-07-02 | Central Glass Co Ltd | 樹脂組成物 |
| DE4302864A1 (de) * | 1993-02-02 | 1994-08-04 | Gernot K Brueck | Elastische Liegen für Sonnenbänke |
| ES2191050T3 (es) | 1994-04-18 | 2003-09-01 | Yasuhiro Koike | Resina de uso optico del tipo de distribucion de indice de refraccion y el procedimiento de produccion de esta resina. |
| US7452602B2 (en) * | 2004-08-11 | 2008-11-18 | Kaneka Corporation | Vinylidene fluoride-based resin film |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3253060A (en) * | 1964-08-03 | 1966-05-24 | Pennsalt Chemicals Corp | Molding compositions comprising polyvinylidene fluoride and polymethyl methacrylate |
| GB1065780A (en) * | 1965-02-15 | 1967-04-19 | American Cyanamid Co | Poly(vinylidene fluoride) compositions |
| US3524906A (en) * | 1967-10-10 | 1970-08-18 | American Cyanamid Co | Transparent and weatherable polymer blends of acrylate polymers and polyvinylidene fluoride |
| JPS4834956A (OSRAM) * | 1971-09-10 | 1973-05-23 | ||
| JPS5017457A (OSRAM) * | 1973-06-15 | 1975-02-24 |
-
1975
- 1975-05-23 JP JP50061571A patent/JPS51137741A/ja active Granted
-
1976
- 1976-05-19 US US05/687,763 patent/US4091055A/en not_active Expired - Lifetime
- 1976-05-20 DE DE2622498A patent/DE2622498C3/de not_active Expired
- 1976-05-20 FI FI761420A patent/FI64181C/fi not_active IP Right Cessation
- 1976-05-21 SE SE7605785A patent/SE411356B/xx unknown
- 1976-05-21 NO NO761740A patent/NO143972C/no unknown
- 1976-05-21 GB GB21127/76A patent/GB1541306A/en not_active Expired
- 1976-05-21 FR FR7615539A patent/FR2311803A1/fr active Granted
- 1976-05-21 CA CA253,052A patent/CA1062841A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| DE2622498B2 (de) | 1978-01-19 |
| JPS541586B2 (OSRAM) | 1979-01-26 |
| SE411356B (sv) | 1979-12-17 |
| FI64181C (fi) | 1983-10-10 |
| DE2622498A1 (de) | 1976-12-02 |
| GB1541306A (en) | 1979-02-28 |
| FR2311803B1 (OSRAM) | 1981-09-18 |
| SE7605785L (sv) | 1976-11-24 |
| US4091055A (en) | 1978-05-23 |
| NO143972B (no) | 1981-02-09 |
| FI761420A7 (OSRAM) | 1976-11-24 |
| JPS51137741A (en) | 1976-11-27 |
| NO761740L (OSRAM) | 1976-11-24 |
| FR2311803A1 (fr) | 1976-12-17 |
| FI64181B (fi) | 1983-06-30 |
| NO143972C (no) | 1981-05-20 |
| DE2622498C3 (de) | 1978-09-21 |
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