CA1061043A - Process for the preparation of water dispersible polyurethanes - Google Patents

Process for the preparation of water dispersible polyurethanes

Info

Publication number
CA1061043A
CA1061043A CA235,512A CA235512A CA1061043A CA 1061043 A CA1061043 A CA 1061043A CA 235512 A CA235512 A CA 235512A CA 1061043 A CA1061043 A CA 1061043A
Authority
CA
Canada
Prior art keywords
groups
prepolymer
water
sulphonate
group
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
CA235,512A
Other languages
English (en)
French (fr)
Inventor
Wolfgang Wenzel
Helmut Reiff
Jurgen Grammel
Dieter Dieterich
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bayer AG
Original Assignee
Bayer AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bayer AG filed Critical Bayer AG
Application granted granted Critical
Publication of CA1061043A publication Critical patent/CA1061043A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40High-molecular-weight compounds
    • C08G18/42Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4236Polycondensates having carboxylic or carbonic ester groups in the main chain containing only aliphatic groups
    • C08G18/4238Polycondensates having carboxylic or carbonic ester groups in the main chain containing only aliphatic groups derived from dicarboxylic acids and dialcohols
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08Processes
    • C08G18/0804Manufacture of polymers containing ionic or ionogenic groups
    • C08G18/0819Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups
    • C08G18/0828Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups containing sulfonate groups or groups forming them
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30Low-molecular-weight compounds
    • C08G18/32Polyhydroxy compounds; Polyamines; Hydroxyamines
    • C08G18/3225Polyamines
    • C08G18/3228Polyamines acyclic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30Low-molecular-weight compounds
    • C08G18/38Low-molecular-weight compounds having heteroatoms other than oxygen
    • C08G18/3819Low-molecular-weight compounds having heteroatoms other than oxygen having nitrogen
    • C08G18/3823Low-molecular-weight compounds having heteroatoms other than oxygen having nitrogen containing -N-C=O groups
    • C08G18/3829Low-molecular-weight compounds having heteroatoms other than oxygen having nitrogen containing -N-C=O groups containing ureum groups
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30Low-molecular-weight compounds
    • C08G18/38Low-molecular-weight compounds having heteroatoms other than oxygen
    • C08G18/3855Low-molecular-weight compounds having heteroatoms other than oxygen having sulfur
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30Low-molecular-weight compounds
    • C08G18/38Low-molecular-weight compounds having heteroatoms other than oxygen
    • C08G18/3855Low-molecular-weight compounds having heteroatoms other than oxygen having sulfur
    • C08G18/3857Low-molecular-weight compounds having heteroatoms other than oxygen having sulfur having nitrogen in addition to sulfur
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40High-molecular-weight compounds
    • C08G18/42Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4205Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups
    • C08G18/4208Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing aromatic groups
    • C08G18/4211Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing aromatic groups derived from aromatic dicarboxylic acids and dialcohols
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72Polyisocyanates or polyisothiocyanates
    • C08G18/73Polyisocyanates or polyisothiocyanates acyclic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04Polyurethanes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2170/00Compositions for adhesives
    • C08G2170/80Compositions for aqueous adhesives

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
CA235,512A 1974-09-28 1975-09-11 Process for the preparation of water dispersible polyurethanes Expired CA1061043A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19742446440 DE2446440C3 (de) 1974-09-28 1974-09-28 Verfahren zur Herstellung von wäßrigen Dispersionen von Sulfonatgruppen aufweisenden Polyurethanen

Publications (1)

Publication Number Publication Date
CA1061043A true CA1061043A (en) 1979-08-21

Family

ID=5927019

Family Applications (1)

Application Number Title Priority Date Filing Date
CA235,512A Expired CA1061043A (en) 1974-09-28 1975-09-11 Process for the preparation of water dispersible polyurethanes

Country Status (9)

Country Link
JP (1) JPS5416998B2 (ja)
BE (1) BE833823A (ja)
CA (1) CA1061043A (ja)
DE (1) DE2446440C3 (ja)
ES (1) ES441321A1 (ja)
FR (1) FR2286154A1 (ja)
GB (1) GB1462597A (ja)
IT (1) IT1047095B (ja)
NL (1) NL177691C (ja)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6767958B2 (en) 2000-05-18 2004-07-27 Bayer Aktiengesellschaft Modified polyisocyanates
US8629195B2 (en) 2006-04-08 2014-01-14 Bayer Materialscience Ag Production of polyurethane foams
US9034985B2 (en) 2009-02-13 2015-05-19 Bayer Materialscience Ag Aqueous coating systems based on physically drying urethane acrylates
US9195215B2 (en) 2011-11-29 2015-11-24 Bayer Intellectual Property Gmbh Holographic medium having a protective layer
US9783926B2 (en) 2011-10-18 2017-10-10 Covestro Deutschland Ag Process for the coating of textiles
US10745591B2 (en) 2015-04-07 2020-08-18 Covestro Deutschland Ag Method for adhesively bonding substrates using adhesives
US11511211B2 (en) 2016-06-28 2022-11-29 Covestro Deutschland Ag Distillative separation of ketazine from polyurethane dispersions

Families Citing this family (159)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2708442C2 (de) 1977-02-26 1984-10-25 Bayer Ag, 5090 Leverkusen Verfahren zur Herstellung von modifizierten wäßrigen Kunststoff-Dispersionen
DE2721985A1 (de) * 1977-05-14 1978-11-16 Bayer Ag Verfahren zur herstellung von urethan- und/oder harnstoffgruppen aufweisenden polyisocyanat polyadditionsprodukten
DE2816815A1 (de) * 1978-04-18 1979-10-31 Bayer Ag In wasser dispergierbare oder loesliche polyurethane, sowie ein verfahren zu ihrer herstellung
DE2843790A1 (de) 1978-10-06 1980-04-17 Bayer Ag Verfahren zur herstellung von waessrigen dispersionen oder loesungen von polyurethan-polyharnstoffen, die nach diesem verfahren erhaeltlichen dispersionen oder loesungen, sowie ihre verwendung
DE3216567A1 (de) 1982-05-04 1983-11-10 Bayer Ag, 5090 Leverkusen Verfahren zur herstellung von waessrigen dispersionen von, chemisch fixierte carboxylat- und/oder sulfonatgruppen aufweisenden, polyurethanen
DE3437918A1 (de) * 1984-10-17 1986-04-17 Bayer Ag, 5090 Leverkusen Waessrige oligourethan-dispersionen mit eingebauten, ungesaettigten gruppen und ihre verwendung zur herstellung von hochglaenzenden lacken auf leder aus waessriger phase
JPS61200113A (ja) * 1985-03-01 1986-09-04 Sumitomo Bayer Urethane Kk バインダ−組成物
DE3827378A1 (de) 1988-08-12 1990-02-22 Henkel Kgaa Haushaltsalleskleber auf polyurethanbasis
US5037864A (en) * 1989-07-11 1991-08-06 The Dow Chemical Company Semi-continuous process for the preparation of polyurethane-urea aqueous dispersions
US5155163A (en) * 1990-08-06 1992-10-13 Uniroyal Adhesives And Sealants, Inc. Aqueous polyurethane dispersion synthesis for adhesive thermoforming applications
DE4222530A1 (de) * 1992-07-09 1994-01-13 Hoechst Ag Polyurethan-Dispersionen
US5608000A (en) * 1993-09-24 1997-03-04 H. B. Fuller Licensing & Financing, Inc. Aqueous polyurethane dispersion adhesive compositions with improved heat resistance
US5703158A (en) * 1993-09-24 1997-12-30 H.B. Fuller Licensing & Financing, Inc. Aqueous anionic poly (urethane/urea) dispersions
US5610232A (en) * 1993-09-24 1997-03-11 H.B. Fuller Licensing & Financing, Inc. Aqueous non-gelling, anionic polyurethane dispersions and process for their manufacture
US5872182A (en) * 1994-09-09 1999-02-16 H. B. Fuller Licensing & Financing, Inc. Water-based polyurethanes for footwear
DE4433929A1 (de) 1994-09-23 1996-03-28 Basf Ag Wasseremulgierbare Polyisocyanate
DE19520092A1 (de) * 1995-06-01 1996-12-05 Bayer Ag Verfahren zur Papierveredlung unter Verwendung von Polyisocyanaten mit anionischen Gruppen
DE19548030A1 (de) 1995-12-21 1997-06-26 Bayer Ag Verwendung wässriger Dispersionen nachvernetzbarer Beschichtungsmittel zur Textil- und Lederbeschichtung
EP1002001B1 (de) * 1997-07-31 2002-03-27 Basf Aktiengesellschaft Wässerige dispersionen enthaltend polyurethane mit carbodiimidgruppen
US6599975B1 (en) * 1997-07-31 2003-07-29 Basf Aktiengesellschaft Latent cross-linking aqueous dispersions comprising a polyurethane
DE19837377A1 (de) * 1998-08-18 2000-02-24 Basf Ag Latent vernetzende wässerige Dispersionen enthaltend ein Polyurethan
DE19840786A1 (de) * 1998-09-08 2000-01-27 Bayer Ag Polyurethan-Dispersionen zur Klebung von SBS
US6649727B1 (en) 2000-07-27 2003-11-18 3M Innovative Properties Company Aqueous colloidal dispersions of sulfonated polyurethane ureas and products
JP4886191B2 (ja) * 2002-11-04 2012-02-29 インヴィスタ テクノロジーズ エスアエルエル ポリ(ウレア/ウレタン)の水性分散体により処理した物品
DE10251797A1 (de) 2002-11-07 2004-05-19 Bayer Ag Polyurethanharz mit hohem Carbonatgruppengehalt
DE10359704A1 (de) 2003-12-18 2005-07-14 Wacker-Chemie Gmbh Dispersionen enthaltend Organopolysiloxan-Polyharnstoff-Copolymere
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DE102007048078A1 (de) 2007-10-05 2009-04-09 Bayer Materialscience Ag Polyurethan-Schäume für die Wundbehandlung
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DE102007059858A1 (de) 2007-12-12 2009-06-18 Bayer Materialscience Ag Energiewandler hergestellt aus filmbildenden wässrigen Polymer-Dispersionen, insbesondere Polyurethan-Dispersionen
DE102008014211A1 (de) 2008-03-14 2009-09-17 Bayer Materialscience Ag Wässrige Dispersion aus anionisch modifizierten Polyurethanharnstoffen zur Beschichtung eines textilen Flächengebildes
EP2105124A1 (de) * 2008-03-26 2009-09-30 Bayer MaterialScience AG Sonnenschutz-Zusammensetzungen
EP2105127A1 (de) * 2008-03-26 2009-09-30 Bayer MaterialScience AG Haarfestiger-Zusammensetzung
EP2105125A1 (de) * 2008-03-26 2009-09-30 Bayer MaterialScience AG Hautpflege-Zusammensetzung
EP2105120A1 (de) 2008-03-26 2009-09-30 Bayer MaterialScience AG Kosmetische Zusammensetzungen zum Auftrag auf die Haut
EP2105126A1 (de) * 2008-03-26 2009-09-30 Bayer MaterialScience AG Dekorative kosmetische Zusammensetzungen
EP2106833A1 (de) 2008-04-02 2009-10-07 Bayer MaterialScience AG Partikel, erhältlich durch Trocknung einer wässrigen Nanoharnstoff-Dispersion
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WO2012130762A1 (en) 2011-03-28 2012-10-04 Bayer Materialscience Ag Aqueous polyurethane acrylate dispersions with a comb-like structure of the polymer
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BE833823A (fr) 1976-03-25
NL177691B (nl) 1985-06-03
NL177691C (nl) 1985-11-01
JPS5416998B2 (ja) 1979-06-26
DE2446440A1 (de) 1976-04-08
FR2286154B1 (ja) 1981-12-31
FR2286154A1 (fr) 1976-04-23
DE2446440B2 (de) 1980-07-31
DE2446440C3 (de) 1981-04-30
ES441321A1 (es) 1977-03-16
NL7511315A (nl) 1976-03-30
JPS5160294A (ja) 1976-05-26
GB1462597A (en) 1977-01-26
IT1047095B (it) 1980-09-10

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