BRPI1013814A2 - oligomerização de alfa olefinas, empregando sistemas catalisadores metaloceno-ssa e uso das resultantes polialfa olefinas para o preparo de misturas lubrificantes - Google Patents

oligomerização de alfa olefinas, empregando sistemas catalisadores metaloceno-ssa e uso das resultantes polialfa olefinas para o preparo de misturas lubrificantes

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Publication number
BRPI1013814A2
BRPI1013814A2 BRPI1013814A BRPI1013814A BRPI1013814A2 BR PI1013814 A2 BRPI1013814 A2 BR PI1013814A2 BR PI1013814 A BRPI1013814 A BR PI1013814A BR PI1013814 A BRPI1013814 A BR PI1013814A BR PI1013814 A2 BRPI1013814 A2 BR PI1013814A2
Authority
BR
Brazil
Prior art keywords
metallocene
resulting
preparation
catalyst systems
alpha olefin
Prior art date
Application number
BRPI1013814A
Other languages
English (en)
Inventor
Albert P Masino
Brooke L Small
Bruce Kreischer
Eduardo J Baralt
Eric J Netemeyer
Kenneth D Hope
Max P Mcdaniel
Qing Yang
Richard M Buck
William B Beaulieu
Original Assignee
Chevron Phillps Chemical Company Lp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Chevron Phillps Chemical Company Lp filed Critical Chevron Phillps Chemical Company Lp
Priority to BR122013014965-1A priority Critical patent/BR122013014965B1/pt
Publication of BRPI1013814A2 publication Critical patent/BRPI1013814A2/pt
Publication of BRPI1013814B1 publication Critical patent/BRPI1013814B1/pt

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    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/26—Catalytic processes with hydrides or organic compounds
    • C07C2/32—Catalytic processes with hydrides or organic compounds as complexes, e.g. acetyl-acetonates
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    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
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    • B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
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    • C10G2300/20—Characteristics of the feedstock or the products
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    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/22—Higher olefins
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    • C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
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    • C—CHEMISTRY; METALLURGY
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    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
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    • C10M2205/026—Butene
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    • C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
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    • C10M2205/0265—Butene used as base material
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    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
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    • C10M2205/028—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers containing aliphatic monomers having more than four carbon atoms
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    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
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    • C10N2030/34—Fragrance or deodorizing properties
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    • C10N2070/00—Specific manufacturing methods for lubricant compositions
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

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  • Chemical & Material Sciences (AREA)
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  • Oil, Petroleum & Natural Gas (AREA)
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  • Crystallography & Structural Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Lubricants (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
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Families Citing this family (100)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2007011462A1 (en) 2005-07-19 2007-01-25 Exxonmobil Chemical Patents Inc. Lubricants from mixed alpha-olefin feeds
US7226886B2 (en) 2005-09-15 2007-06-05 Chevron Phillips Chemical Company, L.P. Polymerization catalysts and process for producing bimodal polymers in a single reactor
US7619047B2 (en) 2006-02-22 2009-11-17 Chevron Phillips Chemical Company, Lp Dual metallocene catalysts for polymerization of bimodal polymers
US7863210B2 (en) 2007-12-28 2011-01-04 Chevron Phillips Chemical Company Lp Nano-linked metallocene catalyst compositions and their polymer products
US8080681B2 (en) 2007-12-28 2011-12-20 Chevron Phillips Chemical Company Lp Nano-linked metallocene catalyst compositions and their polymer products
US8012900B2 (en) * 2007-12-28 2011-09-06 Chevron Phillips Chemical Company, L.P. Nano-linked metallocene catalyst compositions and their polymer products
US7884163B2 (en) 2008-03-20 2011-02-08 Chevron Phillips Chemical Company Lp Silica-coated alumina activator-supports for metallocene catalyst compositions
US11208514B2 (en) 2008-03-20 2021-12-28 Chevron Phillips Chemical Company Lp Silica-coated alumina activator-supports for metallocene catalyst compositions
US7884165B2 (en) 2008-07-14 2011-02-08 Chevron Phillips Chemical Company Lp Half-metallocene catalyst compositions and their polymer products
US8114946B2 (en) 2008-12-18 2012-02-14 Chevron Phillips Chemical Company Lp Process for producing broader molecular weight distribution polymers with a reverse comonomer distribution and low levels of long chain branches
US8309485B2 (en) * 2009-03-09 2012-11-13 Chevron Phillips Chemical Company Lp Methods for producing metal-containing sulfated activator-supports
MX2011013662A (es) 2009-06-16 2012-06-19 Chevron Phillips Chemical Co Oligomerizacion de alfa oleifinas usando sistemas de catalizador de metaloceno-ssa y uso de las polialfaolefinas resultantes para preparar mezclas lubricantes.
US7919639B2 (en) 2009-06-23 2011-04-05 Chevron Phillips Chemical Company Lp Nano-linked heteronuclear metallocene catalyst compositions and their polymer products
SG177344A1 (en) 2009-06-29 2012-02-28 Chevron Phillips Chemical Co The use of hydrogen scavenging catalysts to control polymer molecular weight and hydrogen levels in a polymerization reactor
MX2012000250A (es) 2009-06-29 2012-01-25 Chevron Philips Chemical Company Lp Sistemas catalizadores duales de metaloceno para disminuir el indice de fusion e incrementar las velocidades de produccion de polimero.
US9522854B2 (en) * 2009-07-29 2016-12-20 The United States Of America As Represented By The Secretary Of The Navy Process and apparatus for the selective dimerization of terpenes and poly-alpha-olefins with a single-stage reactor and a single-stage fractionation system
WO2011044150A1 (en) * 2009-10-06 2011-04-14 Chevron Phillips Chemical Company Lp Oligomerization of olefin waxes using metallocene-based catalyst systems
CN102648219B (zh) * 2009-12-07 2014-07-23 埃克森美孚化学专利公司 由壬烯生产低聚物
CA2782873C (en) * 2009-12-24 2016-06-28 Exxonmobil Chemical Patents Inc. Process for producing novel synthetic basestocks
KR20130103652A (ko) * 2010-04-02 2013-09-24 이데미쓰 고산 가부시키가이샤 내연 기관용 윤활유 조성물
US8637616B2 (en) 2010-10-07 2014-01-28 Chevron Philips Chemical Company Lp Bridged metallocene catalyst systems with switchable hydrogen and comonomer effects
US8629292B2 (en) 2010-10-07 2014-01-14 Chevron Phillips Chemical Company Lp Stereoselective synthesis of bridged metallocene complexes
US8609793B2 (en) 2010-10-07 2013-12-17 Chevron Phillips Chemical Company Lp Catalyst systems containing a bridged metallocene
US8309748B2 (en) 2011-01-25 2012-11-13 Chevron Phillips Chemical Company Lp Half-metallocene compounds and catalyst compositions
US8809562B2 (en) 2011-06-06 2014-08-19 Chevron Phillips Chemical Company Lp Use of metallocene compounds for cancer treatment
US9365788B2 (en) * 2011-10-10 2016-06-14 Exxonmobil Chemical Patents Inc. Process to produce improved poly alpha olefin compositions
US8821800B2 (en) * 2012-10-18 2014-09-02 Chevron Phillips Chemical Company Lp System and method for catalyst preparation
US8937139B2 (en) 2012-10-25 2015-01-20 Chevron Phillips Chemical Company Lp Catalyst compositions and methods of making and using same
US8895679B2 (en) 2012-10-25 2014-11-25 Chevron Phillips Chemical Company Lp Catalyst compositions and methods of making and using same
US9266793B2 (en) 2012-12-26 2016-02-23 Chevron Phillips Chemical Company Lp Acid-catalyzed olefin oligomerizations
US9034991B2 (en) 2013-01-29 2015-05-19 Chevron Phillips Chemical Company Lp Polymer compositions and methods of making and using same
US8877672B2 (en) 2013-01-29 2014-11-04 Chevron Phillips Chemical Company Lp Catalyst compositions and methods of making and using same
US20140275664A1 (en) * 2013-03-13 2014-09-18 Chevron Phillips Chemical Company Lp Processes for Preparing Low Viscosity Lubricants
WO2014142206A1 (ja) 2013-03-14 2014-09-18 出光興産株式会社 α－オレフィン重合体及び水添α－オレフィン重合体の製造方法
US9708549B2 (en) 2013-12-18 2017-07-18 Chevron Phillips Chemical Company Lp Method for making polyalphaolefins using aluminum halide catalyzed oligomerization of olefins
KR102293490B1 (ko) 2014-02-11 2021-08-26 유니베이션 테크놀로지즈, 엘엘씨 폴리올레핀 생성물의 제조 방법
FR3021664B1 (fr) * 2014-05-30 2020-12-04 Total Marketing Services Polyolefines lubrifiantes de basse viscosite
BR112017003314A2 (pt) 2014-08-19 2018-01-23 Univation Tech Llc suportes de catalisador fluorados e sistemas de catalisador
CN106714967B (zh) 2014-08-19 2020-07-17 尤尼威蒂恩技术有限责任公司 氟化催化剂载体和催化剂系统
SG11201701260WA (en) 2014-08-19 2017-03-30 Univation Tech Llc Fluorinated catalyst supports and catalyst systems
WO2016099702A1 (en) * 2014-12-18 2016-06-23 Dow Global Technologies Llc Process for purification of vent streams
US9732300B2 (en) 2015-07-23 2017-08-15 Chevron Phillipa Chemical Company LP Liquid propylene oligomers and methods of making same
US10435491B2 (en) 2015-08-19 2019-10-08 Chevron Phillips Chemical Company Lp Method for making polyalphaolefins using ionic liquid catalyzed oligomerization of olefins
US10059898B2 (en) 2015-08-21 2018-08-28 Exxonmobil Chemical Patents Inc. High-viscosity metallocene polyalpha-olefins with high electrohydrodynamic performance
JP2018523746A (ja) 2015-08-21 2018-08-23 エクソンモービル・ケミカル・パテンツ・インク 潤滑油基油ブレンド
US10611980B2 (en) 2015-10-15 2020-04-07 Exxonmobil Chemical Patents Inc. Lubricant containing high-viscosity metallocene polyalpha-olefins
CN108473897B (zh) * 2015-11-13 2022-01-04 埃克森美孚研究工程公司 高粘度基础油料组合物
WO2017083085A1 (en) 2015-11-13 2017-05-18 Exxonmobil Research And Engineering Company High viscosity base stock compositions
CN109415641B (zh) 2015-11-13 2021-11-09 埃克森美孚研究工程公司 高粘度基础油料组合物
US9890093B2 (en) * 2015-12-22 2018-02-13 Chevron Phillips Chemical Company Lp Olefin oligomerizations using chemically-treated solid oxides
CA3023946C (en) 2016-05-11 2024-02-13 Reg Synthetic Fuels, Llc Biorenewable kerosene, jet fuel, jet fuel blendstock, and method of manufacturing
US20170335217A1 (en) * 2016-05-19 2017-11-23 Chevron U.S.A. Inc. Alkylation of metallocene-oligomer with isoalkane to make heavy base oil
US9707549B1 (en) * 2016-05-26 2017-07-18 Chevron Phillips Chemical Company Lp Ethylene oligomerization catalyst systems using chemically-treated solid oxides
US9687825B1 (en) 2016-06-27 2017-06-27 Chevron U.S.A. Inc. Stable tungsten-phosphorus modified support for a Fischer-Tropsch catalyst
US10351488B2 (en) 2016-08-02 2019-07-16 Exxonmobil Chemical Patents Inc. Unsaturated polyalpha-olefin materials
US9951158B2 (en) 2016-08-12 2018-04-24 Chevron Phillips Chemical Company Lp Process for reducing the light oligomer content of polypropylene oils
US20180105478A1 (en) * 2016-10-19 2018-04-19 Chevron Phillips Chemical Company Lp Process for Reducing the Light Oligomer Content of Polypropylene Oils
WO2018089457A2 (en) 2016-11-09 2018-05-17 Novvi Llc Synthetic oligomer compositions and methods of manufacture
KR102139364B1 (ko) * 2016-12-20 2020-07-29 주식회사 엘지화학 올레핀 중합체 및 이의 제조 방법
KR102087340B1 (ko) * 2016-12-20 2020-03-10 주식회사 엘지화학 폴리올레핀계 필름
US10240102B2 (en) * 2017-03-16 2019-03-26 Chevron Phillips Chemical Company, Lp Lubricant compositions containing hexene-based oligomers
CN107142133A (zh) * 2017-04-12 2017-09-08 沈阳工业大学 新型润滑油粘度指数改进剂的制备方法
WO2019014540A1 (en) * 2017-07-14 2019-01-17 Novvi Llc BASIC OILS AND PROCESSES FOR PRODUCING THEM
EP3652280A4 (en) 2017-07-14 2021-07-07 Novvi LLC BASE OILS AND THEIR PREPARATION PROCESSES
US10697889B2 (en) 2017-07-21 2020-06-30 Chevron Phillips Chemical Company Lp Methods for determining transition metal compound concentrations in multicomponent liquid systems
US10030086B1 (en) 2017-07-21 2018-07-24 Chevron Phillips Chemical Company Lp Methods for determining transition metal compound concentrations in multicomponent liquid systems
US10336663B2 (en) * 2017-09-12 2019-07-02 Chevron Phillips Chemical Company Lp Methods for the preparation and use of suspensions of chemically-treated solid oxides in an olefin-derived liquid medium
CN109749812B (zh) * 2017-11-03 2021-11-19 中国石油化工股份有限公司 一种制备聚α-烯烃合成润滑油基础油的方法
EP3752540A4 (en) 2018-02-12 2021-12-01 ExxonMobil Chemical Patents Inc. CATALYST SYSTEMS AND PROCESSES FOR POLY ALPHA-OLEFIN WITH HIGH VINYLIDENE CONTENT
US11021553B2 (en) 2018-02-12 2021-06-01 Exxonmobil Chemical Patents Inc. Metallocene dimer selective catalysts and processes to produce poly alpha-olefin dimers
US11078308B2 (en) 2018-02-12 2021-08-03 Exxonmobil Chemical Patents Inc. Processes to produce poly alpha-olefin trimers
US11253844B2 (en) * 2018-03-14 2022-02-22 Evonik Operations Gmbh Oligomerization catalyst and process for the production thereof
US10507445B2 (en) 2018-03-29 2019-12-17 Chevron Phillips Chemical Company Lp Methods for determining transition metal compound concentrations in multicomponent liquid systems
US10679734B2 (en) 2018-03-29 2020-06-09 Chevron Phillips Chemical Company Lp Methods for determining transition metal compound concentrations in multicomponent liquid systems
US10787526B2 (en) 2018-04-06 2020-09-29 Chevron Phillips Chemical Company Lp Method for startup of a gas phase polymerization reactor
CN108484801B (zh) * 2018-05-09 2019-09-10 亚培烯科技（杭州）有限公司 一类含卤素的合成基础油及其制备方法和用途
KR20210036376A (ko) 2018-07-22 2021-04-02 메다센스 바이오메트릭스 엘티디. 투열 요법 동안 생리학적 파라미터들을 모니터링하기 위한 시스템들 및 방법들
KR102604431B1 (ko) * 2018-07-26 2023-11-22 에스케이이노베이션 주식회사 선형 알파 올레핀 제조방법
EP3853273A4 (en) * 2018-09-17 2022-08-31 ExxonMobil Chemical Patents Inc. METALLOCENE-SELECTIVE DIMER CATALYSTS AND METHODS FOR PRODUCING POLY ALPHA-OLEFIN DIMERS
CA3112325A1 (en) 2018-09-27 2020-04-02 Chevron Phillips Chemical Company Lp Processes for producing fluorided solid oxides and uses thereof in metallocene-based catalyst systems
KR102586499B1 (ko) * 2018-10-26 2023-10-11 에스케이이노베이션 주식회사 고점도 윤활기유 제조 방법
KR102111865B1 (ko) * 2018-11-27 2020-05-18 대림산업 주식회사 균일한 구조를 가지는 폴리알파올레핀 및 이의 제조방법
US11014997B2 (en) 2019-05-16 2021-05-25 Chevron Phillips Chemical Company Lp Dual catalyst system for producing high density polyethylenes with long chain branching
EP4010307A1 (en) * 2019-08-09 2022-06-15 ExxonMobil Chemical Patents Inc. Processes for producing poly alpha olefins and method of analysis and apparatuses therefor
CN114555543B (zh) * 2019-08-09 2024-07-12 埃克森美孚化学专利公司 制备聚α-烯烃的方法及其装置
CN112745415B (zh) * 2019-10-30 2022-09-09 中国石油化工股份有限公司 一种制备高粘度指数聚α-烯烃的方法
RU2731901C1 (ru) * 2019-11-07 2020-09-09 Общество С Ограниченной Ответственностью "Ника-Инновации" Способ получения основы синтетических моторных масел
KR102398899B1 (ko) * 2019-11-29 2022-05-17 디엘케미칼 주식회사 낮은 점도 알파-올레핀 올리고머 및 이의 제조방법
EP4103536A1 (en) 2020-02-14 2022-12-21 Chevron Oronite Company LLC Alkyl-substituted hydroxyaromatic compounds with highly- structured alkyl branches
US11339279B2 (en) 2020-04-01 2022-05-24 Chevron Phillips Chemical Company Lp Dual catalyst system for producing LLDPE and MDPE copolymers with long chain branching for film applications
US11174205B2 (en) 2020-04-16 2021-11-16 Chevron Phillips Chemical Company, Lp C20 2-substituted alpha olefins produced by dimerization of branched C10 olefins
US11267919B2 (en) 2020-06-11 2022-03-08 Chevron Phillips Chemical Company Lp Dual catalyst system for producing polyethylene with long chain branching for blow molding applications
CN112517074B (zh) * 2020-11-18 2023-06-27 江苏欣诺科催化剂有限公司 负载型茂金属催化剂及其制备方法和应用
CN117642434A (zh) 2021-05-17 2024-03-01 雪佛龙美国公司 高度结构化的高亚乙烯基丙烯寡聚物及制备方法
US11912809B2 (en) 2022-06-02 2024-02-27 Chevron Phillips Chemical Company Lp High porosity fluorided silica-coated alumina activator-supports and uses thereof in metallocene-based catalyst systems for olefin polymerization
US11753488B1 (en) 2022-06-24 2023-09-12 Chevron Phillips Chemical Company Lp Processes for preparing metallocene-based catalyst systems with an alcohol compound
WO2024129687A1 (en) 2022-12-15 2024-06-20 Chevron Phillips Chemical Company Lp Solid oxide and chemically-treated solid oxide catalysts for the production of polyalphaolefins
WO2024129579A1 (en) 2022-12-15 2024-06-20 Chevron Phillips Chemical Company Lp Oligomerization of alpha olefins using supported metallocene catalysts in selective production of vinylidene dimers
US11920089B1 (en) 2023-05-11 2024-03-05 Chevron Phillips Chemical Company Lp Solid oxide and chemically-treated solid oxide catalysts for the pyrolysis of polyethylene
CN118221849A (zh) * 2024-03-20 2024-06-21 亚培烯科技(上海)有限公司 一种茂金属催化剂组合物在聚α烯烃蜡制备中作为催化剂的用途

Family Cites Families (206)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2001108A (en) 1931-07-06 1935-05-14 Standard Oil Co California Stabilized hydrocarbon oil
US2163622A (en) 1936-02-07 1939-06-27 Standard Oil Co California Compounded lubricating oil
US2081075A (en) 1936-07-06 1937-05-18 Sinclair Refining Co Lubricating oil composition
US2144078A (en) 1937-05-11 1939-01-17 Standard Oil Co Compounded mineral oil
US2095538A (en) 1937-05-14 1937-10-12 Sinclair Refining Co Lubricating oil composition
US2292205A (en) 1938-10-04 1942-08-04 Standard Oil Co Aluminum phenate
US2270183A (en) 1941-03-13 1942-01-13 American Cyanamid Co Dialkylphenol sulphides
USRE22910E (en) 1941-12-31 1947-09-02 E-oxcxs-m
US2451346A (en) 1943-05-10 1948-10-12 Standard Oil Dev Co Compounded lubricating oil
US2416281A (en) 1944-06-09 1947-02-25 Socony Vacuum Oil Co Inc Mineral oil composition
US2399877A (en) 1944-07-07 1946-05-07 Standard Oil Dev Co Chemical process, etc.
US2451345A (en) 1944-10-24 1948-10-12 Standard Oil Dev Co Compounded lubricating oil
US2485861A (en) 1945-10-01 1949-10-25 Sumner E Campbell Lubricating oil
US2501731A (en) 1946-10-14 1950-03-28 Union Oil Co Modified lubricating oil
US2501732A (en) 1946-10-14 1950-03-28 Union Oil Co Modified lubricating oil
US2585520A (en) 1948-12-03 1952-02-12 Shell Dev Lubricating compositions containing highly basic metal sulfonates
US2671758A (en) 1949-09-27 1954-03-09 Shell Dev Colloidal compositions and derivatives thereof
US2616911A (en) 1951-03-16 1952-11-04 Lubrizol Corp Organic alkaline earth metal complexes formed by use of sulfonic promoters
US2616904A (en) 1951-03-16 1952-11-04 Lubrizol Corp Organic alkaline earth metal complex and method of making same
US2617049A (en) 1951-03-16 1952-11-04 Lubrizol Corp Organic barium complexes and method of making same
US2616924A (en) 1951-03-16 1952-11-04 Lubrizol Corp Organic alkaline earth metal complexes and method of making same
US2616925A (en) 1951-03-16 1952-11-04 Lubrizol Corp Organic alkaline earth metal complexes formed by use of thiophosphoric promoters
US2695910A (en) 1951-05-03 1954-11-30 Lubrizol Corp Methods of preparation of superbased salts
US2616905A (en) 1952-03-13 1952-11-04 Lubrizol Corp Organic alkaline earth metal complexes and methods of making same
US2616906A (en) 1952-03-28 1952-11-04 Lubrizol Corp Organic alkaline earth metal complexes and method of making same
DE1248643B (de) 1959-03-30 1967-08-31 The Lubrizol Corporation, Cleveland, Ohio (V. St. A.) Verfahren zur Herstellung von öllöslichen aeylierten Aminen
NL124842C (pt) 1959-08-24
NL124306C (pt) 1959-08-24
NL262417A (pt) 1960-03-15
US3248179A (en) 1962-02-26 1966-04-26 Phillips Petroleum Co Method and apparatus for the production of solid polymers of olefins
US3178368A (en) 1962-05-15 1965-04-13 California Research Corp Process for basic sulfurized metal phenates
US3185704A (en) 1962-09-04 1965-05-25 Exxon Research Engineering Co Formamide of mono-alkenyl succinimide
NL296139A (pt) 1963-08-02
US3242099A (en) 1964-03-27 1966-03-22 Union Carbide Corp Olefin polymerization catalysts
US3368972A (en) 1965-01-06 1968-02-13 Mobil Oil Corp High molecular weight mannich bases as engine oil additives
NL145565B (nl) 1965-01-28 1975-04-15 Shell Int Research Werkwijze ter bereiding van een smeermiddelcompositie.
US3574576A (en) 1965-08-23 1971-04-13 Chevron Res Distillate fuel compositions having a hydrocarbon substituted alkylene polyamine
US3985802A (en) 1965-10-22 1976-10-12 Standard Oil Company (Indiana) Lubricating oils containing high molecular weight Mannich condensation products
US3539633A (en) 1965-10-22 1970-11-10 Standard Oil Co Di-hydroxybenzyl polyamines
US3697574A (en) 1965-10-22 1972-10-10 Standard Oil Co Boron derivatives of high molecular weight mannich condensation products
US3272746A (en) 1965-11-22 1966-09-13 Lubrizol Corp Lubricating composition containing an acylated nitrogen compound
US3367867A (en) 1966-01-04 1968-02-06 Chevron Res Low-foaming overbased phenates
US3413347A (en) 1966-01-26 1968-11-26 Ethyl Corp Mannich reaction products of high molecular weight alkyl phenols, aldehydes and polyaminopolyalkyleneamines
US3480548A (en) 1967-06-21 1969-11-25 Texaco Inc Alkaline earth metal polyborate carbonate overbased alkaline earth metal sulfonate lube oil composition
US3496105A (en) 1967-07-12 1970-02-17 Lubrizol Corp Anion exchange process and composition
US3876722A (en) 1968-09-16 1975-04-08 Exxon Research Engineering Co Copolymer of c' 3 'to c' 8 'alpha-olefin and c' 22 'to c' 40 'alpha-olefin
US3726882A (en) 1968-11-08 1973-04-10 Standard Oil Co Ashless oil additives
US3725480A (en) 1968-11-08 1973-04-03 Standard Oil Co Ashless oil additives
US3629109A (en) 1968-12-19 1971-12-21 Lubrizol Corp Basic magnesium salts processes and lubricants and fuels containing the same
US3576743A (en) 1969-04-11 1971-04-27 Lubrizol Corp Lubricant and fuel additives and process for making the additives
US3829381A (en) 1970-02-02 1974-08-13 Lubrizol Corp Boron-and calcium-containing compositions and process
US3679584A (en) 1970-06-01 1972-07-25 Texaco Inc Overbased alkaline earth metal sulfonate lube oil composition manufacture
US3798247A (en) 1970-07-13 1974-03-19 Standard Oil Co Oil soluble aliphatic acid derivatives of molecular weight mannich condensation products
US3803039A (en) 1970-07-13 1974-04-09 Standard Oil Co Oil solution of aliphatic acid derivatives of high molecular weight mannich condensation product
GB1443436A (en) 1973-01-29 1976-07-21 Rca Corp Antenna rotator controller and direction indicating display
US4231759A (en) 1973-03-12 1980-11-04 Standard Oil Company (Indiana) Liquid hydrocarbon fuels containing high molecular weight Mannich bases
US3865737A (en) 1973-07-02 1975-02-11 Continental Oil Co Process for preparing highly-basic, magnesium-containing dispersion
US3907691A (en) 1974-07-15 1975-09-23 Chevron Res Extreme-pressure mixed metal borate lubricant
SU644811A1 (ru) 1975-07-14 1980-02-05 Всесоюзный научно-исследовательский институт по переработке нефти Способ получени сульфидалкилфенол тной присадки к смазочных маслам
IT1059547B (it) 1975-12-24 1982-06-21 Liquichimica Robassomero Spa Procedimento per la preparazione di additivi per olii lubrificanti
US4129589A (en) 1976-07-15 1978-12-12 Surpass Chemicals Limited Over-based magnesium salts of sulphonic acids
FR2366588A1 (fr) 1976-10-01 1978-04-28 Thomson Csf Coupleur multivoies pour liaison par fibres optiques
US4137184A (en) 1976-12-16 1979-01-30 Chevron Research Company Overbased sulfonates
US4142980A (en) 1977-09-09 1979-03-06 Standard Oil Company (Indiana) Mannich reaction products made with alkyphenol substituted aliphatic unsaturated carboxylic acids
US4235435A (en) 1978-08-25 1980-11-25 Stewart & Shea Sheet sorter
US4234435A (en) 1979-02-23 1980-11-18 The Lubrizol Corporation Novel carboxylic acid acylating agents, derivatives thereof, concentrate and lubricant compositions containing the same, and processes for their preparation
US4873009A (en) 1982-03-29 1989-10-10 Amoco Corporation Borated lube oil additive
US4647387A (en) 1985-04-11 1987-03-03 Witco Chemical Corp. Succinic anhydride promoter overbased magnesium sulfonates and oils containing same
US5177276A (en) * 1985-06-17 1993-01-05 Chevron Research Company Alpha-olefin oligomers useful as base stocks and viscosity index improvers, and lubricating oils containing same
US4808561A (en) 1985-06-21 1989-02-28 Exxon Chemical Patents Inc. Supported polymerization catalyst
US4939217A (en) 1987-04-03 1990-07-03 Phillips Petroleum Company Process for producing polyolefins and polyolefin catalysts
US4794096A (en) 1987-04-03 1988-12-27 Fina Technology, Inc. Hafnium metallocene catalyst for the polymerization of olefins
US4827073A (en) * 1988-01-22 1989-05-02 Mobil Oil Corporation Process for manufacturing olefinic oligomers having lubricating properties
EP0422019B1 (en) * 1988-06-23 1993-12-01 Mobil Oil Corporation Olefinic oligomers having lubricating properties and process of making such oligomers
US4880550A (en) 1988-08-26 1989-11-14 Amoco Corporation Preparation of high base calcium sulfonates
IT8919252A0 (it) * 1989-01-31 1989-01-31 Ilano Catalizzatori per la polimerizzazione di olefine.
US4965003A (en) 1989-04-21 1990-10-23 Texaco Inc. Borated detergent additive by an improved process
US4965004A (en) 1989-04-21 1990-10-23 Texaco Inc. Process for a borated detergent additive
EP0500944B1 (en) * 1990-07-24 1998-10-07 Mitsui Chemicals, Inc. Catalyst for alpha-olefin polymerization and production of poly-alpha-olefin therewith
US5270273A (en) * 1991-04-29 1993-12-14 Mobil Oil Corporation Olefin oligomerization catalyst
US5631335A (en) 1991-05-09 1997-05-20 Phillips Petroleum Company Process of polymerizing olefins using diphenylsilyl or dimethyl tin bridged 1-methyl fluorenyl metallocenes
US5210352A (en) 1991-05-09 1993-05-11 Phillips Petroleum Company Fluorene compounds
US5436305A (en) 1991-05-09 1995-07-25 Phillips Petroleum Company Organometallic fluorenyl compounds, preparation, and use
US5401817A (en) 1991-05-09 1995-03-28 Phillips Petroleum Company Olefin polymerization using silyl-bridged metallocenes
US5466766A (en) 1991-05-09 1995-11-14 Phillips Petroleum Company Metallocenes and processes therefor and therewith
US5191132A (en) 1991-05-09 1993-03-02 Phillips Petroleum Company Cyclopentadiene type compounds and method for making
US5571880A (en) 1991-05-09 1996-11-05 Phillips Petroleum Company Organometallic fluorenyl compounds and use thereof in an alpha-olefin polymerization process
US5399636A (en) 1993-06-11 1995-03-21 Phillips Petroleum Company Metallocenes and processes therefor and therewith
US5347026A (en) 1993-06-11 1994-09-13 Phillips Petroleum Company Fluorene compounds and methods for making
US5451649A (en) 1991-05-09 1995-09-19 Phillips Petroleum Company Organometallic fluorenyl compounds, preparation, and use
US5594078A (en) 1991-07-23 1997-01-14 Phillips Petroleum Company Process for producing broad molecular weight polyolefin
US5668230A (en) 1991-07-23 1997-09-16 Phillips Petroleum Company Olefin polymerization
EP0544308B1 (en) * 1991-11-28 1998-02-18 Showa Denko Kabushikikaisha Novel metallocene and process for producing polyolefin using the same
US6043401A (en) 1992-05-26 2000-03-28 Bp Amoco Corporation Reactive, low molecular weight, viscous poly(1-olefins) and copoly(1-olefins) and their method of manufacture
IT1264680B1 (it) * 1993-07-07 1996-10-04 Spherilene Srl Catalizzatori supportati per la polimerizzazione delle olefine
US5576259A (en) 1993-10-14 1996-11-19 Tosoh Corporation Process for producing α-olefin polymer
DE4344688A1 (de) * 1993-12-27 1995-06-29 Hoechst Ag Metallocenverbindung
US5416179A (en) * 1994-03-16 1995-05-16 Phillips Petroleum Company Catalyst compositions and olefin polymerization
US5496781A (en) 1994-05-16 1996-03-05 Phillips Petroleum Company Metallocene catalyst systems, preparation, and use
US5498581A (en) 1994-06-01 1996-03-12 Phillips Petroleum Company Method for making and using a supported metallocene catalyst system
US5541272A (en) 1994-06-03 1996-07-30 Phillips Petroleum Company High activity ethylene selective metallocenes
US5420320A (en) 1994-06-08 1995-05-30 Phillips Petroleum Company Method for preparing cyclopentadienyl-type ligands and metallocene compounds
US5563284A (en) 1994-09-09 1996-10-08 Phillips Petroleum Company Cyclopentadienyl-type ligands, metallocenes, catalyst systems, preparation, and use
EP0727443B1 (en) 1995-02-20 2001-01-17 Tosoh Corporation Catalyst for olefin polymerization and process for producing olefin polymers
US5631203A (en) 1995-05-04 1997-05-20 Phillips Petroleum Company Metallocene compounds and preparation thereof containing terminal alkynes
DE19517851A1 (de) * 1995-05-16 1996-11-21 Hoechst Ag Organometallverbindung
US5654454A (en) 1995-05-30 1997-08-05 Phillips Petroleum Company Metallocene preparation and use
DE19519884A1 (de) * 1995-05-31 1996-12-05 Basf Ag Verfahren zur Herstellung von verbrückten Metallocenkomplexen
US5756609A (en) * 1995-10-19 1998-05-26 Amoco Corporation Homogeneous metallocene-based olefin polymerization system with increased activity
ATE199093T1 (de) * 1995-11-28 2001-02-15 Lg Chemical Ltd Verfahren zur herstellung von olefinpolymeren mittels metallocenkatalysator
US5919983A (en) 1996-03-27 1999-07-06 The Dow Chemical Company Highly soluble olefin polymerization catalyst activator
GB9611316D0 (en) 1996-05-31 1996-08-07 Exxon Chemical Patents Inc Overbased metal-containing detergents
GB9611318D0 (en) 1996-05-31 1996-08-07 Exxon Chemical Patents Inc Overbased metal-containing detergents
GB9611428D0 (en) 1996-05-31 1996-08-07 Exxon Chemical Patents Inc Overbased metal-containing detergents
GB9611424D0 (en) 1996-05-31 1996-08-07 Exxon Chemical Patents Inc Overbased metal-containing detergents
WO1998001481A1 (de) * 1996-07-04 1998-01-15 Basf Aktiengesellschaft Verfahren zur herstellung von geträgerten übergangsmetallkatalysatoren
US5705579A (en) 1996-07-17 1998-01-06 Phillips Petroleum Company Olefin polymerization
DE19644039A1 (de) * 1996-10-31 1998-05-07 Hoechst Ag Metallocene
DE19719517A1 (de) * 1997-05-09 1998-11-12 Basf Ag Katalysatorlösung zur Polymerisation von alpha-Olefinen
WO1999005152A1 (de) * 1997-07-28 1999-02-04 Targor Gmbh Verfahren zur herstellung von metallocenen
DE19737306A1 (de) * 1997-08-27 1999-03-04 Basf Ag Katalysatorzubereitung für die (Co)polymerisation von Alk-l-enen
FR2769245B1 (fr) * 1997-10-02 1999-10-29 Atochem Elf Sa Support solide activateur des catalyseurs metallocenes en polymerisation des olefines, son procede de preparation, systeme catalytique et procede de polymerisation correspondants
CN1243763C (zh) * 1998-01-14 2006-03-01 蒙特尔技术有限公司 茂金属化合物的制备方法
US6300271B1 (en) 1998-05-18 2001-10-09 Phillips Petroleum Company Compositions that can produce polymers
US6107230A (en) * 1998-05-18 2000-08-22 Phillips Petroleum Company Compositions that can produce polymers
US6165929A (en) 1998-05-18 2000-12-26 Phillips Petroleum Company Compositions that can produce polymers
US6894131B2 (en) * 1998-08-21 2005-05-17 Univation Technologies, Llc Polymerization process using a metallocene catalyst system
US6632901B2 (en) * 1998-08-21 2003-10-14 Univation Technologies, Llc Polymerization process using an improved bulky ligand metallocene-type catalyst system
BR9913221B1 (pt) * 1998-08-26 2008-11-18 composiÇço catalisadora suportada de metaloceno.
US6294494B1 (en) 1998-12-18 2001-09-25 Phillips Petroleum Company Olefin polymerization processes and products thereof
US6169051B1 (en) * 1999-01-25 2001-01-02 Chisso Corporation Metallocene compounds, processes for the preparation thereof, catalyst components for olefin polymerization, and processes for the production of olefin polymers
US6326493B1 (en) * 1999-01-25 2001-12-04 Chisso Corporation Metallocene compounds, processes for the preparation thereof, catalyst components for olefin polymerization, and processes for the production of olefin polymers
US6187880B1 (en) 1999-02-16 2001-02-13 Phillips Petroleum Company Process for producing an olefin polymer using a metallocene
KR100676105B1 (ko) * 1999-09-23 2007-02-01 비피 코포레이션 노쓰 아메리카 인코포레이티드 올리고머 오일 및 그의 제조
US6355594B1 (en) 1999-09-27 2002-03-12 Phillips Petroleum Company Organometal catalyst compositions
US6376415B1 (en) * 1999-09-28 2002-04-23 Phillips Petroleum Company Organometal catalyst compositions
US6395666B1 (en) * 1999-09-29 2002-05-28 Phillips Petroleum Company Organometal catalyst compositions
US6391816B1 (en) 1999-10-27 2002-05-21 Phillips Petroleum Organometal compound catalyst
US6548441B1 (en) 1999-10-27 2003-04-15 Phillips Petroleum Company Organometal catalyst compositions
US6548442B1 (en) * 1999-12-03 2003-04-15 Phillips Petroleum Company Organometal compound catalyst
DE19960123A1 (de) 1999-12-13 2001-06-21 Basf Ag Verfahren zur homogenkatalytischen Herstellung von hochverzweigten amorphen Polyolefinen
US6750302B1 (en) 1999-12-16 2004-06-15 Phillips Petroleum Company Organometal catalyst compositions
US6524987B1 (en) 1999-12-22 2003-02-25 Phillips Petroleum Company Organometal catalyst compositions
US6667274B1 (en) * 1999-12-30 2003-12-23 Phillips Petroleum Company Polymerization catalysts
US20080281063A9 (en) * 1999-12-30 2008-11-13 Sukhadia Ashish M Ethylene polymers and copolymers with high optical opacity and methods of making the same
US20030130447A1 (en) * 1999-12-30 2003-07-10 Welch M Bruce Method and catalyst system for producing polyolefins with a selected melt index
US7041617B2 (en) * 2004-01-09 2006-05-09 Chevron Phillips Chemical Company, L.P. Catalyst compositions and polyolefins for extrusion coating applications
US6528448B1 (en) 2000-04-28 2003-03-04 Phillips Petroleum Company Polymerization catalyst compositions and processes to produce polymers and bimodal polymers
JP4931269B2 (ja) * 2000-05-30 2012-05-16 出光興産株式会社 α−オレフィン重合体の製造方法及び潤滑油
US20020128532A1 (en) * 2000-05-31 2002-09-12 Chevron Chemical Company Llc High viscosity polyalphaolefins prepared with ionic liquid catalyst
US7259284B2 (en) * 2000-05-31 2007-08-21 Chevron Phillips Chemical Company, Lp Method for manufacturing high viscosity polyalphaolefins using ionic liquid catalysts
US6395948B1 (en) * 2000-05-31 2002-05-28 Chevron Chemical Company Llc High viscosity polyalphaolefins prepared with ionic liquid catalyst
US6858767B1 (en) * 2000-08-11 2005-02-22 Uniroyal Chemical Company, Inc. Process for producing liquid polyalphaolefin polymer, metallocene catalyst therefor, the resulting polymer and lubricant containing same
US6720396B2 (en) * 2000-11-30 2004-04-13 Univation Technologies, Llc Polymerization process
MY139205A (en) * 2001-08-31 2009-08-28 Pennzoil Quaker State Co Synthesis of poly-alpha olefin and use thereof
JP2003147009A (ja) 2001-11-09 2003-05-21 Idemitsu Petrochem Co Ltd オレフィン系重合体の製造方法
US20030092564A1 (en) * 2001-11-15 2003-05-15 Industrial Technology Research Institute Metallocene catalyst supported on a molecular sieve having "tubules-within-a-tubule" morphology for preparing olefin polymer
US6646174B2 (en) * 2002-03-04 2003-11-11 Bp Corporation North America Inc. Co-oligomerization of 1-dodecene and 1-decene
EP1497243A2 (en) * 2002-04-22 2005-01-19 Chevron Phillips Chemical Company LP Method for manufacturing high viscosity polyalphaolefins using ionic liquid catalysts
US6706828B2 (en) * 2002-06-04 2004-03-16 Crompton Corporation Process for the oligomerization of α-olefins having low unsaturation
AU2003250043A1 (en) * 2002-07-15 2004-02-02 Basell Polyolefine Gmbh Preparation of catalyst systems
US6995279B2 (en) * 2002-08-02 2006-02-07 Chisso Corporation Metallocene compounds, processes for the production of olefin polymers using catalysts containing the compounds, and olefin polymers produced by the processes
AU2003261617A1 (en) * 2002-08-29 2004-03-19 Lg Chem, Ltd. Fulvene, metallocene catalysts and preparation method thereof, and preparation of polyolefines copolymer using the same
RU2335504C2 (ru) * 2003-05-08 2008-10-10 Базелль Полиолефине Гмбх Способ получения галогенидметаллоценовых соединений
US20040259743A1 (en) 2003-06-18 2004-12-23 The Lubrizol Corporation, A Corporation Of The State Of Ohio Lubricating oil composition with antiwear performance
US7501372B2 (en) 2003-11-21 2009-03-10 Chevron Phillips Chemical Company Lp Catalyst compositions for producing polyolefins in the absence of cocatalysts
US7045583B2 (en) * 2003-12-22 2006-05-16 Exxon Mobil Chemical Patents Inc. Olefin polymerization catalyst system
US7119153B2 (en) * 2004-01-21 2006-10-10 Jensen Michael D Dual metallocene catalyst for producing film resins with good machine direction (MD) elmendorf tear strength
CN100487005C (zh) * 2004-01-30 2009-05-13 托塔尔石油化学产品研究弗吕公司 茂金属催化用的活化载体
US7148298B2 (en) * 2004-06-25 2006-12-12 Chevron Phillips Chemical Company, L.P. Polymerization catalysts for producing polymers with low levels of long chain branching
US7294599B2 (en) * 2004-06-25 2007-11-13 Chevron Phillips Chemical Co. Acidic activator-supports and catalysts for olefin polymerization
US7214749B2 (en) 2004-07-09 2007-05-08 The Texas A&M University Systems Catalyst system for high activity and stereoselectivity in the homopolymerization and copolymerization of olefins
JP2008519092A (ja) 2004-11-04 2008-06-05 シェブロン フィリップス ケミカル カンパニー エルピー 双峰型樹脂を製造するための有機クロム／メタロセン併用触媒
US7163906B2 (en) * 2004-11-04 2007-01-16 Chevron Phillips Chemical Company, Llp Organochromium/metallocene combination catalysts for producing bimodal resins
US7199073B2 (en) 2004-11-10 2007-04-03 Chevron Phillips Chemical Company, Lp Resins that yield low haze films and the process for their production
US7527686B2 (en) * 2004-11-23 2009-05-05 Chevron Phillips Chemical Company, Lp Olefin waxes having improved hardness or viscosity
EP1661921B1 (en) * 2004-11-26 2019-07-17 Mitsui Chemicals, Inc. Synthetic lubricating oil and lubricating oil composition thereof
RU2287552C2 (ru) 2004-12-22 2006-11-20 Институт Проблем Химической Физики Российской Академии Наук (Ипхф Ран) Способ получения полиолефиновых основ синтетических масел
US7026494B1 (en) 2005-01-10 2006-04-11 Chevron Phillips Chemical Company, Lp Polymerization catalysts for producing high melt index polymers without the use of hydrogen
US8399390B2 (en) * 2005-06-29 2013-03-19 Exxonmobil Chemical Patents Inc. HVI-PAO in industrial lubricant and grease compositions
US7989670B2 (en) * 2005-07-19 2011-08-02 Exxonmobil Chemical Patents Inc. Process to produce high viscosity fluids
AU2006270083B2 (en) * 2005-07-19 2011-01-20 Exxonmobil Chemical Patents Inc. Lubricants from mixed alpha-olefin feeds
WO2007011462A1 (en) * 2005-07-19 2007-01-25 Exxonmobil Chemical Patents Inc. Lubricants from mixed alpha-olefin feeds
AU2006270436B2 (en) * 2005-07-19 2011-12-15 Exxonmobil Chemical Patents Inc. Polyalpha-olefin compositions and processes to produce the same
US7312283B2 (en) * 2005-08-22 2007-12-25 Chevron Phillips Chemical Company Lp Polymerization catalysts and process for producing bimodal polymers in a single reactor
US7226886B2 (en) 2005-09-15 2007-06-05 Chevron Phillips Chemical Company, L.P. Polymerization catalysts and process for producing bimodal polymers in a single reactor
US20070105711A1 (en) * 2005-09-30 2007-05-10 Sumitomo Chemical Company, Limited Process for producing prepolymerization catalyst component, prepolymerization catalyst component and process for producing olefin polymer using the same
US7517939B2 (en) * 2006-02-02 2009-04-14 Chevron Phillips Chemical Company, Lp Polymerization catalysts for producing high molecular weight polymers with low levels of long chain branching
US7619047B2 (en) 2006-02-22 2009-11-17 Chevron Phillips Chemical Company, Lp Dual metallocene catalysts for polymerization of bimodal polymers
US7547811B2 (en) * 2006-03-24 2009-06-16 Exxonmobil Chemical Patents Inc. High viscosity polyalphaolefins based on 1-hexene, 1-dodecene and 1-tetradecene
US7576163B2 (en) * 2006-03-31 2009-08-18 Chevron Phillips Chemical Company, Lp Polymerization catalysts for producing polymers with low levels of long chain branching
US20070255022A1 (en) * 2006-04-28 2007-11-01 Fina Technology, Inc. Fluorinated transition metal catalysts and formation thereof
JP5613416B2 (ja) * 2006-07-19 2014-10-22 エクソンモービル・ケミカル・パテンツ・インク 高粘度流体の生成プロセス
DE102007015707A1 (de) * 2007-04-02 2008-10-09 Topas Advanced Polymers Gmbh Cycloolefin-Copolymere, Verfahren zu ihrer Herstellung, deren Verwendung und Katalysatoren
US7897539B2 (en) 2007-05-16 2011-03-01 Chevron Phillips Chemical Company Lp Methods of preparing a polymerization catalyst
US8513478B2 (en) * 2007-08-01 2013-08-20 Exxonmobil Chemical Patents Inc. Process to produce polyalphaolefins
US7799721B2 (en) 2007-09-28 2010-09-21 Chevron Phillips Chemical Company Lp Polymerization catalysts for producing polymers with high comonomer incorporation
US8119553B2 (en) 2007-09-28 2012-02-21 Chevron Phillips Chemical Company Lp Polymerization catalysts for producing polymers with low melt elasticity
US8440872B2 (en) * 2007-10-05 2013-05-14 Exxonmobil Research And Engineering Company Process for preparing poly alpha olefins and lubricant basestocks from Fischer-Tropsch liquids
US8143467B2 (en) * 2007-12-18 2012-03-27 Exxonmobil Research And Engineering Company Process for synthetic lubricant production
US7884163B2 (en) 2008-03-20 2011-02-08 Chevron Phillips Chemical Company Lp Silica-coated alumina activator-supports for metallocene catalyst compositions
US7880047B2 (en) * 2008-05-06 2011-02-01 Chemtura Corporation Polyalphaolefins and processes for forming polyalphaolefins
EP2196481A1 (en) 2008-12-12 2010-06-16 Total Petrochemicals Research Feluy Preparation of long-chain branched isotactic polypropylene.
SG172399A1 (en) 2008-12-26 2011-07-28 Idemitsu Kosan Co PROCESS FOR PRODUCING a-OLEFIN POLYMER, a-OLEFIN POLYMER, AND LUBRICATING OIL COMPOSITION
MX2011013662A (es) 2009-06-16 2012-06-19 Chevron Phillips Chemical Co Oligomerizacion de alfa oleifinas usando sistemas de catalizador de metaloceno-ssa y uso de las polialfaolefinas resultantes para preparar mezclas lubricantes.
WO2011044150A1 (en) * 2009-10-06 2011-04-14 Chevron Phillips Chemical Company Lp Oligomerization of olefin waxes using metallocene-based catalyst systems

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