EP3853273A4 - Metallocene dimer selective catalysts and processes to produce poly alpha-olefin dimers - Google Patents

Metallocene dimer selective catalysts and processes to produce poly alpha-olefin dimers Download PDF

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Publication number
EP3853273A4
EP3853273A4 EP19862626.9A EP19862626A EP3853273A4 EP 3853273 A4 EP3853273 A4 EP 3853273A4 EP 19862626 A EP19862626 A EP 19862626A EP 3853273 A4 EP3853273 A4 EP 3853273A4
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EP
European Patent Office
Prior art keywords
processes
poly alpha
produce poly
selective catalysts
olefin dimers
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
EP19862626.9A
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German (de)
French (fr)
Other versions
EP3853273A1 (en
Inventor
Patrick C. Chen
Jennifer L. Rapp
Jian Yang
Jo Ann M. Canich
Hua Zhou
Craig J. Emett
Kyle G. Lewis
Babak LOTFIZADEHDEHKORDI
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Chemical Patents Inc
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ExxonMobil Chemical Patents Inc
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Filing date
Publication date
Priority claimed from US16/270,085 external-priority patent/US11084894B2/en
Application filed by ExxonMobil Chemical Patents Inc filed Critical ExxonMobil Chemical Patents Inc
Publication of EP3853273A1 publication Critical patent/EP3853273A1/en
Publication of EP3853273A4 publication Critical patent/EP3853273A4/en
Pending legal-status Critical Current

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    • C10M107/00—Lubricating compositions characterised by the base-material being a macromolecular compound
    • C10M107/02—Hydrocarbon polymers; Hydrocarbon polymers modified by oxidation
    • C10M107/10—Hydrocarbon polymers; Hydrocarbon polymers modified by oxidation containing aliphatic monomer having more than 4 carbon atoms
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    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/26—Catalytic processes with hydrides or organic compounds
    • C07C2/32—Catalytic processes with hydrides or organic compounds as complexes, e.g. acetyl-acetonates
    • C07C2/34—Metal-hydrocarbon complexes
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    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
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    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/14—Catalytic processes with inorganic acids; with salts or anhydrides of acids
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    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
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    • C07C2/64—Addition to a carbon atom of a six-membered aromatic ring
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    • C07C41/01—Preparation of ethers
    • C07C41/18—Preparation of ethers by reactions not forming ether-oxygen bonds
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    • B01J2231/20—Olefin oligomerisation or telomerisation
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    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0225—Complexes comprising pentahapto-cyclopentadienyl analogues
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40—Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/49—Hafnium
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    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
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    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
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    • C08F2420/00—Metallocene catalysts
    • C08F2420/07—Heteroatom-substituted Cp, i.e. Cp or analog where at least one of the substituent of the Cp or analog ring is or contains a heteroatom
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    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
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    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Polymerisation Methods In General (AREA)
EP19862626.9A 2018-09-17 2019-08-09 Metallocene dimer selective catalysts and processes to produce poly alpha-olefin dimers Pending EP3853273A4 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201862732311P 2018-09-17 2018-09-17
US16/270,085 US11084894B2 (en) 2018-02-12 2019-02-07 Catalyst systems and processes for poly alpha-olefin having high vinylidene content
PCT/US2019/046015 WO2020060690A1 (en) 2018-09-17 2019-08-09 Metallocene dimer selective catalysts and processes to produce poly alpha-olefin dimers

Publications (2)

Publication Number Publication Date
EP3853273A1 EP3853273A1 (en) 2021-07-28
EP3853273A4 true EP3853273A4 (en) 2022-08-31

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Application Number Title Priority Date Filing Date
EP19863138.4A Pending EP3853191A4 (en) 2018-09-17 2019-08-09 Processes to produce poly alpha-olefin trimer and apparatus therefor
EP19861876.1A Pending EP3853272A4 (en) 2018-09-17 2019-08-09 Processes to produce poly alpha-olefin trimers
EP19862626.9A Pending EP3853273A4 (en) 2018-09-17 2019-08-09 Metallocene dimer selective catalysts and processes to produce poly alpha-olefin dimers

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EP19863138.4A Pending EP3853191A4 (en) 2018-09-17 2019-08-09 Processes to produce poly alpha-olefin trimer and apparatus therefor
EP19861876.1A Pending EP3853272A4 (en) 2018-09-17 2019-08-09 Processes to produce poly alpha-olefin trimers

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EP (3) EP3853191A4 (en)
CN (3) CN113015755B (en)
WO (3) WO2020060691A1 (en)

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CN114845980A (en) 2019-10-28 2022-08-02 埃克森美孚化学专利公司 Dimer-selective metallocene catalyst, non-aromatic hydrocarbon soluble activator and method for preparing poly alpha-olefin oligomer using the same
CN113861422B (en) * 2021-11-15 2023-09-19 西北工业大学 Preparation method of polythioether corrosion inhibitor containing cobaltocene cation side group and corrosion inhibitor system

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