BRPI0914143A8 - Processo para preparar aldeídos ou ácidos carboxílicos insaturados, por oxidação catalítica heterogênea de fase gasosa de hidrocarbonetos insaturados ou saturados, processo para preparar ácidos carboxílicos insaturados purificados; instrumento para preparar um ácido carboxílico insaturado purificado; processo para preparar um polímero baseado em um ácido carboxílico insaturado - Google Patents

Processo para preparar aldeídos ou ácidos carboxílicos insaturados, por oxidação catalítica heterogênea de fase gasosa de hidrocarbonetos insaturados ou saturados, processo para preparar ácidos carboxílicos insaturados purificados; instrumento para preparar um ácido carboxílico insaturado purificado; processo para preparar um polímero baseado em um ácido carboxílico insaturado

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Publication number
BRPI0914143A8
BRPI0914143A8 BRPI0914143A BRPI0914143A BRPI0914143A8 BR PI0914143 A8 BRPI0914143 A8 BR PI0914143A8 BR PI0914143 A BRPI0914143 A BR PI0914143A BR PI0914143 A BRPI0914143 A BR PI0914143A BR PI0914143 A8 BRPI0914143 A8 BR PI0914143A8
Authority
BR
Brazil
Prior art keywords
preparing
unsaturated carboxylic
unsaturated
carboxylic acid
carboxylic acids
Prior art date
Application number
BRPI0914143A
Other languages
English (en)
Inventor
Zanthoff Horst-Werner
Sabbagh Andreas
Becker Oliver
Kuppinger Franz-Felix
Sauer Jorg
Brausch Nicole
Fruhling Dennis
Weber Markus
Original Assignee
Evonik Stockhausen Gmbh
Evonik Degussa Gmbh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Evonik Stockhausen Gmbh, Evonik Degussa Gmbh filed Critical Evonik Stockhausen Gmbh
Publication of BRPI0914143A2 publication Critical patent/BRPI0914143A2/pt
Publication of BRPI0914143A8 publication Critical patent/BRPI0914143A8/pt

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/06Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds in tube reactors; the solid particles being arranged in tubes
    • B01J8/067Heating or cooling the reactor
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24Stationary reactors without moving elements inside
    • B01J19/248Reactors comprising multiple separated flow channels
    • B01J19/249Plate-type reactors
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002Mixed oxides other than spinels, e.g. perovskite
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85Chromium, molybdenum or tungsten
    • B01J23/888Tungsten
    • B01J23/8885Tungsten containing also molybdenum
    • B01J35/56
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/0215Coating
    • B01J37/0219Coating the coating containing organic compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/0215Coating
    • B01J37/0225Coating of metal substrates
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C07C45/34Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
    • C07C45/35Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds in propene or isobutene
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/327Formation of non-aromatic carbon-to-carbon double bonds only
    • C07C5/333Catalytic processes
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • C07C51/252Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008Controlling the process
    • B01J2208/00017Controlling the temperature
    • B01J2208/00106Controlling the temperature by indirect heat exchange
    • B01J2208/00168Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles
    • B01J2208/00212Plates; Jackets; Cylinders
    • B01J2208/00221Plates; Jackets; Cylinders comprising baffles for guiding the flow of the heat exchange medium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/02Processes carried out in the presence of solid particles; Reactors therefor with stationary particles
    • B01J2208/023Details
    • B01J2208/024Particulate material
    • B01J2208/025Two or more types of catalyst
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00002Chemical plants
    • B01J2219/00004Scale aspects
    • B01J2219/00006Large-scale industrial plants
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00002Chemical plants
    • B01J2219/00027Process aspects
    • B01J2219/0004Processes in series
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/24Stationary reactors without moving elements inside
    • B01J2219/2401Reactors comprising multiple separate flow channels
    • B01J2219/245Plate-type reactors
    • B01J2219/2451Geometry of the reactor
    • B01J2219/2453Plates arranged in parallel
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/24Stationary reactors without moving elements inside
    • B01J2219/2401Reactors comprising multiple separate flow channels
    • B01J2219/245Plate-type reactors
    • B01J2219/2476Construction materials
    • B01J2219/2477Construction materials of the catalysts
    • B01J2219/2479Catalysts coated on the surface of plates or inserts
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/24Stationary reactors without moving elements inside
    • B01J2219/2401Reactors comprising multiple separate flow channels
    • B01J2219/245Plate-type reactors
    • B01J2219/2476Construction materials
    • B01J2219/2477Construction materials of the catalysts
    • B01J2219/2481Catalysts in granular from between plates
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00Constitutive chemical elements of heterogeneous catalysts
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/52Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

PROCESSO PARA PREPARAR ALDEÍDOS INSATURADOS ou ÁCIDOS CARBOXÍLICOS INSATURADOS, POR OXIDAÇÃO CATALÍTICA HETEROGÊNEA DE FASE GASOSA DE HIDROCARBONETOS INSATURADOS OU SATURADOS; PROCESSO PARA PREPARAR ÁCIDOS CARBOXÍLICOS INSATURADOS PURIFICADOS; INSTRUMENTO PARA PREPARAR UM ÁCIDO CARBOXÍLICO INSATURADO PURIFICADO; PROCESSO PARA PREPARAR UM POLÍMERO BASEADO EM UM ÁCIDO CARBOXÍLICO INSATURADO. A presente invenção relaciona-se a um processo para preparar aldeídos insaturados ou ácidos carboxílicos insaturados pela oxidação catalítica heterogênea de fase gasosa de hidrocarbonetos saturados ou insaturados, compreendendo as etapas de processo: i) fornecer de uma mistura de gases compreendendo pelo menos um hidrocarboneto saturado e desidrogenar cataliticamente pelo menos um hidrocarboneto saturado na fase gasosa para obter uma mistura de gases que compreende um hidrocarboneto insaturado em um reator de desidrogenação que tem um material catalisador de desidrogenação; ou ii) fornecer uma mistura de gases que compreende pelo menos o oxigênio e pelo menos um hidrocarboneto insaturado; iii) oxidar catali ticamente o hidrocarboneto insaturado obtido na etapa i) do processo, ou fornecido na etapa ii) do processo, na fase gasosa para obter uma mistura de gases compreendendo um aldeído insaturado em um primeiro reator de oxidação que tem um primeiro material catalisador da oxidação; iv) opcionalmente oxidar cataliticamente o aldeído insaturado obtido na etapa iii) do processo na fase gasosa para obter uma mistura de gases que compreende um ácido carboxílico insaturado em um segundo reator de oxidação, que tem um segundo material catalisador da oxidação;onde pelo menos um dos reatores selecionados do reator de desidrogenação, o primeiro reator de oxidação e o segundo reator de oxidação compreendem pelo menos um corpo de espuma. A invenção ainda se refere a um processo para preparar um polímero baseado em um ácido carboxílico insaturado, a um instrumento para preparar um polímero baseado em um ácido carboxílico insaturado e ao uso do instrumento.
BRPI0914143A 2008-08-29 2009-07-29 Processo para preparar aldeídos ou ácidos carboxílicos insaturados, por oxidação catalítica heterogênea de fase gasosa de hidrocarbonetos insaturados ou saturados, processo para preparar ácidos carboxílicos insaturados purificados; instrumento para preparar um ácido carboxílico insaturado purificado; processo para preparar um polímero baseado em um ácido carboxílico insaturado BRPI0914143A8 (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102008044946.6A DE102008044946B4 (de) 2008-08-29 2008-08-29 Einsatz von Schaumkörpern in Oxidations-Reaktoren zur Herstellung ungesättigter Carbonsäuren
PCT/EP2009/059782 WO2010023053A2 (de) 2008-08-29 2009-07-29 Einsatz von schaumkörpern in oxidations-reaktoren zur herstellung ungesättigter aldehyde oder carbonsäuren

Publications (2)

Publication Number Publication Date
BRPI0914143A2 BRPI0914143A2 (pt) 2015-10-20
BRPI0914143A8 true BRPI0914143A8 (pt) 2016-01-19

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ID=41571540

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI0914143A BRPI0914143A8 (pt) 2008-08-29 2009-07-29 Processo para preparar aldeídos ou ácidos carboxílicos insaturados, por oxidação catalítica heterogênea de fase gasosa de hidrocarbonetos insaturados ou saturados, processo para preparar ácidos carboxílicos insaturados purificados; instrumento para preparar um ácido carboxílico insaturado purificado; processo para preparar um polímero baseado em um ácido carboxílico insaturado

Country Status (8)

Country Link
US (1) US8841481B2 (pt)
EP (1) EP2315738B1 (pt)
JP (1) JP2012500820A (pt)
CN (1) CN102137833B (pt)
BR (1) BRPI0914143A8 (pt)
DE (1) DE102008044946B4 (pt)
WO (1) WO2010023053A2 (pt)
ZA (1) ZA201102225B (pt)

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CN102137833B (zh) 2014-04-16
US20110166304A1 (en) 2011-07-07
WO2010023053A3 (de) 2010-05-14
DE102008044946B4 (de) 2022-06-15
US8841481B2 (en) 2014-09-23
EP2315738A2 (de) 2011-05-04
WO2010023053A2 (de) 2010-03-04
CN102137833A (zh) 2011-07-27
BRPI0914143A2 (pt) 2015-10-20
EP2315738B1 (de) 2015-09-02
DE102008044946A1 (de) 2010-03-04

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