PL3246303T3 - Wytwarzanie n-pentanalu z mieszanin surowców ubogich w buten - Google Patents
Wytwarzanie n-pentanalu z mieszanin surowców ubogich w butenInfo
- Publication number
- PL3246303T3 PL3246303T3 PL16170274T PL16170274T PL3246303T3 PL 3246303 T3 PL3246303 T3 PL 3246303T3 PL 16170274 T PL16170274 T PL 16170274T PL 16170274 T PL16170274 T PL 16170274T PL 3246303 T3 PL3246303 T3 PL 3246303T3
- Authority
- PL
- Poland
- Prior art keywords
- pentanal
- preparation
- low
- reaction feed
- butene reaction
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
- C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
- C07C45/505—Asymmetric hydroformylation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/04—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
- C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/18—Stationary reactors having moving elements inside
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/04—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds
- B01J8/0492—Feeding reactive fluids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/04—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds
- B01J8/0496—Heating or cooling the reactor
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C47/00—Compounds having —CHO groups
- C07C47/02—Saturated compounds having —CHO groups bound to acyclic carbon atoms or to hydrogen
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/02—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation
- C07C5/03—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation of non-aromatic carbon-to-carbon double bonds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/02—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation
- C07C5/03—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation of non-aromatic carbon-to-carbon double bonds
- C07C5/05—Partial hydrogenation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
- C07C5/327—Formation of non-aromatic carbon-to-carbon double bonds only
- C07C5/333—Catalytic processes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
- C07C5/327—Formation of non-aromatic carbon-to-carbon double bonds only
- C07C5/333—Catalytic processes
- C07C5/3335—Catalytic processes with metals
- C07C5/3337—Catalytic processes with metals of the platinum group
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C7/00—Purification; Separation; Use of additives
- C07C7/148—Purification; Separation; Use of additives by treatment giving rise to a chemical modification of at least one compound
- C07C7/163—Purification; Separation; Use of additives by treatment giving rise to a chemical modification of at least one compound by hydrogenation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00017—Controlling the temperature
- B01J2208/00106—Controlling the temperature by indirect heat exchange
- B01J2208/00168—Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles
- B01J2208/00176—Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles outside the reactor
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00017—Controlling the temperature
- B01J2208/00389—Controlling the temperature using electric heating or cooling elements
- B01J2208/00415—Controlling the temperature using electric heating or cooling elements electric resistance heaters
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00002—Chemical plants
- B01J2219/00004—Scale aspects
- B01J2219/00006—Large-scale industrial plants
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00002—Chemical plants
- B01J2219/00018—Construction aspects
- B01J2219/00024—Revamping, retrofitting or modernisation of existing plants
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00002—Chemical plants
- B01J2219/00027—Process aspects
- B01J2219/0004—Processes in series
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00051—Controlling the temperature
- B01J2219/00132—Controlling the temperature using electric heating or cooling elements
- B01J2219/00135—Electric resistance heaters
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
- C07C2521/04—Alumina
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/10—Magnesium; Oxides or hydroxides thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
- C07C2523/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
- C07C2523/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36
- C07C2523/56—Platinum group metals
- C07C2523/62—Platinum group metals with gallium, indium, thallium, germanium, tin or lead
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Analytical Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Water Supply & Treatment (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP16170274.1A EP3246303B8 (de) | 2016-05-19 | 2016-05-19 | Herstellung von n-pentanal aus butenarmen einsatzstoffgemischen |
Publications (1)
Publication Number | Publication Date |
---|---|
PL3246303T3 true PL3246303T3 (pl) | 2020-06-01 |
Family
ID=56024160
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PL16170274T PL3246303T3 (pl) | 2016-05-19 | 2016-05-19 | Wytwarzanie n-pentanalu z mieszanin surowców ubogich w buten |
Country Status (10)
Country | Link |
---|---|
US (1) | US9845276B2 (pl) |
EP (1) | EP3246303B8 (pl) |
KR (1) | KR102372604B1 (pl) |
CN (1) | CN107400045B (pl) |
ES (1) | ES2765635T3 (pl) |
MY (1) | MY194916A (pl) |
PL (1) | PL3246303T3 (pl) |
SG (1) | SG10201703994QA (pl) |
TW (1) | TWI731084B (pl) |
ZA (1) | ZA201703324B (pl) |
Families Citing this family (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108474039B (zh) | 2015-12-03 | 2022-06-07 | 雷杰纳荣制药公司 | 抗vegf剂在制备用于治疗新生血管性年龄相关性黄斑变性患者的药物中的用途 |
ZA201808002B (en) | 2017-12-01 | 2019-08-28 | Evonik Degussa Gmbh | Method for obtaining alcohols from aldehydes |
TWI784094B (zh) | 2017-12-01 | 2022-11-21 | 德商贏創運營有限公司 | 自醛獲得醇之方法iii |
US10882027B2 (en) | 2018-03-14 | 2021-01-05 | Evonik Operations Gmbh | Process for producing an oligomerization catalyst |
US11253844B2 (en) | 2018-03-14 | 2022-02-22 | Evonik Operations Gmbh | Oligomerization catalyst and process for the production thereof |
US10882028B2 (en) | 2018-03-14 | 2021-01-05 | Evonik Operations Gmbh | Ni-containing catalyst for the oligomerization of olefins |
US10850261B2 (en) | 2018-03-14 | 2020-12-01 | Evonik Operations Gmbh | Oligomerization catalyst and process for the production thereof |
US11519020B2 (en) | 2018-05-25 | 2022-12-06 | Regeneron Pharmaceuticals, Inc. | Methods of associating genetic variants with a clinical outcome in patients suffering from age-related macular degeneration treated with anti-VEGF |
US11638331B2 (en) | 2018-05-29 | 2023-04-25 | Kontak LLC | Multi-frequency controllers for inductive heating and associated systems and methods |
US11555473B2 (en) | 2018-05-29 | 2023-01-17 | Kontak LLC | Dual bladder fuel tank |
US10633302B2 (en) | 2018-07-25 | 2020-04-28 | Evonik Operations Gmbh | Process for oligomerization of butene with determination of the proportion of acidic catalysis |
US10654784B2 (en) | 2018-10-05 | 2020-05-19 | Evonik Operations Gmbh | Process for hydroformylating short-chain olefins in the gas phase |
US10647650B2 (en) | 2018-10-05 | 2020-05-12 | Evonik Operations Gmbh | Process for hydroformylating short-chain olefins using a heterogenized catalyst system without ionic liquid |
US12064755B2 (en) | 2019-06-12 | 2024-08-20 | Evonik Oxeno Gmbh & Co. Kg | Process for separating one or more components from a mixture |
US11440863B2 (en) | 2019-06-12 | 2022-09-13 | Evonik Operations Gmbh | Process for preparing an alcohol from hydrocarbons |
US11365171B2 (en) | 2019-06-12 | 2022-06-21 | Evonik Operations Gmbh | Process for preparing an ester by alkoxycarbonylation |
US11008275B2 (en) | 2019-06-12 | 2021-05-18 | Evonik Operations Gmbh | Process for preparing carboxylic acids or salts thereof from hydrocarbons |
Family Cites Families (24)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3665049A (en) | 1970-05-28 | 1972-05-23 | Air Prod & Chem | Dehydrogenating propane over chromia-alumina catalyst |
US3778388A (en) | 1970-05-28 | 1973-12-11 | Air Prod & Chem | Chromia-alumina catalyst |
US4152365A (en) | 1975-03-17 | 1979-05-01 | Phillips Petroleum Company | Selective hydrogenation of polyenes |
US4558168A (en) * | 1985-06-19 | 1985-12-10 | Air Products And Chemicals, Inc. | Production of high purity butene-1 from an n-butane feedstock |
US4926005A (en) | 1989-05-17 | 1990-05-15 | Phillips Petroleum Company | Dehydrogenation process |
US5151401A (en) | 1990-11-19 | 1992-09-29 | Phillips Petroleum Company | Preparation of dehydrogenating catalyst |
DE19629903A1 (de) | 1996-07-24 | 1998-01-29 | Huels Chemische Werke Ag | Verfahren zur Herstellung von Buten-Oligomeren aus Feldbutanen |
DE10031517A1 (de) | 2000-06-28 | 2002-01-10 | Basf Ag | Verfahren zur Herstellung von Hydroformylierungspordukten von Olefinen mit 2 bis 8 Kohlenstoffatomen |
DE10031518A1 (de) * | 2000-06-28 | 2002-01-10 | Basf Ag | Verfahren zur Herstellung von Hydroformylierungsprodukten des Propylens und von Acrylsäure und/oder Acrolein |
DE10251262A1 (de) * | 2002-11-04 | 2004-05-13 | Basf Ag | Verfahren zur Herstellung von Aldehyden aus Alkanen |
MY140652A (en) | 2003-10-15 | 2010-01-15 | Shell Int Research | Preparation of branched aliphatic alcohols using a process stream from an isomerization unit with recycle to a dehydrogenation unit |
DE102004041850A1 (de) * | 2004-08-27 | 2006-03-02 | Basf Ag | Verfahren zur Herstellung von C5-Aldehyden und Propen aus einem 1-Buten- und 2-Buten-haltigen C4-Strom |
WO2007096296A1 (de) * | 2006-02-23 | 2007-08-30 | Basf Se | Verfahren zur herstellung von polyisobutylen mit einem gehalt an endständigen doppelbindungen von mehr als 50% aus einem technischen 1-buten-, 2-buten- und isobuten-haltigen c4-kohlenwasserstoffstrom |
DE102008002188A1 (de) * | 2008-06-03 | 2009-12-10 | Evonik Oxeno Gmbh | Verfahren zur Abtrennung von 1-Buten aus C4-haltigen Kohlenwasserstoffströmen durch Hydroformylierung |
DE102008044946B4 (de) | 2008-08-29 | 2022-06-15 | Evonik Superabsorber Gmbh | Einsatz von Schaumkörpern in Oxidations-Reaktoren zur Herstellung ungesättigter Carbonsäuren |
DE102009001594A1 (de) | 2009-03-17 | 2010-09-30 | Evonik Oxeno Gmbh | Verfahren zur Herstellung von alpha, beta-ungesättigten C10-Aldehyden |
DE102011006721A1 (de) | 2011-04-04 | 2012-10-04 | Evonik Oxeno Gmbh | Verfahren zur Herstellung von 1-Buten und einem 1,3-Butadienderivat |
ES2603929T3 (es) | 2012-10-12 | 2017-03-02 | Evonik Degussa Gmbh | Bisfosfito asimétrico |
IN2013MU01513A (pl) | 2013-05-09 | 2015-06-12 | Reliance Ind Ltd | |
DE102013225883A1 (de) | 2013-12-13 | 2015-06-18 | Evonik Industries Ag | Zweistufige Hydroformylierung mit Kreisgas- und SILP-Technologie |
DE102014201756A1 (de) | 2014-01-31 | 2015-08-06 | Evonik Degussa Gmbh | Reinigung chlorverschmutzter Organophosphorverbindungen |
DE102014203960A1 (de) | 2014-03-05 | 2015-09-10 | Evonik Degussa Gmbh | Verfahren zur Herstellung von Aldehyden aus Alkanen und Synthesegas |
EP3059005B1 (de) | 2015-02-18 | 2018-10-24 | Evonik Degussa GmbH | Abtrennung eines homogenkatalysators aus einem reaktionsgemisch mit hilfe organophiler nanofiltration unter besonderer berücksichtigung eines membran-leistungsindikators |
SG10201601501QA (en) | 2015-03-05 | 2016-10-28 | Evonik Degussa Gmbh | Preparation of 2,2`-biaryls in the presence of molybdenum(v) chloride |
-
2016
- 2016-05-19 EP EP16170274.1A patent/EP3246303B8/de active Active
- 2016-05-19 PL PL16170274T patent/PL3246303T3/pl unknown
- 2016-05-19 ES ES16170274T patent/ES2765635T3/es active Active
-
2017
- 2017-04-19 US US15/491,173 patent/US9845276B2/en active Active
- 2017-05-15 ZA ZA2017/03324A patent/ZA201703324B/en unknown
- 2017-05-16 MY MYPI2017701757A patent/MY194916A/en unknown
- 2017-05-16 SG SG10201703994QA patent/SG10201703994QA/en unknown
- 2017-05-18 KR KR1020170061382A patent/KR102372604B1/ko active IP Right Grant
- 2017-05-18 CN CN201710350068.6A patent/CN107400045B/zh not_active Expired - Fee Related
- 2017-05-18 TW TW106116460A patent/TWI731084B/zh not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
SG10201703994QA (en) | 2017-12-28 |
US20170334822A1 (en) | 2017-11-23 |
MY194916A (en) | 2022-12-23 |
CN107400045B (zh) | 2022-07-19 |
EP3246303B8 (de) | 2020-01-01 |
TW201741276A (zh) | 2017-12-01 |
EP3246303A1 (de) | 2017-11-22 |
CN107400045A (zh) | 2017-11-28 |
KR102372604B1 (ko) | 2022-03-10 |
TWI731084B (zh) | 2021-06-21 |
KR20170131253A (ko) | 2017-11-29 |
EP3246303B1 (de) | 2019-11-27 |
ZA201703324B (en) | 2018-08-29 |
US9845276B2 (en) | 2017-12-19 |
ES2765635T3 (es) | 2020-06-10 |
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