BRPI0418791A - método para produzir ácido (met) acrìlico ou (met) acroleìna - Google Patents

método para produzir ácido (met) acrìlico ou (met) acroleìna

Info

Publication number
BRPI0418791A
BRPI0418791A BRPI0418791-1A BRPI0418791A BRPI0418791A BR PI0418791 A BRPI0418791 A BR PI0418791A BR PI0418791 A BRPI0418791 A BR PI0418791A BR PI0418791 A BRPI0418791 A BR PI0418791A
Authority
BR
Brazil
Prior art keywords
meth
acrolein
acrylic acid
catalyst
gas containing
Prior art date
Application number
BRPI0418791-1A
Other languages
English (en)
Inventor
Kimikatsu Jinno
Yasushi Ogawa
Yoshiro Suzuki
Shuhei Yada
Original Assignee
Mitsubishi Chem Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Chem Corp filed Critical Mitsubishi Chem Corp
Publication of BRPI0418791A publication Critical patent/BRPI0418791A/pt

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • C07C51/252Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002Mixed oxides other than spinels, e.g. perovskite
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C07C45/34Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
    • C07C45/35Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds in propene or isobutene
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/215Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of saturated hydrocarbyl groups
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85Chromium, molybdenum or tungsten
    • B01J23/88Molybdenum
    • B01J23/887Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8876Arsenic, antimony or bismuth
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/90Regeneration or reactivation
    • B01J23/94Regeneration or reactivation of catalysts comprising metals, oxides or hydroxides of the iron group metals or copper
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00Constitutive chemical elements of heterogeneous catalysts
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00Regeneration or reactivation of catalysts, in general
    • B01J38/04Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst
    • B01J38/12Treating with free oxygen-containing gas
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/584Recycling of catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

MéTODO PARA PRODUZIR áCIDO (MET) ACRìLICO OU (MET) ACROLEìNA Trata-se de um processo para obter um gás de reação que contém ácido (met) acrílico ou (met) acroleína através das etapas de alimentar propileno, propano ou isobutileno e um gás que contém oxigênio molecular para dentro de um reator carregado com um catalisador e efetuar uma oxidação de fase vaporosa catalítica, em que, quando do reinício da operação após a suspensão da oxidação de fase gasosa catalítica, não há deterioração da atividade catalítica e da seletividade do produto desejado. é apresentado um processo para produzir (met) acroleína ou ácido (met) acrílico, que compreende as etapas de alimentar propileno, propano ou isobutileno e um gás que contém oxigênio molecular para dentro de um reator carregado com um catalisador e executar uma operação de oxidação de fase vaporosa catalítica para a formação de (met) acroleína ou ácido (met) acrílico, em que, quando da suspensão da operação de oxidação de fase vaporosa catalítica, um gás que contém oxigênio molecular é fornecido ao reator carregado com o catalisador.
BRPI0418791-1A 2004-04-30 2004-10-20 método para produzir ácido (met) acrìlico ou (met) acroleìna BRPI0418791A (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2004135311A JP2005314314A (ja) 2004-04-30 2004-04-30 (メタ)アクリル酸または(メタ)アクロレインの製造方法
PCT/JP2004/015873 WO2005105714A1 (ja) 2004-04-30 2004-10-20 (メタ)アクリル酸または(メタ)アクロレインの製造方法

Publications (1)

Publication Number Publication Date
BRPI0418791A true BRPI0418791A (pt) 2007-10-09

Family

ID=35241598

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI0418791-1A BRPI0418791A (pt) 2004-04-30 2004-10-20 método para produzir ácido (met) acrìlico ou (met) acroleìna

Country Status (6)

Country Link
US (1) US7388107B2 (pt)
JP (1) JP2005314314A (pt)
CN (1) CN1697812A (pt)
BR (1) BRPI0418791A (pt)
RU (1) RU2353609C2 (pt)
WO (1) WO2005105714A1 (pt)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5163273B2 (ja) * 2008-05-16 2013-03-13 住友化学株式会社 不飽和アルデヒド及び/又は不飽和カルボン酸製造用触媒の製造方法、並びに不飽和アルデヒド及び/又は不飽和カルボン酸の製造方法
US8962881B2 (en) 2009-03-09 2015-02-24 Nippon Shokubai Co, Ltd Oxidized organic compound manufacturing method
DE102010048405A1 (de) * 2010-10-15 2011-05-19 Basf Se Verfahren zum Langzeitbetrieb einer heterogen katalysierten partiellen Gasphasenoxidation von Proben zu Acrolein
JP6752035B2 (ja) * 2016-03-29 2020-09-09 日本化薬株式会社 再スタートアップ方法
KR102064319B1 (ko) * 2016-10-28 2020-01-09 주식회사 엘지화학 촉매의 재현성이 우수한 부타디엔의 제조방법
JP6522213B1 (ja) 2018-08-03 2019-05-29 住友化学株式会社 メタクロレイン及び/又はメタクリル酸の製造方法

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6133234A (ja) * 1984-07-23 1986-02-17 Mitsubishi Petrochem Co Ltd 触媒の再生法
JPS63137755A (ja) * 1986-11-28 1988-06-09 Nippon Shokubai Kagaku Kogyo Co Ltd 触媒の再活性化法
JPH03170445A (ja) * 1989-11-30 1991-07-24 Mitsui Toatsu Chem Inc アクロレインおよびアクリル酸の製造法
JP3140135B2 (ja) * 1992-01-16 2001-03-05 三菱レイヨン株式会社 劣化触媒の再生法
JP2000513384A (ja) 1997-07-15 2000-10-10 イー・アイ・デユポン・ドウ・ヌムール・アンド・カンパニー プロピレンのアクロレインへの改良された気相酸化
US6437193B1 (en) * 1997-07-15 2002-08-20 E. I. Du Pont De Nemours And Company Vapor phase oxidation of propylene to acrolein
JP3562983B2 (ja) * 1997-11-25 2004-09-08 三菱レイヨン株式会社 メタクロレイン及びメタクリル酸の製造方法
JP2000256257A (ja) * 1999-03-09 2000-09-19 Toagosei Co Ltd アクリル酸の製造方法
JP4871441B2 (ja) * 2000-08-07 2012-02-08 株式会社日本触媒 反応器のスタートアップ方法
JP3884967B2 (ja) * 2002-02-07 2007-02-21 住友化学株式会社 メタクリル酸の製造方法
JP3972718B2 (ja) * 2002-04-16 2007-09-05 住友化学株式会社 メタクリル酸製造用触媒の再生方法

Also Published As

Publication number Publication date
WO2005105714A1 (ja) 2005-11-10
RU2353609C2 (ru) 2009-04-27
JP2005314314A (ja) 2005-11-10
RU2006138033A (ru) 2008-05-10
US20070270610A1 (en) 2007-11-22
US7388107B2 (en) 2008-06-17
CN1697812A (zh) 2005-11-16

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B09B Patent application refused [chapter 9.2 patent gazette]

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