BR112013009788A2 - processo contínuo para produção de acroleína por desidratação catalítica de glicerol ou glicerina na presença de um catalisador ácido, processo para fabricação, a partir de acroleina, de - Google Patents

processo contínuo para produção de acroleína por desidratação catalítica de glicerol ou glicerina na presença de um catalisador ácido, processo para fabricação, a partir de acroleina, de

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Publication number
BR112013009788A2
BR112013009788A2 BR112013009788A BR112013009788A BR112013009788A2 BR 112013009788 A2 BR112013009788 A2 BR 112013009788A2 BR 112013009788 A BR112013009788 A BR 112013009788A BR 112013009788 A BR112013009788 A BR 112013009788A BR 112013009788 A2 BR112013009788 A2 BR 112013009788A2
Authority
BR
Brazil
Prior art keywords
acrolein
glycerol
zone
glycerin
methylthio
Prior art date
Application number
BR112013009788A
Other languages
English (en)
Other versions
BR112013009788B1 (pt
Inventor
Nouria Fatah
Sebastien Paul
Sthephane Pariente
Virginie Belliere-Baca
Original Assignee
Adisseo France Sas
Lille Ecole Centrale
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Adisseo France Sas, Lille Ecole Centrale filed Critical Adisseo France Sas
Publication of BR112013009788A2 publication Critical patent/BR112013009788A2/pt
Publication of BR112013009788B1 publication Critical patent/BR112013009788B1/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/51—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition
    • C07C45/52—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition by dehydration and rearrangement involving two hydroxy groups in the same molecule
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/30—Tungsten
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C319/00—Preparation of thiols, sulfides, hydropolysulfides or polysulfides
    • C07C319/14—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of sulfides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C319/00—Preparation of thiols, sulfides, hydropolysulfides or polysulfides
    • C07C319/14—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of sulfides
    • C07C319/18—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of sulfides by addition of thiols to unsaturated compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C319/00—Preparation of thiols, sulfides, hydropolysulfides or polysulfides
    • C07C319/14—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of sulfides
    • C07C319/20—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of sulfides by reactions not involving the formation of sulfide groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C323/00—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups
    • C07C323/22—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and doubly-bound oxygen atoms bound to the same carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C323/00—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups
    • C07C323/50—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and carboxyl groups bound to the same carbon skeleton
    • C07C323/51—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and carboxyl groups bound to the same carbon skeleton having the sulfur atoms of the thio groups bound to acyclic carbon atoms of the carbon skeleton
    • C07C323/52—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and carboxyl groups bound to the same carbon skeleton having the sulfur atoms of the thio groups bound to acyclic carbon atoms of the carbon skeleton the carbon skeleton being acyclic and saturated
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C323/00—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups
    • C07C323/50—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and carboxyl groups bound to the same carbon skeleton
    • C07C323/51—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and carboxyl groups bound to the same carbon skeleton having the sulfur atoms of the thio groups bound to acyclic carbon atoms of the carbon skeleton
    • C07C323/57—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and carboxyl groups bound to the same carbon skeleton having the sulfur atoms of the thio groups bound to acyclic carbon atoms of the carbon skeleton the carbon skeleton being further substituted by nitrogen atoms, not being part of nitro or nitroso groups
    • C07C323/58—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups containing thio groups and carboxyl groups bound to the same carbon skeleton having the sulfur atoms of the thio groups bound to acyclic carbon atoms of the carbon skeleton the carbon skeleton being further substituted by nitrogen atoms, not being part of nitro or nitroso groups with amino groups bound to the carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C47/00—Compounds having —CHO groups
    • C07C47/20—Unsaturated compounds having —CHO groups bound to acyclic carbon atoms
    • C07C47/21—Unsaturated compounds having —CHO groups bound to acyclic carbon atoms with only carbon-to-carbon double bonds as unsaturation
    • C07C47/22—Acryaldehyde; Methacryaldehyde
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

processo contínuo para produção de acroleína por desidratação catalítica de glicerol ou glicerina na presença de um catalisador ácido, processo para fabricação, a partir de acroleina, de 3-(metiltio)propionaldeído mmp, 2-hidroxi-4-(metiltio)butironitrilo hmtbn, metionina, 2-hidroxi-4-(metiltio) ácido butanóico hmtba, ésteres deste último, ou 2-oxo-4- (metiltio) ácido butanóico kmb e uso dos mesmos. processo contínuo para obtenção de acroleína por desidratação catalítica de glicerol ou glicerina, na presença de um catalisador ácido, em que o dito processo compreende a regeneração concomitante de dito catalisador e é realizado em reator de leito fluidizado, dito reator compreendendo duas zonas, uma primeira zona, ou zona inferior, denominada zona de regeneração do catalisador, na qual um gás de fluidização compreendendo oxigênio é introduzido, e uma segunda zona, ou zona superior, denominada zona de reação, na qual o glicerol ou a glicerina são introduzidos e convertidos em acroleína.
BR112013009788-4A 2010-10-26 2011-10-26 Processo contínuo para produção de acroleína por desidratação catalítica de glicerol ou glicerina na presença de um catalisador ácido e uso dos mesmos BR112013009788B1 (pt)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR1058767A FR2966456B1 (fr) 2010-10-26 2010-10-26 Procede d'obtention d'acroleine par deshydratation catalytique de glycerol ou de glycerine
FR10/58767 2010-10-26
PCT/FR2011/052492 WO2012056166A1 (fr) 2010-10-26 2011-10-26 Procédé d'obtention d'acroléine par déshydratation catalytique de glycérol ou de glycérine

Publications (2)

Publication Number Publication Date
BR112013009788A2 true BR112013009788A2 (pt) 2016-07-19
BR112013009788B1 BR112013009788B1 (pt) 2019-10-01

Family

ID=43877066

Family Applications (1)

Application Number Title Priority Date Filing Date
BR112013009788-4A BR112013009788B1 (pt) 2010-10-26 2011-10-26 Processo contínuo para produção de acroleína por desidratação catalítica de glicerol ou glicerina na presença de um catalisador ácido e uso dos mesmos

Country Status (9)

Country Link
US (1) US9315440B2 (pt)
EP (1) EP2632883B1 (pt)
JP (1) JP5917533B2 (pt)
KR (1) KR101858038B1 (pt)
CN (1) CN103261141B (pt)
BR (1) BR112013009788B1 (pt)
ES (1) ES2652342T3 (pt)
FR (1) FR2966456B1 (pt)
WO (1) WO2012056166A1 (pt)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR3033792B1 (fr) * 2015-03-20 2017-04-21 Innov'ia 3I Compositions pulverulentes d'un complexe entre un acide et un metal a haute teneur en composes organiques soufres et leur procede de preparation
EP3360857A1 (en) * 2017-02-13 2018-08-15 Patheon Austria GmbH Co. & KG Process for preparing pentenoate
CN109293511B (zh) * 2018-11-12 2020-08-25 西南化工研究设计院有限公司 一种丙酸甲酯与甲醛羟醛缩合制甲基丙烯酸甲酯的方法
CN109232247B (zh) * 2018-11-12 2020-06-30 西南化工研究设计院有限公司 一种醋酸甲酯与甲醛羟醛缩合制甲基丙烯酸甲酯的方法

Family Cites Families (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2558520A (en) 1948-01-29 1951-06-26 Us Ind Chemicals Inc Production of acrolein from glycerol
US3669877A (en) 1970-02-05 1972-06-13 Petro Tex Chem Corp Multi-chamber fluidized bed catalytic reactor
US4152393A (en) 1973-03-08 1979-05-01 The Standard Oil Company Reactor for contacting gases and a particulate solid
DE4238493C1 (de) 1992-11-14 1994-04-21 Degussa Verfahren zur Herstellung von Acrolein und dessen Verwendung
AR002174A1 (es) * 1995-06-07 1998-01-07 Novus Int Inc Proceso para la preparacion de 3-(metiltio)propanal y 2-hidroxi-4-metiltio) butanonitrilo
US6197265B1 (en) 1998-01-21 2001-03-06 Iowa State University Research Foundation, Inc. Gas distribution system for a two-zone fluidized bed reactor
WO2001044146A1 (en) 1999-12-17 2001-06-21 Dow Global Technologies Inc. Dehydrogenation of an alkyl aromatic compound and catalyst regeneration in a fluidized bed reactor
DE102004038053A1 (de) * 2004-08-05 2006-04-27 Degussa Ag Verfahren zur Herstellung von 3-(Methylthio)propanal
FR2882052B1 (fr) * 2005-02-15 2007-03-23 Arkema Sa Procede de deshydratation du glycerol en acroleine
FR2882053B1 (fr) * 2005-02-15 2007-03-23 Arkema Sa Procede de deshydratation du glycerol en acrolene
WO2007058221A1 (ja) 2005-11-15 2007-05-24 Nippon Shokubai Co., Ltd. 多価アルコールの脱水方法
FR2894849B1 (fr) 2005-12-20 2008-05-16 Inst Francais Du Petrole Nouveau reacteur a deux zones reactionnelles fluidisees avec systeme de separation gaz/solide integre
JP2008088149A (ja) 2006-01-04 2008-04-17 Nippon Shokubai Co Ltd アクロレイン製造用触媒及びそれを用いたアクロレイン製造方法
JP2008110298A (ja) 2006-10-30 2008-05-15 Nippon Shokubai Co Ltd グリセリン脱水用触媒の再生方法
WO2008052993A2 (en) 2006-11-01 2008-05-08 Bioecon International Holding N.V. Process for production of acrolein and other oxygenated compounds from glycerol in a transported bed reactor
US20090054694A1 (en) 2007-08-24 2009-02-26 Peterson Thomas H Chemical production processes, systems, and catalyst compositions
FR2920767B1 (fr) 2007-09-06 2009-12-18 Arkema France Procede de vaporisation reactive de glycerol
WO2009127889A1 (en) 2008-04-16 2009-10-22 Arkema France Process for manufacturing acrolein from glycerol
ES2335174B1 (es) * 2008-06-19 2010-12-30 Universidad De Zaragoza Reactor de lecho fluido de dos zonas.
DE102008038273A1 (de) 2008-08-18 2010-03-04 Evonik Stockhausen Gmbh Ein Verfahren zur Herstellung von Acrylsäure und daraus herstellbaren Verbindungen basierend auf Glycerin mit Wechselkatalysator
FR2938535B1 (fr) 2008-11-20 2012-08-17 Arkema France Procede de fabrication de methylmercaptopropionaldehyde et de methionine a partir de matieres renouvelables
FR2939791B1 (fr) * 2008-12-16 2011-01-14 Adisseo France Sas Procede de preparation d'acroleine a partir de glycerol ou de glycerine brute
JP2010155183A (ja) * 2008-12-26 2010-07-15 Nippon Shokubai Co Ltd アクロレインの製造方法
CA2784618C (en) * 2009-12-18 2015-08-18 Battelle Memorial Institute Multihydric compound dehydration systems, catalyst compositions, and methods
CN101840249B (zh) 2010-01-27 2012-12-19 鸿富锦精密工业（深圳）有限公司 双显示屏电子装置及其控制方法

Also Published As

Publication number Publication date
ES2652342T3 (es) 2018-02-01
WO2012056166A1 (fr) 2012-05-03
CN103261141A (zh) 2013-08-21
FR2966456B1 (fr) 2013-03-15
KR101858038B1 (ko) 2018-05-15
FR2966456A1 (fr) 2012-04-27
JP2013545732A (ja) 2013-12-26
EP2632883A1 (fr) 2013-09-04
CN103261141B (zh) 2017-02-08
KR20130138253A (ko) 2013-12-18
JP5917533B2 (ja) 2016-05-18
US9315440B2 (en) 2016-04-19
EP2632883B1 (fr) 2017-09-27
BR112013009788B1 (pt) 2019-10-01
US20130217909A1 (en) 2013-08-22

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Legal Events

Date Code Title Description
B07A Application suspended after technical examination (opinion) [chapter 7.1 patent gazette]
B07A Application suspended after technical examination (opinion) [chapter 7.1 patent gazette]
B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]

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B21F Lapse acc. art. 78, item iv - on non-payment of the annual fees in time

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