BRPI0718270B1 - Processo e dispositivo para oxidação catalítica de gases que contêm so2 por meio de oxigênio. - Google Patents
Processo e dispositivo para oxidação catalítica de gases que contêm so2 por meio de oxigênio. Download PDFInfo
- Publication number
- BRPI0718270B1 BRPI0718270B1 BRPI0718270-8A BRPI0718270A BRPI0718270B1 BR PI0718270 B1 BRPI0718270 B1 BR PI0718270B1 BR PI0718270 A BRPI0718270 A BR PI0718270A BR PI0718270 B1 BRPI0718270 B1 BR PI0718270B1
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- BR
- Brazil
- Prior art keywords
- tube
- catalyst
- gas
- volume
- contact
- Prior art date
Links
- 239000007789 gas Substances 0.000 title claims abstract description 146
- 238000000034 method Methods 0.000 title claims abstract description 78
- 230000008569 process Effects 0.000 title claims abstract description 75
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 title claims abstract description 24
- 229910052760 oxygen Inorganic materials 0.000 title claims abstract description 23
- 239000001301 oxygen Substances 0.000 title claims abstract description 23
- 238000007254 oxidation reaction Methods 0.000 title claims abstract description 20
- 230000003647 oxidation Effects 0.000 title claims abstract description 18
- 230000003197 catalytic effect Effects 0.000 title claims abstract description 11
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 claims abstract description 134
- 239000003054 catalyst Substances 0.000 claims abstract description 106
- 238000006243 chemical reaction Methods 0.000 claims abstract description 46
- 239000006096 absorbing agent Substances 0.000 claims abstract description 38
- 239000002826 coolant Substances 0.000 claims abstract description 10
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 68
- 238000009434 installation Methods 0.000 claims description 47
- 238000001816 cooling Methods 0.000 claims description 17
- 239000000463 material Substances 0.000 claims description 17
- 238000011144 upstream manufacturing Methods 0.000 claims description 9
- 238000010438 heat treatment Methods 0.000 claims description 7
- 238000002156 mixing Methods 0.000 claims description 7
- 230000000391 smoking effect Effects 0.000 claims description 7
- 238000010276 construction Methods 0.000 claims description 6
- 238000012546 transfer Methods 0.000 claims description 5
- 238000000746 purification Methods 0.000 claims description 3
- 230000009257 reactivity Effects 0.000 claims description 2
- 239000000543 intermediate Substances 0.000 claims 2
- AKEJUJNQAAGONA-UHFFFAOYSA-N sulfur trioxide Chemical compound O=S(=O)=O AKEJUJNQAAGONA-UHFFFAOYSA-N 0.000 abstract description 42
- GNTDGMZSJNCJKK-UHFFFAOYSA-N divanadium pentaoxide Chemical compound O=[V](=O)O[V](=O)=O GNTDGMZSJNCJKK-UHFFFAOYSA-N 0.000 description 18
- 238000004088 simulation Methods 0.000 description 18
- 230000008901 benefit Effects 0.000 description 16
- 239000000203 mixture Substances 0.000 description 13
- 238000004519 manufacturing process Methods 0.000 description 12
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 10
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 10
- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 description 9
- 229910052792 caesium Inorganic materials 0.000 description 8
- 238000010790 dilution Methods 0.000 description 8
- 239000012895 dilution Substances 0.000 description 8
- 238000005057 refrigeration Methods 0.000 description 6
- 238000010521 absorption reaction Methods 0.000 description 5
- 239000001569 carbon dioxide Substances 0.000 description 5
- 229910002092 carbon dioxide Inorganic materials 0.000 description 5
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 4
- 239000002316 fumigant Substances 0.000 description 4
- JCXJVPUVTGWSNB-UHFFFAOYSA-N nitrogen dioxide Inorganic materials O=[N]=O JCXJVPUVTGWSNB-UHFFFAOYSA-N 0.000 description 4
- 229910052717 sulfur Inorganic materials 0.000 description 4
- 239000011593 sulfur Substances 0.000 description 4
- 229910004298 SiO 2 Inorganic materials 0.000 description 3
- 230000033228 biological regulation Effects 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 238000007634 remodeling Methods 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 2
- 238000009529 body temperature measurement Methods 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 239000000919 ceramic Substances 0.000 description 2
- 238000001311 chemical methods and process Methods 0.000 description 2
- 238000011109 contamination Methods 0.000 description 2
- 238000001514 detection method Methods 0.000 description 2
- 239000000284 extract Substances 0.000 description 2
- 230000002349 favourable effect Effects 0.000 description 2
- -1 for example Substances 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 238000013021 overheating Methods 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 238000005086 pumping Methods 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 230000001105 regulatory effect Effects 0.000 description 2
- 238000010025 steaming Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 230000007704 transition Effects 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 238000006887 Ullmann reaction Methods 0.000 description 1
- TUXLHRPNMCNRFT-UHFFFAOYSA-N [O-2].[O-2].[O-2].O.O.[V+5].[Cs+] Chemical compound [O-2].[O-2].[O-2].O.O.[V+5].[Cs+] TUXLHRPNMCNRFT-UHFFFAOYSA-N 0.000 description 1
- 238000009530 blood pressure measurement Methods 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 230000002427 irreversible effect Effects 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000010310 metallurgical process Methods 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 238000013341 scale-up Methods 0.000 description 1
- 238000005201 scrubbing Methods 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 150000003464 sulfur compounds Chemical class 0.000 description 1
- HIFJUMGIHIZEPX-UHFFFAOYSA-N sulfuric acid;sulfur trioxide Chemical compound O=S(=O)=O.OS(O)(=O)=O HIFJUMGIHIZEPX-UHFFFAOYSA-N 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B17/00—Sulfur; Compounds thereof
- C01B17/69—Sulfur trioxide; Sulfuric acid
- C01B17/74—Preparation
- C01B17/76—Preparation by contact processes
- C01B17/765—Multi-stage SO3-conversion
- C01B17/7655—Multi-stage SO3-conversion with intermediate absorption
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/06—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds in tube reactors; the solid particles being arranged in tubes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/75—Multi-step processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/8603—Removing sulfur compounds
- B01D53/8609—Sulfur oxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/04—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds
- B01J8/0446—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the flow within the beds being predominantly vertical
- B01J8/0476—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the flow within the beds being predominantly vertical in two or more otherwise shaped beds
- B01J8/048—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the flow within the beds being predominantly vertical in two or more otherwise shaped beds the beds being superimposed one above the other
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/04—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds
- B01J8/0446—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the flow within the beds being predominantly vertical
- B01J8/0476—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the flow within the beds being predominantly vertical in two or more otherwise shaped beds
- B01J8/0488—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the flow within the beds being predominantly vertical in two or more otherwise shaped beds the beds being placed in separate reactors
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/04—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds
- B01J8/0496—Heating or cooling the reactor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/06—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds in tube reactors; the solid particles being arranged in tubes
- B01J8/067—Heating or cooling the reactor
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B17/00—Sulfur; Compounds thereof
- C01B17/69—Sulfur trioxide; Sulfuric acid
- C01B17/74—Preparation
- C01B17/76—Preparation by contact processes
- C01B17/765—Multi-stage SO3-conversion
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B17/00—Sulfur; Compounds thereof
- C01B17/69—Sulfur trioxide; Sulfuric acid
- C01B17/74—Preparation
- C01B17/76—Preparation by contact processes
- C01B17/78—Preparation by contact processes characterised by the catalyst used
- C01B17/79—Preparation by contact processes characterised by the catalyst used containing vanadium
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B17/00—Sulfur; Compounds thereof
- C01B17/69—Sulfur trioxide; Sulfuric acid
- C01B17/74—Preparation
- C01B17/76—Preparation by contact processes
- C01B17/80—Apparatus
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B17/00—Sulfur; Compounds thereof
- C01B17/69—Sulfur trioxide; Sulfuric acid
- C01B17/74—Preparation
- C01B17/76—Preparation by contact processes
- C01B17/80—Apparatus
- C01B17/803—Converters
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/20—Metals or compounds thereof
- B01D2255/207—Transition metals
- B01D2255/20723—Vanadium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00017—Controlling the temperature
- B01J2208/00106—Controlling the temperature by indirect heat exchange
- B01J2208/00168—Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles
- B01J2208/00176—Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles outside the reactor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00017—Controlling the temperature
- B01J2208/00106—Controlling the temperature by indirect heat exchange
- B01J2208/00168—Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles
- B01J2208/00203—Coils
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00002—Chemical plants
- B01J2219/00004—Scale aspects
- B01J2219/00006—Large-scale industrial plants
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
- Environmental & Geological Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Biomedical Technology (AREA)
- Analytical Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Materials Engineering (AREA)
- Catalysts (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
- Exhaust Gas Treatment By Means Of Catalyst (AREA)
- Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
- Epoxy Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102006051899A DE102006051899A1 (de) | 2006-10-31 | 2006-10-31 | Verfahren und Vorrichtung zur katalytischen Oxidation von SO2-haltigen Gasen mit Sauerstoff |
| DE102006051899.3 | 2006-10-31 | ||
| PCT/EP2007/008910 WO2008052649A1 (de) | 2006-10-31 | 2007-10-13 | Verfahren und vorrichtung zur katalytischen oxidation von so2-haltigen gasen mit sauerstoff |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| BRPI0718270A2 BRPI0718270A2 (pt) | 2013-11-12 |
| BRPI0718270A8 BRPI0718270A8 (pt) | 2017-02-21 |
| BRPI0718270B1 true BRPI0718270B1 (pt) | 2018-05-02 |
Family
ID=38984433
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BRPI0718270-8A BRPI0718270B1 (pt) | 2006-10-31 | 2007-10-13 | Processo e dispositivo para oxidação catalítica de gases que contêm so2 por meio de oxigênio. |
Country Status (25)
| Country | Link |
|---|---|
| US (1) | US7871593B2 (https=) |
| EP (2) | EP1979270B1 (https=) |
| JP (2) | JP5570216B2 (https=) |
| KR (1) | KR101420127B1 (https=) |
| CN (1) | CN101573291B (https=) |
| AT (1) | ATE503721T1 (https=) |
| AU (1) | AU2007315318B2 (https=) |
| BR (1) | BRPI0718270B1 (https=) |
| CA (1) | CA2668059C (https=) |
| CL (1) | CL2007003153A1 (https=) |
| CY (2) | CY1112064T1 (https=) |
| DE (2) | DE102006051899A1 (https=) |
| DK (2) | DK1979270T3 (https=) |
| ES (2) | ES2361951T3 (https=) |
| MA (1) | MA30915B1 (https=) |
| MX (1) | MX2009004483A (https=) |
| NO (1) | NO342026B1 (https=) |
| PL (2) | PL1979270T3 (https=) |
| PT (2) | PT2256085E (https=) |
| RU (2) | RU2456232C2 (https=) |
| SI (2) | SI1979270T1 (https=) |
| TN (1) | TN2009000150A1 (https=) |
| UA (2) | UA111809C2 (https=) |
| WO (1) | WO2008052649A1 (https=) |
| ZA (1) | ZA200902892B (https=) |
Families Citing this family (43)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102009025510A1 (de) | 2008-12-20 | 2010-06-24 | Bayer Technology Services Gmbh | Verfahren zur Herstellung von Schwefeltrioxid |
| DE102010018172A1 (de) | 2010-04-22 | 2011-10-27 | Bayer Technology Services Gmbh | Verfahren zur Aufarbeitung schwefelwasserstoffhaltiger Abgase |
| EP2507167B1 (de) | 2009-12-01 | 2017-02-15 | Chemetics, Inc. | Vorrichtung und verfahren zur verbrennung von schwefel und schwefelhaltigen verbindungen |
| EP2507164B1 (de) | 2009-12-01 | 2017-10-18 | Chemetics, Inc. | Verfahren zur herstellung von schwefelsäure |
| HUE028069T2 (en) * | 2009-12-01 | 2016-11-28 | Bayer Ag | Process for producing sulfuric acid |
| WO2012136307A1 (en) * | 2011-04-06 | 2012-10-11 | Haldor Topsøe A/S | Process for production of sulphuric acid |
| US8790611B2 (en) * | 2012-07-05 | 2014-07-29 | Basf Se | Reactor for carrying out an exothermic reaction in the gas phase |
| RU2502546C1 (ru) * | 2012-07-20 | 2013-12-27 | Андрей Владиславович Курочкин | Способ очистки углеводородных газов |
| AT513414B1 (de) * | 2012-10-08 | 2014-06-15 | Kanzler Walter | Verfahren zur zweistufigen katalytischen Oxidation von Schwefel-Verbindungen in Abgasen |
| US20150315022A1 (en) * | 2012-12-17 | 2015-11-05 | Chemetics Inc. | Contact apparatus for oxidizing sulfur dioxide and systems for producing sulfuric acid |
| US9994451B2 (en) | 2014-06-09 | 2018-06-12 | Chemetics Inc. | Single contact, single absorption system for producing sulfuric acid with high conversion efficiency |
| DE102014108272A1 (de) | 2014-06-12 | 2015-12-17 | Basf Se | Anlage und Verfahren zur Durchführung von heterogen katalysierten Gasphasen-Reaktionen |
| CN104084094A (zh) * | 2014-07-17 | 2014-10-08 | 科洋环境工程(上海)有限公司 | 一种转化so2浓度的装置及so2转化系统及转化方法 |
| LU92547B1 (de) * | 2014-09-17 | 2016-03-18 | Cppe Carbon Process & Plant Engineering S A | Verfahren zur katalytischen entfernung von schwefeldioxid aus abgasen |
| US9958211B2 (en) | 2015-03-12 | 2018-05-01 | Bayotech, Inc. | Nested-flow heat exchangers and chemical reactors |
| EP3075434A1 (de) | 2015-04-02 | 2016-10-05 | Bayer Technology Services GmbH | Kontinuierliches verfahren zur reinigung von so2-haltigen gasen |
| AU2016287352B2 (en) * | 2015-07-02 | 2021-01-07 | Haldor Topsøe A/S | Process for production of sulfuric acid |
| DE102016103976A1 (de) * | 2016-03-04 | 2017-09-07 | Thyssenkrupp Ag | Verfahren und Vorrichtung zur Herstellung von Schwefelsäure |
| LU93012B1 (en) * | 2016-04-04 | 2017-11-08 | Cppe Carbon Process & Plant Eng S A En Abrege Cppe S A | Sulfur dioxide removal from waste gas |
| LU93014B1 (en) | 2016-04-04 | 2017-10-05 | Ajo Ind S A R L | Catalyst mixture for the treatment of waste gas |
| LU93013B1 (en) | 2016-04-04 | 2017-11-08 | Cppe Carbon Process & Plant Eng S A En Abrege Cppe S A | Process for the removal of heavy metals from fluids |
| CN105967150A (zh) * | 2016-07-08 | 2016-09-28 | 华能国际电力股份有限公司 | 一种铂催化剂制取so3气体的设备及方法 |
| JP6747167B2 (ja) * | 2016-08-18 | 2020-08-26 | 住友金属鉱山株式会社 | 硫酸製造システム |
| CN107973278A (zh) * | 2016-10-25 | 2018-05-01 | 中国石油化工股份有限公司 | 一种连续产生so3气体的方法 |
| CN106915731B (zh) * | 2017-04-14 | 2023-08-08 | 双盾环境科技有限公司 | 一种可调式应用惰性触媒处理高浓度so2烟气生产so3气体的装置 |
| CN107020053A (zh) * | 2017-04-18 | 2017-08-08 | 北京清新环境技术股份有限公司 | 一种产生三氧化硫并维持其气体状态的系统及其方法 |
| FR3070016B1 (fr) * | 2017-08-10 | 2019-08-23 | L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude | Procede et installation de purification d'un flux gazeux d'alimentation comprenant au moins 90% de co2 |
| CN107537316A (zh) * | 2017-09-19 | 2018-01-05 | 中国大唐集团科学技术研究院有限公司华中分公司 | 烟道脱硫系统及方法、烟气催化反应装置 |
| US11007498B2 (en) * | 2017-10-05 | 2021-05-18 | Haldor Topsøe A/S | Layout for inter-bed cooling in sulfuric acid plants |
| CN108046220A (zh) * | 2018-01-16 | 2018-05-18 | 山东润银生物化工股份有限公司 | 一种用合成气脱硫所得h2s生产浓硫酸的装置以及生产方法 |
| CN110606795A (zh) * | 2018-06-15 | 2019-12-24 | 孔繁昇 | 一种利用含硫燃料燃烧烟气制备有机磺酸的方法 |
| CN110615407B (zh) * | 2018-06-19 | 2023-07-07 | 盐城市恒星石油化学有限公司 | 一种基础油磺化用三氧化硫的转化工艺 |
| CN110615408B (zh) * | 2018-06-19 | 2023-08-04 | 盐城市恒星石油化学有限公司 | 一种白油生产用三氧化硫转化工艺 |
| EP4054977B1 (en) * | 2019-11-04 | 2025-08-20 | Metso Metals Oy | Process and plant for producing sulphuric acid |
| ES3053808T3 (en) | 2019-12-13 | 2026-01-26 | Chemetics Inc | Integrated ammonia and sulfuric acid production plant and process |
| WO2022055662A1 (en) | 2020-09-09 | 2022-03-17 | Chemetics Inc. | System and method for producing sulfur dioxide and associated sulfuric acid plant |
| CA3238318A1 (en) | 2021-12-03 | 2023-06-08 | Rene Dijkstra | Systems and methods for producing sulfuric acid or liquefied sulfur dioxide |
| US12264066B2 (en) | 2022-04-25 | 2025-04-01 | Messer Industries Usa, Inc. | Process and apparatus for acid regeneration |
| US12600627B2 (en) | 2023-04-20 | 2026-04-14 | Messer Industries Usa, Inc. | Process and apparatus for oxygen injection in a sulfur furnace |
| US20240351879A1 (en) * | 2023-04-20 | 2024-10-24 | Messer Industries Usa, Inc. | Process and apparatus for preparing sulfur trioxide from sulfur dioxide |
| US12577103B2 (en) | 2023-04-20 | 2026-03-17 | Messer Industries Usa, Inc. | Process and redox furnace for acid regeneration |
| US12607352B2 (en) | 2023-04-20 | 2026-04-21 | Messer Industries Usa, Inc. | Process and burner apparatus for acid regeneration |
| WO2025170980A1 (en) | 2024-02-06 | 2025-08-14 | Chemetics Inc. | Method for producing concentrated oleum or sulfur trioxide |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2026816A1 (de) | 1970-06-02 | 1971-12-16 | Farbwerke Hoechst AG, vorm Meister Lucius & Brumng, 6000 Frankfurt | Verfahren zur Herstellung von Faden aus Poly beta amiden |
| DE2307973A1 (de) * | 1973-02-17 | 1974-08-29 | Metallgesellschaft Ag | Verfahren zur katalytischen umsetzung von so tief 2 zu so tief 3 |
| DE2418216C2 (de) * | 1974-04-13 | 1983-02-17 | Hoechst Ag, 6000 Frankfurt | Verfahren zur Herstellung von Schwefeltrioxyd aus Schwefeldioxyd und Sauerstoff |
| DE2711897C3 (de) * | 1977-03-18 | 1980-01-10 | Davy International Ag, 6000 Frankfurt | Verfahren und Vorrichtung zur katalytischen Oxidation von gasförmigen Schwefelverbindungen zu Schwefeltrioxid |
| SU1011229A1 (ru) * | 1982-01-27 | 1983-04-15 | Государственный Ордена Трудового Красного Знамени Научно-Исследовательский Институт Цветных Металлов | Контактный аппарат дл окислени двуокиси серы |
| DK167242B1 (da) * | 1989-02-16 | 1993-09-27 | Topsoe Haldor As | Apparat og fremgangsmaade til exoterme reaktioner |
| DE4217317A1 (de) * | 1992-05-26 | 1993-12-02 | Metallgesellschaft Ag | Kontaktkessel zur quasi-isothermen katalytischen Umsetzung von SO¶2¶ zu SO¶3¶ und Verfahren zum Betreiben desselben |
| BG61107B1 (bg) * | 1994-08-29 | 1996-11-29 | Институт По Инженерна Химия При Бан | Метод за получаване на серен триокис |
| DE4443774A1 (de) * | 1994-12-08 | 1996-06-13 | Basf Ag | Vorrichtung und Verfahren zur Durchführung exothermer Reaktionen |
| DE10249782A1 (de) | 2002-10-24 | 2004-05-06 | Outokumpu Oyj | Verfahren und Anlage zur Herstellung von Schwefelsäure aus schwefeldioxidreichen Gasen |
| US20090258259A1 (en) * | 2008-04-14 | 2009-10-15 | Michael Leshchiner | Catalytic heat exchangers and methods of operation |
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