DK2256085T3 - Fremgangsmåde og anordning til katalytisk oxidation af SO2-holdige gasser med oxygen - Google Patents

Fremgangsmåde og anordning til katalytisk oxidation af SO2-holdige gasser med oxygen

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Publication number
DK2256085T3
DK2256085T3 DK10172657.8T DK10172657T DK2256085T3 DK 2256085 T3 DK2256085 T3 DK 2256085T3 DK 10172657 T DK10172657 T DK 10172657T DK 2256085 T3 DK2256085 T3 DK 2256085T3
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DK
Denmark
Prior art keywords
catalytic oxidation
oxygen
catalyst
partial
continuous
Prior art date
Application number
DK10172657.8T
Other languages
English (en)
Inventor
Bernd Erkes
Martin Kuerten
Verena Haverkamp
Original Assignee
Bayer Technology Services Gmbh
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Filing date
Publication date
Application filed by Bayer Technology Services Gmbh filed Critical Bayer Technology Services Gmbh
Application granted granted Critical
Publication of DK2256085T3 publication Critical patent/DK2256085T3/da

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/06Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds in tube reactors; the solid particles being arranged in tubes
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B17/00Sulfur; Compounds thereof
    • C01B17/69Sulfur trioxide; Sulfuric acid
    • C01B17/74Preparation
    • C01B17/76Preparation by contact processes
    • C01B17/765Multi-stage SO3-conversion
    • C01B17/7655Multi-stage SO3-conversion with intermediate absorption
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/75Multi-step processes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86Catalytic processes
    • B01D53/8603Removing sulfur compounds
    • B01D53/8609Sulfur oxides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/04Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds
    • B01J8/0446Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the flow within the beds being predominantly vertical
    • B01J8/0476Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the flow within the beds being predominantly vertical in two or more otherwise shaped beds
    • B01J8/048Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the flow within the beds being predominantly vertical in two or more otherwise shaped beds the beds being superimposed one above the other
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/04Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds
    • B01J8/0446Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the flow within the beds being predominantly vertical
    • B01J8/0476Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the flow within the beds being predominantly vertical in two or more otherwise shaped beds
    • B01J8/0488Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds the flow within the beds being predominantly vertical in two or more otherwise shaped beds the beds being placed in separate reactors
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/04Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds
    • B01J8/0496Heating or cooling the reactor
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/06Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds in tube reactors; the solid particles being arranged in tubes
    • B01J8/067Heating or cooling the reactor
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B17/00Sulfur; Compounds thereof
    • C01B17/69Sulfur trioxide; Sulfuric acid
    • C01B17/74Preparation
    • C01B17/76Preparation by contact processes
    • C01B17/765Multi-stage SO3-conversion
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B17/00Sulfur; Compounds thereof
    • C01B17/69Sulfur trioxide; Sulfuric acid
    • C01B17/74Preparation
    • C01B17/76Preparation by contact processes
    • C01B17/78Preparation by contact processes characterised by the catalyst used
    • C01B17/79Preparation by contact processes characterised by the catalyst used containing vanadium
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B17/00Sulfur; Compounds thereof
    • C01B17/69Sulfur trioxide; Sulfuric acid
    • C01B17/74Preparation
    • C01B17/76Preparation by contact processes
    • C01B17/80Apparatus
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B17/00Sulfur; Compounds thereof
    • C01B17/69Sulfur trioxide; Sulfuric acid
    • C01B17/74Preparation
    • C01B17/76Preparation by contact processes
    • C01B17/80Apparatus
    • C01B17/803Converters
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/20Metals or compounds thereof
    • B01D2255/207Transition metals
    • B01D2255/20723Vanadium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008Controlling the process
    • B01J2208/00017Controlling the temperature
    • B01J2208/00106Controlling the temperature by indirect heat exchange
    • B01J2208/00168Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles
    • B01J2208/00176Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles outside the reactor
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008Controlling the process
    • B01J2208/00017Controlling the temperature
    • B01J2208/00106Controlling the temperature by indirect heat exchange
    • B01J2208/00168Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles
    • B01J2208/00203Coils
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00002Chemical plants
    • B01J2219/00004Scale aspects
    • B01J2219/00006Large-scale industrial plants

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Environmental & Geological Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Biomedical Technology (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Health & Medical Sciences (AREA)
  • Materials Engineering (AREA)
  • Catalysts (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)
  • Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
  • Epoxy Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
DK10172657.8T 2006-10-31 2007-10-13 Fremgangsmåde og anordning til katalytisk oxidation af SO2-holdige gasser med oxygen DK2256085T3 (da)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102006051899A DE102006051899A1 (de) 2006-10-31 2006-10-31 Verfahren und Vorrichtung zur katalytischen Oxidation von SO2-haltigen Gasen mit Sauerstoff
EP07818981A EP1979270B1 (de) 2006-10-31 2007-10-13 Vorrichtung zur katalytischen oxidation von so2-haltigen gasen mit sauerstoff

Publications (1)

Publication Number Publication Date
DK2256085T3 true DK2256085T3 (da) 2012-12-17

Family

ID=38984433

Family Applications (2)

Application Number Title Priority Date Filing Date
DK07818981.8T DK1979270T3 (da) 2006-10-31 2007-10-13 Indretning til katalytisk oxidation af SO2-holdige gasser med oxygen
DK10172657.8T DK2256085T3 (da) 2006-10-31 2007-10-13 Fremgangsmåde og anordning til katalytisk oxidation af SO2-holdige gasser med oxygen

Family Applications Before (1)

Application Number Title Priority Date Filing Date
DK07818981.8T DK1979270T3 (da) 2006-10-31 2007-10-13 Indretning til katalytisk oxidation af SO2-holdige gasser med oxygen

Country Status (25)

Country Link
US (1) US7871593B2 (da)
EP (2) EP2256085B1 (da)
JP (2) JP5570216B2 (da)
KR (1) KR101420127B1 (da)
CN (1) CN101573291B (da)
AT (1) ATE503721T1 (da)
AU (1) AU2007315318B2 (da)
BR (1) BRPI0718270B1 (da)
CA (1) CA2668059C (da)
CL (1) CL2007003153A1 (da)
CY (2) CY1112064T1 (da)
DE (2) DE102006051899A1 (da)
DK (2) DK1979270T3 (da)
ES (2) ES2394635T3 (da)
MA (1) MA30915B1 (da)
MX (1) MX2009004483A (da)
NO (1) NO342026B1 (da)
PL (2) PL1979270T3 (da)
PT (2) PT1979270E (da)
RU (2) RU2456232C2 (da)
SI (2) SI1979270T1 (da)
TN (1) TN2009000150A1 (da)
UA (2) UA111809C2 (da)
WO (1) WO2008052649A1 (da)
ZA (1) ZA200902892B (da)

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CN107973278A (zh) * 2016-10-25 2018-05-01 中国石油化工股份有限公司 一种连续产生so3气体的方法
CN106915731B (zh) * 2017-04-14 2023-08-08 双盾环境科技有限公司 一种可调式应用惰性触媒处理高浓度so2烟气生产so3气体的装置
CN107020053A (zh) * 2017-04-18 2017-08-08 北京清新环境技术股份有限公司 一种产生三氧化硫并维持其气体状态的系统及其方法
FR3070016B1 (fr) * 2017-08-10 2019-08-23 L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude Procede et installation de purification d'un flux gazeux d'alimentation comprenant au moins 90% de co2
CN107537316A (zh) * 2017-09-19 2018-01-05 中国大唐集团科学技术研究院有限公司华中分公司 烟道脱硫系统及方法、烟气催化反应装置
EP3691991A1 (en) * 2017-10-05 2020-08-12 Haldor Topsøe A/S A novel layout for inter-bed cooling in sulfuric acid plants
CN108046220A (zh) * 2018-01-16 2018-05-18 山东润银生物化工股份有限公司 一种用合成气脱硫所得h2s生产浓硫酸的装置以及生产方法
CN110606795A (zh) * 2018-06-15 2019-12-24 孔繁昇 一种利用含硫燃料燃烧烟气制备有机磺酸的方法
CN110615408B (zh) * 2018-06-19 2023-08-04 盐城市恒星石油化学有限公司 一种白油生产用三氧化硫转化工艺
CN110615407B (zh) * 2018-06-19 2023-07-07 盐城市恒星石油化学有限公司 一种基础油磺化用三氧化硫的转化工艺
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CA2668059A1 (en) 2008-05-08
DE502007006834D1 (de) 2011-05-12
CA2668059C (en) 2016-07-12
UA111809C2 (uk) 2016-06-24
EP2256085A3 (de) 2011-02-02
AU2007315318B2 (en) 2013-05-30
CL2007003153A1 (es) 2008-05-23
PL1979270T3 (pl) 2011-09-30
AU2007315318A1 (en) 2008-05-08
CY1113349T1 (el) 2016-06-22
CY1112064T1 (el) 2015-11-04
DK1979270T3 (da) 2011-07-25
JP5570216B2 (ja) 2014-08-13
PT1979270E (pt) 2011-06-01
KR20090106459A (ko) 2009-10-09
PT2256085E (pt) 2012-11-06
MX2009004483A (es) 2009-05-20
JP2014240347A (ja) 2014-12-25
CN101573291B (zh) 2014-04-23
PL2256085T3 (pl) 2013-01-31
RU2456232C2 (ru) 2012-07-20
BRPI0718270B1 (pt) 2018-05-02
DE102006051899A1 (de) 2008-05-15
CN101573291A (zh) 2009-11-04
ES2394635T3 (es) 2013-02-04
BRPI0718270A2 (pt) 2013-11-12
WO2008052649A8 (de) 2009-05-22
US7871593B2 (en) 2011-01-18
NO20091768L (no) 2009-05-29
JP2010508222A (ja) 2010-03-18
US20100092374A1 (en) 2010-04-15
SI1979270T1 (sl) 2011-07-29
BRPI0718270A8 (pt) 2017-02-21
WO2008052649A1 (de) 2008-05-08
MA30915B1 (fr) 2009-11-02
ES2361951T3 (es) 2011-06-24
EP2256085A2 (de) 2010-12-01
RU2012109567A (ru) 2013-09-20
UA97381C2 (ru) 2012-02-10
ZA200902892B (en) 2010-07-28
NO342026B1 (no) 2018-03-12
RU2009120402A (ru) 2010-12-10
EP1979270B1 (de) 2011-03-30
EP1979270A1 (de) 2008-10-15
KR101420127B1 (ko) 2014-07-16
TN2009000150A1 (en) 2010-10-18
ATE503721T1 (de) 2011-04-15
EP2256085B1 (de) 2012-08-29
SI2256085T1 (sl) 2013-01-31

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