BR9609057A - Pó de partìcula de polìmero - Google Patents
Pó de partìcula de polìmeroInfo
- Publication number
- BR9609057A BR9609057A BR9609057-0A BR9609057A BR9609057A BR 9609057 A BR9609057 A BR 9609057A BR 9609057 A BR9609057 A BR 9609057A BR 9609057 A BR9609057 A BR 9609057A
- Authority
- BR
- Brazil
- Prior art keywords
- mixture
- polymerization
- polymer particle
- particle powder
- heated
- Prior art date
Links
- 239000002245 particle Substances 0.000 title abstract 2
- 229920000642 polymer Polymers 0.000 title abstract 2
- 239000000843 powder Substances 0.000 title abstract 2
- 239000000203 mixture Substances 0.000 abstract 4
- 238000006116 polymerization reaction Methods 0.000 abstract 4
- 239000003153 chemical reaction reagent Substances 0.000 abstract 2
- 238000004320 controlled atmosphere Methods 0.000 abstract 2
- 239000002904 solvent Substances 0.000 abstract 2
- 239000003999 initiator Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 239000000178 monomer Substances 0.000 abstract 1
- 239000003960 organic solvent Substances 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
- C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
- C08F20/04—Acids, Metal salts or ammonium salts thereof
- C08F20/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J10/00—Chemical processes in general for reacting liquid with gaseous media other than in the presence of solid particles, or apparatus specially adapted therefor
- B01J10/002—Chemical processes in general for reacting liquid with gaseous media other than in the presence of solid particles, or apparatus specially adapted therefor carried out in foam, aerosol or bubbles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J14/00—Chemical processes in general for reacting liquids with liquids; Apparatus specially adapted therefor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/26—Nozzle-type reactors, i.e. the distribution of the initial reactants within the reactor is effected by their introduction or injection through nozzles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2/00—Processes or devices for granulating materials, e.g. fertilisers in general; Rendering particulate materials free flowing in general, e.g. making them hydrophobic
- B01J2/02—Processes or devices for granulating materials, e.g. fertilisers in general; Rendering particulate materials free flowing in general, e.g. making them hydrophobic by dividing the liquid material into drops, e.g. by spraying, and solidifying the drops
- B01J2/04—Processes or devices for granulating materials, e.g. fertilisers in general; Rendering particulate materials free flowing in general, e.g. making them hydrophobic by dividing the liquid material into drops, e.g. by spraying, and solidifying the drops in a gaseous medium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B9/00—Making granules
- B29B9/10—Making granules by moulding the material, i.e. treating it in the molten state
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00051—Controlling the temperature
- B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
- B01J2219/00076—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements inside the reactor
- B01J2219/00083—Coils
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00051—Controlling the temperature
- B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
- B01J2219/00087—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor
- B01J2219/0009—Coils
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00051—Controlling the temperature
- B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
- B01J2219/00087—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor
- B01J2219/00099—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor the reactor being immersed in the heat exchange medium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00051—Controlling the temperature
- B01J2219/00132—Controlling the temperature using electric heating or cooling elements
- B01J2219/00135—Electric resistance heaters
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00051—Controlling the temperature
- B01J2219/0015—Controlling the temperature by thermal insulation means
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00162—Controlling or regulating processes controlling the pressure
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Dispersion Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Polymerisation Methods In General (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US48607995A | 1995-06-07 | 1995-06-07 | |
US48380095A | 1995-06-07 | 1995-06-07 | |
US47916795A | 1995-06-07 | 1995-06-07 | |
PCT/US1996/009132 WO1996040427A1 (en) | 1995-06-07 | 1996-06-06 | A polymerization process, apparatus and polymer |
Publications (1)
Publication Number | Publication Date |
---|---|
BR9609057A true BR9609057A (pt) | 2002-07-16 |
Family
ID=27413475
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BR9609057-0A BR9609057A (pt) | 1995-06-07 | 1996-06-06 | Pó de partìcula de polìmero |
Country Status (7)
Country | Link |
---|---|
EP (1) | EP0873185B1 (en:Method) |
JP (1) | JPH11507094A (en:Method) |
AT (1) | ATE240780T1 (en:Method) |
BR (1) | BR9609057A (en:Method) |
DE (1) | DE69628330D1 (en:Method) |
IN (1) | IN1996KO01040A (en:Method) |
WO (1) | WO1996040427A1 (en:Method) |
Families Citing this family (63)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6391986B1 (en) | 2000-12-05 | 2002-05-21 | Union Carbide Chemicals & Plastics Technology Corporation | Control of solution catalyst droplets |
US6869551B2 (en) * | 2001-03-30 | 2005-03-22 | Picoliter Inc. | Precipitation of solid particles from droplets formed using focused acoustic energy |
DE10314466A1 (de) * | 2003-03-28 | 2004-10-14 | Basf Ag | Verfahren zur Herstellung von kondensierten Harzen in Pulverform |
DE10340253A1 (de) * | 2003-08-29 | 2005-03-24 | Basf Ag | Sprühpolymerisationsverfahren |
CA2557199A1 (en) * | 2004-02-24 | 2005-09-09 | Luna Innovations Incorporated | Process and systems for the efficient production of polymeric microspheres |
DE102004024437A1 (de) * | 2004-05-14 | 2005-12-08 | Basf Ag | Verfahren zur Herstellung wasserquellbarer, polymerer Partikel |
DE102004042948A1 (de) | 2004-09-02 | 2006-03-09 | Basf Ag | Verfahren zur Herstellung von Polymeren durch Sprühpolymerisation |
DE102005002412A1 (de) | 2005-01-18 | 2006-07-27 | Basf Ag | Verfahren zur Herstellung von Polymeren durch Sprühpolymerisation |
JP5101300B2 (ja) | 2005-01-28 | 2012-12-19 | ビーエーエスエフ ソシエタス・ヨーロピア | 気相中での液滴重合によって、吸水性ポリマー粒子を製造する方法 |
DE102005019398A1 (de) * | 2005-04-25 | 2006-10-26 | Basf Ag | Verfahren zur Herstellung von Fällungspolymeren durch Sprühpolymerisation |
DE102005044035A1 (de) | 2005-09-14 | 2007-03-15 | Basf Ag | Verfahren zum Vertropfen von Flüssigkeiten |
WO2007093531A1 (de) * | 2006-02-17 | 2007-08-23 | Basf Se | Verfahren zur herstellung wasserabsorbierender polymerpartikel durch polymerisation von tropfen einer monomerlösung |
RU2463310C2 (ru) | 2006-07-19 | 2012-10-10 | Басф Се | Способ получения водопоглощающих полимерных частиц с высокой проницаемостью путем полимеризации капель мономерного раствора |
CN101489596B (zh) | 2006-07-19 | 2013-05-15 | 巴斯夫欧洲公司 | 通过聚合单体溶液液滴生产具有较高吸收的后固化的吸水性聚合物颗粒的方法 |
BRPI0714444B8 (pt) | 2006-07-19 | 2021-06-22 | Basf Se | processo para preparar partículas poliméricas absorvedoras de água, partículas poliméricas absorvedoras de água, uso das partículas poliméricas, e, artigo de higiene |
JP5637685B2 (ja) * | 2006-07-19 | 2014-12-10 | ビーエーエスエフ ソシエタス・ヨーロピアBasf Se | モノマー溶液の液滴の重合による、高い透過性を有する吸水性ポリマー粒子の製造方法、当該方法により製造できる吸水性ポリマー粒子、及び、当該吸水性ポリマー粒子を含有する衛生製品 |
CN104592437A (zh) * | 2006-07-19 | 2015-05-06 | 巴斯夫欧洲公司 | 通过聚合单体溶液的微滴而生产吸水性聚合物颗粒的方法 |
JP5517622B2 (ja) | 2006-10-05 | 2014-06-11 | ビーエーエスエフ ソシエタス・ヨーロピア | モノマー溶液の液滴の重合による吸収性ポリマー粒子の製造法 |
EP2076547B1 (de) | 2006-10-05 | 2011-03-09 | Basf Se | Verfahren zur herstellung wasserabsorbierender polymerpartikel durch polymerisation von tropfen einer monomerlösung |
US8183331B2 (en) | 2006-10-31 | 2012-05-22 | Basf Se | Regulation of a process for producing water-absorbing polymer particles in a heated gas phase |
US7951304B2 (en) | 2006-12-22 | 2011-05-31 | Basf Se | Method for producing mechanically stable water-absorbent polymer particles |
US8419971B2 (en) | 2006-12-22 | 2013-04-16 | Basf Se | Method for producing mechanically stable water-absorbent polymer particles |
WO2008095901A1 (de) | 2007-02-06 | 2008-08-14 | Basf Se | Verfahren zur herstellung wasserabsorbierender polymerpartikel durch polymerisation von tropfen einer monomerlösung |
DE102008043523A1 (de) | 2007-11-16 | 2009-05-20 | Basf Se | Verfahren zur Herstellung von Polyvinylpyrrolidonen durch Sprühpolymerisation |
JP5410412B2 (ja) | 2008-03-31 | 2014-02-05 | 株式会社日本触媒 | 吸水性樹脂を主成分とする粒子状吸水剤の製造方法及びその製造装置 |
US8546498B2 (en) | 2008-07-07 | 2013-10-01 | Basf Se | Method for producing water-absorbing polymer particles by polymerizing droplets of a monomer solution |
JP5933262B2 (ja) | 2008-08-06 | 2016-06-08 | ビーエーエスエフ ソシエタス・ヨーロピアBasf Se | 流体吸収性物品 |
WO2010015561A1 (en) | 2008-08-06 | 2010-02-11 | Basf Se | Fluid-absorbent articles |
EP2313040B1 (en) | 2008-08-06 | 2013-06-19 | Basf Se | Fluid-absorbent articles |
JP5755142B2 (ja) | 2008-11-21 | 2015-07-29 | ビーエーエスエフ ソシエタス・ヨーロピアBasf Se | モノマー溶液の液滴を重合させることによって浸透性の吸水性ポリマー粒子を製造する方法 |
EP2277557B1 (en) | 2009-07-20 | 2014-06-25 | The Procter and Gamble Company | Coated superabsorbent polymer particles and processes therefore |
EP2277558B1 (en) | 2009-07-20 | 2014-07-02 | The Procter and Gamble Company | Superabsorbent polymer composite particles and processes therefore |
JP5661769B2 (ja) | 2009-08-25 | 2015-01-28 | ビーエーエスエフ ソシエタス・ヨーロピアBasf Se | モノマー溶液の液滴の重合によって改善された血液吸収を有する、吸水性ポリマー粒子の製造方法 |
US20120157302A1 (en) | 2009-08-28 | 2012-06-21 | Basf Se | Process For Producing Triclosan-Coated Superabsorbents |
US8481159B2 (en) | 2009-09-04 | 2013-07-09 | Basf Se | Water-absorbent porous polymer particles having specific sphericity and high bulk density |
BR112012005901A2 (pt) | 2009-09-16 | 2019-09-24 | Basf Se | superabsorvente, processo para produzir um superabsorvente, artigo para absorver fluidos, e, processo para produzir artigos para absorver fluidos |
JP2013505313A (ja) | 2009-09-17 | 2013-02-14 | ビーエーエスエフ ソシエタス・ヨーロピア | 色安定性の超吸収剤 |
WO2011113728A1 (en) | 2010-03-15 | 2011-09-22 | Basf Se | A process for producing water-absorbent polymer particles by polymerizing droplets of a monomer solution |
US8852742B2 (en) | 2010-03-15 | 2014-10-07 | Basf Se | Water absorbent polymer particles formed by polymerizing droplets of a monomer solution and coated with sulfinic acid, sulfonic acid, and/or salts thereof |
EP2550304B2 (de) | 2010-03-24 | 2018-09-19 | Basf Se | Verfahren zur entfernung von restmonomeren aus wasserabsorbierenden polymerpartikeln |
CN102812053B (zh) | 2010-03-24 | 2015-01-14 | 巴斯夫欧洲公司 | 通过聚合单体溶液的液滴制备吸水性聚合物颗粒的方法 |
EP2549968B1 (en) | 2010-03-24 | 2022-01-05 | Basf Se | Ultrathin fluid-absorbent cores |
WO2013045163A1 (en) | 2011-08-12 | 2013-04-04 | Basf Se | A process for producing water-absorbent polymer particles by polymerizing droplets of a monomer solution |
CN104245760A (zh) | 2012-03-30 | 2014-12-24 | 巴斯夫欧洲公司 | 颜色稳定的超吸收剂 |
KR20140144259A (ko) | 2012-03-30 | 2014-12-18 | 바스프 에스이 | 색 안정적 초흡수체 |
BR112015011531B1 (pt) | 2012-11-21 | 2021-08-24 | Basf Se | Processo para a produção de partículas de polímeros absorventes de água pósreticuladas na superfície, partículas de polímeros absorventes de água pós-reticuladas na superfície, e, artigo absorvente de fluido |
WO2014079710A1 (en) | 2012-11-21 | 2014-05-30 | Basf Se | A process for producing water-absorbent polymer particles by polymerizing droplets of a monomer solution |
MX2016001418A (es) | 2013-07-31 | 2016-08-18 | Basf Se | Proceso de polimerizacion de fase inversa. |
JP2016535646A (ja) | 2013-08-26 | 2016-11-17 | ビーエーエスエフ ソシエタス・ヨーロピアBasf Se | 流体吸収性製品 |
EP3096803B1 (en) | 2014-01-24 | 2017-12-20 | Basf Se | A process for producing water-absorbent polymer particles by polymerizing droplets of a monomer solution |
US10881555B2 (en) | 2016-03-30 | 2021-01-05 | Basf Se | Fluid-absorbent article |
US10806640B2 (en) | 2016-03-30 | 2020-10-20 | Basf Se | Ultrathin fluid-absorbent article |
US20170281425A1 (en) | 2016-03-30 | 2017-10-05 | Basf Se | Fluid-absorbent article |
US11931928B2 (en) | 2016-12-29 | 2024-03-19 | Evonik Superabsorber Llc | Continuous strand superabsorbent polymerization |
JP7424832B2 (ja) | 2017-02-06 | 2024-01-30 | ビーエーエスエフ ソシエタス・ヨーロピア | 流体吸収性物品 |
EP3582734B1 (en) | 2017-02-17 | 2021-12-01 | Basf Se | Fluid-absorbent article |
US11813589B2 (en) | 2017-11-10 | 2023-11-14 | Basf Se | Superabsorbent complexed with aluminum ions |
KR102677635B1 (ko) | 2018-04-10 | 2024-06-21 | 바스프 에스이 | 투과성 초흡수제 및 이의 생산 방법 |
EP3781107B1 (en) | 2018-04-20 | 2024-09-25 | Basf Se | Thin fluid absorbent core-absorbent paper |
DE102019216910A1 (de) | 2018-11-12 | 2020-05-14 | Basf Se | Verfahren zur Oberflächennachvernetzung von Superabsorbern |
US12403448B2 (en) | 2019-07-24 | 2025-09-02 | Basf Se | Permeable superabsorbent and process for production thereof |
CN112480300A (zh) * | 2020-11-30 | 2021-03-12 | 浙江卫星新材料科技有限公司 | 一种光缆电缆阻水用高吸收性树脂的制备方法 |
IT202100012473A1 (it) * | 2021-05-14 | 2022-11-14 | Resourseas S R L | Reattore e processo di precipitazione di un prodotto solido |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BE514890A (en:Method) * | 1951-12-18 | 1900-01-01 | ||
US3325455A (en) * | 1963-11-21 | 1967-06-13 | Polymer Corp | Method of producing nylon powders |
US4623706A (en) * | 1984-08-23 | 1986-11-18 | The Dow Chemical Company | Process for preparing uniformly sized polymer particles by suspension polymerization of vibratorily excited monomers in a gaseous or liquid stream |
JPH0819163B2 (ja) * | 1988-04-20 | 1996-02-28 | 旭化成工業株式会社 | 高吸水性材料の製法 |
US4963226A (en) * | 1989-01-23 | 1990-10-16 | The Procter & Gamble Company | Process for spray-drying detergent compositions |
GB9115170D0 (en) * | 1991-07-12 | 1991-08-28 | Dow Corning Sa | Process and apparatus for the production of organosilicon compounds |
US5269980A (en) * | 1991-08-05 | 1993-12-14 | Northeastern University | Production of polymer particles in powder form using an atomization technique |
-
1996
- 1996-06-05 IN IN1040KO1996 patent/IN1996KO01040A/en unknown
- 1996-06-06 AT AT96918199T patent/ATE240780T1/de not_active IP Right Cessation
- 1996-06-06 BR BR9609057-0A patent/BR9609057A/pt not_active Application Discontinuation
- 1996-06-06 DE DE69628330T patent/DE69628330D1/de not_active Expired - Lifetime
- 1996-06-06 JP JP9501525A patent/JPH11507094A/ja active Pending
- 1996-06-06 EP EP96918199A patent/EP0873185B1/en not_active Revoked
- 1996-06-06 WO PCT/US1996/009132 patent/WO1996040427A1/en not_active Application Discontinuation
Also Published As
Publication number | Publication date |
---|---|
WO1996040427A1 (en) | 1996-12-19 |
ATE240780T1 (de) | 2003-06-15 |
EP0873185B1 (en) | 2003-05-21 |
DE69628330D1 (de) | 2003-06-26 |
IN1996KO01040A (en:Method) | 2005-03-04 |
JPH11507094A (ja) | 1999-06-22 |
EP0873185A1 (en) | 1998-10-28 |
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