BR112016019583B1 - Copolímero de propileno heterofásico, processo para preparação de um copolímero de propileno heterofásico, e, artigo - Google Patents
Copolímero de propileno heterofásico, processo para preparação de um copolímero de propileno heterofásico, e, artigo Download PDFInfo
- Publication number
- BR112016019583B1 BR112016019583B1 BR112016019583-3A BR112016019583A BR112016019583B1 BR 112016019583 B1 BR112016019583 B1 BR 112016019583B1 BR 112016019583 A BR112016019583 A BR 112016019583A BR 112016019583 B1 BR112016019583 B1 BR 112016019583B1
- Authority
- BR
- Brazil
- Prior art keywords
- propylene copolymer
- raheco
- fraction
- heterophasic propylene
- range
- Prior art date
Links
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 title claims abstract description 386
- 229920001577 copolymer Polymers 0.000 title claims abstract description 320
- 238000000034 method Methods 0.000 title claims description 36
- 230000008569 process Effects 0.000 title claims description 22
- 238000002360 preparation method Methods 0.000 title description 9
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims abstract description 64
- 239000008096 xylene Substances 0.000 claims abstract description 64
- 238000002844 melting Methods 0.000 claims abstract description 22
- 230000008018 melting Effects 0.000 claims abstract description 22
- 238000004519 manufacturing process Methods 0.000 claims abstract description 6
- 239000004743 Polypropylene Substances 0.000 claims description 134
- 229920001155 polypropylene Polymers 0.000 claims description 128
- -1 polypropylene Polymers 0.000 claims description 70
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 67
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 64
- 239000005977 Ethylene Substances 0.000 claims description 64
- 239000003054 catalyst Substances 0.000 claims description 64
- 239000011159 matrix material Substances 0.000 claims description 38
- 230000009477 glass transition Effects 0.000 claims description 34
- 239000004711 α-olefin Substances 0.000 claims description 28
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 21
- 125000001183 hydrocarbyl group Chemical group 0.000 claims description 19
- 239000007789 gas Substances 0.000 claims description 18
- 229910052739 hydrogen Inorganic materials 0.000 claims description 17
- 239000001257 hydrogen Substances 0.000 claims description 17
- 229920001384 propylene homopolymer Polymers 0.000 claims description 13
- 125000005843 halogen group Chemical group 0.000 claims description 12
- 125000005842 heteroatom Chemical group 0.000 claims description 12
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 claims description 12
- 230000000379 polymerizing effect Effects 0.000 claims description 11
- 239000007787 solid Substances 0.000 claims description 11
- 235000013305 food Nutrition 0.000 claims description 10
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- 125000004432 carbon atom Chemical group C* 0.000 claims description 9
- 125000003118 aryl group Chemical group 0.000 claims description 8
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical group [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 7
- 238000000113 differential scanning calorimetry Methods 0.000 claims description 7
- 125000005647 linker group Chemical group 0.000 claims description 7
- 229910052726 zirconium Inorganic materials 0.000 claims description 7
- 150000001875 compounds Chemical class 0.000 claims description 6
- 229910052735 hafnium Chemical group 0.000 claims description 6
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical group [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 claims description 6
- 125000001072 heteroaryl group Chemical group 0.000 claims description 6
- 229910021482 group 13 metal Inorganic materials 0.000 claims description 4
- 125000001181 organosilyl group Chemical group [SiH3]* 0.000 claims description 4
- 125000006659 (C1-C20) hydrocarbyl group Chemical group 0.000 claims description 3
- 125000006736 (C6-C20) aryl group Chemical group 0.000 claims description 3
- 150000001639 boron compounds Chemical class 0.000 claims description 3
- 125000006574 non-aromatic ring group Chemical group 0.000 claims description 3
- 229920001198 elastomeric copolymer Polymers 0.000 description 37
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 30
- 238000006116 polymerization reaction Methods 0.000 description 25
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 22
- 238000007789 sealing Methods 0.000 description 19
- 125000000008 (C1-C10) alkyl group Chemical group 0.000 description 16
- 229920000642 polymer Polymers 0.000 description 16
- 101100023124 Schizosaccharomyces pombe (strain 972 / ATCC 24843) mfr2 gene Proteins 0.000 description 13
- 239000000178 monomer Substances 0.000 description 13
- 239000000243 solution Substances 0.000 description 13
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 12
- 239000002245 particle Substances 0.000 description 10
- 125000004169 (C1-C6) alkyl group Chemical group 0.000 description 9
- 239000007788 liquid Substances 0.000 description 9
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- 125000000041 C6-C10 aryl group Chemical group 0.000 description 8
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 8
- 239000000839 emulsion Substances 0.000 description 8
- 239000000203 mixture Substances 0.000 description 7
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- 125000000217 alkyl group Chemical group 0.000 description 6
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- 229920002521 macromolecule Polymers 0.000 description 6
- 239000011777 magnesium Substances 0.000 description 6
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- 125000004191 (C1-C6) alkoxy group Chemical group 0.000 description 4
- YIWUKEYIRIRTPP-UHFFFAOYSA-N 2-ethylhexan-1-ol Chemical compound CCCCC(CC)CO YIWUKEYIRIRTPP-UHFFFAOYSA-N 0.000 description 4
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 4
- 238000005481 NMR spectroscopy Methods 0.000 description 4
- 125000003710 aryl alkyl group Chemical group 0.000 description 4
- 238000004364 calculation method Methods 0.000 description 4
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- NNBZCPXTIHJBJL-UHFFFAOYSA-N decalin Chemical compound C1CCCC2CCCCC21 NNBZCPXTIHJBJL-UHFFFAOYSA-N 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 239000000155 melt Substances 0.000 description 4
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- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 4
- 125000006376 (C3-C10) cycloalkyl group Chemical group 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 3
- 239000004698 Polyethylene Substances 0.000 description 3
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- 238000002474 experimental method Methods 0.000 description 3
- 230000004927 fusion Effects 0.000 description 3
- 150000002431 hydrogen Chemical group 0.000 description 3
- 238000010348 incorporation Methods 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 3
- 229920000573 polyethylene Polymers 0.000 description 3
- 230000005855 radiation Effects 0.000 description 3
- 229910052717 sulfur Inorganic materials 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- ZGEGCLOFRBLKSE-UHFFFAOYSA-N 1-Heptene Chemical compound CCCCCC=C ZGEGCLOFRBLKSE-UHFFFAOYSA-N 0.000 description 2
- AFFLGGQVNFXPEV-UHFFFAOYSA-N 1-decene Chemical compound CCCCCCCCC=C AFFLGGQVNFXPEV-UHFFFAOYSA-N 0.000 description 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N 1-nonene Chemical compound CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 2
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 2
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 2
- 229920000181 Ethylene propylene rubber Polymers 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 238000013459 approach Methods 0.000 description 2
- 229910052786 argon Inorganic materials 0.000 description 2
- 239000012298 atmosphere Substances 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 2
- PPAJKSBNLWWSIM-VKAVYKQESA-N bis(2-ethylhexyl) (z)-2-methylbut-2-enedioate Chemical compound CCCCC(CC)COC(=O)\C=C(\C)C(=O)OCC(CC)CCCC PPAJKSBNLWWSIM-VKAVYKQESA-N 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 125000001309 chloro group Chemical group Cl* 0.000 description 2
- MJSNUBOCVAKFIJ-LNTINUHCSA-N chromium;(z)-4-oxoniumylidenepent-2-en-2-olate Chemical compound [Cr].C\C(O)=C\C(C)=O.C\C(O)=C\C(C)=O.C\C(O)=C\C(C)=O MJSNUBOCVAKFIJ-LNTINUHCSA-N 0.000 description 2
- 239000003426 co-catalyst Substances 0.000 description 2
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- 238000000605 extraction Methods 0.000 description 2
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- 239000011521 glass Substances 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 238000002386 leaching Methods 0.000 description 2
- 239000003446 ligand Substances 0.000 description 2
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- 238000007254 oxidation reaction Methods 0.000 description 2
- 239000005022 packaging material Substances 0.000 description 2
- 230000035515 penetration Effects 0.000 description 2
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 2
- LOQGSOTUHASIHI-UHFFFAOYSA-N perfluoro-1,3-dimethylcyclohexane Chemical compound FC(F)(F)C1(F)C(F)(F)C(F)(F)C(F)(F)C(F)(C(F)(F)F)C1(F)F LOQGSOTUHASIHI-UHFFFAOYSA-N 0.000 description 2
- 125000006187 phenyl benzyl group Chemical group 0.000 description 2
- 229920000098 polyolefin Polymers 0.000 description 2
- 229920005606 polypropylene copolymer Polymers 0.000 description 2
- 238000004983 proton decoupled 13C NMR spectroscopy Methods 0.000 description 2
- 238000011002 quantification Methods 0.000 description 2
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- 229910001220 stainless steel Inorganic materials 0.000 description 2
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- 238000003786 synthesis reaction Methods 0.000 description 2
- 238000012546 transfer Methods 0.000 description 2
- OBAJXDYVZBHCGT-UHFFFAOYSA-N tris(pentafluorophenyl)borane Chemical compound FC1=C(F)C(F)=C(F)C(F)=C1B(C=1C(=C(F)C(F)=C(F)C=1F)F)C1=C(F)C(F)=C(F)C(F)=C1F OBAJXDYVZBHCGT-UHFFFAOYSA-N 0.000 description 2
- PXXNTAGJWPJAGM-UHFFFAOYSA-N vertaline Natural products C1C2C=3C=C(OC)C(OC)=CC=3OC(C=C3)=CC=C3CCC(=O)OC1CC1N2CCCC1 PXXNTAGJWPJAGM-UHFFFAOYSA-N 0.000 description 2
- 125000006720 (C1-C6) alkyl (C6-C10) aryl group Chemical group 0.000 description 1
- 125000004209 (C1-C8) alkyl group Chemical group 0.000 description 1
- 125000006649 (C2-C20) alkynyl group Chemical group 0.000 description 1
- 125000006651 (C3-C20) cycloalkyl group Chemical group 0.000 description 1
- 125000006272 (C3-C7) cycloalkyl group Chemical group 0.000 description 1
- 125000006704 (C5-C6) cycloalkyl group Chemical group 0.000 description 1
- QPFMBZIOSGYJDE-QDNHWIQGSA-N 1,1,2,2-tetrachlorethane-d2 Chemical compound [2H]C(Cl)(Cl)C([2H])(Cl)Cl QPFMBZIOSGYJDE-QDNHWIQGSA-N 0.000 description 1
- IDQBJILTOGBZCR-UHFFFAOYSA-N 1-butoxypropan-1-ol Chemical compound CCCCOC(O)CC IDQBJILTOGBZCR-UHFFFAOYSA-N 0.000 description 1
- RWNUSVWFHDHRCJ-UHFFFAOYSA-N 1-butoxypropan-2-ol Chemical compound CCCCOCC(C)O RWNUSVWFHDHRCJ-UHFFFAOYSA-N 0.000 description 1
- SDRZFSPCVYEJTP-UHFFFAOYSA-N 1-ethenylcyclohexene Chemical compound C=CC1=CCCCC1 SDRZFSPCVYEJTP-UHFFFAOYSA-N 0.000 description 1
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 1
- WNFGKTKGWGYAGE-UHFFFAOYSA-N C(CCC)[Mg]CC.CC1=CC=CC=C1 Chemical compound C(CCC)[Mg]CC.CC1=CC=CC=C1 WNFGKTKGWGYAGE-UHFFFAOYSA-N 0.000 description 1
- 125000003358 C2-C20 alkenyl group Chemical group 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 239000004809 Teflon Substances 0.000 description 1
- 229920006362 Teflon® Polymers 0.000 description 1
- 229910003074 TiCl4 Inorganic materials 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
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- 238000013019 agitation Methods 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 150000004703 alkoxides Chemical class 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 238000004630 atomic force microscopy Methods 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 230000002902 bimodal effect Effects 0.000 description 1
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- 150000001642 boronic acid derivatives Chemical class 0.000 description 1
- 125000001246 bromo group Chemical group Br* 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
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- 125000000392 cycloalkenyl group Chemical group 0.000 description 1
- 125000001316 cycloalkyl alkyl group Chemical group 0.000 description 1
- 125000000753 cycloalkyl group Chemical group 0.000 description 1
- SJJCABYOVIHNPZ-UHFFFAOYSA-N cyclohexyl-dimethoxy-methylsilane Chemical compound CO[Si](C)(OC)C1CCCCC1 SJJCABYOVIHNPZ-UHFFFAOYSA-N 0.000 description 1
- 125000004210 cyclohexylmethyl group Chemical group [H]C([H])(*)C1([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C1([H])[H] 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- JWCYDYZLEAQGJJ-UHFFFAOYSA-N dicyclopentyl(dimethoxy)silane Chemical compound C1CCCC1[Si](OC)(OC)C1CCCC1 JWCYDYZLEAQGJJ-UHFFFAOYSA-N 0.000 description 1
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- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 230000005284 excitation Effects 0.000 description 1
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- 229920001519 homopolymer Polymers 0.000 description 1
- 230000003100 immobilizing effect Effects 0.000 description 1
- 125000003114 inden-1-yl group Chemical group [H]C1=C([H])C([H])(*)C2=C([H])C([H])=C([H])C([H])=C12 0.000 description 1
- 239000003701 inert diluent Substances 0.000 description 1
- 229910052809 inorganic oxide Inorganic materials 0.000 description 1
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- 230000037431 insertion Effects 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 125000002346 iodo group Chemical group I* 0.000 description 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- YHNWUQFTJNJVNU-UHFFFAOYSA-N magnesium;butane;ethane Chemical compound [Mg+2].[CH2-]C.CCC[CH2-] YHNWUQFTJNJVNU-UHFFFAOYSA-N 0.000 description 1
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- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 description 1
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- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000002667 nucleating agent Substances 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- 238000013021 overheating Methods 0.000 description 1
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 1
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- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000012429 reaction media Substances 0.000 description 1
- 230000002040 relaxant effect Effects 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
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- 239000006228 supernatant Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 230000000930 thermomechanical effect Effects 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 1
- AZSKHRTUXHLAHS-UHFFFAOYSA-N tris(2,4-di-tert-butylphenyl) phosphate Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(=O)(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C AZSKHRTUXHLAHS-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/04—Monomers containing three or four carbon atoms
- C08F210/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
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- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
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| PCT/EP2015/052198 WO2015139875A1 (en) | 2014-03-21 | 2015-02-03 | Heterophasic propylene copolymer with high melting point |
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| ES2767498T3 (es) * | 2014-02-06 | 2020-06-17 | Borealis Ag | Copolímeros de impacto transparentes y suaves |
| US10100185B2 (en) | 2014-02-06 | 2018-10-16 | Borealis Ag | Soft copolymers with high impact strength |
| BR112017016081B1 (pt) | 2015-02-20 | 2022-05-03 | Borealis Ag | Copolímeros heterofásicos de propileno, seu processo para produção e tubo |
| ES3046758T3 (en) * | 2016-06-28 | 2025-12-02 | Borealis Gmbh | Soft and transparent polypropylene composition |
| FI3601383T3 (fi) * | 2017-03-27 | 2024-05-30 | Basell Poliolefine Italia Srl | Propyleenietyleenisatunnaiskopolymeeri |
| US11078304B2 (en) | 2017-07-07 | 2021-08-03 | Borealis Ag | Process for preparing heterophasic propylene copolymers |
| PL3506323T3 (pl) * | 2017-12-28 | 2023-10-09 | Borealis Ag | Zastosowanie płaszcza kabla |
| EP3740533B1 (en) * | 2018-01-18 | 2022-08-17 | Borealis AG | Heterophasic polypropylene composition with high flexibility and softness |
| EP3856800A1 (en) * | 2018-09-28 | 2021-08-04 | Borealis AG | Process for producing a prepolymerized solid ziegler-natta catalyst |
| ES2945963T3 (es) | 2018-12-14 | 2023-07-11 | Borealis Ag | Composición de polipropileno con combinación favorable de óptica, suavidad y bajo sellado |
| EP3670547B1 (en) * | 2018-12-21 | 2023-06-07 | Borealis AG | Polypropylene composition for film sealing layer |
| CN113924211B (zh) * | 2019-06-05 | 2023-09-22 | 北欧化工公司 | 多层聚丙烯膜 |
| EP3750927A1 (en) | 2019-06-12 | 2020-12-16 | Borealis AG | Heterophasic propylene copolymer with improved mechanical properties |
| EP4103648A1 (en) * | 2020-02-14 | 2022-12-21 | SABIC Global Technologies B.V. | Film comprising heterophasic propylene copolymer composition |
| US20240191015A1 (en) * | 2021-03-24 | 2024-06-13 | Borealis Ag | Copolymer |
| US20240174774A1 (en) * | 2021-03-24 | 2024-05-30 | Borealis Ag | Process for producing heterophasic propylene resin |
| WO2025117354A1 (en) * | 2023-12-01 | 2025-06-05 | ExxonMobil Technology and Engineering Company | Methods for producing impact copolymers using c1 symmetric metallocene catalysts |
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| FI86867C (fi) | 1990-12-28 | 1992-10-26 | Neste Oy | Flerstegsprocess foer framstaellning av polyeten |
| FI111848B (fi) | 1997-06-24 | 2003-09-30 | Borealis Tech Oy | Menetelmä ja laitteisto propeenin homo- ja kopolymeerien valmistamiseksi |
| FI980342A0 (fi) | 1997-11-07 | 1998-02-13 | Borealis As | Polymerroer och -roerkopplingar |
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| EP1484343A1 (en) | 2003-06-06 | 2004-12-08 | Universiteit Twente | Process for the catalytic polymerization of olefins, a reactor system and its use in the same process |
| JP2007505175A (ja) | 2003-09-11 | 2007-03-08 | バセル ポリオレフィン ジーエムビーエイチ | ヘテロ相プロピレンコポリマーを製造するための多段方法 |
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| ATE407970T1 (de) * | 2005-01-14 | 2008-09-15 | Borealis Polymers Oy | Heterophasische polymerzusammensetzung und verfahren zu ihrer herstellung |
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| WO2010052263A1 (en) | 2008-11-07 | 2010-05-14 | Borealis Ag | Solid catalyst composition |
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| EP2264099A1 (en) † | 2009-05-21 | 2010-12-22 | Basell Poliolefine Italia S.R.L. | Propylene polymer compositions |
| KR101538910B1 (ko) † | 2009-05-21 | 2015-07-23 | 바셀 폴리올레핀 이탈리아 에스.알.엘 | 프로필렌 중합체 조성물 |
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| EP2571933B1 (en) † | 2010-05-20 | 2016-11-02 | Basell Poliolefine Italia S.r.l. | Propylene polymer compositions |
| EP2415831A1 (en) * | 2010-08-06 | 2012-02-08 | Borealis AG | Heterophasic propylene copolymer with excellent impact/stiffness balance |
| ES2397547T3 (es) * | 2010-08-27 | 2013-03-07 | Borealis Ag | Composición de polipropileno rígido con excelente alargamiento de rotura |
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| MX340414B (es) * | 2010-09-30 | 2016-07-06 | Dow Global Tech Llc * | Composición polimérica y capa selladora con la misma. |
| ES2462165T3 (es) * | 2011-05-23 | 2014-05-22 | Borealis Ag | Copolímero aleatorio de propileno con alta rigidez y baja turbidez |
| ES2643158T3 (es) | 2011-07-08 | 2017-11-21 | Borealis Ag | Catalizadores |
| ES2559957T3 (es) * | 2011-08-09 | 2016-02-16 | Borealis Ag | Preparación de un copolímero de propileno heterofásico blando |
| WO2013026745A1 (en) * | 2011-08-19 | 2013-02-28 | Borealis Ag | Heterophasic system with improved surface properties |
| BR112016004329B1 (pt) | 2013-09-26 | 2021-12-14 | Blupura S.R.L. | Combinação de dispensador e recipiente para uma pluralidade de recipientes com um sistema para o colocamento correto |
| ES2767498T3 (es) * | 2014-02-06 | 2020-06-17 | Borealis Ag | Copolímeros de impacto transparentes y suaves |
| EP3126411B1 (en) * | 2014-04-04 | 2017-11-29 | Borealis AG | Heterophasic propylene copolymer with low extractables |
| WO2020239583A1 (en) † | 2019-05-29 | 2020-12-03 | Borealis Ag | C2c3 random copolymer |
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2015
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| US10053568B2 (en) | 2018-08-21 |
| RU2654696C2 (ru) | 2018-05-22 |
| KR101742453B1 (ko) | 2017-05-31 |
| CN106062014A (zh) | 2016-10-26 |
| KR20160120354A (ko) | 2016-10-17 |
| WO2015139875A1 (en) | 2015-09-24 |
| RU2016139260A (ru) | 2018-04-23 |
| US20170066912A1 (en) | 2017-03-09 |
| JP2018059116A (ja) | 2018-04-12 |
| JP2017514926A (ja) | 2017-06-08 |
| EP3119816A1 (en) | 2017-01-25 |
| PL3119816T3 (pl) | 2019-02-28 |
| EP3119816B1 (en) | 2018-09-12 |
| EP3119816B2 (en) | 2023-02-22 |
| BR112016019583A2 (enExample) | 2017-08-15 |
| ES2699641T5 (es) | 2023-06-07 |
| PL3119816T5 (pl) | 2023-05-15 |
| CN106062014B (zh) | 2018-03-30 |
| ES2699641T3 (es) | 2019-02-12 |
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