CN106062014B - 具有高熔点的异相丙烯共聚物 - Google Patents

具有高熔点的异相丙烯共聚物 Download PDF

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Publication number
CN106062014B
CN106062014B CN201580008051.1A CN201580008051A CN106062014B CN 106062014 B CN106062014 B CN 106062014B CN 201580008051 A CN201580008051 A CN 201580008051A CN 106062014 B CN106062014 B CN 106062014B
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propylene copolymer
raheco
heterophasic propylene
fraction
mrow
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Chinese (zh)
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CN106062014A (zh
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王静波
佩塔尔·多舍弗
马库斯·加莱特纳
乔安娜·利亚
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Borealis AS
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Borealis AS
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04Monomers containing three or four carbon atoms
    • C08F210/06Propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/16Ethene-propene or ethene-propene-diene copolymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04Monomers containing three or four carbon atoms
    • C08F10/06Propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/001Multistage polymerisation processes characterised by a change in reactor conditions without deactivating the intermediate polymer
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/34Polymerisation in gaseous state
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10Homopolymers or copolymers of propene
    • C08L23/12Polypropene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10Homopolymers or copolymers of propene
    • C08L23/14Copolymers of propene
    • C08L23/142Copolymers of propene at least partially crystalline copolymers of propene with other olefins
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00Properties characterising the ingredient of the composition
    • C08L2207/02Heterophasic composition
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2314/00Polymer mixtures characterised by way of preparation
    • C08L2314/06Metallocene or single site catalysts

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
CN201580008051.1A 2014-03-21 2015-02-03 具有高熔点的异相丙烯共聚物 Active CN106062014B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP14161005 2014-03-21
EP14161005.5 2014-03-21
PCT/EP2015/052198 WO2015139875A1 (en) 2014-03-21 2015-02-03 Heterophasic propylene copolymer with high melting point

Publications (2)

Publication Number Publication Date
CN106062014A CN106062014A (zh) 2016-10-26
CN106062014B true CN106062014B (zh) 2018-03-30

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ID=50336181

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Country Status (10)

Country Link
US (1) US10053568B2 (enExample)
EP (1) EP3119816B2 (enExample)
JP (2) JP2017514926A (enExample)
KR (1) KR101742453B1 (enExample)
CN (1) CN106062014B (enExample)
BR (1) BR112016019583B1 (enExample)
ES (1) ES2699641T5 (enExample)
PL (1) PL3119816T5 (enExample)
RU (1) RU2654696C2 (enExample)
WO (1) WO2015139875A1 (enExample)

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ES2767498T3 (es) * 2014-02-06 2020-06-17 Borealis Ag Copolímeros de impacto transparentes y suaves
US10100185B2 (en) 2014-02-06 2018-10-16 Borealis Ag Soft copolymers with high impact strength
BR112017016081B1 (pt) 2015-02-20 2022-05-03 Borealis Ag Copolímeros heterofásicos de propileno, seu processo para produção e tubo
ES3046758T3 (en) * 2016-06-28 2025-12-02 Borealis Gmbh Soft and transparent polypropylene composition
FI3601383T3 (fi) * 2017-03-27 2024-05-30 Basell Poliolefine Italia Srl Propyleenietyleenisatunnaiskopolymeeri
US11078304B2 (en) 2017-07-07 2021-08-03 Borealis Ag Process for preparing heterophasic propylene copolymers
PL3506323T3 (pl) * 2017-12-28 2023-10-09 Borealis Ag Zastosowanie płaszcza kabla
EP3740533B1 (en) * 2018-01-18 2022-08-17 Borealis AG Heterophasic polypropylene composition with high flexibility and softness
EP3856800A1 (en) * 2018-09-28 2021-08-04 Borealis AG Process for producing a prepolymerized solid ziegler-natta catalyst
ES2945963T3 (es) 2018-12-14 2023-07-11 Borealis Ag Composición de polipropileno con combinación favorable de óptica, suavidad y bajo sellado
EP3670547B1 (en) * 2018-12-21 2023-06-07 Borealis AG Polypropylene composition for film sealing layer
CN113924211B (zh) * 2019-06-05 2023-09-22 北欧化工公司 多层聚丙烯膜
EP3750927A1 (en) 2019-06-12 2020-12-16 Borealis AG Heterophasic propylene copolymer with improved mechanical properties
EP4103648A1 (en) * 2020-02-14 2022-12-21 SABIC Global Technologies B.V. Film comprising heterophasic propylene copolymer composition
US20240191015A1 (en) * 2021-03-24 2024-06-13 Borealis Ag Copolymer
US20240174774A1 (en) * 2021-03-24 2024-05-30 Borealis Ag Process for producing heterophasic propylene resin
WO2025117354A1 (en) * 2023-12-01 2025-06-05 ExxonMobil Technology and Engineering Company Methods for producing impact copolymers using c1 symmetric metallocene catalysts

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101090939A (zh) * 2005-01-14 2007-12-19 北方聚合物有限公司 多相聚合物组合物及其制备方法
WO2012016965A1 (en) * 2010-08-06 2012-02-09 Borealis Ag Heterophasic propylene copolymer with excellent impact/stiffness balance
EP2557118A1 (en) * 2011-08-09 2013-02-13 Borealis AG Preparation of a soft heterophasic propylene copolymer
CN103080210A (zh) * 2010-08-30 2013-05-01 博里利斯股份公司 具有高流动性和增强的机械性能的多相聚丙烯
CN103080212A (zh) * 2010-08-27 2013-05-01 北欧化工公司 具有出色的断裂伸长性的刚性聚丙烯组合物
CN105934476A (zh) * 2014-02-06 2016-09-07 北欧化工公司 软性透明的抗冲击共聚物

Family Cites Families (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FI86867C (fi) 1990-12-28 1992-10-26 Neste Oy Flerstegsprocess foer framstaellning av polyeten
FI111848B (fi) 1997-06-24 2003-09-30 Borealis Tech Oy Menetelmä ja laitteisto propeenin homo- ja kopolymeerien valmistamiseksi
FI980342A0 (fi) 1997-11-07 1998-02-13 Borealis As Polymerroer och -roerkopplingar
FI974175L (fi) 1997-11-07 1999-05-08 Borealis As Menetelmä polypropeenin valmistamiseksi
FI991057A0 (fi) 1999-05-07 1999-05-07 Borealis As Korkean jäykkyyden propeenipolymeerit ja menetelmä niiden valmistamiseksi
CN100349929C (zh) 2001-11-27 2007-11-21 巴塞尔聚烯烃意大利有限公司 透明和柔性的丙烯聚合物组合物
WO2004000899A1 (en) 2002-06-25 2003-12-31 Borealis Technology Oy Polyolefin with improved scratch resistance and process for producing the same
EP1484343A1 (en) 2003-06-06 2004-12-08 Universiteit Twente Process for the catalytic polymerization of olefins, a reactor system and its use in the same process
JP2007505175A (ja) 2003-09-11 2007-03-08 バセル ポリオレフィン ジーエムビーエイチ ヘテロ相プロピレンコポリマーを製造するための多段方法
WO2005052264A2 (en) 2003-11-21 2005-06-09 Gunderboom, Inc. Boom support arm and use thereof
EP2014714A1 (en) 2007-07-11 2009-01-14 Borealis Technology Oy Heterophasic polyolefin composition
ATE457323T1 (de) 2007-12-18 2010-02-15 Borealis Tech Oy Heterophasisches polypropylen mit hoher schlagfestigkeit
EP2147939A1 (en) 2008-07-22 2010-01-27 Borealis AG Polypropylene composition with improved optics for film and moulding applications
WO2010052263A1 (en) 2008-11-07 2010-05-14 Borealis Ag Solid catalyst composition
EP2355927B1 (en) 2008-11-07 2015-03-04 Borealis AG Solid catalyst composition
EP2361267B1 (en) 2008-11-07 2015-03-04 Borealis AG Process to prepare a solid catalyst composition
EP2264099A1 (en) 2009-05-21 2010-12-22 Basell Poliolefine Italia S.R.L. Propylene polymer compositions
KR101538910B1 (ko) 2009-05-21 2015-07-23 바셀 폴리올레핀 이탈리아 에스.알.엘 프로필렌 중합체 조성물
EP2316882A1 (en) * 2009-10-29 2011-05-04 Borealis AG Heterophasic polypropylene resin
EP2571933B1 (en) 2010-05-20 2016-11-02 Basell Poliolefine Italia S.r.l. Propylene polymer compositions
MX340414B (es) * 2010-09-30 2016-07-06 Dow Global Tech Llc * Composición polimérica y capa selladora con la misma.
ES2462165T3 (es) * 2011-05-23 2014-05-22 Borealis Ag Copolímero aleatorio de propileno con alta rigidez y baja turbidez
ES2643158T3 (es) 2011-07-08 2017-11-21 Borealis Ag Catalizadores
WO2013026745A1 (en) * 2011-08-19 2013-02-28 Borealis Ag Heterophasic system with improved surface properties
BR112016004329B1 (pt) 2013-09-26 2021-12-14 Blupura S.R.L. Combinação de dispensador e recipiente para uma pluralidade de recipientes com um sistema para o colocamento correto
EP3126411B1 (en) * 2014-04-04 2017-11-29 Borealis AG Heterophasic propylene copolymer with low extractables
WO2020239583A1 (en) 2019-05-29 2020-12-03 Borealis Ag C2c3 random copolymer

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101090939A (zh) * 2005-01-14 2007-12-19 北方聚合物有限公司 多相聚合物组合物及其制备方法
WO2012016965A1 (en) * 2010-08-06 2012-02-09 Borealis Ag Heterophasic propylene copolymer with excellent impact/stiffness balance
CN103080212A (zh) * 2010-08-27 2013-05-01 北欧化工公司 具有出色的断裂伸长性的刚性聚丙烯组合物
CN103080210A (zh) * 2010-08-30 2013-05-01 博里利斯股份公司 具有高流动性和增强的机械性能的多相聚丙烯
EP2557118A1 (en) * 2011-08-09 2013-02-13 Borealis AG Preparation of a soft heterophasic propylene copolymer
CN105934476A (zh) * 2014-02-06 2016-09-07 北欧化工公司 软性透明的抗冲击共聚物

Also Published As

Publication number Publication date
US10053568B2 (en) 2018-08-21
BR112016019583B1 (pt) 2022-03-29
RU2654696C2 (ru) 2018-05-22
KR101742453B1 (ko) 2017-05-31
CN106062014A (zh) 2016-10-26
KR20160120354A (ko) 2016-10-17
WO2015139875A1 (en) 2015-09-24
RU2016139260A (ru) 2018-04-23
US20170066912A1 (en) 2017-03-09
JP2018059116A (ja) 2018-04-12
JP2017514926A (ja) 2017-06-08
EP3119816A1 (en) 2017-01-25
PL3119816T3 (pl) 2019-02-28
EP3119816B1 (en) 2018-09-12
EP3119816B2 (en) 2023-02-22
BR112016019583A2 (enExample) 2017-08-15
ES2699641T5 (es) 2023-06-07
PL3119816T5 (pl) 2023-05-15
ES2699641T3 (es) 2019-02-12

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