BR112016006256A8 - “processos para produção de partículas de titânia e para preparação de um produto catalisador, e, partículas de titânia - Google Patents

“processos para produção de partículas de titânia e para preparação de um produto catalisador, e, partículas de titânia Download PDF

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Publication number
BR112016006256A8
BR112016006256A8 BR112016006256A BR112016006256A BR112016006256A8 BR 112016006256 A8 BR112016006256 A8 BR 112016006256A8 BR 112016006256 A BR112016006256 A BR 112016006256A BR 112016006256 A BR112016006256 A BR 112016006256A BR 112016006256 A8 BR112016006256 A8 BR 112016006256A8
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Brazil
Prior art keywords
titania
titania particles
controlled
titania sol
sol
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BR112016006256A
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English (en)
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BR112016006256A2 (pt
BR112016006256B1 (pt
Inventor
J Waters Darren
Lalande Edwards John
Robb John
Lowry Karl
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Huntsman P&A Uk Ltd
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Priority claimed from GB201316874A external-priority patent/GB201316874D0/en
Priority claimed from GB201415175A external-priority patent/GB201415175D0/en
Application filed by Huntsman P&A Uk Ltd filed Critical Huntsman P&A Uk Ltd
Publication of BR112016006256A2 publication Critical patent/BR112016006256A2/pt
Publication of BR112016006256A8 publication Critical patent/BR112016006256A8/pt
Publication of BR112016006256B1 publication Critical patent/BR112016006256B1/pt

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/063Titanium; Oxides or hydroxides thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48Silver or gold
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56Platinum group metals
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/20Catalysts, in general, characterised by their form or physical properties characterised by their non-solid state
    • B01J35/23Catalysts, in general, characterised by their form or physical properties characterised by their non-solid state in a colloidal state
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/40Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61Surface area
    • B01J35/61310-100 m2/g
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61Surface area
    • B01J35/615100-500 m2/g
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63Pore volume
    • B01J35/633Pore volume less than 0.5 ml/g
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64Pore diameter
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0027Powdering
    • B01J37/0045Drying a slurry, e.g. spray drying
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/03Precipitation; Co-precipitation
    • B01J37/031Precipitation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/03Precipitation; Co-precipitation
    • B01J37/036Precipitation; Co-precipitation to form a gel or a cogel
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/04Mixing
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01GCOMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G23/00Compounds of titanium
    • C01G23/04Oxides; Hydroxides
    • C01G23/047Titanium dioxide
    • C01G23/053Producing by wet processes, e.g. hydrolysing titanium salts
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01GCOMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G23/00Compounds of titanium
    • C01G23/04Oxides; Hydroxides
    • C01G23/047Titanium dioxide
    • C01G23/053Producing by wet processes, e.g. hydrolysing titanium salts
    • C01G23/0532Producing by wet processes, e.g. hydrolysing titanium salts by hydrolysing sulfate-containing salts
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01GCOMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G23/00Compounds of titanium
    • C01G23/04Oxides; Hydroxides
    • C01G23/047Titanium dioxide
    • C01G23/08Drying; Calcining ; After treatment of titanium oxide
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00Particle morphology
    • C01P2004/01Particle morphology depicted by an image
    • C01P2004/03Particle morphology depicted by an image obtained by SEM
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00Particle morphology
    • C01P2004/01Particle morphology depicted by an image
    • C01P2004/04Particle morphology depicted by an image obtained by TEM, STEM, STM or AFM
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00Particle morphology
    • C01P2004/60Particles characterised by their size
    • C01P2004/61Micrometer sized, i.e. from 1-100 micrometer
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
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    • C01P2006/12Surface area
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00Physical properties of inorganic compounds
    • C01P2006/16Pore diameter
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00Physical properties of inorganic compounds
    • C01P2006/21Attrition-index or crushing strength of granulates

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Environmental & Geological Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Inorganic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
  • Catalysts (AREA)
  • Treatment Of Water By Oxidation Or Reduction (AREA)

Abstract

a invenção provê um processo para a produção de partículas de titânia com uma morfologia desejada. o processo compreende prover um sol de titânia e então secar o sol para prover partículas de titânia secas. o processo é caracterizado em que a morfologia das partículas de titânia secas é controlada aplicando um ou mais dos critérios seguintes: (a) o sol de titânia é produzido a partir de uma pasta fluida contendo tio2 obtida usando uma etapa de precipitação em um processo sulfato, em que o tamanho de micelas formadas durante a precipitação é controlado; (b) o sol de titânia é produzido a partir de uma pasta fluida contendo tio2 e o ph da pasta fluida é controlado a fim de afetar a extensão em que o sol de titânia é floculado; (c) o sol de titânia é produzido a partir de uma pasta fluida contendo tio2 e o ponto isoelétrico da titânia é ajustado a fim de afetar a extensão em que o sol de titânia é floculado; (d) o sol de titânia é seco pela aplicação de calor e a temperatura usada durante a etapa de secagem é controlada.
BR112016006256-6A 2013-09-23 2014-09-22 Processo para produção de partículas de titânia e partículas de titânia BR112016006256B1 (pt)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
GB201316874A GB201316874D0 (en) 2013-09-23 2013-09-23 Titania particles and a process for their production
GB1316874.5 2013-09-23
GB1415175.7 2014-08-27
GB201415175A GB201415175D0 (en) 2014-08-27 2014-08-27 Titania particles and a process for their production
PCT/GB2014/052878 WO2015040426A1 (en) 2013-09-23 2014-09-22 Titania particles and a process for their production

Publications (3)

Publication Number Publication Date
BR112016006256A2 BR112016006256A2 (pt) 2017-08-01
BR112016006256A8 true BR112016006256A8 (pt) 2020-02-18
BR112016006256B1 BR112016006256B1 (pt) 2022-05-03

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BR122020005772-6A BR122020005772B1 (pt) 2013-09-23 2014-09-22 Processo para preparação de um produto catalisador e produto catalisador
BR112016006256-6A BR112016006256B1 (pt) 2013-09-23 2014-09-22 Processo para produção de partículas de titânia e partículas de titânia

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US (2) US10173198B2 (pt)
EP (1) EP3049371A1 (pt)
JP (1) JP6753781B2 (pt)
KR (1) KR102298817B1 (pt)
CN (2) CN109399703B (pt)
AU (2) AU2014322870A1 (pt)
BR (2) BR122020005772B1 (pt)
CA (1) CA2923123C (pt)
MX (2) MX2016003740A (pt)
MY (1) MY176021A (pt)
SA (1) SA516370782B1 (pt)
TW (1) TWI651269B (pt)
UA (1) UA119753C2 (pt)
WO (1) WO2015040426A1 (pt)

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BR112016006256A2 (pt) 2017-08-01
TWI651269B (zh) 2019-02-21
CA2923123C (en) 2023-08-22
CN105555713A (zh) 2016-05-04
MY176021A (en) 2020-07-21
CN109399703A (zh) 2019-03-01
AU2018202398A1 (en) 2018-04-26
WO2015040426A1 (en) 2015-03-26
BR112016006256B1 (pt) 2022-05-03
JP6753781B2 (ja) 2020-09-09
TW201520174A (zh) 2015-06-01
CA2923123A1 (en) 2015-03-26
MX2016003740A (es) 2016-05-31
US10717066B2 (en) 2020-07-21
MX2021011661A (es) 2022-04-28
US20160236174A1 (en) 2016-08-18
KR102298817B1 (ko) 2021-09-08
AU2018202398B2 (en) 2021-04-08
CN105555713B (zh) 2019-06-14
AU2014322870A1 (en) 2016-03-17
SA516370782B1 (ar) 2019-07-18
EP3049371A1 (en) 2016-08-03
BR122020005772B1 (pt) 2022-10-11
UA119753C2 (uk) 2019-08-12
KR20160062086A (ko) 2016-06-01
CN109399703B (zh) 2021-12-03
JP2016536266A (ja) 2016-11-24
US10173198B2 (en) 2019-01-08
US20190076821A1 (en) 2019-03-14

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