BR112016005534B1 - Pigmentos compósitos - Google Patents
Pigmentos compósitos Download PDFInfo
- Publication number
- BR112016005534B1 BR112016005534B1 BR112016005534-9A BR112016005534A BR112016005534B1 BR 112016005534 B1 BR112016005534 B1 BR 112016005534B1 BR 112016005534 A BR112016005534 A BR 112016005534A BR 112016005534 B1 BR112016005534 B1 BR 112016005534B1
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- Brazil
- Prior art keywords
- oxide
- component
- metal oxide
- composite pigment
- composite
- Prior art date
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- 239000002131 composite material Substances 0.000 title claims abstract description 116
- 239000000049 pigment Substances 0.000 title claims abstract description 92
- 239000000203 mixture Substances 0.000 claims abstract description 126
- 238000009472 formulation Methods 0.000 claims abstract description 111
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 82
- 229910044991 metal oxide Inorganic materials 0.000 claims abstract description 65
- 150000004706 metal oxides Chemical class 0.000 claims abstract description 65
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 43
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims abstract description 16
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 94
- 239000011787 zinc oxide Substances 0.000 claims description 49
- 239000003973 paint Substances 0.000 claims description 42
- 239000002245 particle Substances 0.000 claims description 40
- QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Chemical compound [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 claims description 16
- 238000000034 method Methods 0.000 claims description 13
- 229910052725 zinc Inorganic materials 0.000 claims description 11
- 239000011701 zinc Substances 0.000 claims description 11
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 10
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims description 10
- 229910001928 zirconium oxide Inorganic materials 0.000 claims description 10
- 229910000410 antimony oxide Inorganic materials 0.000 claims description 9
- 230000001965 increasing effect Effects 0.000 claims description 9
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical compound [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 claims description 9
- 239000011258 core-shell material Substances 0.000 claims description 8
- 239000000395 magnesium oxide Substances 0.000 claims description 8
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 8
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims description 8
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 8
- 239000002073 nanorod Substances 0.000 claims description 5
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract description 26
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 abstract description 11
- 239000002184 metal Substances 0.000 abstract description 11
- 229910052726 zirconium Inorganic materials 0.000 abstract description 11
- 229910052751 metal Inorganic materials 0.000 abstract description 9
- 229910052914 metal silicate Inorganic materials 0.000 abstract description 4
- 239000000976 ink Substances 0.000 description 83
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 59
- 239000004408 titanium dioxide Substances 0.000 description 28
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 21
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 21
- 239000011541 reaction mixture Substances 0.000 description 15
- 238000000576 coating method Methods 0.000 description 11
- 238000002441 X-ray diffraction Methods 0.000 description 10
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 10
- 239000011248 coating agent Substances 0.000 description 9
- 239000000463 material Substances 0.000 description 9
- 238000006243 chemical reaction Methods 0.000 description 8
- 239000000843 powder Substances 0.000 description 8
- 238000003917 TEM image Methods 0.000 description 7
- 238000001035 drying Methods 0.000 description 7
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 6
- 238000003860 storage Methods 0.000 description 6
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 5
- 239000002086 nanomaterial Substances 0.000 description 5
- 235000012239 silicon dioxide Nutrition 0.000 description 5
- 239000007787 solid Substances 0.000 description 5
- 239000011592 zinc chloride Substances 0.000 description 5
- 235000005074 zinc chloride Nutrition 0.000 description 5
- XIOUDVJTOYVRTB-UHFFFAOYSA-N 1-(1-adamantyl)-3-aminothiourea Chemical compound C1C(C2)CC3CC2CC1(NC(=S)NN)C3 XIOUDVJTOYVRTB-UHFFFAOYSA-N 0.000 description 4
- 238000005054 agglomeration Methods 0.000 description 4
- 230000002776 aggregation Effects 0.000 description 4
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 4
- 230000000845 anti-microbial effect Effects 0.000 description 4
- 239000002585 base Substances 0.000 description 4
- 239000002243 precursor Substances 0.000 description 4
- 230000009467 reduction Effects 0.000 description 4
- 125000006850 spacer group Chemical group 0.000 description 4
- 239000004094 surface-active agent Substances 0.000 description 4
- 229960000583 acetic acid Drugs 0.000 description 3
- 229910052681 coesite Inorganic materials 0.000 description 3
- 229910052906 cristobalite Inorganic materials 0.000 description 3
- 239000002270 dispersing agent Substances 0.000 description 3
- 239000012362 glacial acetic acid Substances 0.000 description 3
- 230000000670 limiting effect Effects 0.000 description 3
- 229910052682 stishovite Inorganic materials 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 229910052905 tridymite Inorganic materials 0.000 description 3
- 150000003751 zinc Chemical class 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 239000004115 Sodium Silicate Substances 0.000 description 2
- 238000005299 abrasion Methods 0.000 description 2
- ZOIORXHNWRGPMV-UHFFFAOYSA-N acetic acid;zinc Chemical compound [Zn].CC(O)=O.CC(O)=O ZOIORXHNWRGPMV-UHFFFAOYSA-N 0.000 description 2
- 230000006978 adaptation Effects 0.000 description 2
- JGDITNMASUZKPW-UHFFFAOYSA-K aluminium trichloride hexahydrate Chemical compound O.O.O.O.O.O.Cl[Al](Cl)Cl JGDITNMASUZKPW-UHFFFAOYSA-K 0.000 description 2
- 229940063656 aluminum chloride Drugs 0.000 description 2
- 229940009861 aluminum chloride hexahydrate Drugs 0.000 description 2
- 230000000844 anti-bacterial effect Effects 0.000 description 2
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 2
- 239000000920 calcium hydroxide Substances 0.000 description 2
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 2
- 239000008119 colloidal silica Substances 0.000 description 2
- 229910052593 corundum Inorganic materials 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 230000002708 enhancing effect Effects 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 230000006870 function Effects 0.000 description 2
- 238000011065 in-situ storage Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 239000003607 modifier Substances 0.000 description 2
- 229920000620 organic polymer Polymers 0.000 description 2
- 230000036961 partial effect Effects 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 230000002829 reductive effect Effects 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 229910052911 sodium silicate Inorganic materials 0.000 description 2
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000000454 talc Substances 0.000 description 2
- 229910052623 talc Inorganic materials 0.000 description 2
- 229910001845 yogo sapphire Inorganic materials 0.000 description 2
- 239000004246 zinc acetate Substances 0.000 description 2
- ONDPHDOFVYQSGI-UHFFFAOYSA-N zinc nitrate Chemical compound [Zn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ONDPHDOFVYQSGI-UHFFFAOYSA-N 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- 241000195493 Cryptophyta Species 0.000 description 1
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 description 1
- 230000006750 UV protection Effects 0.000 description 1
- 239000005083 Zinc sulfide Substances 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 229920000180 alkyd Polymers 0.000 description 1
- ANBBXQWFNXMHLD-UHFFFAOYSA-N aluminum;sodium;oxygen(2-) Chemical compound [O-2].[O-2].[Na+].[Al+3] ANBBXQWFNXMHLD-UHFFFAOYSA-N 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 229910021486 amorphous silicon dioxide Inorganic materials 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 230000000843 anti-fungal effect Effects 0.000 description 1
- 229940121375 antifungal agent Drugs 0.000 description 1
- 239000004599 antimicrobial Substances 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 230000002860 competitive effect Effects 0.000 description 1
- 239000011246 composite particle Substances 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000000706 filtrate Substances 0.000 description 1
- 239000012847 fine chemical Substances 0.000 description 1
- 239000011796 hollow space material Substances 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 230000002452 interceptive effect Effects 0.000 description 1
- 230000002427 irreversible effect Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 description 1
- 230000001699 photocatalysis Effects 0.000 description 1
- 238000007146 photocatalysis Methods 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 230000000750 progressive effect Effects 0.000 description 1
- 230000035755 proliferation Effects 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000013040 rubber vulcanization Methods 0.000 description 1
- 238000004626 scanning electron microscopy Methods 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 229910001388 sodium aluminate Inorganic materials 0.000 description 1
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 1
- 229910001948 sodium oxide Inorganic materials 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 239000012798 spherical particle Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- -1 whitewash Substances 0.000 description 1
- 238000004383 yellowing Methods 0.000 description 1
- 229910021511 zinc hydroxide Inorganic materials 0.000 description 1
- 229910052984 zinc sulfide Inorganic materials 0.000 description 1
- DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 description 1
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- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
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- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/0015—Pigments exhibiting interference colours, e.g. transparent platelets of appropriate thinness or flaky substrates, e.g. mica, bearing appropriate thin transparent coatings
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- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
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- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/0081—Composite particulate pigments or fillers, i.e. containing at least two solid phases, except those consisting of coated particles of one compound
- C09C1/0084—Composite particulate pigments or fillers, i.e. containing at least two solid phases, except those consisting of coated particles of one compound containing titanium dioxide
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- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
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- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
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- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
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- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/80—Particles consisting of a mixture of two or more inorganic phases
- C01P2004/82—Particles consisting of a mixture of two or more inorganic phases two phases having the same anion, e.g. both oxidic phases
- C01P2004/84—Particles consisting of a mixture of two or more inorganic phases two phases having the same anion, e.g. both oxidic phases one phase coated with the other
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/12—Surface area
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2227—Oxides; Hydroxides of metals of aluminium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2244—Oxides; Hydroxides of metals of zirconium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Composite Materials (AREA)
- Nanotechnology (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Paints Or Removers (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Silicon Compounds (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB1316316.7 | 2013-09-13 | ||
| GB1316316.7A GB2518202B (en) | 2013-09-13 | 2013-09-13 | Composite pigments |
| PCT/SG2014/000432 WO2015038073A1 (en) | 2013-09-13 | 2014-09-12 | Composite pigments |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| BR112016005534A2 BR112016005534A2 (enExample) | 2017-08-01 |
| BR112016005534A8 BR112016005534A8 (pt) | 2020-06-30 |
| BR112016005534B1 true BR112016005534B1 (pt) | 2022-02-01 |
Family
ID=49552616
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BR112016005534-9A BR112016005534B1 (pt) | 2013-09-13 | 2014-09-12 | Pigmentos compósitos |
Country Status (21)
| Country | Link |
|---|---|
| US (2) | US10899931B2 (enExample) |
| EP (1) | EP3044256A4 (enExample) |
| JP (3) | JP2016534212A (enExample) |
| KR (1) | KR102128644B1 (enExample) |
| CN (1) | CN105722903B (enExample) |
| AP (1) | AP2016009138A0 (enExample) |
| AU (2) | AU2014319022A1 (enExample) |
| BR (1) | BR112016005534B1 (enExample) |
| CA (1) | CA2924226C (enExample) |
| CL (1) | CL2016000563A1 (enExample) |
| EA (1) | EA039844B1 (enExample) |
| GB (1) | GB2518202B (enExample) |
| IL (1) | IL244558B (enExample) |
| MX (1) | MX2016003275A (enExample) |
| MY (1) | MY172528A (enExample) |
| NZ (1) | NZ718968A (enExample) |
| PH (1) | PH12016500483A1 (enExample) |
| SA (1) | SA516370723B1 (enExample) |
| SG (1) | SG11201601677QA (enExample) |
| WO (1) | WO2015038073A1 (enExample) |
| ZA (1) | ZA201602475B (enExample) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| MX2018004045A (es) * | 2015-10-05 | 2018-08-01 | M Technique Co Ltd | Particulas de oxido de metal y metodo para producir las mismas. |
| CA3016184C (en) | 2016-03-16 | 2020-12-01 | The Sherwin-Williams Company | Opacifying clusters for use in paint compositions |
| KR102431889B1 (ko) | 2016-10-24 | 2022-08-11 | 이시하라 산교 가부시끼가이샤 | 복합 안료 및 이의 제조 방법, 복합 안료를 함유하는 페인트 조성물, 및 코팅 필름 |
| WO2025178005A1 (ja) * | 2024-02-22 | 2025-08-28 | 株式会社日本触媒 | 無機粒子含有組成物 |
Family Cites Families (36)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2882178A (en) * | 1958-01-16 | 1959-04-14 | Nat Lead Co | Composite antimony oxide-silica pigment and process of manufacture |
| GB1532521A (en) * | 1976-04-02 | 1978-11-15 | Laporte Au Ltd | Pigments |
| JPS63199275A (ja) * | 1987-02-13 | 1988-08-17 | Ube Ind Ltd | 油彩画用白系絵具 |
| US5203916A (en) * | 1992-04-10 | 1993-04-20 | Kerr-Mcgee Chemical Corporation | Titanium dioxide pigment and method of preparation |
| US5389140A (en) * | 1992-10-30 | 1995-02-14 | Kansai Paint Co., Ltd. | Electrodeposition paint composition |
| JPH07328421A (ja) * | 1994-06-06 | 1995-12-19 | Nippon Shokubai Co Ltd | 無機化合物微粒子、その製造方法およびその用途 |
| US6200680B1 (en) * | 1994-06-06 | 2001-03-13 | Nippon Shokubai Co., Ltd. | Fine zinc oxide particles, process for producing the same, and use thereof |
| JP3010247B2 (ja) * | 1994-06-10 | 2000-02-21 | 工業技術院長 | 板状アルミナ顔料及びその製造方法 |
| EP0988853B1 (en) | 1997-04-18 | 2012-10-24 | Showa Denko K.K. | Cosmetic preparation, silica-coated metal oxide powder, and process for producing the same |
| JP2002121494A (ja) * | 2000-10-19 | 2002-04-23 | Nippon Paint Co Ltd | 光輝性塗料組成物、塗膜形成方法および塗装物 |
| JP2002192067A (ja) * | 2000-12-28 | 2002-07-10 | Nippon Paint Co Ltd | 光輝性塗膜形成方法および塗装物 |
| JP2003055573A (ja) * | 2001-08-14 | 2003-02-26 | Nippon Shikizai Inc | 積層型干渉性球状顔料及びそれを配合した化粧料 |
| JP3986304B2 (ja) * | 2001-12-06 | 2007-10-03 | 株式会社日本色材工業研究所 | 積層型干渉性紫外線遮蔽顔料及びそれを配合した化粧料 |
| WO2003104319A1 (en) | 2002-06-05 | 2003-12-18 | Showa Denko K. K. | Powder comprising silica-coated zinc oxide, organic polymer composition containing the powder and shaped article thereof |
| DE10259246A1 (de) * | 2002-12-17 | 2004-07-01 | Merck Patent Gmbh | Anorganische sphärische Absorptionspigmente |
| US6866711B2 (en) * | 2003-01-17 | 2005-03-15 | Fitzgerald Alphanso Sinclair | Composite pigment composition containing silica |
| JP2005199261A (ja) * | 2003-12-17 | 2005-07-28 | Fujikura Kasei Co Ltd | 光触媒複合材料、光触媒含有塗料組成物、セルフクリーニング性塗膜 |
| US7498081B2 (en) * | 2005-03-02 | 2009-03-03 | Thw Shwphwed Color Company | Core-shell composite inorganic pigments and method of preparation for crystallizable glass frit compositions |
| JP2007261082A (ja) | 2006-03-28 | 2007-10-11 | Matsushita Electric Works Ltd | 低減視化被膜形成品 |
| DE102006038518A1 (de) * | 2006-08-17 | 2008-02-21 | Evonik Degussa Gmbh | Umhüllte Zinkoxidpartikel |
| KR101455419B1 (ko) * | 2006-10-06 | 2014-10-28 | 사까이가가꾸고오교가부시끼가이샤 | 초미립자 산화아연 및 그의 제조 방법 |
| TW200846027A (en) * | 2006-12-20 | 2008-12-01 | Avon Prod Inc | Nanocomposite pigments in a topical cosmetic application |
| JP5547526B2 (ja) * | 2009-05-19 | 2014-07-16 | 関西ペイント株式会社 | 塗料組成物、塗膜形成方法および塗膜構造 |
| EP2445974A1 (de) * | 2009-06-24 | 2012-05-02 | Basf Se | Modifizierte zno-nanopartikel |
| BR112012002335A2 (pt) * | 2009-08-04 | 2016-05-31 | Oreal | pigmento composto e método para preparação do mesmo |
| JP5455501B2 (ja) * | 2009-08-07 | 2014-03-26 | 日揮触媒化成株式会社 | コアシェル型複合酸化物微粒子の分散液および該分散液の製造方法、該コアシェル型複合酸化物微粒子を含む塗料組成物、硬化性塗膜および硬化性塗膜付き基材 |
| DE102009051171A1 (de) | 2009-10-29 | 2011-05-05 | Merck Patent Gmbh | Pigmente |
| CN101880501B (zh) * | 2010-07-09 | 2012-04-18 | 重庆航利实业有限责任公司 | 纳米ZnO/SiO2溶胶改性硅丙外墙自洁型隔热涂料 |
| JP2012021089A (ja) * | 2010-07-15 | 2012-02-02 | Kansai Paint Co Ltd | 塗料組成物及び塗膜形成方法 |
| JP5713668B2 (ja) | 2010-12-28 | 2015-05-07 | 日揮触媒化成株式会社 | ハードコート層膜形成用塗料組成物 |
| JP5642535B2 (ja) | 2010-12-28 | 2014-12-17 | 日揮触媒化成株式会社 | 新規シリカ系中空微粒子、透明被膜付基材および透明被膜形成用塗料 |
| EP2872106B2 (en) * | 2012-07-13 | 2023-08-02 | L'oreal | Composite pigment and method for preparing the same |
| JP6016548B2 (ja) | 2012-09-19 | 2016-10-26 | 日揮触媒化成株式会社 | 透明被膜形成用塗布液および透明被膜付基材 |
| US20140256849A1 (en) * | 2013-03-11 | 2014-09-11 | Ppg Industries Ohio, Inc. | Silicate enclosed pigment particles |
| CN103242821B (zh) * | 2013-05-21 | 2014-12-24 | 中国科学院上海硅酸盐研究所 | 一种核壳结构的热致变色复合粉体及其制备方法 |
| CN103436111B (zh) * | 2013-07-29 | 2017-11-10 | 复旦大学 | 一种基于ZnO量子点的水性紫外屏蔽涂料的制备方法 |
-
2013
- 2013-09-13 GB GB1316316.7A patent/GB2518202B/en not_active Expired - Fee Related
-
2014
- 2014-09-12 NZ NZ718968A patent/NZ718968A/en not_active IP Right Cessation
- 2014-09-12 AU AU2014319022A patent/AU2014319022A1/en not_active Abandoned
- 2014-09-12 MY MYPI2016000461A patent/MY172528A/en unknown
- 2014-09-12 CN CN201480049554.9A patent/CN105722903B/zh not_active Expired - Fee Related
- 2014-09-12 MX MX2016003275A patent/MX2016003275A/es unknown
- 2014-09-12 US US15/021,558 patent/US10899931B2/en not_active Expired - Fee Related
- 2014-09-12 SG SG11201601677QA patent/SG11201601677QA/en unknown
- 2014-09-12 BR BR112016005534-9A patent/BR112016005534B1/pt not_active IP Right Cessation
- 2014-09-12 CA CA2924226A patent/CA2924226C/en active Active
- 2014-09-12 EA EA201690586A patent/EA039844B1/ru unknown
- 2014-09-12 EP EP14844848.3A patent/EP3044256A4/en not_active Withdrawn
- 2014-09-12 WO PCT/SG2014/000432 patent/WO2015038073A1/en not_active Ceased
- 2014-09-12 KR KR1020167009703A patent/KR102128644B1/ko not_active Expired - Fee Related
- 2014-09-12 AP AP2016009138A patent/AP2016009138A0/en unknown
- 2014-09-12 JP JP2016541937A patent/JP2016534212A/ja active Pending
-
2016
- 2016-03-10 CL CL2016000563A patent/CL2016000563A1/es unknown
- 2016-03-11 PH PH12016500483A patent/PH12016500483A1/en unknown
- 2016-03-12 SA SA516370723A patent/SA516370723B1/ar unknown
- 2016-03-13 IL IL244558A patent/IL244558B/en active IP Right Grant
- 2016-04-12 ZA ZA2016/02475A patent/ZA201602475B/en unknown
-
2018
- 2018-02-20 AU AU2018201207A patent/AU2018201207B2/en not_active Ceased
- 2018-12-06 JP JP2018228795A patent/JP2019077874A/ja active Pending
-
2020
- 2020-12-31 US US17/139,532 patent/US20210163753A1/en not_active Abandoned
-
2022
- 2022-05-02 JP JP2022075955A patent/JP2022110022A/ja active Pending
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