BR112015030698A2 - processo para produção de álcoois graxos a partir do éster de metila de ácido graxo - Google Patents
processo para produção de álcoois graxos a partir do éster de metila de ácido graxoInfo
- Publication number
- BR112015030698A2 BR112015030698A2 BR112015030698A BR112015030698A BR112015030698A2 BR 112015030698 A2 BR112015030698 A2 BR 112015030698A2 BR 112015030698 A BR112015030698 A BR 112015030698A BR 112015030698 A BR112015030698 A BR 112015030698A BR 112015030698 A2 BR112015030698 A2 BR 112015030698A2
- Authority
- BR
- Brazil
- Prior art keywords
- acid methyl
- methyl ester
- fatty
- fatty acid
- production
- Prior art date
Links
- 150000002191 fatty alcohols Chemical class 0.000 title abstract 4
- 235000019387 fatty acid methyl ester Nutrition 0.000 title abstract 3
- 238000000034 method Methods 0.000 title abstract 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 abstract 6
- 239000004164 Wax ester Substances 0.000 abstract 2
- 238000005984 hydrogenation reaction Methods 0.000 abstract 2
- 235000019386 wax ester Nutrition 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 1
- 238000009903 catalytic hydrogenation reaction Methods 0.000 abstract 1
- GDVKFRBCXAPAQJ-UHFFFAOYSA-A dialuminum;hexamagnesium;carbonate;hexadecahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Al+3].[Al+3].[O-]C([O-])=O GDVKFRBCXAPAQJ-UHFFFAOYSA-A 0.000 abstract 1
- 229960001545 hydrotalcite Drugs 0.000 abstract 1
- 229910001701 hydrotalcite Inorganic materials 0.000 abstract 1
- 239000000395 magnesium oxide Substances 0.000 abstract 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 abstract 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 abstract 1
- 238000000926 separation method Methods 0.000 abstract 1
- 238000005809 transesterification reaction Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
- C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
- C07C29/147—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof
- C07C29/149—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof with hydrogen or hydrogen-containing gases
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/10—Magnesium; Oxides or hydroxides thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/128—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by alcoholysis
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/74—Separation; Purification; Use of additives, e.g. for stabilisation
- C07C29/76—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment
- C07C29/80—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment by distillation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/74—Separation; Purification; Use of additives, e.g. for stabilisation
- C07C29/88—Separation; Purification; Use of additives, e.g. for stabilisation by treatment giving rise to a chemical modification of at least one compound
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/03—Preparation of carboxylic acid esters by reacting an ester group with a hydroxy group
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/48—Separation; Purification; Stabilisation; Use of additives
- C07C67/52—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/48—Separation; Purification; Stabilisation; Use of additives
- C07C67/52—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation
- C07C67/54—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation by distillation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
- C07C31/02—Monohydroxylic acyclic alcohols
- C07C31/125—Monohydroxylic acyclic alcohols containing five to twenty-two carbon atoms
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
resumo patente de invenção: "processo para produção de álcoois graxos a partir do éster de metila de ácido graxo". a presente invenção refere-se à matéria objetivo da invenção que é um processo para produção de álcoois graxos por meio de hidrogenação catalítica de éster de metila de ácido graxo (fame), em que o fame inicialmente é hidrogenado para álcool graxo (fa). as frações restantes do fame não convertido no produto da hidrogenação são convertidas em éster de cera e metanol em uma etapa de transesterificação sucedendo com fa. de acordo com a invenção, os catalisadores na base óxido de magnésio ou hidrotalcita são empregados. após a separação do metanol e o fa como produto alvo, uma corrente enriquecida em éster de cera é recirculada no reator de hidrogenação.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102013106382.9A DE102013106382A1 (de) | 2013-06-19 | 2013-06-19 | Verfahren zum Herstellen von Fettalkoholen aus Fettsäuremethylester |
DE102013106382.9 | 2013-06-19 | ||
PCT/EP2014/062712 WO2014202601A1 (en) | 2013-06-19 | 2014-06-17 | Process for producing fatty alcohols from fatty acid methyl ester |
Publications (2)
Publication Number | Publication Date |
---|---|
BR112015030698A2 true BR112015030698A2 (pt) | 2017-07-25 |
BR112015030698B1 BR112015030698B1 (pt) | 2020-12-15 |
Family
ID=51022302
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BR112015030698-5A BR112015030698B1 (pt) | 2013-06-19 | 2014-06-17 | Processo para produção de álcoois graxos a partir do éster de metila de ácido graxo |
Country Status (9)
Country | Link |
---|---|
US (1) | US9353036B1 (pt) |
EP (1) | EP3010876B1 (pt) |
CN (1) | CN105492414B (pt) |
BR (1) | BR112015030698B1 (pt) |
DE (1) | DE102013106382A1 (pt) |
ES (1) | ES2693372T3 (pt) |
MY (1) | MY179992A (pt) |
PL (1) | PL3010876T3 (pt) |
WO (1) | WO2014202601A1 (pt) |
Family Cites Families (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2425001A (en) | 1943-10-11 | 1947-08-05 | Minnesota Linseed Oil Paint Co | Winterizing vegetable oils |
IT1190783B (it) | 1981-04-29 | 1988-02-24 | Davy Mckee Oil & Chem | Processo per l'idrogenolisi di esteri di acidi carbossilici |
GB8900993D0 (en) | 1989-01-17 | 1989-03-08 | Davy Mckee London | Process |
AU641630B2 (en) | 1989-01-17 | 1993-09-30 | Davy Mckee (London) Limited | Process for the production of fatty alcohols |
JPH0344354A (ja) | 1989-07-11 | 1991-02-26 | Daicel Chem Ind Ltd | ジアルキルカーボネートの製造方法 |
JPH06107601A (ja) | 1992-09-30 | 1994-04-19 | Nippon Shokubai Co Ltd | ジアルキルカーボネートの製造方法 |
JP2003081893A (ja) | 2001-09-10 | 2003-03-19 | Mitsui Chemicals Inc | ジアルキルカーボネートとグリコールの連続的同時製造方法 |
ITMI20042163A1 (it) | 2004-11-11 | 2005-02-11 | Aser S R L | Processo per la produzione di esteri da oli vegetali o grassi animali con l'impiego di catalizzatori eterogenei |
AT502218B1 (de) * | 2005-07-25 | 2010-09-15 | Bdi Biodiesel Internat Ag | Verfahren zur herstellung von carbonsäurealkylestern |
DE102007033636A1 (de) | 2007-07-19 | 2009-01-22 | Cognis Ip Management Gmbh | Reinigung von Fettalkoholen |
US7815694B2 (en) | 2007-09-27 | 2010-10-19 | Chevron U.S.A. Inc. | Production of biofuels and biolubricants from a common feedstock |
DE102007061872A1 (de) * | 2007-12-19 | 2009-06-25 | Bayer Technology Services Gmbh | Verfahren zur Herstellung von Fettsäurealkylestern |
US8507702B2 (en) * | 2011-03-29 | 2013-08-13 | Southwest Research Institute | Continuous production of bioderived esters via supercritical solvent processing using solid heterogeneous catalysts |
GB201119871D0 (en) * | 2011-11-17 | 2011-12-28 | Davy Process Techn Ltd | Process |
-
2013
- 2013-06-19 DE DE102013106382.9A patent/DE102013106382A1/de not_active Ceased
-
2014
- 2014-06-17 CN CN201480034961.2A patent/CN105492414B/zh active Active
- 2014-06-17 MY MYPI2015704363A patent/MY179992A/en unknown
- 2014-06-17 PL PL14733117T patent/PL3010876T3/pl unknown
- 2014-06-17 WO PCT/EP2014/062712 patent/WO2014202601A1/en active Application Filing
- 2014-06-17 EP EP14733117.7A patent/EP3010876B1/en not_active Revoked
- 2014-06-17 US US14/898,613 patent/US9353036B1/en active Active
- 2014-06-17 BR BR112015030698-5A patent/BR112015030698B1/pt not_active IP Right Cessation
- 2014-06-17 ES ES14733117.7T patent/ES2693372T3/es active Active
Also Published As
Publication number | Publication date |
---|---|
EP3010876B1 (en) | 2018-08-08 |
CN105492414B (zh) | 2017-09-15 |
WO2014202601A1 (en) | 2014-12-24 |
PL3010876T3 (pl) | 2019-01-31 |
ES2693372T3 (es) | 2018-12-11 |
BR112015030698B1 (pt) | 2020-12-15 |
CN105492414A (zh) | 2016-04-13 |
DE102013106382A1 (de) | 2014-12-24 |
US9353036B1 (en) | 2016-05-31 |
MY179992A (en) | 2020-11-19 |
US20160137568A1 (en) | 2016-05-19 |
EP3010876A1 (en) | 2016-04-27 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
B06F | Objections, documents and/or translations needed after an examination request according [chapter 6.6 patent gazette] | ||
B06U | Preliminary requirement: requests with searches performed by other patent offices: procedure suspended [chapter 6.21 patent gazette] | ||
B06A | Patent application procedure suspended [chapter 6.1 patent gazette] | ||
B09A | Decision: intention to grant [chapter 9.1 patent gazette] | ||
B16A | Patent or certificate of addition of invention granted [chapter 16.1 patent gazette] |
Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 17/06/2014, OBSERVADAS AS CONDICOES LEGAIS. |
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B21F | Lapse acc. art. 78, item iv - on non-payment of the annual fees in time |
Free format text: REFERENTE A 10A ANUIDADE. |