BR112014014855B1 - Processo de polimerização em solução para formar um interpolímero de etileno/aolefina/polieno não conjugado - Google Patents
Processo de polimerização em solução para formar um interpolímero de etileno/aolefina/polieno não conjugado Download PDFInfo
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- BR112014014855B1 BR112014014855B1 BR112014014855-4A BR112014014855A BR112014014855B1 BR 112014014855 B1 BR112014014855 B1 BR 112014014855B1 BR 112014014855 A BR112014014855 A BR 112014014855A BR 112014014855 B1 BR112014014855 B1 BR 112014014855B1
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Images
Classifications
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- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
- C08F210/18—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers with non-conjugated dienes, e.g. EPT rubbers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
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- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
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| PCT/US2012/070859 WO2013096573A1 (en) | 2011-12-20 | 2012-12-20 | Ethylene/alpha-olefin/nonconjugated polyene interpolymers and processes to form the same |
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| BR112014014855A2 BR112014014855A2 (pt) | 2017-06-13 |
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| JP5946331B2 (ja) * | 2012-06-01 | 2016-07-06 | 三井化学株式会社 | エチレン・α−オレフィン非共役ポリエン共重合体ゴムペレット |
| JP6320407B2 (ja) * | 2012-11-30 | 2018-05-09 | ダウ グローバル テクノロジーズ エルエルシー | エチレン／αオレフィン／ポリエン系組成物 |
| EP2938643B1 (en) * | 2012-12-27 | 2018-01-31 | Dow Global Technologies LLC | Catalyst systems for olefin polymerization |
| RU2643149C2 (ru) | 2013-01-18 | 2018-01-31 | ДАУ ГЛОБАЛ ТЕКНОЛОДЖИЗ ЭлЭлСи | Способы полимеризации для высокомолекулярных полиолефинов |
| EP3738927A1 (en) | 2014-05-31 | 2020-11-18 | Bridgestone Corporation | Metallic complex catalyst, polymerization methods employing same and polymer products thereof |
| WO2016089935A1 (en) * | 2014-12-04 | 2016-06-09 | Dow Global Technologies Llc | Five-coordinate bis-phenylphenoxy catalysts for the preparation of ethylene-based polymers |
| MY184826A (en) | 2014-12-04 | 2021-04-24 | Dow Technology Investments Llc | Hydroformylation process |
| SG11201705239SA (en) | 2014-12-29 | 2017-07-28 | Dow Global Technologies Llc | Process to form ethylene/alpha-olefin interpolymers |
| KR102439497B1 (ko) | 2014-12-29 | 2022-09-05 | 다우 글로벌 테크놀로지스 엘엘씨 | 오일 함유 에틸렌계 폴리머의 형성 방법 |
| CN107428878B (zh) * | 2015-03-31 | 2020-08-28 | 陶氏环球技术有限责任公司 | 用于制备具有低含量长链支化的高分子量乙烯/α-烯烃/非共轭互聚物的方法 |
| EP3303427B1 (en) * | 2015-05-28 | 2023-11-29 | Dow Global Technologies LLC | Process to form ethylene/alpha-olefin/diene interpolymers |
| MX2018002459A (es) * | 2015-09-02 | 2018-06-15 | Dow Global Technologies Llc | Aislamiento de cable reticulado flexible y metodos para hacer el aislamiento de cable reticulado flexible. |
| WO2017040088A1 (en) * | 2015-09-02 | 2017-03-09 | Dow Global Technologies Llc | Flexible crosslinked cable insulation and methods for making flexible crosslinked cable insulation |
| EP3368602B1 (en) | 2015-10-29 | 2020-07-08 | Dow Global Technologies, LLC | Crosslinkable polymeric compositions for flexible crosslinked cable insulation and methods for making flexible crosslinked cable insulation |
| WO2017206008A1 (en) | 2016-05-30 | 2017-12-07 | Dow Global Technologies Llc | Ethylene/alpha-olefin/diene interpolymer |
| WO2017206009A1 (en) | 2016-05-30 | 2017-12-07 | Dow Global Technologies Llc | Ethylene/alpha-olefin/diene interpolymers compositions |
| CN109601004B (zh) * | 2016-06-30 | 2022-08-09 | 陶氏环球技术有限责任公司 | 乙烯/α-烯烃/多烯互聚物以及含有其的组合物 |
| KR102396055B1 (ko) * | 2016-06-30 | 2022-05-11 | 다우 글로벌 테크놀로지스 엘엘씨 | 에틸렌/알파-올레핀/폴리엔계 조성물 |
| US11352451B2 (en) | 2016-07-13 | 2022-06-07 | Exxonmobil Chemical Patents Inc. | Dual metallocene catalyst copolymer compositions |
| US10808049B2 (en) | 2016-07-13 | 2020-10-20 | Exxonmobil Chemical Patents Inc. | Dual metallocene catalyst copolymer compositions |
| JP6850862B2 (ja) | 2016-07-14 | 2021-03-31 | エクソンモービル・ケミカル・パテンツ・インク | 粘度調整剤として有用な、２元メタロセン触媒で重合されたバイモーダルのコポリマー組成物 |
| BR112019001249B1 (pt) * | 2016-07-29 | 2022-10-18 | Dow Global Technologies Llc | Elastômero multimodal, olefina termoplástica e método para produzir um elastômero multimodal |
| WO2018022279A1 (en) | 2016-07-29 | 2018-02-01 | Exxonmobil Chemical Patents Inc. | Phenolate transition metal complexes, production and use thereof |
| US10221260B2 (en) | 2016-07-29 | 2019-03-05 | Exxonmobil Chemical Patents Inc. | Phenolate transition metal complexes, production and use thereof |
| KR102653792B1 (ko) * | 2016-12-26 | 2024-04-03 | 다우 글로벌 테크놀로지스 엘엘씨 | 에틸렌/α-올레핀/비공액 폴리엔 혼성 중합체 조성물 및 이로부터 제조된 물품 |
| JP7173983B2 (ja) * | 2017-03-31 | 2022-11-17 | ダウ グローバル テクノロジーズ エルエルシー | オレフィン重合のためのビス－ビフェニル－フェノキシ触媒 |
| US11390704B2 (en) | 2017-06-14 | 2022-07-19 | Exxonmobil Chemical Patents Inc. | Ethylene copolymer blends for cross-linking applications |
| WO2019040845A1 (en) | 2017-08-24 | 2019-02-28 | Dow Global Technologies Llc | ETHYLENE / ALPHA-OLEFIN C5-C10 / POLYENE INTERPOLYMERS |
| EP3752560B1 (en) * | 2018-02-14 | 2024-09-25 | Dow Global Technologies LLC | Ethylene/alpha-olefin interpolymer compositions with improved long term heat aging performance |
| WO2020046597A1 (en) | 2018-08-29 | 2020-03-05 | Exxonmobil Chemical Patents Inc. | Methods of making polymer compositions with enhanced elasticity by employing vtp and hmp catalyst systems in parallel processes |
| KR102538844B1 (ko) * | 2018-12-21 | 2023-06-01 | 주식회사 엘지화학 | 방향족 비닐 화합물-비닐시안 화합물 공중합체의 제조방법 및 이를 포함하는 열가소성 수지 조성물의 제조방법 |
| EP3940009A4 (en) | 2019-03-12 | 2023-03-15 | Mitsui Chemicals, Inc. | OLEFIN-BASED RESIN, CROSSLINKER THEREOF, AND METHODS OF PRODUCTION THEREOF |
| WO2020198918A1 (en) * | 2019-03-29 | 2020-10-08 | Dow Global Technologies Llc | Oil-extended pellet form ethylene alpha-olefin diene interpolymers for thermoplastic vulcanizates |
| CN113874439B (zh) * | 2019-04-30 | 2024-03-29 | 陶氏环球技术有限责任公司 | 乙烯/丙烯/非共轭二烯互聚物组合物 |
| BR112022005584A2 (pt) | 2019-09-24 | 2022-06-21 | Dow Global Technologies Llc | Composição, e, artigo |
| WO2021061580A1 (en) | 2019-09-24 | 2021-04-01 | Dow Global Technologies Llc | Polymer compositions for extruded profiles |
| JP2022549319A (ja) | 2019-09-24 | 2022-11-24 | ダウ グローバル テクノロジーズ エルエルシー | エチレン／アルファ－オレフィン／ポリエンインターポリマー組成物 |
| WO2021133925A1 (en) * | 2019-12-27 | 2021-07-01 | Dow Global Technologies Llc | Ethylene/butene multi-block copolymer and process for producing same |
| JP2021147420A (ja) * | 2020-03-16 | 2021-09-27 | 三井化学株式会社 | オレフィン・環状オレフィン共重合体の製造方法 |
| CN115397875B (zh) * | 2020-03-27 | 2025-03-11 | 陶氏环球技术有限责任公司 | 用于产生长链支化基于乙烯的聚合物的方法 |
| EP4127061A1 (en) | 2020-03-30 | 2023-02-08 | ExxonMobil Chemical Patents Inc. | Comb-block copolymers and methods thereof |
| US20230303597A1 (en) * | 2020-12-28 | 2023-09-28 | Sabic Sk Nexlene Company Pte. Ltd. | Metal-ligand complex, catalyst composition for preparing ethylene-based polymer containing the same, and preparation method of ethylene -based polymer using the same |
| KR20240074467A (ko) * | 2022-11-21 | 2024-05-28 | 롯데케미칼 주식회사 | 에틸렌-알파-올레핀 공중합체 제조방법 |
| WO2025117273A1 (en) | 2023-12-01 | 2025-06-05 | ExxonMobil Technology and Engineering Company | Support-bound activators, supported catalyst systems, and processes for use thereof |
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| US6545088B1 (en) | 1991-12-30 | 2003-04-08 | Dow Global Technologies Inc. | Metallocene-catalyzed process for the manufacture of EP and EPDM polymers |
| US5977251A (en) | 1996-04-01 | 1999-11-02 | The Dow Chemical Company | Non-adiabatic olefin solution polymerization |
| US6680361B1 (en) * | 1998-11-02 | 2004-01-20 | Dupont Dow Elastomers Llc | Shear thinning ethylene/α-olefin interpolymers and their preparation |
| US6897276B2 (en) * | 2002-04-24 | 2005-05-24 | Symyx Technologies, Inc. | Bridged bi-aromatic ligands, catalysts, processes for polymerizing and polymers therefrom |
| WO2006020624A1 (en) | 2004-08-09 | 2006-02-23 | Dow Global Technologies Inc. | Supported bis(hydroxyarylaryloxy) catalysts for manufacture of polymers |
| ES2534469T3 (es) | 2006-05-17 | 2015-04-23 | Dow Global Technologies Llc | Procedimiento de polimerización de polietileno en disolución a alta temperatura |
| ES2435568T3 (es) | 2007-11-19 | 2013-12-20 | Dow Global Technologies Llc | Copolímeros de propileno-alfa-olefina con ramificación de cadena larga |
| US8772414B2 (en) * | 2008-09-16 | 2014-07-08 | Dow Global Technologies Llc | Polymeric compositions and foams, methods of making the same, and articles prepared from the same |
| SG178222A1 (en) | 2009-07-01 | 2012-03-29 | Dow Global Technologies Llc | Ethylenic polymer and its use |
| SG10201403765WA (en) | 2009-07-01 | 2014-09-26 | Dow Global Technologies Llc | Ethylenic Polymer And Its Use |
| US9102824B2 (en) | 2009-07-15 | 2015-08-11 | Dow Global Technologies Llc | Polymer compositions, methods of making the same, and articles prepared from the same |
| KR101865645B1 (ko) * | 2010-08-25 | 2018-06-11 | 다우 글로벌 테크놀로지스 엘엘씨 | 중합성 올레핀의 중합 방법 및 그를 위한 촉매 |
| EP2791190B1 (en) * | 2011-12-13 | 2016-07-06 | Dow Global Technologies LLC | Ethylene-propylene-diene interpolymer composition |
| CN104169313B (zh) | 2011-12-20 | 2016-09-21 | 陶氏环球技术有限责任公司 | 乙烯/α-烯烃/非共轭多烯烃互聚物及其制备方法 |
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2012
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- 2012-12-20 IN IN4444CHN2014 patent/IN2014CN04444A/en unknown
- 2012-12-20 JP JP2014548874A patent/JP6189325B2/ja active Active
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- 2012-12-20 US US14/367,478 patent/US9422383B2/en active Active
- 2012-12-20 ES ES12815929T patent/ES2835807T3/es active Active
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|---|---|
| WO2013096573A1 (en) | 2013-06-27 |
| EP2794693B1 (en) | 2020-09-23 |
| KR101989206B1 (ko) | 2019-09-24 |
| KR20140107263A (ko) | 2014-09-04 |
| JP2015500920A (ja) | 2015-01-08 |
| EP2794693A1 (en) | 2014-10-29 |
| JP6189325B2 (ja) | 2017-08-30 |
| US9422383B2 (en) | 2016-08-23 |
| BR112014014855A2 (pt) | 2017-06-13 |
| ES2835807T3 (es) | 2021-06-23 |
| CN104169313B (zh) | 2016-09-21 |
| CN104169313A (zh) | 2014-11-26 |
| IN2014CN04444A (https=) | 2015-09-04 |
| US20150322185A1 (en) | 2015-11-12 |
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